Hybrid Metal Organic Framework And Covalent Organic Framework Polymers

Author : Bo Wang
Publisher : Royal Society of Chemistry
Page : 407 pages
File Size : 53,8 Mb
Release : 2021-11-12
Category : Technology & Engineering
ISBN : 9781839163463

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Hybrid Metal-Organic Framework and Covalent Organic Framework Polymers by Bo Wang Pdf

Metal–organic frameworks (MOFs) are crystalline porous materials constructed from metal ions/clusters and organic linkers, combining the merits of both organic and inorganic components. Due to high porosity, rich functionalities, well-defined open channels and diverse structures, MOFs show great potentials in field such as gas storage and separation, catalysis, and sensing. Combining them with polymers tunes their chemical, mechanical, electrical and optical properties, and endows MOFs with processability. Covalent organic frameworks (COFs) are crystalline porous materials built from organic molecular units with diverse structures and applications. Hybrid materials with intriguing properties can be achieved by appropriate preparation methods and careful selection of MOFs/COFs and polymers, broadening their potential applications. This book documents the latest research progress in MOF/COF-polymer hybrid materials and reviews and summarises hybridization strategies to achieve MOF/COF polymeric composites. It also introduces various applications and potential applicable scenarios of hybrid MOF/COF polymers. Hybrid Metal–Organic Framework and Covalent Organic Framework Polymers offers an overview to readers who are new to this field, and will appeal to graduate students and researchers working on porous materials, polymers, hybrid materials, and supramolecular chemistry.

Author : Oscar L. Ortiz,Luis D. Ramírez
Publisher : Unknown
Page : 0 pages
File Size : 40,7 Mb
Release : 2011-10
Category : Coordination polymers
ISBN : 1614708991

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Coordination Polymers and Metal Organic Frameworks by Oscar L. Ortiz,Luis D. Ramírez Pdf

In this book, the authors present topical research in the study of coordination polymers and metal organic frameworks. Topics discussed include hybrid vanadates and metal organic frameworks; structure and magnetic properties of mono- and poly-nuclear complexes containing Re(IV)l; metal organic framework applications in the fields of hydrogen storage and catalysis; MOF-Based mixed-matrix-membranes for industrial applications; coordination polymers in heterogeneous catalysis; high pressure gas storage on porous solids; metal organic frameworks for CO2 capture and halogen bonding in the assembly of high-dimensional supramolecular coordination polymers.

Author : Ram K. Gupta,Tahir Rasheed,Tuan Anh Nguyen,Muhammad Bilal
Publisher : CRC Press
Page : 349 pages
File Size : 44,5 Mb
Release : 2022-06-22
Category : Technology & Engineering
ISBN : 9781000569124

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Metal-Organic Frameworks-Based Hybrid Materials for Environmental Sensing and Monitoring by Ram K. Gupta,Tahir Rasheed,Tuan Anh Nguyen,Muhammad Bilal Pdf

With an unprecedented population boom and rapid industrial development, environmental pollution has become a severe problem for the ecosystem and public health. Classical techniques for sensing and determining environmental contaminants often require complex pretreatments, expensive equipment, and longer testing times. Therefore, new, and state-of-the-art sensing technologies possessing the advantages of excellent sensitivity, rapid detection, ease of use, and suitability for in situ, real-time, and continuous monitoring of environmental pollutants, are highly desirable. Metal-Organic Frameworks-based Hybrid Materials for Environmental Sensing and Monitoring covers the current-state-of-the-art hybrid nanomaterials based on metal-organic frameworks for electrochemical monitoring purposes. Accomplished authors cover various synthetic routes, methods, and theories behind enhancing the electrochemical properties and applications of metal-organic frameworks-based hybrid nanomaterials for electrochemical sensing of environmental pollutants under one roof. This book is essential reading for all academic and industrial researchers working in the fields of materials science and nanotechnology.

Author : Ali Morsali,Kayhaneh Berijani
Publisher : John Wiley & Sons
Page : 226 pages
File Size : 47,8 Mb
Release : 2021-10-12
Category : Science
ISBN : 9781119792048

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Metal-Organic Frameworks with Heterogeneous Structures by Ali Morsali,Kayhaneh Berijani Pdf

METAL-ORGANIC FRAMEWORKS WITH HETEROGENEOUS STRUCTURES A unique book that sheds light on Metal-Organic Frameworks complex systems that often display behaviors that surprise and cannot be easily described. In this book, MOF-based heterostructures technology with key characteristics is completely analyzed and the current state-of-the-art is discussed. The authors focus on the complex heterostructures promoted by MOFs with advantage of their recent new advances for various applications with particular emphasis on their design. As an extension of the design and synthesis, the shaping technology of heterostructure MOFs is also of great significance to the future practical applications in industry (adsorption/desorption, gas storage, catalysis, conductivity, optical activity) of this class of complex porous materials. As this unique book covers all of the aspects of complexity in MOFs with heterogeneous structures, it serves as an essential reference to the concepts of introducing complexity to designing the future new platforms of materials with advanced and superior properties. This important compact book provides the reader with: The principal aspects of heterogeneity that produce complexity in MOFs, their effects in the structure chemistry, performance and applications The effects of complexities on the structure of metal-organic frameworks The roles of complexities on metal-organic frameworks applications Explanation of synthesis strategies of the complex heterostructure MOFs. Audience This book will be beneficial for chemists, materials engineers, advanced postgraduate and graduate students, researchers and specialists who are working in the area of materials design and their chemistry, porous crystalline materials, coordination polymers, hybrid and functional materials, as well as industry professionals, such as those working on selective catalysis and adsorption-separation, optics, gas capture, processes of biological and pharmaceutical.

Author : Guangshan Zhu,Hao Ren
Publisher : Springer
Page : 135 pages
File Size : 49,5 Mb
Release : 2014-11-28
Category : Technology & Engineering
ISBN : 9783662454565

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Porous Organic Frameworks by Guangshan Zhu,Hao Ren Pdf

This book describes the design, synthesis, characterization and applications of porous organic frameworks (POFs). Special emphasis is placed on the utilization of porous materials for CO2 capture and CH4 and H2 storage, which have promising potential for addressing the issues of environmental degradation and climate change. It also includes two chapters introducing the properties of POFs and defining the principles of synthesis, as well as a chapter dealing with post-modified POFs. This book is intended for those readers who are interested in porous materials and their applications. Guangshan Zhu is a professor at the College of Chemistry, Jilin University, China.

Author : Martin Schröder
Publisher : Springer Science & Business Media
Page : 270 pages
File Size : 48,7 Mb
Release : 2010-09-07
Category : Science
ISBN : 9783642146121

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Functional Metal-Organic Frameworks: Gas Storage, Separation and Catalysis by Martin Schröder Pdf

- Microporous Organic Polymers: Design, Synthesis, and Function By J.-X. Jiang and A. I. Cooper - Hydrogen, Methane and Carbon Dioxide Adsorption in Metal-Organic Framework Materials By X. Lin, N. R. Champness, and M. Schröder -Doping of Metal-Organic Frameworks with Functional Guest Molecules and Nanoparticles By F. Schröder and R. A. Fischer -Chiral Metal-Organic Porous Materials: Synthetic Strategies and Applications in Chiral Separation and Catalysis By K. Kim, M. Banerjee, M. Yoon, and S. Das -Controlled Polymerization by Incarceration of Monomers in Nanochannels By T. Uemura and S. Kitagawa -Designing Metal-Organic Frameworks for Catalytic Applications L. Ma and W. Lin -Magnetic and Porous Molecule-Based Materials By N. Roques, V. Mugnaini, and J. Veciana

Author : Ma Shengqian,Perman Jason A
Publisher : World Scientific
Page : 732 pages
File Size : 46,7 Mb
Release : 2018-01-29
Category : Science
ISBN : 9789813226746

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Elaboration And Applications Of Metal-organic Frameworks by Ma Shengqian,Perman Jason A Pdf

Author : Hemanta Kalita,Anamika Talukdar
Publisher : GRIN Verlag
Page : 50 pages
File Size : 55,9 Mb
Release : 2022-08-09
Category : Science
ISBN : 9783346690357

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Applications of Porous Coordination Polymers and Metal Organic Frameworks (MOFs) by Hemanta Kalita,Anamika Talukdar Pdf

Document from the year 2022 in the subject Chemistry - Macromolecular Chemistry, Polymer Chemistry, grade: 17, Gauhati University, language: English, abstract: Porous coordination polymers, also known as metal organic frameworks are a new type of hybrid material constructed via self-assembly of metal ions/metal clusters which function as nodes and organic ligands which act as bridges or linkers. They are one of the earliest developed classes of metal containing polymers. They extend infinitely one, two or three dimensional framework through coordination bonding, hydrogen bonding, π–π stacking, C-H-π interactions as well as van der Waal forces. These weaker non-covalent interactions, are important for the packing of the one dimensional chains, two-dimensional nets and three-dimensional frameworks. In view of the tunable structures and promising properties shown by these systems various complexities have been prepared and thoroughly investigated over last decade. MOFs are currently flourishing fields of research owing to their intriguing structural motifs and various potential applications, in the field of gas storage, gas separation, catalysis, ion exchange, microelectronics, non linear optics, sensors, medicine and molecular magnetism etc. They possess structural regularity, high porosity, high surface area resulting in greater potential applications than conventional zeolites or activated carbons and mesoporous silica. For the construction of porous coordination polymers with diverse structures and properties selection of the special inorganic and organic building blocks is one of the important factors. Multicarboxylate organic ligands have proved to be an excellent choice for the construction of MOFs of higher nuclearity due to their different coordination modes with the metals, molecular flexibilities and structural stabilities. Metal carboxylate linker in combination with cross linked or pillered polypyridine have generated many interesting coordination architecture. Making use of transition metal carboxylate and linear bridging auxiliary ligands it is possible to construct 1-D, 2-D and 3-D porous coordination polymer of different pore structures and porosities. Aside from coordination bonding interactions, various non-covalent bonding or some weak intra- or intermolecular interactions, such as hydrogen-bonding, π–π stacking and C–H–π interactions or van der Waals interactions also influence the formation of final architectures.

Author : Anish Khan
Publisher : Materials Research Forum LLC
Page : 426 pages
File Size : 47,9 Mb
Release : 2019-10-25
Category : Technology & Engineering
ISBN : 9781644900437

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Metal-Organic Framework Composites by Anish Khan Pdf

Because of their nanoporous structures and ultra-high surface areas Metal-Organic Framework Composites (MOFs) are very interesting materials. The book focusses on the following applications: gas capture and storage, especially molecular hydrogen storage; performance enhancement of Li-ion batteries; gas separation, nano-filtration, ionic sieving, water treatment, and catalysis; sustainable renewable energy resources, electrochemical capacitors, including supercapacitors, asymmetric supercapacitors and hybrid supercapacitors; biomedical disciplines including drug delivery, theranostics; biological detection and imaging; nanoparticle photosensitizers for photodynamic therapy (PDT) and photothermal therapy (PTT).

Author : Yun-Pei Zhu,Zhong-Yong Yuan
Publisher : Springer
Page : 127 pages
File Size : 55,7 Mb
Release : 2014-11-28
Category : Science
ISBN : 9783662456347

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Mesoporous Organic-Inorganic Non-Siliceous Hybrid Materials by Yun-Pei Zhu,Zhong-Yong Yuan Pdf

This book provides extensive information on organic-inorganic hybrid materials with controllable compositions and structures developed over the past few decades, including metal sulfonates, carboxylates, phosphonates, metal-organic frameworks (MOFs), etc. A variety of judicious strategies for optimizing mesoporosity are also introduced, aiming at realizing the corresponding superiorities of hybrid frameworks in practical applications at the nano-/meso-scale. The morphological design and modification methods are also described in detail, which extend the potential application range of hybrid materials from traditional areas to high-tech fields. The book offers an ideal reference work for readers in the fields of chemistry, chemical engineering, physics, materials and biology, especially those who are interested in porous hybrid materials. Zhong-Yong Yuan is a Chair Professor at the College of Chemistry, Nankai University, China.

Author : Shengqian Ma,Jason A. Perman
Publisher : Unknown
Page : 128 pages
File Size : 41,6 Mb
Release : 2017
Category : Materials science
ISBN : 9813226722

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Elaboration and Applications of Metal-organic Frameworks by Shengqian Ma,Jason A. Perman Pdf

Author : Ashok Kumar Nadda,Swati Sharma,Susheel Kalia
Publisher : Elsevier
Page : 432 pages
File Size : 50,6 Mb
Release : 2023-02-21
Category : Technology & Engineering
ISBN : 9780323858212

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CO2-philic Polymers, Nanocomposites and Solvents by Ashok Kumar Nadda,Swati Sharma,Susheel Kalia Pdf

CO2-philic Polymers, Nanocomposites and Chemical Solvents: Capture, Conversion and Industrial Products is a multidisciplinary book that provides a compilation of concrete information on various polymers, porous materials hydrogels, membranes, nanoparticles, biochar metal-organic frameworks, bioinspired surfaces, polysaccharides, organic solvents, chemicals, eutectic solvents, amine-based chemical compounds, porphyrins, ionic liquids, ceramics and cutting-edge technologies for CO2 sequestration and conversion. Each chapter covers the latest developments and methods of synthesis and applications in the area. The book discusses, in detail, valuable commercial products from CO2, such as ethanol, methanol, formic acid, and precursors of other fine chemicals. The book covers the scientific, technological and practical concepts concerning the research, development and realization of CO2-philic polymers, nanocomposites and chemical solvents. This makes it a valuable resource for academic researchers and graduate students in chemical engineering, materials science and chemical engineers/engineers working in the industry. Provides a comprehensive overview of candidates and techniques for CO2 capture and conversion Written by worldwide experts from academia Contains numerous illustrations, tables, figures, graphs, bibliographies and extensive references Appeals to a broad academic audience with its interdisciplinary content

Author : Tuan Anh Nguyen,Ram K. Gupta
Publisher : CRC Press
Page : 643 pages
File Size : 46,7 Mb
Release : 2022-08-25
Category : Science
ISBN : 9781000632958

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Covalent Organic Frameworks by Tuan Anh Nguyen,Ram K. Gupta Pdf

Covalent organic frameworks-based nanomaterials have emerged as promising candidates for energy applications owing to their superior electrochemical properties, surface area, nano-device integration, multifunctionality, printability, and mechanical flexibility. This book provides fundamentals, various synthesis approaches, and applications of covalent organic frameworks-based nanomaterials and their composites for generating energy. The main objective of this book is to provide current, state-of-the-art knowledge about covalent organic frameworks-based nanomaterials and their composites for supercapacitors, batteries, photovoltaics, and fuel cells, covering almost the entire spectrum in the energy field under one title. Aimed at widening our fundamental understanding of covalent organic frameworks and mechanisms for realization and advancement in devices with improved energy efficiency and high storage capacity, this book will provide new directions for scientists, researchers, and students to better understand the principles, technologies, and applications of covalent organic frameworks.

Author : Maria Grazia De Angelis,Giulio C. Sarti
Publisher : MDPI
Page : 256 pages
File Size : 44,7 Mb
Release : 2021-04-22
Category : Technology & Engineering
ISBN : 9783036502120

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Gas Transport in Glassy Polymers by Maria Grazia De Angelis,Giulio C. Sarti Pdf

This Special Issue of Membranes focuses on several new aspects of fluid transport in glassy polymers, with application in relevant membrane separations such as gas purification, VOC removal and CO2 capture. In particular, the focus lies on novel experimental techniques, and detailed characterization of specific phenomena like polar and multicomponent interactions during transport. The properties of novel materials, such as mixed matrix membranes based on glassy polymers and different selective fillers, are also presented. A critical review of existing modeling approaches to describe the sorption and transport in glassy polymers suitable for membrane separations is provided, including both macroscopic and atomistic models, and relying both on the standard solution–diffusion process and on the facilitated transport mechanism.

Author : Wenbin Cao
Publisher : BoD – Books on Demand
Page : 678 pages
File Size : 50,7 Mb
Release : 2016-08-24
Category : Science
ISBN : 9789535124849

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Semiconductor Photocatalysis by Wenbin Cao Pdf

Photocatalysis is a hot topic because it is an environmentally friendly approach toward the conversion of light energy into chemical energy at mild reaction environments. Also, it is well applied in several major areas such as water splitting, bacterial inactivation, and pollutants elimination, which is a possible solution to energy shortage and environmental issues. The fundamental knowledge and the frontier research progress in typical photocatalytic materials, such as TiO2-based and non-TiO2-based photocatalysts, are included in this book. Methods to improve the photocatalytic efficiency and to provide a hint for the rational design of the new photocatalysts are covered.