Hydrogen Bonded Supramolecular Materials

Author : Zhan-Ting Li,Li-Zhu Wu
Publisher : Springer
Page : 238 pages
File Size : 44,9 Mb
Release : 2015-01-05
Category : Technology & Engineering
ISBN : 9783662457801

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Hydrogen Bonded Supramolecular Materials by Zhan-Ting Li,Li-Zhu Wu Pdf

This book is an up-to-date text covering topics in utilizing hydrogen bonding for constructing functional architectures and supramolecular materials. The first chapter addresses the control of photo-induced electron and energy transfer. The second chapter summarizes the formation of nano-porous materials. The following two chapters introduce self-assembled gels, many of which exhibit unique functions. Other chapters cover the advances in supramolecular liquid crystals and the versatility of hydrogen bonding in tuning/improving the properties and performance of materials. This book is designed to bring together in a single volume the most important and active fields of hydrogen bonding strategy for designing supramolecular materials. The book will be a valuable resource for graduates and researchers working in the fields of supramolecular chemistry and materials sciences. Zhan-Ting Li, PhD, is a Professor of Organic Chemistry at the Department of Chemistry, Fudan University, China Li-Zhu Wu, PhD, is a Professor of Organic Chemistry at the Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, China

Author : Wolfgang Binder
Publisher : Springer Science & Business Media
Page : 215 pages
File Size : 54,9 Mb
Release : 2007-03-16
Category : Technology & Engineering
ISBN : 9783540685876

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Hydrogen Bonded Polymers by Wolfgang Binder Pdf

Control of polymeric structure is among the most important endeavours of modern macromolecular science. In particular, tailoring the positioning and strength of intermolecular forces within macromolecules by synthetic methods and thus gaining structural control over the final polymeric materials has become feasible, resulting in the field of supramolecular polymer science. Besides other intermolecular forces, hydrogen bonds are unique intermolecular forces enabling the tuning of material properties via self-assembly processes over a wide range of interactions strength ranging from several kJmol to several tens of kJmol . Central for the formation of these structures are precursor molecules of small molecular weight (usually lower than 10 000), which can assemble in solid or solution to aggregates of defined geometry.

Author : Zhan-Ting Li,Li-Zhu Wu
Publisher : Unknown
Page : 364 pages
File Size : 48,8 Mb
Release : 2015-01-31
Category : Electronic
ISBN : 3662457571

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Hydrogen Bonded Supramolecular Structures by Zhan-Ting Li,Li-Zhu Wu Pdf

Author : Zhan-Ting Li,Li-Zhu Wu
Publisher : Springer
Page : 357 pages
File Size : 42,8 Mb
Release : 2015-01-12
Category : Science
ISBN : 9783662457566

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Hydrogen Bonded Supramolecular Structures by Zhan-Ting Li,Li-Zhu Wu Pdf

This book covers the advances in the studies of hydrogen-bonding-driven supramolecular systems made over the past decade. It is divided into four parts, with the first introducing the basics of hydrogen bonding and important hydrogen bonding patterns in solution as well as in the solid state. The second part covers molecular recognition and supramolecular structures driven by hydrogen bonding. The third part introduces the formation of hollow and giant macrocycles directed by hydrogen bonding, while the last part summarizes hydrogen bonded supramolecular polymers. This book is designed to bring together in a single volume the many important aspects of hydrogen bonding supramolecular chemistry and will be a valuable resource for graduates and researchers working in supramolecular and related sciences. Zhan-Ting Li, PhD, is a Professor of Organic Chemistry at the Department of Chemistry, Fudan University, China. Li-Zhu Wu, PhD, is a Professor of Organic Chemistry at the Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, China.

Author : Julius Rebek Jr.
Publisher : World Scientific
Page : 220 pages
File Size : 42,9 Mb
Release : 2015-09-23
Category : Science
ISBN : 9789814678377

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Hydrogen-bonded Capsules by Julius Rebek Jr. Pdf

This monograph describes the behavior of molecules confined to small spaces. The small spaces are created by the self-assembly of modules into hollow capsular structures through hydrogen bonding; capsules assembled by metal/ligand binding or other forces are not included. Topics discussed include how assembly of capsules occurs, how molecules get in and out of the capsules, new spatial arrangements (stereochemistry) created in the capsules, and the altered shapes, interactions and reactivities of molecules held inside the small spaces. The descriptions emphasize molecular recognition phenomena and the perspective is that of physical organic chemistry. The book is the first monograph to treat reversible molecular encapsulation. More than 20 university and institute groups worldwide engage in this research, which represents the leading edge of activity in molecular recognition and the physical organic chemistry of confined molecules. Contents:Spherical and Similar CapsulesCalixarene CapsulesThe Cylindrical CapsuleHexameric Capsules from Resorcinarenes and PyrogallolarenesStereochemistry of Confined MoleculesChiral CapsulesExpanded and Contracted CapsulesReactions Inside Capsules Readership: Graduate students and researchers in physical organic chemistry, nanotechnology and nanoscience and materials science. Keywords:Capsules;Encapsulation;Recognition;Reactivity;Stereochemistry;Resorcinarenes;Calixarenes;Dynamics;ThermodynamicsKey Features:The last monograph to deal with molecules inside molecules was published in 1994. Hydrogen bonded capsules have been invented since that time and this monograph summarizes the results of more than 100 publications in this fieldMolecules in small spaces behave differently than those that are free in solution; this monograph reveals these new behaviors and draws parallels to the related behavior of small molecules confined in enzymes and biological receptorsThe monograph provides recipes for construction of molecular devices at the sub-nano scale. The principles of self-assembly are involved and offer applications in nanoscience using an approach "from the bottom up"

Author : David M.P. Mingos
Publisher : Springer
Page : 180 pages
File Size : 43,6 Mb
Release : 2004-02-20
Category : Science
ISBN : 354020086X

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Supramolecular Assembly via Hydrogen Bonds II by David M.P. Mingos Pdf

D. Braga, L. Maini, M. Polito: Hydrogen Bonding Interactions Between Ions: A Powerful Tool in Molecular Crystal Engineering .- P. Hubberstey, U. Suksangpanya, M. Schröder: Hydrogen-Bonded Supramolecular Chain and Sheet Formation by Co-ordinated Guandine Derivatives .- R. Vilar: Hydrogen-Bonding Templated Assemblies .- M. J. Hardie: Hydrogen Bonded Network Structures Constructed From Molecular Hosts

Author : D. M. P. Mingos
Publisher : Springer Science & Business Media
Page : 202 pages
File Size : 55,7 Mb
Release : 2004-01-28
Category : Science
ISBN : 3540200843

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Supramolecular Assembly Via Hydrogen Bonds I by D. M. P. Mingos Pdf

Author : Shiao-Wei Kuo
Publisher : John Wiley & Sons
Page : 350 pages
File Size : 52,8 Mb
Release : 2018-01-24
Category : Science
ISBN : 9783527804283

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Hydrogen Bonding in Polymeric Materials by Shiao-Wei Kuo Pdf

Summarizing our current knowledge of the topic, this book describes the roles and effects of hydrogen bonding in polymer materials by reviewing the latest developments over recent years. To this end, it discusses all relevant aspects from the fundamentals, via characterization, to properties and applications in various polymeric materials, including polymer blends, block copolymers, mesoporous materials, biomacromolecules and nanocomposites. Invaluable reading for scientists in polymers and materials as well as those working in macromolecular chemistry.

Author : Joerg Lahann
Publisher : John Wiley & Sons
Page : 432 pages
File Size : 53,6 Mb
Release : 2009-12-15
Category : Technology & Engineering
ISBN : 0470748850

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Click Chemistry for Biotechnology and Materials Science by Joerg Lahann Pdf

Mimicking natural biochemical processes, click chemistry is a modular approach to organic synthesis, joining together small chemical units quickly, efficiently and predictably. In contrast to complex traditional synthesis, click reactions offer high selectivity and yields, near-perfect reliability and exceptional tolerance towards a wide range of functional groups and reaction conditions. These ‘spring loaded’ reactions are achieved by using a high thermodynamic driving force, and are attracting tremendous attention throughout the chemical community. Originally introduced with the focus on drug discovery, the concept has been successfully applied to materials science, polymer chemistry and biotechnology. The first book to consider this topic, Click Chemistry for Biotechnology and Materials Science examines the fundamentals of click chemistry, its application to the precise design and synthesis of macromolecules, and its numerous applications in materials science and biotechnology. The book surveys the current research, discusses emerging trends and future applications, and provides an important nucleation point for research. Edited by one of the top 100 young innovators with the greatest potential to have an impact on technology in the 21st century according to Technology Review and with contributions from pioneers in the field, Click Chemistry for Biotechnology and Materials Science provides an ideal reference for anyone wanting to learn more about click reactions.

Author : David M.P. Mingos,D. Braga
Publisher : Springer Science & Business Media
Page : 198 pages
File Size : 50,6 Mb
Release : 2004-02-20
Category : Science
ISBN : 354020086X

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Supramolecular Assembly Via Hydrogen Bonds II by David M.P. Mingos,D. Braga Pdf

Author : Wolfgang Binder
Publisher : Springer
Page : 206 pages
File Size : 49,8 Mb
Release : 2007-02-20
Category : Technology & Engineering
ISBN : 9783540685883

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Hydrogen Bonded Polymers by Wolfgang Binder Pdf

Control of polymeric structure is among the most important endeavours of modern macromolecular science. In particular, tailoring the positioning and strength of intermolecular forces within macromolecules by synthetic me- odsandthusgaining structuralcontrolover the?nalpolymeric materials has become feasible, resulting in the?eld of supramolecular polymer science. - sides other intermolecular forces, hydrogen bonds are unique intermolecular forces enabling the tuning of material properties via self-assembly processes -1 overawiderangeofinteractionstrengthrangingfromseveralkJmol tosev- -1 eraltensofkJmol . Centralfortheformationofthesestructuresareprecursor molecules of small molecular weight (usually lower than 10 000), which can assembleinsolidorsolutiontoaggregatesofde?nedgeometry. Intermolecular hydrogenbondsatde?nedpositionsofthesebuildingblocksaswellastheir- spectivestartinggeometryandtheinitialsizedeterminethemodeofassembly into supramolecular polymers forming network-, rodlike-,?brous-, disclike-, helical-, lamellar- and chainlike architectures. In all cases, weak to strong hydrogen-bondinginteractionscanactasthecentralstructure-directingforce fortheorganizationofpolymerchainsandthusthe?nalmaterials'properties. Theimportantcontributionofhydrogenbondstotheareaofsupramole- lar polymer chemistry is de?nitely outstanding, most of all since the potency of hydrogen-bonding systems has been found to be unique in relation to other supramolecular interactions. Thus the high level of structural diversity of many hydrogen-bonding systems as well as their high level of direction- ity and speci?city in recognition-phenomena is unbeaten in supramolecular chemistry. The realization, that their stability can be tuned over a wide range of binding strength is important for tuning the resulting material prop- ties, ranging from elastomeric to thermoplastic and even highly crosslinked duroplastic structures and networks. On the basis of the thermal reversib- ity, new materials with highly tunable properties can now be prepared, - ing able to change their mechanical and optoelectronic properties with very smallchangesofexternalstimuli. Thusthe?eldofhydrogen-bondedpolymers forms the basis for stimuli responsive and adaptable materials of the future.

Author : Akira Harada
Publisher : John Wiley & Sons
Page : 391 pages
File Size : 51,7 Mb
Release : 2012-09-27
Category : Science
ISBN : 9783527639793

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Supramolecular Polymer Chemistry by Akira Harada Pdf

Presenting the work of pioneering experts in this exciting field of supramolecular polymer chemistry, this monograph covers an extensive range of applications, including drug delivery and catalysis. It focuses on new structures and phenomena of cyclodextrin-based supramolecular polymers and many other compound classes. While providing a deeper insight in macromolecular recognition and the mechanisms of living systems, this book also introduces fascinating novel phenomena beyond natural systems.

Author : Y. Zhao,Tomiki Ikeda
Publisher : John Wiley & Sons
Page : 542 pages
File Size : 50,6 Mb
Release : 2009-04-22
Category : Technology & Engineering
ISBN : 9780470439081

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Smart Light-Responsive Materials by Y. Zhao,Tomiki Ikeda Pdf

This book reviews the cutting-edge significant research in the field of smart light-responsive materials based on azobenzene polymers and liquid crystals. Emphasis is placed on the discovery of new phenomena from the past 5 years, their underlying mechanisms, new functionalities, and properties achieved through rational design. Edited by leading authorities in the field, Zhao and Ikeda, the chapters are authored by an internationally-recognized team of experts from North America, Europe, and Asia. Smart Light-Responsive Materials will serve to catalyze new research that will lead this field over the next 5-10 years.

Author : Alberto Ciferri
Publisher : CRC Press
Page : 778 pages
File Size : 41,7 Mb
Release : 2005-04-26
Category : Science
ISBN : 9781420027921

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Supramolecular Polymers by Alberto Ciferri Pdf

Supramolecular Polymers, Second Edition details assembly processes and structure-function correlation in natural and synthetic self-assembling materials, focusing on developments occurred over the past five years. The book highlights developments in the synthesis of complex structures, chemical design principles, and theoretical models of

Author : Makoto Fujita
Publisher : Springer
Page : 254 pages
File Size : 52,9 Mb
Release : 2003-09-04
Category : Science
ISBN : 9783540465911

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Molecular Self-Assembly by Makoto Fujita Pdf

Self-assembly is undoubtedly a topic of special interest in current chemistry and is related to very wide scientific areas. Recent progress in this field seems to be featured by the construction of well-defined discrete systems exploiting complementary hydrogen bonding as well as coordination bonding. Seven leading international experts introduce the current topics in this very interesting field, focusing on two major subjects: organic assemblies and inorganic assemblies. All researchers who are interested in molecular recognition, material science, nanotechnology, and supramolecular chemistry will welcome this book as an inspiring source for creative research ideas.