Hydrogen Bonded Supramolecular Structures

Author : Zhan-Ting Li,Li-Zhu Wu
Publisher : Springer
Page : 357 pages
File Size : 53,7 Mb
Release : 2015-01-12
Category : Science
ISBN : 9783662457566

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Hydrogen Bonded Supramolecular Structures by Zhan-Ting Li,Li-Zhu Wu Pdf

This book covers the advances in the studies of hydrogen-bonding-driven supramolecular systems made over the past decade. It is divided into four parts, with the first introducing the basics of hydrogen bonding and important hydrogen bonding patterns in solution as well as in the solid state. The second part covers molecular recognition and supramolecular structures driven by hydrogen bonding. The third part introduces the formation of hollow and giant macrocycles directed by hydrogen bonding, while the last part summarizes hydrogen bonded supramolecular polymers. This book is designed to bring together in a single volume the many important aspects of hydrogen bonding supramolecular chemistry and will be a valuable resource for graduates and researchers working in supramolecular and related sciences. Zhan-Ting Li, PhD, is a Professor of Organic Chemistry at the Department of Chemistry, Fudan University, China. Li-Zhu Wu, PhD, is a Professor of Organic Chemistry at the Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, China.

Author : Zhan-Ting Li,Li-Zhu Wu
Publisher : Springer
Page : 238 pages
File Size : 45,8 Mb
Release : 2015-01-05
Category : Technology & Engineering
ISBN : 9783662457801

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Hydrogen Bonded Supramolecular Materials by Zhan-Ting Li,Li-Zhu Wu Pdf

This book is an up-to-date text covering topics in utilizing hydrogen bonding for constructing functional architectures and supramolecular materials. The first chapter addresses the control of photo-induced electron and energy transfer. The second chapter summarizes the formation of nano-porous materials. The following two chapters introduce self-assembled gels, many of which exhibit unique functions. Other chapters cover the advances in supramolecular liquid crystals and the versatility of hydrogen bonding in tuning/improving the properties and performance of materials. This book is designed to bring together in a single volume the most important and active fields of hydrogen bonding strategy for designing supramolecular materials. The book will be a valuable resource for graduates and researchers working in the fields of supramolecular chemistry and materials sciences. Zhan-Ting Li, PhD, is a Professor of Organic Chemistry at the Department of Chemistry, Fudan University, China Li-Zhu Wu, PhD, is a Professor of Organic Chemistry at the Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, China

Author : David M.P. Mingos
Publisher : Springer
Page : 180 pages
File Size : 43,6 Mb
Release : 2004-02-20
Category : Science
ISBN : 354020086X

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Supramolecular Assembly via Hydrogen Bonds II by David M.P. Mingos Pdf

D. Braga, L. Maini, M. Polito: Hydrogen Bonding Interactions Between Ions: A Powerful Tool in Molecular Crystal Engineering .- P. Hubberstey, U. Suksangpanya, M. Schröder: Hydrogen-Bonded Supramolecular Chain and Sheet Formation by Co-ordinated Guandine Derivatives .- R. Vilar: Hydrogen-Bonding Templated Assemblies .- M. J. Hardie: Hydrogen Bonded Network Structures Constructed From Molecular Hosts

Author : David M.P. Mingos,D. Braga
Publisher : Springer Science & Business Media
Page : 198 pages
File Size : 46,7 Mb
Release : 2004-02-20
Category : Science
ISBN : 354020086X

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Supramolecular Assembly Via Hydrogen Bonds II by David M.P. Mingos,D. Braga Pdf

Author : Gautam R. Desiraju,Thomas Steiner
Publisher : International Union of Crystal
Page : 530 pages
File Size : 40,9 Mb
Release : 2001
Category : Hydrogen bonding
ISBN : 0198509707

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The Weak Hydrogen Bond by Gautam R. Desiraju,Thomas Steiner Pdf

The weak or non-conventional hydrogen bond has been subject of intense scrutiny over recent years in several fields, in particular in structural chemistry, structural biology, and also in the pharmaceutical sciences. There is today a large body of experimental and theoretical evidenceconfirming that hydrogen bonds like C-H...O, N-H...pi, C-H...pi and even bonds like O-H...metal play distinctive roles in molecular recognition, guiding molecular association, and in determining molecular and supramolecular architectures. The relevant compound classes include organometalliccomplexes, organic and bio-organic systems, and also DNA and proteins. The book provides a comprehensive assessment of this interaction type, and is of interest to all those interested in structural and supramolecular science, including fields as crystal engineering and drug design.

Author : Neil R. Champness
Publisher : John Wiley & Sons
Page : 242 pages
File Size : 49,5 Mb
Release : 2022-05-31
Category : Science
ISBN : 9783527344918

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Supramolecular Chemistry on Surfaces by Neil R. Champness Pdf

Supramolecular Chemistry on Surfaces 2D Networks and 2D Structures Explore the cutting-edge in 2D chemistry on surfaces and its applications In Supramolecular Chemistry on Surfaces: 2D Networks and 2D Structures, expert chemist Neil R. Champness delivers a comprehensive overview of the rapidly developing field of two-dimensional supramolecular chemistry on surfaces. The book offers explorations of the state-of-the-art in the discipline and demonstrates the potential of the latest advances and the challenges faced by researchers in different areas. The editor includes contributions from leading researchers that address new spectroscopic methods which allow for investigations at a sub-molecular level, opening up new areas of understanding in the field. Included resources also discuss important supramolecular strategies, like hydrogen-bonding, van der Waals interactions, metal-ligand coordination, multicomponent assembly, and more. The book also provides: A thorough introduction to two-dimensional supramolecular chemistry on surfaces Comprehensive explorations of the characterization and interpretation of on-surface chemical reactions studied by ultra-high resolution scanning probe microscopy Practical discussions of complexity in two-dimensional multicomponent assembly, including explorations of coordination bonds and quasicrystalline structures In-depth examinations of covalently bonded organic structures via on-surface synthesis Perfect for polymer chemists, spectroscopists, and materials scientists, Supramolecular Chemistry on Surfaces: 2D Networks and 2D Structures will also earn a place in the libraries of physical and surface chemists, as well as surface physicists.

Author : Vitaliy V. Khutoryanskiy,Georgios Staikos
Publisher : World Scientific
Page : 377 pages
File Size : 40,6 Mb
Release : 2009
Category : Technology & Engineering
ISBN : 9789812707857

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Hydrogen-bonded Interpolymer Complexes by Vitaliy V. Khutoryanskiy,Georgios Staikos Pdf

Noncovalent interactions play key roles in many natural processes leading to the self-assembly of molecules with the formation of supramolecular structures. One of the most important forces responsible for self-assembly is hydrogen bonding, which also plays an important role in the self-assembly of synthetic polymers in aqueous solutions. Proton-accepting polymers can associate with proton-donating polymers via hydrogen bonding in aqueous solutions and form polymerndash;polymer or interpolymer complexes. There has been an increased interest among researchers in hydrogen-bonded interpolymer complexes since the first pioneering papers were published in the early 1960s. Several hundred research papers have been published on various aspects of complex formation reactions in solutions and interfaces, properties of interpolymer complexes and their potential applications. This book focuses on the latest developments in the area of interpolymer complexation via hydrogen bonding. It represents a collection of original and review articles written by recognized experts from Germany, Greece, Kazakhstan, Poland, Romania, Russia, UK, Ukraine, and the USA. It highlights many important applications of interpolymer complexes, including the stabilization of colloidal systems, pharmaceuticals, and nanomaterials.

Author : D. M. P. Mingos
Publisher : Springer Science & Business Media
Page : 202 pages
File Size : 41,6 Mb
Release : 2004-01-28
Category : Science
ISBN : 3540200843

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Supramolecular Assembly Via Hydrogen Bonds I by D. M. P. Mingos Pdf

Author : Julius Rebek Jr.
Publisher : World Scientific
Page : 220 pages
File Size : 53,6 Mb
Release : 2015-09-23
Category : Science
ISBN : 9789814678377

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Hydrogen-bonded Capsules by Julius Rebek Jr. Pdf

This monograph describes the behavior of molecules confined to small spaces. The small spaces are created by the self-assembly of modules into hollow capsular structures through hydrogen bonding; capsules assembled by metal/ligand binding or other forces are not included. Topics discussed include how assembly of capsules occurs, how molecules get in and out of the capsules, new spatial arrangements (stereochemistry) created in the capsules, and the altered shapes, interactions and reactivities of molecules held inside the small spaces. The descriptions emphasize molecular recognition phenomena and the perspective is that of physical organic chemistry. The book is the first monograph to treat reversible molecular encapsulation. More than 20 university and institute groups worldwide engage in this research, which represents the leading edge of activity in molecular recognition and the physical organic chemistry of confined molecules. Contents:Spherical and Similar CapsulesCalixarene CapsulesThe Cylindrical CapsuleHexameric Capsules from Resorcinarenes and PyrogallolarenesStereochemistry of Confined MoleculesChiral CapsulesExpanded and Contracted CapsulesReactions Inside Capsules Readership: Graduate students and researchers in physical organic chemistry, nanotechnology and nanoscience and materials science. Keywords:Capsules;Encapsulation;Recognition;Reactivity;Stereochemistry;Resorcinarenes;Calixarenes;Dynamics;ThermodynamicsKey Features:The last monograph to deal with molecules inside molecules was published in 1994. Hydrogen bonded capsules have been invented since that time and this monograph summarizes the results of more than 100 publications in this fieldMolecules in small spaces behave differently than those that are free in solution; this monograph reveals these new behaviors and draws parallels to the related behavior of small molecules confined in enzymes and biological receptorsThe monograph provides recipes for construction of molecular devices at the sub-nano scale. The principles of self-assembly are involved and offer applications in nanoscience using an approach "from the bottom up"

Author : Wolfgang Binder
Publisher : Springer Science & Business Media
Page : 215 pages
File Size : 43,6 Mb
Release : 2007-03-16
Category : Technology & Engineering
ISBN : 9783540685876

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Hydrogen Bonded Polymers by Wolfgang Binder Pdf

Control of polymeric structure is among the most important endeavours of modern macromolecular science. In particular, tailoring the positioning and strength of intermolecular forces within macromolecules by synthetic methods and thus gaining structural control over the final polymeric materials has become feasible, resulting in the field of supramolecular polymer science. Besides other intermolecular forces, hydrogen bonds are unique intermolecular forces enabling the tuning of material properties via self-assembly processes over a wide range of interactions strength ranging from several kJmol to several tens of kJmol . Central for the formation of these structures are precursor molecules of small molecular weight (usually lower than 10 000), which can assemble in solid or solution to aggregates of defined geometry.

Author : George A. Jeffrey,Wolfram Saenger
Publisher : Springer Science & Business Media
Page : 575 pages
File Size : 54,8 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783642851353

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Hydrogen Bonding in Biological Structures by George A. Jeffrey,Wolfram Saenger Pdf

Hydrogen bonds are weak attractions, with a binding strength less than one-tenth that of a normal covalent bond. However, hydrogen bonds are of extraordinary importance; without them all wooden structures would collapse, cement would crumble, oceans would vaporize, and all living things would disintegrate into random dispersions of inert matter. Hydrogen Bonding in Biological Structures is informative and eminently usable. It is, in a sense, a Rosetta stone that unlocks a wealth of information from the language of crystallography and makes it accessible to all scientists. (From a book review of Kenneth M. Harmon, Science 1992)

Author : Wolfgang Binder
Publisher : Springer
Page : 206 pages
File Size : 50,5 Mb
Release : 2007-02-20
Category : Technology & Engineering
ISBN : 9783540685883

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Hydrogen Bonded Polymers by Wolfgang Binder Pdf

Control of polymeric structure is among the most important endeavours of modern macromolecular science. In particular, tailoring the positioning and strength of intermolecular forces within macromolecules by synthetic me- odsandthusgaining structuralcontrolover the?nalpolymeric materials has become feasible, resulting in the?eld of supramolecular polymer science. - sides other intermolecular forces, hydrogen bonds are unique intermolecular forces enabling the tuning of material properties via self-assembly processes -1 overawiderangeofinteractionstrengthrangingfromseveralkJmol tosev- -1 eraltensofkJmol . Centralfortheformationofthesestructuresareprecursor molecules of small molecular weight (usually lower than 10 000), which can assembleinsolidorsolutiontoaggregatesofde?nedgeometry. Intermolecular hydrogenbondsatde?nedpositionsofthesebuildingblocksaswellastheir- spectivestartinggeometryandtheinitialsizedeterminethemodeofassembly into supramolecular polymers forming network-, rodlike-,?brous-, disclike-, helical-, lamellar- and chainlike architectures. In all cases, weak to strong hydrogen-bondinginteractionscanactasthecentralstructure-directingforce fortheorganizationofpolymerchainsandthusthe?nalmaterials'properties. Theimportantcontributionofhydrogenbondstotheareaofsupramole- lar polymer chemistry is de?nitely outstanding, most of all since the potency of hydrogen-bonding systems has been found to be unique in relation to other supramolecular interactions. Thus the high level of structural diversity of many hydrogen-bonding systems as well as their high level of direction- ity and speci?city in recognition-phenomena is unbeaten in supramolecular chemistry. The realization, that their stability can be tuned over a wide range of binding strength is important for tuning the resulting material prop- ties, ranging from elastomeric to thermoplastic and even highly crosslinked duroplastic structures and networks. On the basis of the thermal reversib- ity, new materials with highly tunable properties can now be prepared, - ing able to change their mechanical and optoelectronic properties with very smallchangesofexternalstimuli. Thusthe?eldofhydrogen-bondedpolymers forms the basis for stimuli responsive and adaptable materials of the future.

Author : Nazario Martin,Jean-Francois Nierengarten
Publisher : John Wiley & Sons
Page : 421 pages
File Size : 44,5 Mb
Release : 2012-09-21
Category : Technology & Engineering
ISBN : 9783527650149

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Supramolecular Chemistry of Fullerenes and Carbon Nanotubes by Nazario Martin,Jean-Francois Nierengarten Pdf

Collating our current knowledge and the latest developments for enabling breakthrough discoveries, this book focuses on the synthesis and applications of materials that are based on supramolecular assemblies of carbon nanostructures, with an emphasis on fullerenes and nanotubes. In so doing, it provides readers with an overview of the different types of supramolecular architectures, accentuating the outstanding geometrical, electronic and photophysical properties of the building blocks and the resulting structures. It makes use of basic concepts and real-life applications -- from simple syntheses to complex architectures, from instructive examples to working experimental procedures, and from photophysics to solar cells. A large part of each chapter is devoted to the methods and possibilities of controlling and tuning these molecular assemblies in order to obtain working devices. Fascinating reading for materials scientists, organic chemists, molecular physicists, and those in the semiconductor industry.

Author : Vladimir I. Bakhmutov
Publisher : John Wiley & Sons
Page : 256 pages
File Size : 51,8 Mb
Release : 2008-03-03
Category : Science
ISBN : 0470226749

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Dihydrogen Bond by Vladimir I. Bakhmutov Pdf

This definitive reference consolidates current knowledge on dihydrogen bonding, emphasizing its role in organizing interactions in different chemical reactions and molecular aggregations. After an overview, it analyzes the differences between dihydrogen bonds, classical hydrogen bonds, and covalent bonds. It describes dihydrogen bonds as intermediates in intramolecular and intermolecular proton transfer reactions. It describes dihydrogen bonding in the solid-state, the gas phase, and in solution. This is the premier reference for physical chemists, biochemists, biophysicists, and chemical engineers.

Author : Stefan Kubik
Publisher : John Wiley & Sons
Page : 586 pages
File Size : 54,5 Mb
Release : 2019-09-03
Category : Science
ISBN : 9783527344673

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Supramolecular Chemistry in Water by Stefan Kubik Pdf

Provides deep insight into the concepts and recent developments in the area of supramolecular chemistry in water Written by experts in their respective field, this comprehensive reference covers various aspects of supramolecular chemistry in water?from fundamental aspects to applications. It provides readers with a basic introduction to the current understanding of the properties of water and how they influence molecular recognition, and examines the different receptor types available in water and the types of substrates that can be bound. It also looks at areas to where they can be applied, such as materials, optical sensing, medicinal imaging, and catalysis. Supramolecular Chemistry in Water offers five major sections that address important topics like water properties, molecular recognition, association and aggregation phenomena, optical detection and imaging, and supramolecular catalysis. It covers chemistry and physical chemistry of water; water-mediated molecular recognition; peptide and protein receptors; nucleotide receptors; carbohydrate receptors; and ion receptors. The book also teaches readers all about coordination compounds; self-assembled polymers and gels; foldamers; vesicles and micelles; and surface-modified nanoparticles. In addition, it provides in-depth information on indicators and optical probes, as well as probes for medical imaging. -Covers, in a timely manner, an emerging area in chemistry that is growing more important every day -Addresses topics such as molecular recognition, aggregation, catalysis, and more -Offers comprehensive coverage of everything from fundamental aspects of supramolecular chemistry in water to its applications -Edited by one of the leading international scientists in the field Supramolecular Chemistry in Water is a one-stop-resource for all polymer chemists, catalytic chemists, biochemists, water chemists, and physical chemists involved in this growing area of research.