Hypervalent Iodine In Organic Synthesis

Author : A. Varvoglis
Publisher : Academic Press
Page : 223 pages
File Size : 47,5 Mb
Release : 1996-11-14
Category : Science
ISBN : 9780080534367

Get Book

Hypervalent Iodine in Organic Synthesis by A. Varvoglis Pdf

This book describes the fascinating chemistry of the many kinds of organic compounds of hypervalent iodine. Each chapter deals with a particular iodine compound or families of compounds which have been used as reagents in a plethora of useful transformations. These include assorted oxidation, such as with the precious Dess-Martin reagent as well as with a wide range of further reactions. Prominent features of hypervalent iodine reagents derived from iodobenzene are: ready availability, operational simplicity, mild reaction conditions, and high efficiency. They are environmentally safe and can be recycled. New species may be easily prepared by introducing substituents in the benzene ring or changing the ligand attached to iodine. Their combination with other reagents broadens considerably their synthetic potential. Today, no synthetic chemist can afford to ignore the valuable hypervalentiodine reagents. Key Features * Features up-to-date coverage of a wide range of topics * Includes many tables featuring a diversity of reactivity, and a comprehensive index * Acts as a comprehensive, up-to-date reference on all aspects of hypervalent iodine chemistry * Contains a section on unusual efficiency of hypervalent iodine reactions

Author : Kazuaki Ishihara,Kilian Muniz
Publisher : John Wiley & Sons
Page : 452 pages
File Size : 47,5 Mb
Release : 2022-05-16
Category : Technology & Engineering
ISBN : 9783527348299

Get Book

Iodine Catalysis in Organic Synthesis by Kazuaki Ishihara,Kilian Muniz Pdf

Iodine Catalysis in Organic Synthesis The first book of its kind to highlight iodine as a sustainable alternative to conventional transition metal catalysis Iodine Catalysis in Organic Synthesis provides detailed coverage of recent advances in iodine chemistry and catalysis, focusing on the utilization of various iodine-containing compounds as oxidative catalysts. Featuring contributions by an international panel of leading research chemists, this authoritative volume explores the development of environmentally benign organic reactions and summarizes catalytic transformations of molecular iodine and iodine compounds such as hypervalent organoiodine and inorganic iodine salts. Readers are first introduced to the history of iodine chemistry, the conceptual background of homogeneous catalysis, and the benefits of iodine catalysis in comparison with transition metals. Next, chapters organized by reaction type examine enantioselective transformations, catalytic reactions involving iodine, catalyst states, oxidation in iodine and iodine catalyses, and catalytic reactions based on halogen bonding. Practical case studies and real-world examples of different applications in organic synthesis and industry are incorporated throughout the text. An invaluable guide for synthetic chemists in both academic and industrial laboratories, Iodine Catalysis in Organic Synthesis: Provides a thorough overview of typical iodine-catalyzed reactions, catalyst systems, structures, and reactivity Explores promising industrial applications of iodine-based reagents for organic synthesis Highlights the advantages iodine catalysis has over classical metal-catalyzed reactions Discusses sustainable and eco-friendly methods in hypervalent iodine chemistry Edited by two world authorities on the catalytic applications of organoiodine compounds, Iodine Catalysis in Organic Synthesis is required reading for catalytic, organic, and organometallic chemists, medicinal and pharmaceutical chemists, industrial chemists, and academic researchers and advanced students in relevant fields.

Author : Viktor V. Zhdankin
Publisher : John Wiley & Sons
Page : 630 pages
File Size : 52,9 Mb
Release : 2013-10-01
Category : Science
ISBN : 9781118341308

Get Book

Hypervalent Iodine Chemistry by Viktor V. Zhdankin Pdf

Hypervalent Iodine Chemistry is the first comprehensive text covering all of the main aspects of the chemistry of organic and inorganic polyvalent iodine compounds, including applications in chemical research, medicine, and industry. Providing a comprehensive overview of the preparation, properties, and synthetic applications of this important class of reagents, the text is presented in the following way: The introductory chapter provides a historical background and describes the general classification of iodine compounds, nomenclature, hypervalent bonding, structural features, and the principles of reactivity of polyvalent iodine compounds. Chapter 2 gives a detailed description of the preparative methods and structural features of all known classes of organic and inorganic derivatives of polyvalent iodine. Chapter 3, the key chapter of the book, deals with the many applications of hypervalent iodine reagents in organic synthesis. Chapter 4 describes the most recent achievements in hypervalent iodine catalysis. Chapter 5 deals with recyclable polymer-supported and nonpolymeric hypervalent iodine reagents. Chapter 6 covers the "green" reactions of hypervalent iodine reagents under solvent-free conditions or in aqueous solutions. The final chapter provides an overview of the important practical applications of polyvalent iodine compounds in medicine and industry. This book is aimed at all chemists interested in iodine compounds, including academic and industrial researchers in inorganic, organic, physical, medicinal, and biological chemistry. It will be particularly useful to synthetic organic and inorganic chemists, including graduate and advanced undergraduate students. It comprehensively covers the green chemistry aspects of hypervalent iodine chemistry, making it especially useful for industrial chemists.

Author : Thomas Wirth
Publisher : Springer
Page : 264 pages
File Size : 53,7 Mb
Release : 2003-07-01
Category : Science
ISBN : 9783540461142

Get Book

Hypervalent Iodine Chemistry by Thomas Wirth Pdf

Annotation The pioneers of hypervalent iodine chemistry have already realized that the chemistry of iodine(iii) and iodine(v) containing compounds offers multiple advantages over established methods. A wide range of reactions is possible. Hypervalent Iodine Chemistry presents a comprehensive overview of the various facets, scope, and limitations of organic chemistry with hypervalent iodine compounds.

Author : Robert M. Moriarty,Om Prakash
Publisher : Wiley
Page : 500 pages
File Size : 44,8 Mb
Release : 2020-01-28
Category : Science
ISBN : 0470007222

Get Book

Hypervalent Iodine in Organic Chemistry by Robert M. Moriarty,Om Prakash Pdf

This title provides the only comprehensive review and analysis ofthe use of hypervalent iodine in organic synthesis. Detailed coverage includes: synthetic transformations such asaddition reactions to carbon-carbon double bonds, formation ofcarbon-carbon double bonds, intramolecular insertion at unactivatedC-H bonds, cyclopropanation creation of the nitrogen, creation ofelectron deficient carbon, simple oxidation of sulfides and amines,Dess-Martin reagent and Koser's reagent. This title aims to be practical to the reader, with a focus onsynthesis, particularly in natural products and commercialapplications.

Author : Kazuaki Ishihara,Kilian Muniz
Publisher : John Wiley & Sons
Page : 452 pages
File Size : 44,8 Mb
Release : 2022-05-16
Category : Technology & Engineering
ISBN : 9783527348299

Get Book

Iodine Catalysis in Organic Synthesis by Kazuaki Ishihara,Kilian Muniz Pdf

Iodine Catalysis in Organic Synthesis The first book of its kind to highlight iodine as a sustainable alternative to conventional transition metal catalysis Iodine Catalysis in Organic Synthesis provides detailed coverage of recent advances in iodine chemistry and catalysis, focusing on the utilization of various iodine-containing compounds as oxidative catalysts. Featuring contributions by an international panel of leading research chemists, this authoritative volume explores the development of environmentally benign organic reactions and summarizes catalytic transformations of molecular iodine and iodine compounds such as hypervalent organoiodine and inorganic iodine salts. Readers are first introduced to the history of iodine chemistry, the conceptual background of homogeneous catalysis, and the benefits of iodine catalysis in comparison with transition metals. Next, chapters organized by reaction type examine enantioselective transformations, catalytic reactions involving iodine, catalyst states, oxidation in iodine and iodine catalyses, and catalytic reactions based on halogen bonding. Practical case studies and real-world examples of different applications in organic synthesis and industry are incorporated throughout the text. An invaluable guide for synthetic chemists in both academic and industrial laboratories, Iodine Catalysis in Organic Synthesis: Provides a thorough overview of typical iodine-catalyzed reactions, catalyst systems, structures, and reactivity Explores promising industrial applications of iodine-based reagents for organic synthesis Highlights the advantages iodine catalysis has over classical metal-catalyzed reactions Discusses sustainable and eco-friendly methods in hypervalent iodine chemistry Edited by two world authorities on the catalytic applications of organoiodine compounds, Iodine Catalysis in Organic Synthesis is required reading for catalytic, organic, and organometallic chemists, medicinal and pharmaceutical chemists, industrial chemists, and academic researchers and advanced students in relevant fields.

Author : Thomas Wirth
Publisher : Springer
Page : 264 pages
File Size : 40,6 Mb
Release : 2014-03-12
Category : Science
ISBN : 3662146231

Get Book

Hypervalent Iodine Chemistry by Thomas Wirth Pdf

Author : Toshifumi Dohi,Jian-Wei Han,Ravi Kumar
Publisher : Frontiers Media SA
Page : 125 pages
File Size : 53,5 Mb
Release : 2021-03-30
Category : Science
ISBN : 9782889666508

Get Book

New Hypervalent Iodine Reagents for Oxidative Coupling by Toshifumi Dohi,Jian-Wei Han,Ravi Kumar Pdf

Author : Kin-ya Akiba
Publisher : John Wiley & Sons
Page : 438 pages
File Size : 40,5 Mb
Release : 1998-12-18
Category : Science
ISBN : 0471240192

Get Book

Chemistry of Hypervalent Compounds by Kin-ya Akiba Pdf

Eine umfassende Einführung in das Gebiet der hypervalenten Moleküle und anschauliche Darstellung grundlegender Aufbauprinzipien von Verbindungen der Hauptgruppenelemente und metallorganischen Spezies. Gleichermaßen tiefgründig behandelt werden organische Verbindungen, beispielsweise von Silicium, Phosphor, Schwefel und Iod, und anorganische Moleküle, die unter anderem Antimon, Zinn und Lithium enthalten. (12/98)

Author : Thomas Baumgartner,Frieder Jaekle
Publisher : John Wiley & Sons
Page : 557 pages
File Size : 48,8 Mb
Release : 2018-03-12
Category : Science
ISBN : 9781119235972

Get Book

Main Group Strategies towards Functional Hybrid Materials by Thomas Baumgartner,Frieder Jaekle Pdf

Showcases the highly beneficial features arising from the presence of main group elements in organic materials, for the development of more sophisticated, yet simple advanced functional materials Functional organic materials are already a huge area of academic and industrial interest for a host of electronic applications such as Organic Light-Emitting Diodes (OLEDs), Organic Photovoltaics (OPVs), Organic Field-Effect Transistors (OFETs), and more recently Organic Batteries. They are also relevant to a plethora of functional sensory applications. This book provides an in-depth overview of the expanding field of functional hybrid materials, highlighting the incredibly positive aspects of main group centers and strategies that are furthering the creation of better functional materials. Main Group Strategies towards Functional Hybrid Materials features contributions from top specialists in the field, discussing the molecular, supramolecular and polymeric materials and applications of boron, silicon, phosphorus, sulfur, and their higher homologues. Hypervalent materials based on the heavier main group elements are also covered. The structure of the book allows the reader to compare differences and similarities between related strategies for several groups of elements, and to draw crosslinks between different sections. The incorporation of main group elements into functional organic materials has emerged as an efficient strategy for tuning materials properties for a wide range of practical applications Covers molecular, supramolecular and polymeric materials featuring boron, silicon, phosphorus, sulfur, and their higher homologues Edited by internationally leading researchers in the field, with contributions from top specialists Main Group Strategies towards Functional Hybrid Materials is an essential reference for organo-main group chemists pursuing new advanced functional materials, and for researchers and graduate students working in the fields of organic materials, hybrid materials, main group chemistry, and polymer chemistry.

Author : Tatsuo Kaiho
Publisher : John Wiley & Sons
Page : 512 pages
File Size : 47,7 Mb
Release : 2014-10-09
Category : Science
ISBN : 9781118878651

Get Book

Iodine Chemistry and Applications by Tatsuo Kaiho Pdf

This book comprehensively covers iodine, its chemistry, and itsrole in functional materials, reagents, and compounds. • Provides an up-to-date, detailed overview of iodinechemistry with discussion on elemental aspects: characteristics,properties, iodides, and halogen bonding • Acts as a useful guide for readers to learn how tosynthesize complex compounds using iodine reagents orintermediates • Describes traditional and modern processingtechniques, such as starch, cupper, blowing out, and ion exchangeresin methods • Includes seven detailed sections devoted to theapplications of iodine: Characteristics, Production, Synthesis,Biological Applications, Industrial Applications, BioorganicChemistry and Environmental Chemistry, and Radioisotopes • Features hot topics in the field, such as hypervalentiodine-mediated cross coupling reactions, agrochemicals, dyesensitized solar cells, and therapeutic agents

Author : Berit Olofsson,Ilan Marek,Zvi Rappoport
Publisher : John Wiley & Sons
Page : 1068 pages
File Size : 54,7 Mb
Release : 2019-04-29
Category : Science
ISBN : 9781119352303

Get Book

The Chemistry of Hypervalent Halogen Compounds, 2 Volume Set by Berit Olofsson,Ilan Marek,Zvi Rappoport Pdf

The understanding of functional groups is the key to understanding organic chemistry. In the tradition of Patai's Chemistry of Functional Groups each volume treats all aspects of functional groups, touching on theoretical, analytical, synthetic, biological, and industrial aspects. Hypervalent halogen compounds, in particular iodine compounds, are very efficient and selective oxidants which tolerate a wide range of functional groups. The electrophilic properties of these reagents can also be used to introduce other functionalizations. The present volume is the first in the series to survey the properties and chemical behaviour of hypervalent iodine and bromine, their use in organic synthesis, as well as their industrial application. As with all new volumes, the chapters are first published online in Patai's Chemistry of Functional Groups. Once a volume is completed online, it is then published in print format. The printed book offers the traditional quality of the Patai Book Series, complete with an extensive index.

Author : Thomas Wirth
Publisher : John Wiley & Sons
Page : 441 pages
File Size : 54,9 Mb
Release : 2012-01-09
Category : Science
ISBN : 9783527641956

Get Book

Organoselenium Chemistry by Thomas Wirth Pdf

Selenium-based methods in synthetic chemistry have developed rapidly over the past years and are now offering highly useful tools for organic synthesis. Filling the gap for a comprehensive handbook and ready reference, this book covers all modern developments within the field, including biochemical aspects. The chemistry chapters are organized according to the different reactivities of various selenium compounds and reagents, with each chapter dealing with a special reaction type. Also includes a table with 77Se NMR shifts to aid in practical problems. From the Contents: * Electrophilic and Nucleophilic Selenium * Selenium Compounds in Radical Reactions * Selenium-Stabilized Carbanions * Selenium Compounds with Valency Higher than Two * Selenocarbonyls * Selenoxide Elimination and [2,3]-Sigmatropic Rearrangement * Selenium Compounds as Ligands and Catalysts * Biological and Biochemical Aspects of Selenium Compounds

Author : Thomas Wirth
Publisher : Springer
Page : 320 pages
File Size : 40,6 Mb
Release : 2016-06-02
Category : Science
ISBN : 9783319337333

Get Book

Hypervalent Iodine Chemistry by Thomas Wirth Pdf

The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students.

Author : Dmitry V. Liskin,Penny Chaloner
Publisher : CRC Press
Page : 81 pages
File Size : 46,5 Mb
Release : 2015-11-04
Category : Medical
ISBN : 9781498722537

Get Book

Advanced Organic Synthesis by Dmitry V. Liskin,Penny Chaloner Pdf

Laboratory experience equips students with techniques that are necessary for professional practice. Advanced Organic Synthesis: A Laboratory Manual focuses on a mechanistic background of key reactions in organic chemistry, gives insight into well-established trends, and introduces new developments in the field.The book features experiments performe