Hypervalent Iodine Chemistry

Author : Thomas Wirth
Publisher : Springer Science & Business Media
Page : 275 pages
File Size : 53,6 Mb
Release : 2003-02-12
Category : Medical
ISBN : 9783540441076

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Hypervalent Iodine Chemistry by Thomas Wirth Pdf

T. Wirth: Introduction and General Aspects.- M. Ochiai: Reactivities, Properties and Structures.- A. Varvoglis: Preparation of Hypervalent Iodine Compounds.- V.V. Zhdankin: C-C-Bond Forming Reactions.- G.F. Koser: C- Heteroatom-Bond Forming Reactions.- G.F. Koser: Heteroatom- Heteroatom-Bond Forming Reactions.- T. Wirth: Oxidations and Rearrangements.- H. Tohma, Y. Kita: Synthetic Applications (Total Synthesis and Natural Product Synthesis).

Author : Viktor V. Zhdankin
Publisher : John Wiley & Sons
Page : 630 pages
File Size : 43,7 Mb
Release : 2013-10-01
Category : Science
ISBN : 9781118341308

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Hypervalent Iodine Chemistry by Viktor V. Zhdankin Pdf

Hypervalent Iodine Chemistry is the first comprehensive text covering all of the main aspects of the chemistry of organic and inorganic polyvalent iodine compounds, including applications in chemical research, medicine, and industry. Providing a comprehensive overview of the preparation, properties, and synthetic applications of this important class of reagents, the text is presented in the following way: The introductory chapter provides a historical background and describes the general classification of iodine compounds, nomenclature, hypervalent bonding, structural features, and the principles of reactivity of polyvalent iodine compounds. Chapter 2 gives a detailed description of the preparative methods and structural features of all known classes of organic and inorganic derivatives of polyvalent iodine. Chapter 3, the key chapter of the book, deals with the many applications of hypervalent iodine reagents in organic synthesis. Chapter 4 describes the most recent achievements in hypervalent iodine catalysis. Chapter 5 deals with recyclable polymer-supported and nonpolymeric hypervalent iodine reagents. Chapter 6 covers the "green" reactions of hypervalent iodine reagents under solvent-free conditions or in aqueous solutions. The final chapter provides an overview of the important practical applications of polyvalent iodine compounds in medicine and industry. This book is aimed at all chemists interested in iodine compounds, including academic and industrial researchers in inorganic, organic, physical, medicinal, and biological chemistry. It will be particularly useful to synthetic organic and inorganic chemists, including graduate and advanced undergraduate students. It comprehensively covers the green chemistry aspects of hypervalent iodine chemistry, making it especially useful for industrial chemists.

Author : A. Varvoglis
Publisher : Academic Press
Page : 223 pages
File Size : 40,6 Mb
Release : 1996-11-14
Category : Science
ISBN : 9780080534367

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Hypervalent Iodine in Organic Synthesis by A. Varvoglis Pdf

This book describes the fascinating chemistry of the many kinds of organic compounds of hypervalent iodine. Each chapter deals with a particular iodine compound or families of compounds which have been used as reagents in a plethora of useful transformations. These include assorted oxidation, such as with the precious Dess-Martin reagent as well as with a wide range of further reactions. Prominent features of hypervalent iodine reagents derived from iodobenzene are: ready availability, operational simplicity, mild reaction conditions, and high efficiency. They are environmentally safe and can be recycled. New species may be easily prepared by introducing substituents in the benzene ring or changing the ligand attached to iodine. Their combination with other reagents broadens considerably their synthetic potential. Today, no synthetic chemist can afford to ignore the valuable hypervalentiodine reagents. Key Features * Features up-to-date coverage of a wide range of topics * Includes many tables featuring a diversity of reactivity, and a comprehensive index * Acts as a comprehensive, up-to-date reference on all aspects of hypervalent iodine chemistry * Contains a section on unusual efficiency of hypervalent iodine reactions

Author : Tatsuo Kaiho
Publisher : John Wiley & Sons
Page : 512 pages
File Size : 50,6 Mb
Release : 2014-10-09
Category : Science
ISBN : 9781118878651

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Iodine Chemistry and Applications by Tatsuo Kaiho Pdf

This book comprehensively covers iodine, its chemistry, and itsrole in functional materials, reagents, and compounds. • Provides an up-to-date, detailed overview of iodinechemistry with discussion on elemental aspects: characteristics,properties, iodides, and halogen bonding • Acts as a useful guide for readers to learn how tosynthesize complex compounds using iodine reagents orintermediates • Describes traditional and modern processingtechniques, such as starch, cupper, blowing out, and ion exchangeresin methods • Includes seven detailed sections devoted to theapplications of iodine: Characteristics, Production, Synthesis,Biological Applications, Industrial Applications, BioorganicChemistry and Environmental Chemistry, and Radioisotopes • Features hot topics in the field, such as hypervalentiodine-mediated cross coupling reactions, agrochemicals, dyesensitized solar cells, and therapeutic agents

Author : Kazuaki Ishihara,Kilian Muniz
Publisher : John Wiley & Sons
Page : 452 pages
File Size : 49,8 Mb
Release : 2022-05-16
Category : Technology & Engineering
ISBN : 9783527348299

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Iodine Catalysis in Organic Synthesis by Kazuaki Ishihara,Kilian Muniz Pdf

Iodine Catalysis in Organic Synthesis The first book of its kind to highlight iodine as a sustainable alternative to conventional transition metal catalysis Iodine Catalysis in Organic Synthesis provides detailed coverage of recent advances in iodine chemistry and catalysis, focusing on the utilization of various iodine-containing compounds as oxidative catalysts. Featuring contributions by an international panel of leading research chemists, this authoritative volume explores the development of environmentally benign organic reactions and summarizes catalytic transformations of molecular iodine and iodine compounds such as hypervalent organoiodine and inorganic iodine salts. Readers are first introduced to the history of iodine chemistry, the conceptual background of homogeneous catalysis, and the benefits of iodine catalysis in comparison with transition metals. Next, chapters organized by reaction type examine enantioselective transformations, catalytic reactions involving iodine, catalyst states, oxidation in iodine and iodine catalyses, and catalytic reactions based on halogen bonding. Practical case studies and real-world examples of different applications in organic synthesis and industry are incorporated throughout the text. An invaluable guide for synthetic chemists in both academic and industrial laboratories, Iodine Catalysis in Organic Synthesis: Provides a thorough overview of typical iodine-catalyzed reactions, catalyst systems, structures, and reactivity Explores promising industrial applications of iodine-based reagents for organic synthesis Highlights the advantages iodine catalysis has over classical metal-catalyzed reactions Discusses sustainable and eco-friendly methods in hypervalent iodine chemistry Edited by two world authorities on the catalytic applications of organoiodine compounds, Iodine Catalysis in Organic Synthesis is required reading for catalytic, organic, and organometallic chemists, medicinal and pharmaceutical chemists, industrial chemists, and academic researchers and advanced students in relevant fields.

Author : Thomas Wirth
Publisher : Springer
Page : 320 pages
File Size : 51,7 Mb
Release : 2016-06-02
Category : Science
ISBN : 9783319337333

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Hypervalent Iodine Chemistry by Thomas Wirth Pdf

The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students.

Author : Berit Olofsson,Ilan Marek,Zvi Rappoport
Publisher : John Wiley & Sons
Page : 1068 pages
File Size : 52,7 Mb
Release : 2019-04-29
Category : Science
ISBN : 9781119352303

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The Chemistry of Hypervalent Halogen Compounds, 2 Volume Set by Berit Olofsson,Ilan Marek,Zvi Rappoport Pdf

The understanding of functional groups is the key to understanding organic chemistry. In the tradition of Patai's Chemistry of Functional Groups each volume treats all aspects of functional groups, touching on theoretical, analytical, synthetic, biological, and industrial aspects. Hypervalent halogen compounds, in particular iodine compounds, are very efficient and selective oxidants which tolerate a wide range of functional groups. The electrophilic properties of these reagents can also be used to introduce other functionalizations. The present volume is the first in the series to survey the properties and chemical behaviour of hypervalent iodine and bromine, their use in organic synthesis, as well as their industrial application. As with all new volumes, the chapters are first published online in Patai's Chemistry of Functional Groups. Once a volume is completed online, it is then published in print format. The printed book offers the traditional quality of the Patai Book Series, complete with an extensive index.

Author : Kin-ya Akiba
Publisher : John Wiley & Sons
Page : 438 pages
File Size : 52,6 Mb
Release : 1998-12-18
Category : Science
ISBN : 0471240192

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Chemistry of Hypervalent Compounds by Kin-ya Akiba Pdf

Eine umfassende Einführung in das Gebiet der hypervalenten Moleküle und anschauliche Darstellung grundlegender Aufbauprinzipien von Verbindungen der Hauptgruppenelemente und metallorganischen Spezies. Gleichermaßen tiefgründig behandelt werden organische Verbindungen, beispielsweise von Silicium, Phosphor, Schwefel und Iod, und anorganische Moleküle, die unter anderem Antimon, Zinn und Lithium enthalten. (12/98)

Author : Robert M. Moriarty,Om Prakash
Publisher : Wiley
Page : 500 pages
File Size : 54,9 Mb
Release : 2020-01-28
Category : Science
ISBN : 0470007222

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Hypervalent Iodine in Organic Chemistry by Robert M. Moriarty,Om Prakash Pdf

This title provides the only comprehensive review and analysis ofthe use of hypervalent iodine in organic synthesis. Detailed coverage includes: synthetic transformations such asaddition reactions to carbon-carbon double bonds, formation ofcarbon-carbon double bonds, intramolecular insertion at unactivatedC-H bonds, cyclopropanation creation of the nitrogen, creation ofelectron deficient carbon, simple oxidation of sulfides and amines,Dess-Martin reagent and Koser's reagent. This title aims to be practical to the reader, with a focus onsynthesis, particularly in natural products and commercialapplications.

Author : Toshifumi Dohi,Jian-Wei Han,Ravi Kumar
Publisher : Frontiers Media SA
Page : 125 pages
File Size : 55,6 Mb
Release : 2021-03-30
Category : Science
ISBN : 9782889666508

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New Hypervalent Iodine Reagents for Oxidative Coupling by Toshifumi Dohi,Jian-Wei Han,Ravi Kumar Pdf

Author : Thomas Wirth
Publisher : John Wiley & Sons
Page : 441 pages
File Size : 44,8 Mb
Release : 2012-01-09
Category : Science
ISBN : 9783527641956

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Organoselenium Chemistry by Thomas Wirth Pdf

Selenium-based methods in synthetic chemistry have developed rapidly over the past years and are now offering highly useful tools for organic synthesis. Filling the gap for a comprehensive handbook and ready reference, this book covers all modern developments within the field, including biochemical aspects. The chemistry chapters are organized according to the different reactivities of various selenium compounds and reagents, with each chapter dealing with a special reaction type. Also includes a table with 77Se NMR shifts to aid in practical problems. From the Contents: * Electrophilic and Nucleophilic Selenium * Selenium Compounds in Radical Reactions * Selenium-Stabilized Carbanions * Selenium Compounds with Valency Higher than Two * Selenocarbonyls * Selenoxide Elimination and [2,3]-Sigmatropic Rearrangement * Selenium Compounds as Ligands and Catalysts * Biological and Biochemical Aspects of Selenium Compounds

Author : Tatsuo Kaiho
Publisher : John Wiley & Sons
Page : 668 pages
File Size : 52,9 Mb
Release : 2014-11-24
Category : Science
ISBN : 9781118466292

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Iodine Chemistry and Applications by Tatsuo Kaiho Pdf

This book comprehensively covers iodine, its chemistry, and its role in functional materials, reagents, and compounds. • Provides an up-to-date, detailed overview of iodine chemistry with discussion on elemental aspects: characteristics, properties, iodides, and halogen bonding • Acts as a useful guide for readers to learn how to synthesize complex compounds using iodine reagents or intermediates • Describes traditional and modern processing techniques, such as starch, cupper, blowing out, and ion exchange resin methods • Includes seven detailed sections devoted to the applications of iodine: Characteristics, Production, Synthesis, Biological Applications, Industrial Applications, Bioorganic Chemistry and Environmental Chemistry, and Radioisotopes • Features hot topics in the field, such as hypervalent iodine-mediated cross coupling reactions, agrochemicals, dye sensitized solar cells, and therapeutic agents

Author : Gabriel Tojo,Marcos I. Fernandez
Publisher : Springer Science & Business Media
Page : 388 pages
File Size : 41,5 Mb
Release : 2006-06-15
Category : Science
ISBN : 9780387257259

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Oxidation of Alcohols to Aldehydes and Ketones by Gabriel Tojo,Marcos I. Fernandez Pdf

The aim of this book is to help people performing routine operations in Organic Synthesis in a laboratory. This book, the first one in a series, focuses on the oxidation of alcohols to aldehydes and ketones. Probably, this is the most important routine operation in Organic Synthesis.

Author : Alan R. Katritzky
Publisher : Elsevier
Page : 568 pages
File Size : 45,6 Mb
Release : 2017-01-31
Category : Science
ISBN : 9781483293424

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Handbook of Heterocyclic Chemistry by Alan R. Katritzky Pdf

Provides a one-volume overall picture of the largest of the classical divisions of organic chemistry, suitable for the graduate or advanced undergraduate student, as well as for research workers, both specialists in the field and those engaged in another discipline and requiring knowledge of heterocyclic chemistry. It represents Volume 9 of Comprehensive Heterocyclic Chemistry and utilizes the general chapters which appear in the 8-volume work. The highly systematic coverage given to the subject makes this the most authoritative one-volume account of modern heterocyclic chemistry available.

Author : Thomas Wirth
Publisher : John Wiley & Sons
Page : 493 pages
File Size : 54,9 Mb
Release : 2013-02-22
Category : Science
ISBN : 9783527659746

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Microreactors in Organic Chemistry and Catalysis by Thomas Wirth Pdf

For the second edition of 'Microreactors in Organic Chemistry and Catalysis' all chapters have been revised and updated to reflect the latest developments in this rapidly developing field. This new edition has 60% more content, and it remains a comprehensive publication covering most aspects of the topic. The use of microreactors in homogeneous, heterogeneous as well as biphasic reactions is covered in the main part of the book, together with catalytic, bioorganic and automation approaches. The initial chapters also provide a solid physical chemistry background on fluidics in microdevices. Finally, a chapter on industrial applications and developments covers recent progress in process chemistry. An excellent reference for beginners and experts alike.