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Author : Alfred Beverley Philip Lever
Publisher : Elsevier Science & Technology
Page : 888 pages
File Size : 55,6 Mb
Release : 1984
Category : Science
ISBN : UOM:39015051256819
Author : Alfred Beverly Philip Lever
Publisher : Unknown
Page : 0 pages
File Size : 43,7 Mb
Release : 1986
Category : Electronic
ISBN : 0444416994
Author : Alfred Beverly Philip Lever
Publisher : Unknown
Page : 863 pages
File Size : 45,9 Mb
Release : 1997
Category : Electronic
ISBN : 0444416994
Author : Edward I. Solomon,A. B. P. Lever
Publisher : Wiley-Interscience
Page : 682 pages
File Size : 45,6 Mb
Release : 1999-06-23
Category : Science
ISBN : UOM:39015047451094
Spectroscopy is an analytical method used to detect and identify samples, and analyze the electronic structure and behavior of a compound. Electronic structure is the bonding of inorganic compounds that give rise to a compounds' physical properties and reactivity. The two volume set covers current development in inorganic electronic spectroscopy. Because the field is inextricably linked to the more general area of electronic structure, the volumes will cover both inorganic spectroscopy and electronic structure. This second volume includes a series of case studies demonstrating how various methods and procedures in Volume 1 can be applied to important and topical areas of inorganic spectroscopy and electronic structure
Author : Chintamani Nagesa Ramachandra Rao,John R. Ferraro
Publisher : Unknown
Page : 434 pages
File Size : 49,5 Mb
Release : 1970
Category : Chemistry
ISBN : UCAL:B4566971
Spectroscopy in Inorganic Chemistry V1 ...
Author : Edward I. Solomon,A. B. P. Lever
Publisher : Wiley-Interscience
Page : 754 pages
File Size : 50,7 Mb
Release : 1999-06-23
Category : Science
ISBN : UOM:39015047451086
Includes information on modern, state-of-the-art & widely applied techniques. * Covers fundamental concepts & timely applications of the methodology in the field. * Illustrates modern procedures for collecting & processing electronic spectroscopic & structural data. * Includes case studies written by key people in the field showing application in important & topical areas of inorganic spectroscopy & electronic structure.
Author : Mandeep Dalal
Publisher : Dalal Institute
Page : 480 pages
File Size : 49,7 Mb
Release : 2017-01-01
Category : Science
ISBN : 9788193872000
An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Author : C.N.R. Rao
Publisher : Elsevier
Page : 328 pages
File Size : 49,9 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323155793
Spectroscopy in Inorganic Chemistry, Volume II is a collection of research studies on some of the spectroscopic methods and areas of inorganic chemistry in which spectroscopy has been used effectively. This book is divided into seven chapters that present the status reports and potentialities in the fields of study. Each chapter outlines the theoretical and experimental aspects, as well as the application to a specific field of the analytical method. The first three chapters deal with the molecular structure determination by neutron and X-ray diffraction, high-pressure vibrational spectroscopy, and electronic Raman transitions of rare earth ions. Other chapters explore the potential of electron spin resonance spectroscopy for inorganic radical and radical ion determination, as well as the application of electron spin resonance for coordination compound analysis. The remaining chapters examine the use of electronic spectroscopy for organometalloid study and the fluorescence and laser action in rare earth chelates. This book is intended primarily for analytical and inorganic chemists and spectroscopists who are interested in inorganic systems.
Author : B. Henderson,G. Frank Imbusch
Publisher : Oxford University Press
Page : 678 pages
File Size : 55,9 Mb
Release : 2006
Category : Science
ISBN : 0199298629
This text describes the technique of optical spectroscopy applied to problems in condensed matter physics. It relates theoretical understanding to experimental measurement, including discussion of the optical spectroscopy of inorganic insulators, with many illustrative examples. Symmetry arguments are developed from a formal group theoretical basis and are frequently used, and a special effort is made to treat the subject of lattice vibrations and to show how these can affect the spectroscopic properties of solids. The elements of laser theory are developed, and the authors also explore the use of optically detected magnetic resonance techniques for the investigation of semiconducting materials.
Author : C. R. Brundle
Publisher : Mittal Publications
Page : 274 pages
File Size : 45,9 Mb
Release : 2002
Category : Electron spectroscopy
ISBN : 8170998255
Author : D. W. H. Rankin,Norbert Mitzel,Carole Morrison
Publisher : John Wiley & Sons
Page : 606 pages
File Size : 48,9 Mb
Release : 2013-01-02
Category : Science
ISBN : 9781118462881
Determining the structure of molecules is a fundamental skill that all chemists must learn. Structural Methods in Molecular Inorganic Chemistry is designed to help readers interpret experimental data, understand the material published in modern journals of inorganic chemistry, and make decisions about what techniques will be the most useful in solving particular structural problems. Following a general introduction to the tools and concepts in structural chemistry, the following topics are covered in detail: • computational chemistry • nuclear magnetic resonance spectroscopy • electron paramagnetic resonance spectroscopy • Mössbauer spectroscopy • rotational spectra and rotational structure • vibrational spectroscopy • electronic characterization techniques • diffraction methods • mass spectrometry The final chapter presents a series of case histories, illustrating how chemists have applied a broad range of structural techniques to interpret and understand chemical systems. Throughout the textbook a strong connection is made between theoretical topics and the real world of practicing chemists. Each chapter concludes with problems and discussion questions, and a supporting website contains additional advanced material. Structural Methods in Molecular Inorganic Chemistry is an extensive update and sequel to the successful textbook Structural Methods in Inorganic Chemistry by Ebsworth, Rankin and Cradock. It is essential reading for all advanced students of chemistry, and a handy reference source for the professional chemist.
Author : Daniel C. Harris,Michael D. Bertolucci
Publisher : Courier Corporation
Page : 588 pages
File Size : 40,9 Mb
Release : 1989-01-01
Category : Science
ISBN : 048666144X
Informal, effective undergraduate-level text introduces vibrational and electronic spectroscopy, presenting applications of group theory to the interpretation of UV, visible, and infrared spectra without assuming a high level of background knowledge. 200 problems with solutions. Numerous illustrations. "A uniform and consistent treatment of the subject matter." — Journal of Chemical Education.
Author : Edward I. Stiefel
Publisher : John Wiley & Sons
Page : 752 pages
File Size : 48,9 Mb
Release : 2004-01-16
Category : Science
ISBN : 9780471471912
The Progress in Inorganic Chemistry series provides inorganic chemistry with a forum for critical, authoritative evaluations of advances in every area of the discipline. Volume 52, Dithiolene Chemistry: Synthesis, Properties, and Applications continues this forum with a focus on dithiolene chemistry and a significant, up-to-date selection of papers by internationally recognized researchers. Dithiolene complexes have a remarkable set of properties, a fact which has made them the object of intense study for new materials and sensors.
Author : Alan Earnshaw
Publisher : Elsevier
Page : 127 pages
File Size : 49,8 Mb
Release : 2013-10-22
Category : Science
ISBN : 9781483270692
Introduction to Magnetochemistry provides an introduction to the more important aspects of magnetochemistry. The measurement of magnetic moment has been one of the most consistently useful to coordination chemists. For teaching purposes it provides a simple method of illustrating the ideas of electronic structure, and in research it can provide fundamental information about the bonding and stereochemistry of complexes. The book contains six chapters covering topics such as free atoms and ions, transition metal complexes, crystal field theory, second and third row transition metal complexes, antiferromagnetism, and spin-pairing of electrons. The final chapter describes important experimental methods and then to shows briefly the way in which the problems of interpretation may be tackled.
Author : Edward I. Solomon,A. B. P. Lever
Publisher : Unknown
Page : 128 pages
File Size : 54,6 Mb
Release : 2005-12
Category : Science
ISBN : 0470038284