Ion Radical Organic Chemistry

Author : Zory Vlad Todres
Publisher : CRC Press
Page : 496 pages
File Size : 42,7 Mb
Release : 2008-10-20
Category : Science
ISBN : 1420008390

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Ion-Radical Organic Chemistry by Zory Vlad Todres Pdf

Consolidating knowledge from a number of disciplines, Ion-Radical Organic Chemistry: Principles and Applications, Second Edition presents the recent changes that have occurred in the field since the publication of the first edition in 2003. This volume examines the formation, transformation, and application of ion-radicals in typical conditions of organic synthesis. Avoiding complex mathematics, the author explains the principles of ion-radical organic chemistry and presents an overview of organic ion-radical reactions. He reviews methods of determining ion-radical mechanisms and controlling ion-radical reactions. Wherever applicable, the text addresses issues relating to ecology and biomedical concerns as well as inorganic participants of the ion-radical organic reactions. After reviewing the nature of organic ion-radicals and their ground-state electronic structure, the book discusses their formation, the relationship between electronic structure and reactivity, mechanism and regulation of reactions, stereochemical aspects, synthetic opportunities, and practical applications. Additional topics include electronic and opto-electronic devices, organic magnets and conductors, lubricants, other materials, and reactions of industrial or biomedical importance. The book concludes by providing an outlook on possible future development in this field. Researchers and practitioners engaged in active work on synthetic or mechanistic organic chemistry and its practical applications will find this text to be invaluable in both its scope and its depth.

Author : Zory Vlad Todres
Publisher : CRC Press
Page : 464 pages
File Size : 49,7 Mb
Release : 2002-09-10
Category : Science
ISBN : 0203909399

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Ion-Radical Organic Chemistry by Zory Vlad Todres Pdf

Examining the formation, transformation, and application of ion radicals in typical conditions of organic synthesis, Organic Ion Radicals: Chemistry and Applications explains the reactions and principles of ion radical chemistry. The author addresses methods of determining ion- radical mechanisms and controlling ion radical reactions, issues relati

Author : Zory Vlad Todres
Publisher : CRC Press
Page : 464 pages
File Size : 49,9 Mb
Release : 2002-09-10
Category : Science
ISBN : 0824708105

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Ion-Radical Organic Chemistry by Zory Vlad Todres Pdf

Examining the formation, transformation, and application of ion radicals in typical conditions of organic synthesis, Organic Ion Radicals: Chemistry and Applications explains the reactions and principles of ion radical chemistry. The author addresses methods of determining ion- radical mechanisms and controlling ion radical reactions, issues relating to ecology and biology, and inorganic participants in ion radical organic reactions. Applications discussed include the roles of ion radicals in biological systems and their uses in optoelectronics, organic metals, and the manufacture of paper.

Author : Zory V. Todres
Publisher : Unknown
Page : 464 pages
File Size : 41,8 Mb
Release : 2003
Category : Electronic book
ISBN : OCLC:1066491792

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Organic Ion Radicals by Zory V. Todres Pdf

Annotation Examining the formation, transformation, and application of ion radicals in typical conditions of organic synthesis, Organic Ion Radicals: Chemistry and Applications explains the reactions and principles of ion radical chemistry. The author addresses methods of determining ion- radical mechanisms and controlling ion radical reactions, issues relating to ecology and biology, and inorganic participants in ion radical organic reactions. Applications discussed include the roles of ion radicals in biological systems and their uses in optoelectronics, organic metals, and the manufacture of paper.

Author : D. C. Nonhebel,J. C. Walton
Publisher : CUP Archive
Page : 620 pages
File Size : 46,9 Mb
Release : 1974-01-31
Category : Science
ISBN : 0521201497

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Free-Radical Chemistry by D. C. Nonhebel,J. C. Walton Pdf

Author : Nathan L. Bauld
Publisher : Wiley-VCH
Page : 0 pages
File Size : 48,8 Mb
Release : 1997-09-26
Category : Science
ISBN : 0471190357

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Radicals, Ion Radicals, and Triplets by Nathan L. Bauld Pdf

Written by an internationally acknowledged expert in the field, this book provides an overview of all major types of spin-bearing radicals, important intermediates in organic reactions. Many new synthetic methods involving radicals have been developed and discussed in the past five years; this is the only source book that focuses on the physical-organic aspects of radical chemistry.

Author : David Crich
Publisher : John Wiley & Sons
Page : 1874 pages
File Size : 48,5 Mb
Release : 2013-05-30
Category : Science
ISBN : 9781118634899

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Reagents for Radical and Radical Ion Chemistry by David Crich Pdf

Radicals and radical ions are important intermediates with wide use in organic synthesis. The first book to concentrate on reagents for the creation and use of radicals and radical ions, this new volume in the Handbooks of Reagents for Organic Synthesis series compiles articles taken from the e-eros database, on reagents for use in radical and radical chemistry, to help the chemist in the lab choose the right reagents. Reflecting the enormous growth of radical chemistry over the past ten years, this is an essential guide for all synthetic chemists.

Author : Emil Thomas Kaiser
Publisher : Unknown
Page : 814 pages
File Size : 51,9 Mb
Release : 1968
Category : Science
ISBN : MINN:319510004688118

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Radical Ions by Emil Thomas Kaiser Pdf

Electron spin densities / James R. Bolton -- Metal ketyls and related radical ions - electron structures and ion pair equilibria / Noboru Hirota -- Semidione radical anions / Glen A. Russell -- Radical cations / Gershon Vincow -- Orbital degeneracy in benzene and substituent effects / Kerry W. Bowers -- Recent advances in the chemistry of aromatic anion radicals / M. Thomas Jones -- Some organometallic radicals and ion radicals of the group IV elements / Grant Urry -- Radical anions of sulfur-containing aromatic compounds / M.M. Urberg and E.T. Kaiser -- Ionic processes in [gamma]-irradiated organic solids at -196 [degrees] / William H. Hamill -- The structure of inorganic radicals / Hilary J. Bower, M.C.R. Symons and D.J.A. Tinling -- Fragments in irradiated ionic solids / Joseph Cunningham -- Trapped radicals in inorganic glasses / A. Treinin -- Electron spin resonance of first row transition metal complex ions / H.A. Kuska and Max t. Rogers.

Author : Samuel McManus
Publisher : Elsevier
Page : 552 pages
File Size : 52,6 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323146272

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Organic reactive intermediates by Samuel McManus Pdf

Organic Chemistry: A Series of Monographs, Volume 26: Organic Reactive Intermediates focuses on the study of reactive intermediates. This book discusses the methods of formation and investigation, factors affecting the stability, and reactions of the intermediate. Other topics include the formation and reaction of free radicals; kinetic aspects of free-radical chain reactions; electronic states and structures of carbenes; and formation of transient carbenes and carbenoids in solution. The intermediacy of nitrenes in reactions; electronic structure and spectra; methods of investigating carbonium ions; and reactions of carbonium ions are also elaborated. This publication likewise covers the preparation of carbanions; factors affecting the stability of carbanions; reactions involving radical ions; and methods of investigating arynes. This volume serves as a textbook for the first graduate-level course, as well as a reference for industrial chemists interested in organic reaction mechanisms.

Author : D. I. Davies,M. J. Parrott
Publisher : Springer Science & Business Media
Page : 181 pages
File Size : 52,6 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783642669224

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Free Radicals in Organic Synthesis by D. I. Davies,M. J. Parrott Pdf

Author : Anders Lund,Masaru Shiotani
Publisher : Springer Science & Business Media
Page : 498 pages
File Size : 54,6 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789401137508

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Radical Ionic Systems by Anders Lund,Masaru Shiotani Pdf

It is now more than 20 years since the book "Radical Ions" edited by Kaiser and Kevan appeared. It contained aspects regarding generation, identification, spin density determination and reactivity of charged molecules with an odd number of electrons. New classes of reactive ion radicals have been detected and characterised since then, most notably cation radicals of saturated organic compounds. Trapping of electrons has been found to occur not only in frozen glasses but also in organic crystals. The structure and reactions of anion radicals of saturated compounds have been clarified during the last 20 years. We have asked leading experts in the field to write separate chapters about cation radicals, anion radicals and trapped electrons as well as more complex systems of biological or technological interest. More attention is paid to recent studies of the ions of saturated compounds than to the older and previously reviewed work on aromatic ions. In the case of trapped electrons full coverage is out of the question, and focus is on recent efforts to characterise the solvation structure in ordered and disordered systems.

Author : Samir Z. Zard
Publisher : Oxford Chemistry Masters
Page : 280 pages
File Size : 49,8 Mb
Release : 2003
Category : Science
ISBN : 0198502419

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Radical Reactions in Organic Synthesis by Samir Z. Zard Pdf

Samir Zard provides a description of radical reactions and their applications in organic synthesis. This book shows that an with an elementary knowledge of kinetic and some common sense, it is possible to harness radicals into a tremendously powerful tool for solving synthetic problems.

Author : Michael D. Greenberg
Publisher : John Wiley & Sons
Page : 400 pages
File Size : 42,9 Mb
Release : 2009-09-22
Category : Science
ISBN : 9780470526262

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Radical and Radical Ion Reactivity in Nucleic Acid Chemistry by Michael D. Greenberg Pdf

Comprehensive coverage of radical reactive intermediates in nucleic acid chemistry and biochemistry The Wiley Series on Reactive Intermediates in Chemistry and Biology investigates reactive intermediates from the broadest possible range of disciplines. The contributions in each volume offer readers fresh insights into the latest findings, emerging applications, and ongoing research in the field from a diverse perspective. The chemistry and biochemistry of reactive intermediates is central to organic chemistry and biochemistry, and underlies a significant portion of modern synthetic chemistry. Radical and Radical Ion Reactivity in Nucleic Acid Chemistry provides the only comprehensive review of the chemistry and biochemistry of nucleic acid radical intermediates. With contributions by world leaders in the field, the text covers a broad range of topics, including: A discussion of the relevant theory Ionization of DNA Nucleic acid sugar radicals Halopyrimidines Oxidative, reductive, and low energy electron transfer Electron affinity sensitizers Photochemical generative of reactive oxygen species Reactive nitrogen species Enediyne rearrangements Phenoxyl radicals A unique compilation on the cutting edge of our understanding, Radical and Radical Ion Reactivity in Nucleic Acid Chemistry provides an unparalleled resource to student and professional researchers in such fields as organic chemistry, biochemistry, molecular biology, and physical chemistry, as well as the industries associated with these disciplines.

Author : Zory Vlad Todres
Publisher : Springer Science & Business Media
Page : 194 pages
File Size : 43,9 Mb
Release : 2013-07-17
Category : Science
ISBN : 9783319001586

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Organic Chemistry in Confining Media by Zory Vlad Todres Pdf

Zory Vlad Todres' monograph offers a fresh insight into an important and developed area of organic chemistry. Calixarene, cyclodextrins, and cucurbiturils as host molecules are well known, but the corresponding new and demonstrative publications deserve new exposition. This book principally widens our consideration of organic reactivity in confining media. Topics discussed include: effects of micellization, porous effects, effects of solvent cages, complexation to organometallic compounds, hydrogen-bond or charge-transfer complexation, sorption effects, effects of solvents, and stereochemical changes upon confinement. Organic Chemistry in Confining Media is useful for experienced organic chemists working in academia or industry, as well as chemists working in fields contiguous to organic chemistry.

Author : Zory Vlad Todres
Publisher : CRC Press
Page : 310 pages
File Size : 54,5 Mb
Release : 2011-08-24
Category : Science
ISBN : 9781420066081

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Chalcogenadiazoles by Zory Vlad Todres Pdf

A timely and authoritative treatise on the chemistry and diverse applications of chalcogenadiazoles — the five-membered rings containing two carbons, two nitrogens, and one chalcogen (an member of group 16, the oxygen family). The number of different chalcogenadiazoles and their structural diversity make it difficult to gain a clear understanding of the subject by studying an individual system in isolation. Chalcogenadiazoles: Chemistry and Applications emphasizes general features of this class of heterocyclic compounds. It concentrates on properties of each class of chalcogenadiazoles and their cycle-fused derivatives, considering chemical reactions of functional groups only in cases when these reactions permit to characterize the heterocycles as substituents or in respect of its aromaticity. Covering an important and rapidly developing branch of heterocyclic chemistry, this book is an essential resource for students, young professionals and experienced specialists in adjacent fields who are interested in: Trends in the search for compounds with established bioactivity or use in medicine, as agrochemicals, or as reagents for environmental and biochemical analysis Differences in classes of chalcogenadiazoles with respect to their degree of aromaticity and similar general concepts helpful to the nonspecialist The effects of the chalcogen nature and the alternation manner of all atomic constituents on properties of these heterocyclic compounds Combining data from organic, biological, medicinal, materials science, and supramolecular chemistry, Chalcogenadiazoles: Chemistry and Applications is an important source of information not only for chemists in the fields of organic, inorganic, and organometallic chemistry, but also for anyone interested in the research and development of chalcogenadiazoles and related species.