Metal Based Catalysts In Organic Synthesis

Author : Manas Sutradhar
Publisher : MDPI
Page : 68 pages
File Size : 41,5 Mb
Release : 2021-08-30
Category : Science
ISBN : 9783036510620

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Metal-Based Catalysts in Organic Synthesis by Manas Sutradhar Pdf

Catalysts play a crucial role in the path towards the transformation of organic compounds. This book describes the recent development of metal-based catalysis in organic synthesis. Applications of various catalysts to interesting organic transformations are discussed. It covers important organic reactions such as cyclohexane oxidation under different energy stimuli, use of Pd-nanoparticles for carbonylation of aniline, ammoximation of methyl ethyl ketone by Ni-modified TS-1 and carbozincation of substituted 2-alkynylamines. This book will be a useful reference for researchers in the field of catalysis, organic chemistry and materials science. It is also intended to attract the attention of researchers with an industrial interest.

Author : Manas Sutradhar
Publisher : Unknown
Page : 128 pages
File Size : 51,6 Mb
Release : 2021
Category : Electronic
ISBN : 303651063X

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Metal-based Catalysts in Organic Synthesis by Manas Sutradhar Pdf

Author : L. Brandsma,S.F. Vasilevsky,H.D. Verkruijsse
Publisher : Springer Science & Business Media
Page : 349 pages
File Size : 52,7 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783642603280

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Application of Transition Metal Catalysts in Organic Synthesis by L. Brandsma,S.F. Vasilevsky,H.D. Verkruijsse Pdf

Homogeneous catalysis is an important strategy for the synthesis of high-valued chemicals. L. Brandsma has carefully selected and checked the experimental procedures illustrating the catalytic use of copper, nickel, and palladium compounds in organic synthesis. All procedures are on a preparative scale, make economic use of solvents and catalysts, avoid toxic substances and have high yields.

Author : Mike G. Scaros,Michael L. Prunier
Publisher : CRC Press
Page : 632 pages
File Size : 54,6 Mb
Release : 1994-10-20
Category : Science
ISBN : 0824793641

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Catalysis of Organic Reactions by Mike G. Scaros,Michael L. Prunier Pdf

Based on the papers and posters presented at the 15th Conference on Catalysis of Organic Reactions, this work covers developments in the study of catalysis as it relates to organic synthesis, emphasizing applications in industrial processes. Over 1000 bibliographic citations and over 250 tables, drawings, and photographs are provided. Theoretical and practical aspects of the field are highlighted.

Author : Naohiko Yoshikai
Publisher : Georg Thieme Verlag
Page : 876 pages
File Size : 42,8 Mb
Release : 2023-09-06
Category : Science
ISBN : 9783132455047

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Base-Metal Catalysis 2 by Naohiko Yoshikai Pdf

Recent advances in catalytic methods based on earth-abundant metals are discussed. Catalysis with earth-abundant metals, often referred to as base metals, is having a transformative impact on synthetic chemistry. Research in this area is driven not only by the common interest in the sustainability of chemical synthesis but also by the vast opportunity to discover and develop novel reaction chemistry that is not attainable with rare and precious metal catalysts. This work provides representative developments in base-metal catalysis, specifically catalysis with 3d-transition metals, in a format suitable for practitioners of organic synthesis. Volume 2 is focused on recent advances in catalysis involving cobalt, iron, manganese, and chromium. Topics covered include various types of cross-coupling processes, hydrofunctionalization of alkenes and alkynes, C-H functionalizations, and catalytic Nozaki–Hiyama–Kishi-type reactions.

Author : Abdullah Mohammed Ah Asiri,Anish Khan,Showkat Ahmad Bhawani,Bahaa Mohamed Mahmoud Abu-Zied,Suchart Siengchin,Hurija Dzudzevic-Cancar
Publisher : Elsevier
Page : 290 pages
File Size : 42,9 Mb
Release : 2022-05-11
Category : Technology & Engineering
ISBN : 9780323885188

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Carbon-Based Metal Free Catalysts by Abdullah Mohammed Ah Asiri,Anish Khan,Showkat Ahmad Bhawani,Bahaa Mohamed Mahmoud Abu-Zied,Suchart Siengchin,Hurija Dzudzevic-Cancar Pdf

Carbon-Based Metal Free Catalysts: Preparation, Structural and Morphological Property and Application covers the different aspects of carbon-based metal free catalysts, including the fabrication of catalysts from natural sources and carbon allotropes, their manufacturing and design, characterization techniques, and applications. Special features in the book include illustrations and tables which summarize up-to-date information on research carried out on manufacturing, design, characterization and applications of metal free catalysts. This book assembles the information and knowledge on metal free catalysts and emphasizes the concept of green technology in the field of manufacturing and design. It is an ideal reference source for lecturers, students, researchers and industrialists working in the field of new catalyst development, especially polymer composites and is a valuable reference book handbook for teaching, learning, and research. Describes the design on metal-free catalysts Includes manufacturing technique of carbon-based metal free catalysts Lists applications of carbon-based metal free catalysts Discusses the characterization of carbon-based metal free catalysts

Author : A. Noels,M. Graziani,A.J Hubert
Publisher : Springer Science & Business Media
Page : 375 pages
File Size : 50,5 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789401134088

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Metal Promoted Selectivity in Organic Synthesis by A. Noels,M. Graziani,A.J Hubert Pdf

The demand for selective organic reactions is growing more acute everyday. Indeed, greater product selectivity has an important impact on energy and resource utilization, in terms of reduced process energy requirements for product separation and purification, in terms of low-value by-products, and in terms of environmental acceptance and compatibility. Moreover, more and more chemicals, especially pharmaceuticals, have to be sold in an optically active form. The search for selectivity constitutes a tremendous challenge for the chemists. In the last two decades, homogeneous transition metal based catalysis has emerged as one of the most promising tools for obtaining selectivity. In connection with developments in this area, this book contains updated and expanded versions of most of the lectures presented at a Cornett course held in Trieste (Italy) in 1989 and sponsored by the European Community. A primary aim is to cultivate a deeper understanding of the parameters that govern the selectivities and stimulate a wider utilization of transition metal based catalysis in organic synthesis. All aspects of selectivity, chemo-, regio-, stereo- and enantioselectivity are considered and illustrated by applications in various fields or organic synthesis. The impact of catalysis in oxydation, reduction, carbonylation reactions, carbene chemistry, in Ni and Pd promoted dimerizations, oligomerizations as well as fonctionalisations is stressed, quite often with special emphasis laid on reaction mechanisms. In this aspect, the last chapter examplifies the interest of high pressure NMR and IR when investigating the nature of reaction intermediates in homogeneous reactions.

Author : Jiro Tsuji
Publisher : John Wiley & Sons
Page : 500 pages
File Size : 55,9 Mb
Release : 2002-08-16
Category : Science
ISBN : 0471560278

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Transition Metal Reagents and Catalysts by Jiro Tsuji Pdf

Im Laufe der vergangenen 35 Jahre wurden unzahlige Synthesewege entwickelt, bei denen Ubergangsmetallkomplexe entweder als Reagenzien oder als Katalysatoren fungieren. Dieses Buch bietet besonders denjenigen Synthesechemikern interessante und moderne Einblicke, die bisher noch nicht mit den vielfaltigen Moglichkeiten der Organometallchemie mit Ubergangsmetallen vertraut sind. Zu wichtigen ubergangsmetallkatalysierten Reaktionen werden Anwendungsbeispiele diskutiert. (01/00)

Author : K. Smith
Publisher : Prentice Hall
Page : 362 pages
File Size : 49,8 Mb
Release : 1992
Category : Science
ISBN : UOM:39015028480674

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Solid Supports and Catalysts in Organic Synthesis by K. Smith Pdf

Author : Masakatsu Shibasaki,Yoshinori Yamamoto
Publisher : John Wiley & Sons
Page : 310 pages
File Size : 42,9 Mb
Release : 2006-03-06
Category : Science
ISBN : 9783527604326

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Multimetallic Catalysts in Organic Synthesis by Masakatsu Shibasaki,Yoshinori Yamamoto Pdf

This first book to comprehensively cover this hot topic presents the information hitherto scattered throughout smaller reviews or single book chapters to provide an introduction to this rapidly expanding field. In ten chapters, the international team of expert authors treats asymmetric syntheses, new transformations, and organometallic reactions using homo- and hetero-bimetallic catalysts. Written for advanced researchers, this very timely publication is of significant benefit to organic and organometallic chemists in both academia and industry.

Author : Jianbo Wang,Chi-Ming Che,Michael P. Doyle
Publisher : John Wiley & Sons
Page : 450 pages
File Size : 40,9 Mb
Release : 2022-05-16
Category : Science
ISBN : 9783527347995

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Transition Metal-Catalyzed Carbene Transformations by Jianbo Wang,Chi-Ming Che,Michael P. Doyle Pdf

Presents an up-to-date overview of the rapidly growing field of carbene transformations Carbene transformations have had an enormous impact on catalysis and organometallic chemistry. With the growth of transition metal-catalyzed carbene transformations in recent decades, carbene transformations are today an important compound class in organic synthesis as well as in the pharmaceutical and agrochemical industries. Edited by leading experts in the field, Transition Metal-Catalyzed Carbene Transformations is a thorough summary of the most recent advances in the rapidly expanding research area. This authoritative volume covers different reaction types such as ring forming reactions and rearrangement reactions, details their conditions and properties, and provides readers with accurate information on a wide range of carbene reactions. Twelve in-depth chapters address topics including carbene C-H bond insertion in alkane functionalization, the application of engineered enzymes in asymmetric carbene transfer, progress in transition-metal-catalyzed cross-coupling using carbene precursors, and more. Throughout the text, the authors highlight novel catalytic systems, transformations, and applications of transition-metal-catalyzed carbene transfer. Highlights the dynamic nature of the field of transition-metal-catalyzed carbene transformations Summarizes the catalytic radical approach for selective carbene cyclopropanation, high enantioselectivity in X-H insertions, and bio-inspired carbene transformations Introduces chiral N,N'-dioxide and chiral guanidine-based catalysts and different transformations with gold catalysis Discusses approaches in cycloaddition reactions with metal carbenes and polymerization with carbene transformations Outlines multicomponent reactions through gem-difunctionalization and transition-metal-catalyzed cross-coupling using carbene precursors Transition Metal-Catalyzed Carbene Transformations is essential reading for all chemists involved in organometallics, including organic and inorganic chemists, catalytic chemists, and chemists working in industry.

Author : H.M. Colquhoun,J. Holton,D.J. Thompson,M.V. Twigg
Publisher : Springer Science & Business Media
Page : 459 pages
File Size : 45,6 Mb
Release : 2012-12-06
Category : Science
ISBN : 9781461326519

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New Pathways for Organic Synthesis by H.M. Colquhoun,J. Holton,D.J. Thompson,M.V. Twigg Pdf

The continually growing contribution of transition metal chemistry to synthetic organic chemistry is, of course, widely recognized. Equally well known is the difficulty in keeping up-to-date with the multifarious reactions and procedures that seem to be spawned at an ever-increasing rate. These can certainly be summarized on the basis of reviews under the headings of the individual transition metals. More useful to the bench organic chemist, however, would be the opposite type of concordance based on the structural type of the desired synthetic product. This is the approach taken in the present monograph, which presents for each structural entity a conspectus of the transition metal-mediated processes that can be employed in its production. The resulting comparative survey should be a great help in devising the optimum synthetic approach for a particular goal. It is presented from an essentially practical viewpoint, with detailed direc tions interspersed in the Houben-Weyl style. The wide scope of the volume should certainly encourage synthetic organic chemists to utilize fully the range and versatility of these transition metal-mediated processes. This will certainly be a well-thumbed reference book! R. A. RAPHAEL Cambridge University v Preface In recent years an enormous amount of work has been done on the catalysis of organic reactions by various transition metal species and on the organic reactivity of organo-transition-metal compounds.

Author : Roderick Bates
Publisher : John Wiley & Sons
Page : 5 pages
File Size : 51,5 Mb
Release : 2012-04-30
Category : Science
ISBN : 9781119978930

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Organic Synthesis Using Transition Metals by Roderick Bates Pdf

Transition metals open up new opportunities for synthesis, because their means of bonding and their reaction mechanisms differ from those of the elements of the s and p blocks. In the last two decades the subject has mushroomed - established reactions are seeing both technical improvements and increasing numbers of applications, and new reactions are being developed. The practicality of the subject is demonstrated by the large number of publications coming from the process development laboratories of pharmaceutical companies, and its importance is underlined by the fact that three Nobel prizes have been awarded for discoveries in this field in the 21st Century already. Organic Synthesis Using Transition Metals, 2nd Edition considers the ways in which transition metals, as catalysts and reagents, can be used in organic synthesis, both for pharmaceutical compounds and for natural products. It concentrates on the bond-forming reactions that set transition metal chemistry apart from "classical" organic chemistry. Each chapter is extensively referenced and provides a convenient point of entry to the research literature. Topics covered include: introduction to transition metals in organic synthesis coupling reactions C-H activation carbonylative coupling reactions alkene and alkyne insertion reactions electrophilic alkene and alkyne complexes reactions of alkyne complexes carbene complexes h3- or p-allyl -allyl complexes diene, dienyl and arene complexes cycloaddition and cycloisomerisation reactions For this second edition the text has been extensively revised and expanded to reflect the significant improvements and advances in the field since the first edition, as well as the large number of new transition metal-catalysed processes that have come to prominence in the last 10 years – for example the extraordinary progress in coupling reactions using “designer” ligands, catalysis using gold complexes, new opportunities arising from metathesis chemistry, and C-H activation – without neglecting the well established chemistry of metals such as palladium. Organic Synthesis Using Transition Metals, 2nd Edition will find a place on the bookshelves of advanced undergraduates and postgraduates working in organic synthesis, catalysis, medicinal chemistry and drug discovery. It is also useful for practising researchers who want to refresh and enhance their knowledge of the field.

Author : Varun Rawat,Anirban Das,Chandra Mohan Srivastava
Publisher : CRC Press
Page : 249 pages
File Size : 45,7 Mb
Release : 2022-04-06
Category : Science
ISBN : 9781000555530

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Heterogeneous Catalysis in Organic Transformations by Varun Rawat,Anirban Das,Chandra Mohan Srivastava Pdf

As the broad challenges around energy and the environment have become the focus of much research, scientists and experts have dedicated their efforts to developing more active and selective catalytic systems for key chemical transformations. For many decades environmentally viable protocols for the synthesis of fine chemicals have been the crux of academic and industrial research. Heterogeneous Catalysis in Organic Transformations serves as an overview of this work, providing a complete description of role of heterogeneous catalysis in organic transformations and offering a review of the current and near future technologies and applications. Discusses the fundamentals of catalysis and compares the advantages and disadvantages of different types of catalyst systems Examines oxide nanoparticles and noble metal nanoparticles Consider organometallic compounds, solid-supported catalysts, and mesoporous materials Describes recent advances in metal-based heterogeneous catalysts and new reactions with possible mechanistic pathways Providing a comprehensive review of heterogeneous catalysis from the basics through recent advances, this book will be of keen interest to undergraduates, graduates, and researchers in chemistry, chemical engineering, and associated fields.

Author : James Spivey,Yi-Fan Han,Dushyant Shekhawat
Publisher : Royal Society of Chemistry
Page : 246 pages
File Size : 46,8 Mb
Release : 2020-02-05
Category : Science
ISBN : 9781788017749

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Catalysis by James Spivey,Yi-Fan Han,Dushyant Shekhawat Pdf

Catalysts are required for a variety of applications and researchers are increasingly challenged to find cost effective and environmentally benign catalysts to use. This volume looks at modern approaches to catalysis and reviews the extensive literature. Chapters highlight reactions active under oxidative coupling of methane conditions and how they are interlinked, heterogeneous nickel catalysts and their use in laboratory and industry, the reaction mechanism of heterogeneous catalysis with the surface science probe, the concepts of electroless deposition (ED) methods for preparation of true bimetallic catalysts, the general subject of metal-support interactions occurring over ruthenium-based catalysts and benzene as the target volatile organic compound (VOC). Appealing broadly to researchers in academia and industry, these illustrative chapters bridge the gap from academic studies in the laboratory to practical applications in industry not only for catalysis field but also for environmental protection. The book will be of great benefit to any researcher wanting a succinct reference on developments in this area now and looking to the future.