Modern Heterogeneous Oxidation Catalysis

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Modern Heterogeneous Oxidation Catalysis

Author : Noritaka Mizuno
Publisher : John Wiley & Sons
Page : 356 pages
File Size : 45,7 Mb
Release : 2009-11-18
Category : Science
ISBN : 9783527627554

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Modern Heterogeneous Oxidation Catalysis by Noritaka Mizuno Pdf

Filling a gap in the current literature, this comprehensive reference presents all important catalyst classes, including metal oxides, polyoxometalates, and zeolites. Readers will find here everything they need to know -- from structure design to characterization, and from immobilization to industrial processes. A true must-have for anyone working in this key technology.

Selective Oxidation by Heterogeneous Catalysis

Author : Gabriele Centi,Fabrizio Cavani,Ferrucio Trifirò
Publisher : Springer Science & Business Media
Page : 519 pages
File Size : 42,8 Mb
Release : 2012-12-06
Category : Science
ISBN : 9781461541752

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Selective Oxidation by Heterogeneous Catalysis by Gabriele Centi,Fabrizio Cavani,Ferrucio Trifirò Pdf

Selective Oxidation by Heterogeneous Catalysis covers one of the major areas of industrial petrochemical production, outlining open questions and new opportunities. It gives keys for the interpretation and analysis of data and design of new catalysts and reactions, and provides guidelines for future research. A distinctive feature of this book is the use of concept by example. Rather than reporting an overview of the literature results, the authors have selected some representative examples, the in-depth analysis of which makes it possible to clarify the fundamental, but new concepts necessary for a better understanding of the new opportunities in this field and the design of new catalysts or catalytic reactions. Attention is given not only to the catalyst itself, but also to the use of the catalyst inside the process, thus evidencing the relationship between catalyst design and engineering aspects of the process. This book provides suggestions for new innovative directions of research and indications on how to reconsider the field of selective oxidation from different perspectives, outlining that is not a mature field of research, but that new important breakthroughs can be derived from fundamental and applied research. Suggestions are offered on how to use less conventional approaches in terms of both catalyst design and analysis of the data.

Liquid Phase Oxidation via Heterogeneous Catalysis

Author : Mario G. Clerici,Oxana A. Kholdeeva
Publisher : John Wiley & Sons
Page : 438 pages
File Size : 42,7 Mb
Release : 2013-04-26
Category : Science
ISBN : 9781118356753

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Liquid Phase Oxidation via Heterogeneous Catalysis by Mario G. Clerici,Oxana A. Kholdeeva Pdf

Sets the stage for environmentally friendly industrial organic syntheses From basic principles to new and emerging industrial applications, this book offers comprehensive coverage of heterogeneous liquid-phase selective oxidation catalysis. It fully examines the synthesis, characterization, and application of catalytic materials for environmentally friendly organic syntheses. Readers will find coverage of all the important classes of catalysts, with an emphasis on their stability and reusability. Liquid Phase Oxidation via Heterogeneous Catalysis features contributions from an international team of leading chemists representing both industry and academia. The book begins with a chapter on environmentally benign oxidants and then covers: Selective oxidations catalyzed by TS-1 and other metal-substituted zeolites Selective catalytic oxidation over ordered nanoporous metallo-aluminophosphates Selective oxidations catalyzed by mesoporous metal-silicates Liquid phase oxidation of organic compounds by supported metal-based catalysts Selective liquid phase oxidations in the presence of supported polyoxometalates Selective oxidations catalyzed by supported metal complexes Liquid phase oxidation of organic compounds by metal-organic frameworks Heterogeneous photocatalysis for selective oxidations with molecular oxygen All the chapters dedicated to specific types of catalysts follow a similar organization and structure, making it easy to compare the advantages and disadvantages of different catalysts. The final chapter examines the latest industrial applications, such as the production of catechol and hydroquinone, cyclohexanone oxime, and propylene oxide. With its unique focus on liquid phase heterogeneous oxidation catalysis, this book enables researchers in organic synthesis and oxidation catalysis to explore and develop promising new catalytic materials and synthetic routes for a broad range of industrial applications.

Modern Applications of High Throughput R&D in Heterogeneous Catalysis

Author : Alfred Hagemeyer,Anthony F. Volpe
Publisher : Bentham Science Publishers
Page : 404 pages
File Size : 49,6 Mb
Release : 2014-04-04
Category : Science
ISBN : 9781608058723

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Modern Applications of High Throughput R&D in Heterogeneous Catalysis by Alfred Hagemeyer,Anthony F. Volpe Pdf

This eBook covers the application of high-throughput R&D to both fundamental and applied catalysis including catalyst synthesis, characterization, and testing in various reactor types. Chapters include topics such as applications ranging from optimizations of established industrial catalysts to the discovery of innovative new materials, examples of the development of innovative parallel characterization methods, and cases of real catalyst testing in small scale reactor systems. Readers will also find chapters that cover commodity chemicals produced using continuous gas phase processes as well as fine chemicals produced in liquid phase batch reactors. The potential of industrial chemicals production from biorenewable feedstocks is also presented. The steadily improving high throughput workflows are today being applied to relevant reactions and targets such as hydrotreating, Deacon oxidation, Fischer-Tropsch, propane dehydrogenation, C4 oxidation, methane coupling, exhaust gas catalysis, bio-based Nylon, fuel cells and vitamins. The topics presented in this eBook have been contributed by researchers from academia as well as industry, making this eBook a well-balanced reference, which could be of particular interest to professional, industrial or service R&D labs.

New Developments in Selective Oxidation by Heterogeneous Catalysis

Author : P. Ruiz,B. Delmon
Publisher : Elsevier
Page : 476 pages
File Size : 44,9 Mb
Release : 1992-02-06
Category : Technology & Engineering
ISBN : 0080887139

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New Developments in Selective Oxidation by Heterogeneous Catalysis by P. Ruiz,B. Delmon Pdf

This volume contains invited papers and communications presented at the Third European Workshop Meeting on Selective Oxidation by Heterogeneous Catalysis. The purpose of the meeting was to present recent results and to discuss new aspects of partial oxidation by heterogeneous catalysis. The following topics were discussed: Novel processes for obtaining new fine chemicals by catalytic partial oxidation; selective oxidation and oxidative dehydrogenation of alkanes; new catalysts and advances in preparation methods of oxidation catalysts; new phenomena in partial oxidation and new aspects of surface chemistry in oxide catalysts; new applications of physicochemical methods for characterization of oxide catalysts; oxidation with other agents than oxygen and catalytic oxidation of carbohydrates. This book will provide a valuable set of data on reactions of selective oxidation which will be extremely useful to catalyst and related practitioners, whether fundamentalists or highly applied, and to process engineers who wish to evaluate current findings in this field. The wide-range approach to reactions of selective oxidation will disseminate knowledge in specialized areas of selective oxidation and encourage innovation and creativity.

Handbook Of Advanced Methods And Processes In Oxidation Catalysis: From Laboratory To Industry

Author : Duprez Daniel,Cavani Fabrizio
Publisher : World Scientific
Page : 1036 pages
File Size : 43,8 Mb
Release : 2014-07-24
Category : Science
ISBN : 9781783263349

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Handbook Of Advanced Methods And Processes In Oxidation Catalysis: From Laboratory To Industry by Duprez Daniel,Cavani Fabrizio Pdf

This book offers a comprehensive overview of the most recent developments in both total oxidation and combustion and also in selective oxidation. For each topic, fundamental aspects are paralleled with industrial applications. The book covers oxidation catalysis, one of the major areas of industrial chemistry, outlining recent achievements, current challenges and future opportunities. One distinguishing feature of the book is the selection of arguments which are emblematic of current trends in the chemical industry, such as miniaturization, use of alternative, greener oxidants, and innovative systems for pollutant abatement. Topics outlined are described in terms of both catalyst and reaction chemistry, and also reactor and process technology.

Modern Heterogeneous Catalysis

Author : Rutger A. van Santen
Publisher : John Wiley & Sons
Page : 190 pages
File Size : 40,6 Mb
Release : 2017-02-15
Category : Technology & Engineering
ISBN : 9783527694501

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Modern Heterogeneous Catalysis by Rutger A. van Santen Pdf

Written by one of the world's leading experts on the topic, this advanced textbook is the perfect introduction for newcomers to this exciting field. Concise and clear, the text focuses on such key aspects as kinetics, reaction mechanism and surface reactivity, concentrating on the essentials. The author also covers various catalytic systems, catalysis by design, and activation-deactivation. A website with supplementary material offers additional figures, original material and references.

Concepts of Modern Catalysis and Kinetics

Author : I. Chorkendorff,J. W. Niemantsverdriet
Publisher : John Wiley & Sons
Page : 50 pages
File Size : 49,6 Mb
Release : 2017-05-30
Category : Technology & Engineering
ISBN : 9783527691289

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Concepts of Modern Catalysis and Kinetics by I. Chorkendorff,J. W. Niemantsverdriet Pdf

In the past 12 years since its publication, Concepts of Modern Catalysis and Kinetics has become a standard textbook for graduate students at universities worldwide. Emphasizing fundamentals from thermodynamics, physical chemistry, spectroscopy, solid state chemistry and quantum chemistry, it introduces catalysis from a molecular perspective, and stresses how it is interwoven with the field of reaction kinetics. The authors go on to explain how the world of reacting molecules is connected to the real world of industry, by discussing the various scales (nano - micro - macro) that play a role in catalysis. Reflecting the modern-day focus on energy supplies, this third edition devotes attention to such processes as gas-to-liquids, coal-to-liquids, biomass conversion and hydrogen production. From reviews of the prior editions: 'Overall, this is a valuable book that I will use in teaching undergraduates and postgraduates.' (Angewandte Chemie - I. E.) '...this excellent book is highly recommended to students at technical universities, but also entrants in chemical industry. Furthermore, this informative handbook is also a must for all professionals in the community.' (AFS) 'I am impressed by the coverage of the book and it is a valuable addition to the catalysis literature and I highly recommend purchase' (Energy Sources)

Heterogeneous Catalysts for Clean Technology

Author : Karen Wilson,Adam F. Lee
Publisher : John Wiley & Sons
Page : 466 pages
File Size : 47,8 Mb
Release : 2013-09-17
Category : Science
ISBN : 9783527659005

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Heterogeneous Catalysts for Clean Technology by Karen Wilson,Adam F. Lee Pdf

Reactive, but not a reactant. Heterogeneous catalysts play an unseen role in many of today's processes and products. With the increasing emphasis on sustainability in both products and processes, this handbook is the first to combine the hot topics of heterogeneous catalysis and clean technology. It focuses on the development of heterogeneous catalysts for use in clean chemical synthesis, dealing with how modern spectroscopic techniques can aid the design of catalysts for use in liquid phase reactions, their application in industrially important chemistries - including selective oxidation, hydrogenation, solid acid- and base-catalyzed processes - as well as the role of process intensification and use of renewable resources in improving the sustainability of chemical processes. With its emphasis on applications, this book is of high interest to those working in the industry.

Modern Heterogeneous Catalysis

Author : Rutger A. van Santen
Publisher : John Wiley & Sons
Page : 190 pages
File Size : 50,5 Mb
Release : 2017-02-15
Category : Technology & Engineering
ISBN : 9783527694525

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Modern Heterogeneous Catalysis by Rutger A. van Santen Pdf

Written by one of the world's leading experts on the topic, this advanced textbook is the perfect introduction for newcomers to this exciting field. Concise and clear, the text focuses on such key aspects as kinetics, reaction mechanism and surface reactivity, concentrating on the essentials. The author also covers various catalytic systems, catalysis by design, and activation-deactivation. A website with supplementary material offers additional figures, original material and references.

Metal Oxides in Heterogeneous Catalysis

Author : Jacques C. Vedrine
Publisher : Elsevier
Page : 618 pages
File Size : 43,5 Mb
Release : 2018-01-11
Category : Technology & Engineering
ISBN : 9780128116326

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Metal Oxides in Heterogeneous Catalysis by Jacques C. Vedrine Pdf

Metal Oxides in Heterogeneous Catalysis is an overview of the past, present and future of heterogeneous catalysis using metal oxides catalysts. The book presents the historical, theoretical, and practical aspects of metal oxide-based heterogeneous catalysis. Metal Oxides in Heterogeneous Catalysis deals with fundamental information on heterogeneous catalysis, including reaction mechanisms and kinetics approaches.There is also a focus on the classification of metal oxides used as catalysts, preparation methods and touches on zeolites, mesoporous materials and Metal-organic frameworks (MOFs) in catalysis. It will touch on acid or base-type reactions, selective (partial) and total oxidation reactions, and enzymatic type reactions The book also touches heavily on the biomass applications of metal oxide catalysts and environmentally related/depollution reactions such as COVs elimination, DeNOx, and DeSOx. Finally, the book also deals with future trends and prospects in metal oxide-based heterogeneous catalysis. Presents case studies in each chapter that provide a focus on the industrial applications Includes fundamentals, key theories and practical applications of metal oxide-based heterogeneous catalysis in one comprehensive resource Edited, and contributed, by leading experts who provide perspectives on synthesis, characterization and applications

Fundamental Concepts in Heterogeneous Catalysis

Author : Jens K. Nørskov,Felix Studt,Frank Abild-Pedersen,Thomas Bligaard
Publisher : John Wiley & Sons
Page : 228 pages
File Size : 44,6 Mb
Release : 2014-10-27
Category : Technology & Engineering
ISBN : 9781118888957

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Fundamental Concepts in Heterogeneous Catalysis by Jens K. Nørskov,Felix Studt,Frank Abild-Pedersen,Thomas Bligaard Pdf

This book is based on a graduate course and suitable as a primer for any newcomer to the field, this book is a detailed introduction to the experimental and computational methods that are used to study how solid surfaces act as catalysts. Features include: First comprehensive description of modern theory of heterogeneous catalysis Basis for understanding and designing experiments in the field Allows reader to understand catalyst design principles Introduction to important elements of energy transformation technology Test driven at Stanford University over several semesters

Heterogeneous Catalysis in Organic Chemistry

Author : Gerard V. Smith,Ferenc Notheisz
Publisher : Academic Press
Page : 346 pages
File Size : 43,9 Mb
Release : 1999-06-30
Category : Science
ISBN : 008052480X

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Heterogeneous Catalysis in Organic Chemistry by Gerard V. Smith,Ferenc Notheisz Pdf

The features of this book which will be of special interest to academic organic chemists are the introduction (Chapter 1), which presents a short course on the concepts and language of heterogeneous catalysis, covers organic reaction mechanisms of hydrogenation (Chapter 2), hydrogenolysis (Chapter 4), and oxidation (Chapter 6), a presents problems and solutions specific for running heterogeneous catalytic organic reactions in solution. These materials can supplement advanced chemistry courses. Most synthetic organic chemists use a variety of "protecting groups" which they attach to functional groups (reactive groups of atoms) while some reaction is being conducted on another part of the molecule. These protecting groups prevent reactions of the functional groups during other reactions and are removed later by a heterogeneous catalytic method called hydrogenolysis. One unique feature of this book, not found in other books on catalysis, is an exhaustive chapter (Chapter 4) on hydrogenolysis, which is dredged from the recent synthetic literature published by modern organic chemists. Academic organic chemists should find this chapter extremely useful and may wish to adopt the book as a supplement for advanced organic chemistry courses designed for seniors and for graduate students. It will also be useful for professors and their research groups engaged in synthetic organic chemistry. Many academic organic chemists are not aware of recent advances in heterogeneous enantioselective catalysis (Chapter 3) or in selective low temperature, liquid phase heterogeneous catalytic oxidations by hydrogen peroxide (Chapter 6). These specialty topics are timely and may be new to academic organic chemists and can be used to supplement their advanced courses. Several features of this book will also be of special interest to industrial chemists who are unfamiliar with heterogeneous catalysis. Many good organic chemists are hire by industry. They synthesize a new compound using standard organic synthetic techniques but are informed by their supervisor that they must convert some of their synthetic steps into heterogeneous catalytic steps. They may not have been exposed to heterogeneous catalysis and have few places to turn. This book offers them a crash course in heterogeneous catalysis as well as many examples of reactions and conditions with which they can start their search. Those industrial organic chemists already familiar with heterogeneous catalysis will find this book useful as a reference to many examples in the recent literature. They will find recent surface science discoveries correlated with heterogeneous catalysis or organic reactions and mechanistic suggestions designed to stimulate innovative nontraditional thinking about organic reactions on surfaces. Written by organic chemists for organic chemists Introduces heterogeneous catalysis concepts and language Presents a comprehensive compilation of protecting group removal procedures Covers liquid-phase hydrogenations, hydrogenolysis, and oxidations Addresses heterogeneous methods for producing pure enantiomers of chiral products Examines the emerging field of heterogenized homogeneous catalysts Mixes practical applications with mechanistic interpretations

Catalytic Oxidation: Principles And Applications - A Course Of The Netherlands Institute For Catalysis Research (Niok)

Author : R A Sheldon,Rutger A Van Santen
Publisher : World Scientific
Page : 392 pages
File Size : 44,9 Mb
Release : 1995-10-30
Category : Electronic
ISBN : 9789814579711

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Catalytic Oxidation: Principles And Applications - A Course Of The Netherlands Institute For Catalysis Research (Niok) by R A Sheldon,Rutger A Van Santen Pdf

This book consists of lectures presented by international authorities in the field, at a course on Oxidation Catalysis organized by the Dutch Research School in Catalysis at Rolduc in June 1994.The material covered spans the whole range of the subject from the fundamental principles of gas and liquid phase oxidations to reactor engineering for industrial processing. The use of catalytic oxidation in both bulk and fine chemicals manufacture and the different types of catalysis — heterogeneous-gas phase, homogeneous-liquid phase and heterogeneous-liquid phase — are discussed. In addition, a few special topics, such as electrocatalytic and high-temperature oxidation are dealt with.The book is intended for graduate students or industrial researchers who wish to acquaint themselves with the underlying principles of catalytic oxidations and the numerous applications of this important technology.

Heterogeneous Catalytic Oxidation

Author : B. K. Hodnett
Publisher : John Wiley & Sons
Page : 366 pages
File Size : 41,8 Mb
Release : 2000-07-13
Category : Science
ISBN : UOM:39015050256836

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Heterogeneous Catalytic Oxidation by B. K. Hodnett Pdf

This authoritative and comprehensive volume presents the essence of catalytic chemistry, describing the structure of catalysts, the technology in which they are used and the chemical transformations that occur during reaction. Heterogeneous catalytic oxidation is a key technique used in the large-scale production of organic chemicals. This text uses catalytic oxidation to explain the principles of heterogeneous catalysis and includes descriptions of how reactants and products interact on the molecular scale with the active sites on the surface of these materials. Following an introduction to the principles and chemistry of catalytic oxidation, Professor Hodnett uses detailed case studies which represent and illustrate the fundamentals and technology for specific aspects of heterogeneous catalytic oxidation including: * Propene Oxidation to Acrolein * n-Butane Oxidation to Maleic Anhydride * Epoxidation over Silver Catalysts * Fundamentals and Technologies of the Catalytic Destruction of Volatile Organic Compounds * Ammoxidation for the Insertion of Nitrogen into Organic Structures * Oxidative Insertion of Chlorine into Ethylene and Catalytic Combustion of Chlorinated Hydrocarbons * Liquid Phase Oxidations with Particular Emphasis on the Use of Hydrogen Peroxide as an Oxidizing Agent