Selective Oxidation By Heterogeneous Catalysis

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Selective Oxidation by Heterogeneous Catalysis

Gabriele Centi,Fabrizio Cavani,Ferrucio Trifirò
Selective Oxidation by Heterogeneous Catalysis Book PDF

Author : Gabriele Centi,Fabrizio Cavani,Ferrucio Trifirò
Publisher : Springer Science & Business Media
Page : 519 pages
File Size : 41,6 Mb
Release : 2012-12-06
Category : Science
ISBN : 9781461541752

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Selective Oxidation by Heterogeneous Catalysis by Gabriele Centi,Fabrizio Cavani,Ferrucio Trifirò Pdf

Selective Oxidation by Heterogeneous Catalysis covers one of the major areas of industrial petrochemical production, outlining open questions and new opportunities. It gives keys for the interpretation and analysis of data and design of new catalysts and reactions, and provides guidelines for future research. A distinctive feature of this book is the use of concept by example. Rather than reporting an overview of the literature results, the authors have selected some representative examples, the in-depth analysis of which makes it possible to clarify the fundamental, but new concepts necessary for a better understanding of the new opportunities in this field and the design of new catalysts or catalytic reactions. Attention is given not only to the catalyst itself, but also to the use of the catalyst inside the process, thus evidencing the relationship between catalyst design and engineering aspects of the process. This book provides suggestions for new innovative directions of research and indications on how to reconsider the field of selective oxidation from different perspectives, outlining that is not a mature field of research, but that new important breakthroughs can be derived from fundamental and applied research. Suggestions are offered on how to use less conventional approaches in terms of both catalyst design and analysis of the data.

New Developments in Selective Oxidation by Heterogeneous Catalysis

P. Ruiz,B. Delmon
New Developments in Selective Oxidation by Heterogeneous Catalysis Book PDF

Author : P. Ruiz,B. Delmon
Publisher : Elsevier
Page : 476 pages
File Size : 40,7 Mb
Release : 1992-02-06
Category : Technology & Engineering
ISBN : 0080887139

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New Developments in Selective Oxidation by Heterogeneous Catalysis by P. Ruiz,B. Delmon Pdf

This volume contains invited papers and communications presented at the Third European Workshop Meeting on Selective Oxidation by Heterogeneous Catalysis. The purpose of the meeting was to present recent results and to discuss new aspects of partial oxidation by heterogeneous catalysis. The following topics were discussed: Novel processes for obtaining new fine chemicals by catalytic partial oxidation; selective oxidation and oxidative dehydrogenation of alkanes; new catalysts and advances in preparation methods of oxidation catalysts; new phenomena in partial oxidation and new aspects of surface chemistry in oxide catalysts; new applications of physicochemical methods for characterization of oxide catalysts; oxidation with other agents than oxygen and catalytic oxidation of carbohydrates. This book will provide a valuable set of data on reactions of selective oxidation which will be extremely useful to catalyst and related practitioners, whether fundamentalists or highly applied, and to process engineers who wish to evaluate current findings in this field. The wide-range approach to reactions of selective oxidation will disseminate knowledge in specialized areas of selective oxidation and encourage innovation and creativity.

Liquid Phase Oxidation via Heterogeneous Catalysis

Mario G. Clerici,Oxana A. Kholdeeva
Liquid Phase Oxidation via Heterogeneous Catalysis Book PDF

Author : Mario G. Clerici,Oxana A. Kholdeeva
Publisher : John Wiley & Sons
Page : 438 pages
File Size : 50,5 Mb
Release : 2013-04-26
Category : Science
ISBN : 9781118356753

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Liquid Phase Oxidation via Heterogeneous Catalysis by Mario G. Clerici,Oxana A. Kholdeeva Pdf

Sets the stage for environmentally friendly industrial organic syntheses From basic principles to new and emerging industrial applications, this book offers comprehensive coverage of heterogeneous liquid-phase selective oxidation catalysis. It fully examines the synthesis, characterization, and application of catalytic materials for environmentally friendly organic syntheses. Readers will find coverage of all the important classes of catalysts, with an emphasis on their stability and reusability. Liquid Phase Oxidation via Heterogeneous Catalysis features contributions from an international team of leading chemists representing both industry and academia. The book begins with a chapter on environmentally benign oxidants and then covers: Selective oxidations catalyzed by TS-1 and other metal-substituted zeolites Selective catalytic oxidation over ordered nanoporous metallo-aluminophosphates Selective oxidations catalyzed by mesoporous metal-silicates Liquid phase oxidation of organic compounds by supported metal-based catalysts Selective liquid phase oxidations in the presence of supported polyoxometalates Selective oxidations catalyzed by supported metal complexes Liquid phase oxidation of organic compounds by metal-organic frameworks Heterogeneous photocatalysis for selective oxidations with molecular oxygen All the chapters dedicated to specific types of catalysts follow a similar organization and structure, making it easy to compare the advantages and disadvantages of different catalysts. The final chapter examines the latest industrial applications, such as the production of catechol and hydroquinone, cyclohexanone oxime, and propylene oxide. With its unique focus on liquid phase heterogeneous oxidation catalysis, this book enables researchers in organic synthesis and oxidation catalysis to explore and develop promising new catalytic materials and synthetic routes for a broad range of industrial applications.

New Developments in Selective Oxidation

G. Centi,F. Trifiró
New Developments in Selective Oxidation Book PDF

Author : G. Centi,F. Trifiró
Publisher : Elsevier
Page : 890 pages
File Size : 48,9 Mb
Release : 1990-04-26
Category : Technology & Engineering
ISBN : 0080879187

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New Developments in Selective Oxidation by G. Centi,F. Trifiró Pdf

This volume describes state-of-the-art advances in fundamental and applied aspects of partial selective oxidation in homogeneous and heterogeneous catalysis, including electrochemical and photo-oxidation. Comprising 93 papers, this book will provide a valuable set of data on reactions of selective oxidation which will be extremely useful to catalyst and related practitioners, whether fundamentalists or highly applied, and to process engineers who wish to evaluate current findings in this field. The wide-range approach to reactions of selective oxidation will disseminate knowledge in specialized areas of selective oxidation, serve as a springboard for new ideas and encourage innovation and creativity. Being an up-to-date reference source for all those studying in this field, this book should be on the bookshelf of all applied and academic research centres involved in the functionalization of molecules by selective oxidation.

Handbook Of Advanced Methods And Processes In Oxidation Catalysis: From Laboratory To Industry

Duprez Daniel,Cavani Fabrizio
Handbook Of Advanced Methods And Processes In Oxidation Catalysis From Laboratory To Industry Book PDF

Author : Duprez Daniel,Cavani Fabrizio
Publisher : World Scientific
Page : 1036 pages
File Size : 42,6 Mb
Release : 2014-07-24
Category : Science
ISBN : 9781783263349

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Handbook Of Advanced Methods And Processes In Oxidation Catalysis: From Laboratory To Industry by Duprez Daniel,Cavani Fabrizio Pdf

This book offers a comprehensive overview of the most recent developments in both total oxidation and combustion and also in selective oxidation. For each topic, fundamental aspects are paralleled with industrial applications. The book covers oxidation catalysis, one of the major areas of industrial chemistry, outlining recent achievements, current challenges and future opportunities. One distinguishing feature of the book is the selection of arguments which are emblematic of current trends in the chemical industry, such as miniaturization, use of alternative, greener oxidants, and innovative systems for pollutant abatement. Topics outlined are described in terms of both catalyst and reaction chemistry, and also reactor and process technology.

New Developments in Selective Oxidation by Heterogeneous Catalysis

Patricio Ruiz,Bernard Delmon
New Developments in Selective Oxidation by Heterogeneous Catalysis Book PDF

Author : Patricio Ruiz,Bernard Delmon
Publisher : Elsevier Science Limited
Page : 477 pages
File Size : 43,8 Mb
Release : 1992-01-01
Category : Science
ISBN : 0444894667

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New Developments in Selective Oxidation by Heterogeneous Catalysis by Patricio Ruiz,Bernard Delmon Pdf

This volume contains invited papers and communications presented at the Third European Workshop Meeting on Selective Oxidation by Heterogeneous Catalysis. The purpose of the meeting was to present recent results and to discuss new aspects of partial oxidation by heterogeneous catalysis. The following topics were discussed: Novel processes for obtaining new fine chemicals by catalytic partial oxidation; selective oxidation and oxidative dehydrogenation of alkanes; new catalysts and advances in preparation methods of oxidation catalysts; new phenomena in partial oxidation and new aspects of surface chemistry in oxide catalysts; new applications of physicochemical methods for characterization of oxide catalysts; oxidation with other agents than oxygen and catalytic oxidation of carbohydrates. This book will provide a valuable set of data on reactions of selective oxidation which will be extremely useful to catalyst and related practitioners, whether fundamentalists or highly applied, and to process engineers who wish to evaluate current findings in this field. The wide-range approach to reactions of selective oxidation will disseminate knowledge in specialized areas of selective oxidation and encourage innovation and creativity.

Modern Heterogeneous Oxidation Catalysis

Noritaka Mizuno
Modern Heterogeneous Oxidation Catalysis Book PDF

Author : Noritaka Mizuno
Publisher : John Wiley & Sons
Page : 356 pages
File Size : 44,6 Mb
Release : 2009-11-18
Category : Science
ISBN : 9783527627554

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Modern Heterogeneous Oxidation Catalysis by Noritaka Mizuno Pdf

Filling a gap in the current literature, this comprehensive reference presents all important catalyst classes, including metal oxides, polyoxometalates, and zeolites. Readers will find here everything they need to know -- from structure design to characterization, and from immobilization to industrial processes. A true must-have for anyone working in this key technology.

Heterogeneous Catalytic Oxidation

B. K. Hodnett
Heterogeneous Catalytic Oxidation Book PDF

Author : B. K. Hodnett
Publisher : John Wiley & Sons
Page : 366 pages
File Size : 41,6 Mb
Release : 2000-07-13
Category : Science
ISBN : UOM:39015050256836

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Heterogeneous Catalytic Oxidation by B. K. Hodnett Pdf

This authoritative and comprehensive volume presents the essence of catalytic chemistry, describing the structure of catalysts, the technology in which they are used and the chemical transformations that occur during reaction. Heterogeneous catalytic oxidation is a key technique used in the large-scale production of organic chemicals. This text uses catalytic oxidation to explain the principles of heterogeneous catalysis and includes descriptions of how reactants and products interact on the molecular scale with the active sites on the surface of these materials. Following an introduction to the principles and chemistry of catalytic oxidation, Professor Hodnett uses detailed case studies which represent and illustrate the fundamentals and technology for specific aspects of heterogeneous catalytic oxidation including: * Propene Oxidation to Acrolein * n-Butane Oxidation to Maleic Anhydride * Epoxidation over Silver Catalysts * Fundamentals and Technologies of the Catalytic Destruction of Volatile Organic Compounds * Ammoxidation for the Insertion of Nitrogen into Organic Structures * Oxidative Insertion of Chlorine into Ethylene and Catalytic Combustion of Chlorinated Hydrocarbons * Liquid Phase Oxidations with Particular Emphasis on the Use of Hydrogen Peroxide as an Oxidizing Agent

New Developments in Selective Oxidation II

V. Cortés Corberán,S. Vic Bellón
New Developments in Selective Oxidation II Book PDF

Author : V. Cortés Corberán,S. Vic Bellón
Publisher : Elsevier
Page : 883 pages
File Size : 40,8 Mb
Release : 1994-06-21
Category : Technology & Engineering
ISBN : 008087990X

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New Developments in Selective Oxidation II by V. Cortés Corberán,S. Vic Bellón Pdf

This volume contains invited papers and communications presented at the Second World Congress and Fourth European Workshop Meeting on New Developments in Selective Oxidation. The purpose of the meeting was to present new topics and recent advances as well as the discussion of new aspects of fundamental and applied aspects of partial selective oxidation in heterogeneous and homogeneous catalysis. The following topics were discussed: New processes for fine chemicals by catalytic oxidation; Recent developments in surface chemistry of oxide catalysts; Novel catalytic systems and preparation methods; Heterogenized homogeneous oxidation catalysts; Selective oxidation and oxidative dehydrogenation of alkanes; New industrial developments based on catalytic oxidation reactions; Bio-, photo-, and electro-catalytic oxidation; Oxidation by other agents than dioxygen; Bifunctional metal-on-metal oxide catalysts for selective oxidation. This book provides a valuable set of data on selective oxidation reactions which will be extremely useful to catalyst and related practitioners, whether fundamentalists or highly applied, and to process engineers who wish to evaluate current findings in this field.

Mechanisms In Heterogeneous Catalysis

Rutger A Van Santen
Mechanisms In Heterogeneous Catalysis Book PDF

Author : Rutger A Van Santen
Publisher : World Scientific
Page : 719 pages
File Size : 51,5 Mb
Release : 2023-06-28
Category : Science
ISBN : 9781800614024

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Mechanisms In Heterogeneous Catalysis by Rutger A Van Santen Pdf

Heterogeneous catalysis has developed over the past two centuries as a technology driven by the needs of society, and is part of Nobel Prize-winning science. This book describes the spectacular increase in molecular understanding of heterogenous catalytic reactions in important industrial processes. Reaction mechanism and kinetics are discussed with a unique focus on their relation with the inorganic chemistry of the catalyst material. An introductory chapter presents the development of catalysis science and catalyst discovery from a historical perspective. Five chapters that form the thrust of the book are organized by type of reaction, reactivity principles, and mechanistic theories, which provide the scientific basis to structure-function relationships of catalyst performance. Present-day challenges to catalysis are sketched in a final chapter. Written by one of the world's leading experts on the topic, this definitive text is an essential reference for students, researchers and engineers working in this multibillion-dollar field.

Catalytic Oxidation: Principles And Applications - A Course Of The Netherlands Institute For Catalysis Research (Niok)

R A Sheldon,Rutger A Van Santen
Catalytic Oxidation Principles And Applications A Course Of The Netherlands Institute For Catalysis Research Niok Book PDF

Author : R A Sheldon,Rutger A Van Santen
Publisher : World Scientific
Page : 392 pages
File Size : 52,9 Mb
Release : 1995-10-30
Category : Electronic
ISBN : 9789814579711

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Catalytic Oxidation: Principles And Applications - A Course Of The Netherlands Institute For Catalysis Research (Niok) by R A Sheldon,Rutger A Van Santen Pdf

This book consists of lectures presented by international authorities in the field, at a course on Oxidation Catalysis organized by the Dutch Research School in Catalysis at Rolduc in June 1994.The material covered spans the whole range of the subject from the fundamental principles of gas and liquid phase oxidations to reactor engineering for industrial processing. The use of catalytic oxidation in both bulk and fine chemicals manufacture and the different types of catalysis — heterogeneous-gas phase, homogeneous-liquid phase and heterogeneous-liquid phase — are discussed. In addition, a few special topics, such as electrocatalytic and high-temperature oxidation are dealt with.The book is intended for graduate students or industrial researchers who wish to acquaint themselves with the underlying principles of catalytic oxidations and the numerous applications of this important technology.

Heterogeneous Catalysts for Clean Technology

Karen Wilson,Adam F. Lee
Heterogeneous Catalysts for Clean Technology Book PDF

Author : Karen Wilson,Adam F. Lee
Publisher : John Wiley & Sons
Page : 466 pages
File Size : 51,6 Mb
Release : 2013-09-17
Category : Science
ISBN : 9783527659005

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Heterogeneous Catalysts for Clean Technology by Karen Wilson,Adam F. Lee Pdf

Reactive, but not a reactant. Heterogeneous catalysts play an unseen role in many of today's processes and products. With the increasing emphasis on sustainability in both products and processes, this handbook is the first to combine the hot topics of heterogeneous catalysis and clean technology. It focuses on the development of heterogeneous catalysts for use in clean chemical synthesis, dealing with how modern spectroscopic techniques can aid the design of catalysts for use in liquid phase reactions, their application in industrially important chemistries - including selective oxidation, hydrogenation, solid acid- and base-catalyzed processes - as well as the role of process intensification and use of renewable resources in improving the sustainability of chemical processes. With its emphasis on applications, this book is of high interest to those working in the industry.

Vanadium Catalysis

Manas Sutradhar,Armando J L Pombeiro,José Armando L da Silva
Vanadium Catalysis Book PDF

Author : Manas Sutradhar,Armando J L Pombeiro,José Armando L da Silva
Publisher : Royal Society of Chemistry
Page : 513 pages
File Size : 51,7 Mb
Release : 2020-11-05
Category : Science
ISBN : 9781839160899

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Vanadium Catalysis by Manas Sutradhar,Armando J L Pombeiro,José Armando L da Silva Pdf

Vanadium is one of the more abundant elements in the Earth’s crust and exhibits a wide range of oxidation states in its compounds making it potentially a more sustainable and more economical choice as a catalyst than the noble metals. A wide variety of reactions have been found to be catalysed by homogeneous, supported and heterogeneous vanadium complexes and the number of applications is growing fast. Bringing together the research on the catalytic uses of this element into one essential resource, including theoretical perspectives on proposed mechanisms for vanadium catalysis and an overview of its relevance in biological processes, this book is a useful reference for industrial and academic chemists alike.

Frontiers of Green Catalytic Selective Oxidations

Konstantin P. Bryliakov
Frontiers of Green Catalytic Selective Oxidations Book PDF

Author : Konstantin P. Bryliakov
Publisher : Springer Nature
Page : 295 pages
File Size : 41,6 Mb
Release : 2019-10-02
Category : Science
ISBN : 9789813297517

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Frontiers of Green Catalytic Selective Oxidations by Konstantin P. Bryliakov Pdf

The demand for novel efficient and environmentally sustainable chemo, regio- and stereoselective catalyst systems for the oxidation of organic substrates is continuously growing in line with toughening economic and environmental constraints. This book addresses these issues; it consists of eleven chapters written by world-recognized experts in green and sustainable oxidation catalysis. The most urgent and challenging topics, in the judgment of the editor, such as green asymmetric epoxidations, sulfoxidatiuons, C–H oxidations; oxidation catalysis by polyoxometalates and oxidations in non-conventional solvents, etc. have been critically reviewed in this book. Both fundamental aspects, such as catalysts design, catalytic properties, nature of catalytically active sites and reaction mechanisms, and practical outlook of the oxidations have been addressed by the authors. The book appeals to a broad readership, particularly graduate students, employees of universities and research organizations, and industrial researchers, particularly those working in the areas of homogeneous oxidation catalysis, asymmetric synthesis, organocatalysis, sustainable catalytic processes and green chemistry, mechanisms of catalytic reactions, synthesis of bioactive compounds, biomimetic chemistry, etc. Konstantin Bryliakov is Leading Researcher at the Boreskov Institute of Catalysis. In 2016, he was elected Honorary Professor of the Russian Academy of Sciences.

Heterogeneous Catalysis of Mixed Oxides

Makoto Misono
Heterogeneous Catalysis of Mixed Oxides Book PDF

Author : Makoto Misono
Publisher : Elsevier Inc. Chapters
Page : 192 pages
File Size : 40,7 Mb
Release : 2013-02-28
Category : Science
ISBN : 9780128081099

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Heterogeneous Catalysis of Mixed Oxides by Makoto Misono Pdf

The chemistry of metal oxides, both single and mixed metal oxides, relevant to heterogeneous catalysis such as relationships among the composition, structure, and chemical properties of mixed oxides, is provided in perspective. The important chemical properties in heterogeneous catalysis are acid–base and reduction–oxidation (redox) properties, where ionic radii, electronegativity, valency, and tendency to form covalent bond of constituent elements are most influential. Structural factors such as lattice defects and nonstoichiometry are also relevant. Although the surface of metal oxides is different from the solid bulk and changes depending on various factors, the surface reflects more or less the solid bulk and the knowledge of bulk properties is useful to understand the catalysis of mixed oxides. In some cases, the solid bulk actually takes part in catalysis. Other fundamental features of metal oxide catalysis like synergistic effects of more than two different active sites (acid and base, acid and oxidation, etc.) are also discussed.