Modern Synthesis Processes And Reactivity Of Fluorinated Compounds

Author : Henri Groult,Frederic Leroux,Alain Tressaud
Publisher : Elsevier
Page : 760 pages
File Size : 41,9 Mb
Release : 2016-11-04
Category : Science
ISBN : 9780128037904

Get Book

Modern Synthesis Processes and Reactivity of Fluorinated Compounds by Henri Groult,Frederic Leroux,Alain Tressaud Pdf

Modern Synthesis Processes and Reactivity of Fluorinated Compounds focuses on the exceptional character of fluorine and fluorinated compounds. This comprehensive work explores examples taken from all classes of fluorine chemistry and illustrates the extreme reactivity of fluorinating media and the peculiar synthesis routes to fluorinated materials. The book provides advanced and updated information on the latest synthesis routes to fluorocompounds and the involved reaction mechanisms. Special attention is given to the unique reactivity of fluorine and fluorinated media, along with the correlation of those properties to valuable applications of fluorinated compounds. Contains quality content edited, and contributed, by leading scholars in the field Presents applied guidance on the preparation of original fluorinated compounds, potentially transferable from the lab scale to industrial applications Provides practical synthesis information for a wide audience interested in fluorine compounds in many branches of chemistry, materials science, and physics

Author : Peer Kirsch
Publisher : John Wiley & Sons
Page : 457 pages
File Size : 41,7 Mb
Release : 2013-03-18
Category : Science
ISBN : 9783527651375

Get Book

Modern Fluoroorganic Chemistry by Peer Kirsch Pdf

The second edition of this classic reference work has been completely revised and updated, as well as being enlarged by 20% to reflect the latest developments in synthetic organic fluorine chemistry, taking into account new applications in materials science and medicinal chemistry. The new developments in transition-metal-catalyzed methods for the introduction of fluorine and fluorinated groups are discussed. In addition, new chapters have been added on such important applications as organic electronics (OLEDs) and fluorinated dyes. Appendices containing synthetic procedures and conversions round off this comprehensive work. This work is a valuable reference for fluorine chemists that also provides nonspecialists with an introduction to the field. From reviews of the first edition: ''... a well-produced book with attractive graphics, photos and schemes. Throughout the book, coloured electrostatic maps of small organofluorine compounds are used toillustrate charge distributions. These are effective as well as attractive. I would point any organic chemist to this book who wants to learn about and do some fluorine chemistry. It provides uncluttered descriptions and a clear orientation to the literature in this important area of the organic chemistry.'' CHEMBIOCHEM - A European Journal of Chemical Biology

Author : T. Nakajima,B. Žemva,A. Tressaud
Publisher : Elsevier
Page : 716 pages
File Size : 50,5 Mb
Release : 2000-05-12
Category : Science
ISBN : 0080525482

Get Book

Advanced Inorganic Fluorides: Synthesis, Characterization and Applications by T. Nakajima,B. Žemva,A. Tressaud Pdf

This book summarizes recent progresses in inorganic fluorine chemistry. Highlights include new aspects of inorganic fluorine chemistry, such as new synthetic methods, structures of new fluorides and oxide fluorides, their physical and chemical properties, fluoride catalysts, surface modifications of inorganic materials by fluorination process, new energy conversion materials and industrial applications. Fluorine has quite unique properties (highest electronegativity; very small polarizability). In fact, fluorine is so reactive that it forms fluorides with all elements except with the lightest noble gases helium, neon and argon. Originally, due to its high reactivity, fluoride chemistry faced many technical difficulties and remained undeveloped for many years. Now, however, a large number of fluorine-containing materials are currently produced for practical uses on an industrial scale and their applications are rapidly extending to many fields. Syntheses and structure analyses of thermodynamically unstable high-oxidation-state fluorides have greatly contributed to inorganic chemistry in this decade. Fluoride catalysts and surface modifications using fluorine are developing a new field of fluorine chemistry and will enable new syntheses of various compounds. The research on inorganic fluorides is now contributing to many chemical energy conversion processes such as lithium batteries. Furthermore, new theoretical approaches to determining the electronic structures of fluorine compounds are also progressing. On the industrial front, the use of inorganic fluorine compounds is constantly increasing, for example, in semi-conductor industry. "Advanced Inorganic Fluorides: Synthesis, Characterization and Applications" focuses on these new features in inorganic fluorine chemistry and its industrial applications. The authors are outstanding experts in their fields, and the contents of the book should prove to be of valuable assistance to all chemists, graduates, students and researchers in the field of fluorine chemistry.

Author : James H. Clark,David Wails,Tony W. Bastock
Publisher : CRC Press
Page : 208 pages
File Size : 49,8 Mb
Release : 1996-04-17
Category : Science
ISBN : UOM:39015037479428

Get Book

Aromatic Fluorination by James H. Clark,David Wails,Tony W. Bastock Pdf

Academia and industry join forces in Aromatic Fluorination, as an expert from each domain contributes to this new text on fluorination of carbocyclic and heterocyclic rings. The book begins with a discussion of fluorine's unique combination of properties, including size, electronic effects, and hydrophobicity, as well as the historical development of its product applications. It explains methods for introducing fluorine into an aromatic ring, focusing on nucleophilic fluorine transfer reactions. The role of catalysts, solvents, and other variables are examined, and the scope and limitations of the methods are discussed. Of particular interest to those working in non-specialist laboratories, Aromatic Fluorination includes detailed descriptions of the new electrophilic routes to fluoroaromatics, in addition to traditional routes and alternative methods involving radical chemistry. Because one of the most important fluorine-containing substituent is CF3, the book explains routes to benzotrifluorides (ArCF3), including traditional industrial methods and modern alternatives employing C-1 halofluorocarbons and other fluoroaliphatics. An alternative to CF3 is CF3S, and several methods of synthesizing aromatic CF3S-containing molecules are described. Since the successful development and diverse applications of aromatic fluorine compounds have led to the search for new compounds and novel substituents, the incorporation of other substituents is also explored. Aromatic Fluorination concludes with discussion of the factors responsible for the successful development of pharmaceutical, agrochemical and liquid crystal applications and the potential for applications in high-performance polymers and other areas. This section also describes in detail important industrial aromatic fluorination processes and the relative merits of different process technologies and their costs.

Author : Kalman J. Szabo,Nicklas Selander
Publisher : John Wiley & Sons
Page : 464 pages
File Size : 42,8 Mb
Release : 2021-03-22
Category : Science
ISBN : 9783527347117

Get Book

Organofluorine Chemistry by Kalman J. Szabo,Nicklas Selander Pdf

By presenting novel methods for the efficient preparation of fluorinated compounds and their application in pharmaceutical and agrochemical chemistry as well as medicine, this is a valuable source of information for all researchers in academia and industry!

Author : L.A. Alekseeva
Publisher : Springer
Page : 306 pages
File Size : 45,8 Mb
Release : 1989-11-02
Category : Science
ISBN : UOM:39015021563823

Get Book

New Fluorinating Agents in Organic Synthesis by L.A. Alekseeva Pdf

The book summarizes and gives a critical analysis of the literature on the use of reactive covalent fluorides (organic and inorganic) for the synthesis of fluoroorganic compounds. New methods of using SF4 for the fluorination of complex polyfunctional organic compounds are described. The prospects are shown for the selective fluorinations of complex compounds with non-traditional fluorinating agents (halogen fluorides, XeF2, fluorosulphuranes, N-F- and O-F-containing compounds). The book gives recommendations for the practical use of these fluorides, and typical synthetic procedures. It introduces the beginner to modern methods of fluorination and helps qualified scientists and technologists to choose the optimal methods of synthesis. Using the fluorinating agents described in this book, it is possible to synthesize various fluorine-containing substances.

Author : B. Baasner,Hermann Hagemann,J. C. Tatlow
Publisher : Unknown
Page : 128 pages
File Size : 53,9 Mb
Release : 1999
Category : Electronic
ISBN : 3131174943

Get Book

Organo-fluorine Compounds by B. Baasner,Hermann Hagemann,J. C. Tatlow Pdf

Author : Milos Hudlicky,Attila E. Pavlath
Publisher : Wiley-VCH
Page : 1328 pages
File Size : 40,5 Mb
Release : 1995-08
Category : Science
ISBN : UVA:X002240225

Get Book

Chemistry of Organic Fluorine Compounds by Milos Hudlicky,Attila E. Pavlath Pdf

Provides complete coverage of the chemistry of organic fluorine compounds. Topics include fluorinating agents, fluorination processes, reactions of fluorinated compounds, modern analytical methods, and properties and applications of fluorinated compounds. Offers a critical review of the literature and provides over 4,500 references. Updates the 1976 volume Chemistry of Organic Fluorine Compounds.

Author : Herbert W. Roesky
Publisher : John Wiley & Sons
Page : 490 pages
File Size : 48,9 Mb
Release : 2012-10-11
Category : Science
ISBN : 9781118409442

Get Book

Efficient Preparations of Fluorine Compounds by Herbert W. Roesky Pdf

The definitive guide to creating fluorine-based compounds—and the materials of tomorrow Discovered as an element by the French chemist Henri Moissan in 1886, through electrolysis of potassium fluoride in anhydrous hydrogen fluoride—"le fluor," or fluorine, began its chemical history as a substance both elusive and dangerous. With a slight pale yellow hue, fluorine is at room temperature a poisonous diatomic gas. Resembling a spirit from a chemical netherworld, fluorine is highly reactive, difficult to handle, yet very versatile as a reagent—with the power to form compounds with almost any other element. Comprising 20% of pharmaceutical products and 30% of agrochemical compounds, as well as playing a key role in electric cars, electronic devices, and space technology, compounds containing fluorine have grown in importance across the globe. Learning how to safely handle fluorine in the preparation of innovative new materials—with valuable new properties—is of critical importance to chemists today. Bringing together the research and methods of leading scientists in the fluorine field, Efficient Preparations of Fluorine Compounds is the definitive manual to creating, and understanding the reaction mechanisms integral to a wide variety of fluorine compounds. With sixty-eight contributed chapters, the book's extensive coverage includes: Preparation of Elemental Fluorine Synthesis Methods for Exotic Inorganic Fluorides with Varied Applications Introduction of Fluorine into Compounds via Electrophilic and Nucleophilic Reactions Direct Fluorination of Organic Compounds with Elemental Fluorine Efficient Preparations of Bioorganic Fluorine Compounds Asymmetric Fluorocyclization Reactions Preparations of Rare Earth Fluorosulfides and Oxyfluorosulfides The book offers methods and results that can be reproduced by students involved in advanced studies, as well as practicing chemists, pharmaceutical scientists, biologists, and environmental researchers. The only chemical resource of its kind, Efficient Preparations of Fluorine Compounds—from its first experiment to its last—is a unique window into the centuries old science of fluorine and the limitless universe of fluorine-based compounds.

Author : Gunter Haufe,Frederic Leroux
Publisher : Academic Press
Page : 686 pages
File Size : 54,5 Mb
Release : 2018-09-19
Category : Science
ISBN : 9780128127346

Get Book

Fluorine in Life Sciences: Pharmaceuticals, Medicinal Diagnostics, and Agrochemicals by Gunter Haufe,Frederic Leroux Pdf

Fluorine in Life Sciences: Pharmaceuticals, Medicinal Diagnostics and Agrochemicals, volume four in Alain Tressaud’s Progress in Fluorine Science series, presents a critical, multidisciplinary overview of the contributions of fluorinated products to solve important global issues in various life science fields, particularly in medicinal chemistry, molecular imaging techniques and agriculture. Edited by recognized experts, this book provides unique coverage of the wide-ranging uses and implications of fluorine and fluorinated compounds. Topics include medicinal monitoring and diagnosis, 19F MRI in medicine and in vivo cell tracking, 18F-labeled radiopharmaceuticals, brain imaging and neurology, risk assessment of reactive metabolites in drug discovery, and more. Edited by Alain Tressaud, past Chair and founder of the CNRS French Fluorine Network, each book in the collection also includes the work of highly-respected volume editors and contributors from both academia and industry who bring valuable and varied content to this active field. Covers a wide range of topics - from organic and physical chemistry, to pharmaceuticals, agrochemicals and medical diagnostics Describes major modern syntheses and unique reaction mechanisms yielding fluorine compounds in these diverse life science settings Features contributions from a wealth of global experts Acts as the fourth volume in Alain Tressaud’s Progress in Fluorine Science

Author : Anonim
Publisher : John Wiley & Sons
Page : 1130 pages
File Size : 40,7 Mb
Release : 2019-12-05
Category : Science
ISBN : 9781119456667

Get Book

Organic Reactions, Volume 100 by Anonim Pdf

Written by a "who is who" of leading organic chemists, this anniversary volume represent the Organic Reactions editors' choice of the most important, ground-breaking and versatile reactions in current organic synthesis. The 15 reaction types selected for this volume include reactions for carbon-carbon bond formation, cross-coupling reactions, hydro- and halofunctionalizations, among many others. In line with the successful recipe of the series, each chapter is focused on a single reaction, discussing its mechanism and stereochemistry, scope and limitations, applications to synthesis, comparison with other methods, and experimental procedures. Each chapter concludes with a tabular survey of selected key application examples, complete with reported reaction conditions and yields, to serve as a quick reference guide for synthesis planning.

Author : Ferenc Darvas,György Dormán,Volker Hessel,Steven V. Ley
Publisher : Walter de Gruyter GmbH & Co KG
Page : 448 pages
File Size : 42,5 Mb
Release : 2021-10-25
Category : Technology & Engineering
ISBN : 9783110693676

Get Book

Flow Chemistry – Fundamentals by Ferenc Darvas,György Dormán,Volker Hessel,Steven V. Ley Pdf

The fully up-dated edition of the two-volume work covers both the theoretical foundation as well as the practical aspects. Presenting the complete insight into driving a chemical reaction provides a deep understanding for new potential technologies. Updated overview on devices and new key concepts of experimental procedures. Vol. 2: Applications.

Author : Ioannis D. Kostas
Publisher : MDPI
Page : 273 pages
File Size : 40,7 Mb
Release : 2018-03-23
Category : Electronic book
ISBN : 9783038425564

Get Book

Suzuki–Miyaura Cross- Coupling Reaction and Potential Applications by Ioannis D. Kostas Pdf

This book is a printed edition of the Special Issue "Suzuki–Miyaura Cross-Coupling Reaction and Potential Applications" that was published in Catalysts

Author : Merin Sara Thomas,Józef T. Haponiuk,Sabu Thomas,Anne George
Publisher : CRC Press
Page : 326 pages
File Size : 49,7 Mb
Release : 2022-12-23
Category : Technology & Engineering
ISBN : 9781000572834

Get Book

Advanced Microscopy by Merin Sara Thomas,Józef T. Haponiuk,Sabu Thomas,Anne George Pdf

This interdisciplinary book, Advanced Microscopy: A Strong Analytical Tool in Materials Science, covers the methodology and applications of different advanced microscopic techniques in various research fields, including chemistry, nanotechnology, polymers, chemical engineering, and biomedical engineering, providing an informative overview that helps to determine the best applications for advanced materials. Materials usually behave very differently at nanoscale in all aspects, and this volume shows how microscopy can help provide a detailed understanding of materials such as semiconductors, metals, polymers, biopolymers, etc. The volume illustrates advanced microscopic techniques that include scanning electron microscopy (SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM), confocal microscopy, and others. The microscopy techniques presented in the volume show applications in many areas of science, including botany and plant science, medicine, nanotechnology, chemistry, food science, waste management, and others. This book presents the diverse advanced microscopic techniques for researchers, giving a better understanding as well as implementation of novel techniques in materials science.

Author : ConferenceSeries
Publisher : ConferenceSeries
Page : 105 pages
File Size : 47,7 Mb
Release : 2024-06-17
Category : Electronic
ISBN : 8210379456XXX

Get Book

Proceedings of 6th International Conference and Exhibition on Materials Science and Chemistry 2018 by ConferenceSeries Pdf

May 17-18, 2018 Rome, Italy Key Topics : Materials Science and Chemistry, Materials Science and Engineering, Materials Chemistry in Developing Areas, Materials Synthesis and Characterization, Analytical Techniques and Instrumentation in Materials Chemistry, Polymeric Materials, Nanomaterials, Inorganic Materials Chemistry, Organic Materials Chemistry, Applied Materials Chemistry, Materials Chemistry and Physics, Science and Technology of Advanced Materials,