Optoelectronic Properties Of Organic Semiconductors

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Organic Semiconductors for Optoelectronics

Author : Hiroyoshi Naito
Publisher : John Wiley & Sons
Page : 388 pages
File Size : 46,5 Mb
Release : 2021-07-30
Category : Science
ISBN : 9781119146124

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Organic Semiconductors for Optoelectronics by Hiroyoshi Naito Pdf

Comprehensive coverage of organic electronics, including fundamental theory, basic properties, characterization methods, device physics, and future trends Organic semiconductor materials have vast commercial potential for a wide range of applications, from self-emitting OLED displays and solid-state lighting to plastic electronics and organic solar cells. As research in organic optoelectronic devices continues to expand at an unprecedented rate, organic semiconductors are being applied to flexible displays, biosensors, and other cost-effective green devices in ways not possible with conventional inorganic semiconductors. Organic Semiconductors for Optoelectronics is an up-to-date review of the both the fundamental theory and latest research and development advances in organic semiconductors. Featuring contributions from an international team of experts, this comprehensive volume covers basic properties of organic semiconductors, characterization techniques, device physics, and future trends in organic device development. Detailed chapters provide key information on the device physics of organic field-effect transistors, organic light-emitting diodes, organic solar cells, organic photosensors, and more. This authoritative resource: Provides a clear understanding of the optoelectronic properties of organic semiconductors and their influence to overall device performance Explains the theories behind relevant mechanisms in organic semiconducting materials and in organic devices Discusses current and future trends and challenges in the development of organic optoelectronic devices Reviews electronic properties, device mechanisms, and characterization techniques of organic semiconducting materials Covers theoretical concepts of optical properties of organic semiconductors including fluorescent, phosphorescent, and thermally-assisted delayed fluorescent emitters An important new addition to the Wiley Series in Materials for Electronic & Optoelectronic Applications, Organic Semiconductors for Optoelectronics bridges the gap between advanced books and undergraduate textbooks on semiconductor physics and solid-state physics. It is essential reading for academic researchers, graduate students, and industry professionals involved in organic electronics, materials science, thin film devices, and optoelectronics research and development.

Optoelectronic Properties of Organic Semiconductors

Author : Nasim Zarrabi
Publisher : Unknown
Page : 0 pages
File Size : 50,7 Mb
Release : 2022
Category : Electronic
ISBN : 3030931633

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Optoelectronic Properties of Organic Semiconductors by Nasim Zarrabi Pdf

This book focuses on organic semiconductors with particular attention paid to their use as photovoltaic devices. It addresses a fundamental and hitherto overlooked concept in the field of organic optoelectronics, namely the role that sub-gap states play in the performance of organic semiconducting devices. From a technological point of view, organic semiconductor-based devices are of significant interest due to their lightweight, ease of processability, conformal flexibility, and potentially low cost and low embodied energy production. Motivated by these rather unique selling points, the performance of organic semiconductors has been a subject of multidisciplinary study for more than 60 years with steady progress in applications such as solar cells, transistors, light emitting diodes, and various sensors. The book begins with a review of the main electro-optical phenomena in organic solar cells and presents a new method for measuring exciton diffusion lengths based on a low-quencher-content device structure. Furthermore, the book reveals how mid-gap trap states are a universal feature in organic semiconductor donor-acceptor blends, unexpectedly contributing to charge generation and recombination, and having profound impact on the thermodynamic limit of organic photovoltaic devices. Featuring cutting-edge experimental observations supported with robust and novel theoretical arguments, this book delivers important new insight as to the underlying dynamics of exciton generation and diffusion, charge transfer state dissociation, and indeed the ultimate fate of photogenerated free carriers.

Organic Optoelectronic Materials

Author : Yongfang Li
Publisher : Springer
Page : 392 pages
File Size : 42,5 Mb
Release : 2015-05-30
Category : Technology & Engineering
ISBN : 9783319168623

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Organic Optoelectronic Materials by Yongfang Li Pdf

This volume reviews the latest trends in organic optoelectronic materials. Each comprehensive chapter allows graduate students and newcomers to the field to grasp the basics, whilst also ensuring that they have the most up-to-date overview of the latest research. Topics include: organic conductors and semiconductors; conducting polymers and conjugated polymer semiconductors, as well as their applications in organic field-effect-transistors; organic light-emitting diodes; and organic photovoltaics and transparent conducting electrodes. The molecular structures, synthesis methods, physicochemical and optoelectronic properties of the organic optoelectronic materials are also introduced and described in detail. The authors also elucidate the structures and working mechanisms of organic optoelectronic devices and outline fundamental scientific problems and future research directions. This volume is invaluable to all those interested in organic optoelectronic materials.

Optoelectronic Properties of Organic Semiconductors

Author : Nasim Zarrabi
Publisher : Springer Nature
Page : 116 pages
File Size : 40,9 Mb
Release : 2022-02-26
Category : Technology & Engineering
ISBN : 9783030931629

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Optoelectronic Properties of Organic Semiconductors by Nasim Zarrabi Pdf

This book focuses on organic semiconductors with particular attention paid to their use as photovoltaic devices. It addresses a fundamental and hitherto overlooked concept in the field of organic optoelectronics, namely the role that sub-gap states play in the performance of organic semiconducting devices. From a technological point of view, organic semiconductor-based devices are of significant interest due to their lightweight, ease of processability, conformal flexibility, and potentially low cost and low embodied energy production. Motivated by these rather unique selling points, the performance of organic semiconductors has been a subject of multidisciplinary study for more than 60 years with steady progress in applications such as solar cells, transistors, light emitting diodes, and various sensors. The book begins with a review of the main electro-optical phenomena in organic solar cells and presents a new method for measuring exciton diffusion lengths based on a low-quencher-content device structure. Furthermore, the book reveals how mid-gap trap states are a universal feature in organic semiconductor donor–acceptor blends, unexpectedly contributing to charge generation and recombination, and having profound impact on the thermodynamic limit of organic photovoltaic devices. Featuring cutting-edge experimental observations supported with robust and novel theoretical arguments, this book delivers important new insight as to the underlying dynamics of exciton generation and diffusion, charge transfer state dissociation, and indeed the ultimate fate of photogenerated free carriers.

Optical Properties of Materials and Their Applications

Author : Jai Singh
Publisher : John Wiley & Sons
Page : 667 pages
File Size : 49,9 Mb
Release : 2020-01-07
Category : Science
ISBN : 9781119506317

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Optical Properties of Materials and Their Applications by Jai Singh Pdf

Provides a semi-quantitative approach to recent developments in the study of optical properties of condensed matter systems Featuring contributions by noted experts in the field of electronic and optoelectronic materials and photonics, this book looks at the optical properties of materials as well as their physical processes and various classes. Taking a semi-quantitative approach to the subject, it presents a summary of the basic concepts, reviews recent developments in the study of optical properties of materials and offers many examples and applications. Optical Properties of Materials and Their Applications, 2nd Edition starts by identifying the processes that should be described in detail and follows with the relevant classes of materials. In addition to featuring four new chapters on optoelectronic properties of organic semiconductors, recent advances in electroluminescence, perovskites, and ellipsometry, the book covers: optical properties of disordered condensed matter and glasses; concept of excitons; photoluminescence, photoinduced changes, and electroluminescence in noncrystalline semiconductors; and photoinduced bond breaking and volume change in chalcogenide glasses. Also included are chapters on: nonlinear optical properties of photonic glasses; kinetics of the persistent photoconductivity in crystalline III-V semiconductors; and transparent white OLEDs. In addition, readers will learn about excitonic processes in quantum wells; optoelectronic properties and applications of quantum dots; and more. Covers all of the fundamentals and applications of optical properties of materials Includes theory, experimental techniques, and current and developing applications Includes four new chapters on optoelectronic properties of organic semiconductors, recent advances in electroluminescence, perovskites, and ellipsometry Appropriate for materials scientists, chemists, physicists and electrical engineers involved in development of electronic materials Written by internationally respected professionals working in physics and electrical engineering departments and government laboratories Optical Properties of Materials and Their Applications, 2nd Edition is an ideal book for senior undergraduate and postgraduate students, and teaching and research professionals in the fields of physics, chemistry, chemical engineering, materials science, and materials engineering.

Optoelectronic Devices and Properties

Author : Oleg Sergiyenko
Publisher : BoD – Books on Demand
Page : 678 pages
File Size : 42,7 Mb
Release : 2011-04-19
Category : Technology & Engineering
ISBN : 9789533072043

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Optoelectronic Devices and Properties by Oleg Sergiyenko Pdf

Optoelectronic devices impact many areas of society, from simple household appliances and multimedia systems to communications, computing, spatial scanning, optical monitoring, 3D measurements and medical instruments. This is the most complete book about optoelectromechanic systems and semiconductor optoelectronic devices; it provides an accessible, well-organized overview of optoelectronic devices and properties that emphasizes basic principles.

Effects of Energetic Disorder on the Optoelectronic Properties of Organic Solar Cells

Author : Nikolaos Felekidis
Publisher : Linköping University Electronic Press
Page : 60 pages
File Size : 55,6 Mb
Release : 2018-09-10
Category : Electronic
ISBN : 9789176852712

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Effects of Energetic Disorder on the Optoelectronic Properties of Organic Solar Cells by Nikolaos Felekidis Pdf

Organic photovoltaics (OPVs) is a promising low-cost and environmental-friendly technology currently achieving 12-14% power conversion efficiency. Despite the extensive focus of the research community over the last years, critical mechanisms defining the performance of OPVs are still topics of debate. While energetic disorder is known to be characteristic of organic semiconductors in general, its potential role in OPV has received surprisingly little attention. In this thesis we investigate some aspects of the relation between energetic disorder and several optoelectronic properties of OPV. Charge carrier mobility is a key parameter in characterizing the performance of organic semiconductors. Analyzing the temperature dependence of the mobility is also an oftenused method to obtain (estimates for) the energetic disorder in the HOMO and LUMO levels of an organic semiconductor material. Different formalisms to extract and analyze mobilities from space charge limited conductivity (SCLC) experiments are reviewed. Surprisingly, the Murgatroyd-Gill analytical model in combination with the Gaussian disorder model in the Boltzmann limit yields similar mobilities and energetic disorders as a more elaborate drift-diffusion model with parametrized mobility functionals. Common analysis and measurement errors are discussed. All the models are incorporated in an automated analysis freeware tool. The open circuit voltage (Voc) has attracted considerable interest as the large difference between Voc and the bandgap is the main loss mechanism in bulk heterojunction OPVs. Surprisingly, in ternary devices composed of two donors and one acceptor, the Voc is not pinned to the shallowest HOMO but demonstrates a continuous tunability between the binary extremities. We show that this phenomenon can be explained with an equilibrium model where Voc is defined as the splitting of the quasi-Fermi levels of the photo-created holes and electrons in a common density of states accounting for the stoichiometry, i.e. the ratio of the donor materials and the broadening by Gaussian disorder. Evaluating the PCE, it is found that ternary devices do not offer advantages over binary unless the fill factor (FF) is increased at intermediate compositions, as a result of improved transport/recombination upon material blending. Stressing the importance of material intermixing to improve the performance, we found that the presence of an acceptor may drastically alter the mobility and energetic disorder of the donor and vice versa. The effect of different acceptors was studied in a ternary onedonor- two-acceptors system, where the unpredictable variability with composition of the energetic disorder in the HOMO and the LUMO explained the almost linear tunability of Voc. Designing binary OPVs based on the design rule that the energetic disorder can be reduced upon material blending, as we observed, can yield a relative PCE improvement of at least 20%. CT states currently play a key role in evaluating the performance of OPVs and CTelectroluminescence (CT-EL) is assumed to stem from the recombination of thermalized electron-hole pairs. The varying width of the CT-EL peak for different material combinations is intuitively expected to reflect the energetic disorder of the effective HOMO and LUMO. We employ kinetic Monte Carlo (kMC) CT-EL simulations, using independently measured disorder parameters as input, to calculate the ground-to-ground state (0-0) transition spectrum. Including the vibronic broadening according to the Franck Condon principle, we reproduce the width and current dependence of the measured CT-EL peak for a large number of donor-acceptor combinations. The fitted dominant phonon modes compare well with the values measured using the spectral line narrowing technique. Importantly, the calculations show that CT-EL originates from a narrow, non-thermalized subset of all available CT states, which can be understood by considering the kinetic microscopic process with which electron-hole pairs meet and recombine. Despite electron-hole pairs being strongly bound in organic materials, the charge separation process following photo-excitation is found to be extremely efficient and independent of the excitation energy. However, at low photon energies where the charges are excited deep in the tail of the DOS, it is intuitively expected for the extraction yield to be quenched. Internal Quantum Efficiency (IQE) experiments for different material systems show both inefficient and efficient charge dissociation for excitation close to the CT energy. This finding is explained by kinetic Monte Carlo simulations accounting for a varying degree of e-h delocalization, where strongly bound localized CT pairs (< 2nm distance) are doomed to recombine at low excitation energies while extended delocalization over 3-5nm yields an increased and energy-independent IQE. Using a single material parameter set, the experimental CT electroluminescence and absorption spectra are reproduced by the same kMC model by accounting for the vibronic progression of the calculated 0-0 transition. In contrast to CT-EL, CT-absorption probes the complete CT manifold. Charge transport in organic solar cells is currently modelled as either an equilibrium or a non-equilibrium process. The former is described by drift-diffusion (DD) equations, which can be calculated quickly but assume local thermal equilibrium of the charge carriers with the lattice. The latter is described by kMC models, that are time-consuming but treat the charge carriers individually and can probe all relevant time and energy scales. A hybrid model that makes use of the multiple trap and release (MTR) concept in combination with the DD equations is shown to describe both steady-state space charge limited conductivity experiments and non-equilibrium time-resolved transport experiments using a single parameter set. For the investigated simulations, the DD-MTR model is in good agreement with kMC and ~10 times faster. Steady-state mobilities from DD equations have been argued to be exclusively relevant for operating OPVs while charge carrier thermalization and non-equilibrium time-dependent mobilities (although acknowledged) can be disregarded. This conclusion, based on transient photocurrent experiments with ?s time resolution, is not complete. We show that non-equilibrium kMC simulations can describe the extraction of charge carriers from subps to 100 ?s timescales with a single parameter set. The majority of the fast charge carriers, mostly non-thermalized electrons, are extracted at time scales below the resolution of the experiment. In other words, the experiment resolves only the slower fraction of the charges, predominantly holes.

Introduction to Organic Electronic and Optoelectronic Materials and Devices

Author : Sam-Shajing Sun,Larry R. Dalton
Publisher : CRC Press
Page : 936 pages
File Size : 44,9 Mb
Release : 2008-05-29
Category : Technology & Engineering
ISBN : 9781420009194

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Introduction to Organic Electronic and Optoelectronic Materials and Devices by Sam-Shajing Sun,Larry R. Dalton Pdf

Reflecting rapid growth in research and development on organic/polymeric electronic and photonic materials and devices, Introduction to Organic Electronic and Optoelectronic Materials and Devices provides comprehensive coverage of the state-of-the-art in an accessible format. The book presents fundamentals, principles, and mechanisms complem

Optoelectronic Properties of Inorganic Compounds

Author : D. Max Roundhill,John P. Fackler Jr.
Publisher : Springer Science & Business Media
Page : 422 pages
File Size : 55,9 Mb
Release : 2013-03-09
Category : Science
ISBN : 9781475761016

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Optoelectronic Properties of Inorganic Compounds by D. Max Roundhill,John P. Fackler Jr. Pdf

This book is intended to offer the reader a snapshot of the field of optoelectronic materials from the viewpoint of inorganic chemists. The field of inorganic chemistry is transforming from one focused on the synthesis of compounds having interesting coordination numbers, structures, and stereochemistries, to one focused on preparing compounds that have potentially useful practical applica tions. Two such applications are in the area of optics and electronics. These are fields where the use of inorganic materials has a long history. As the field of microelectronics develops the demands on the performance of such materials increases, and it becomes necessary to discover compounds that will meet these demands. The field of optoelectronics represents a merging of the two disciplines. Its emergence is a natural one because many of the applications involve both of these properties, and also because the electronic structure of a metal compound that confers novel optical properties is often one that also influences its electron transfer and conductivity characteristics. Two of the more important growth areas that have led to these developments are communications and medicine. Within the communications field there is the microelectronics that is involved in information storage and transmittal, some of which will be transferred into the optical regime. Within the medical field there are chemical probes that transmit analytical information from an in vivo environment. This information needs to be readily accessible from an external site, and then quickly converted into images or data that yield accurate and inexpensive diagnoses.

Handbook of Organic Materials for Optical and (Opto)Electronic Devices

Author : Oksana Ostroverkhova
Publisher : Elsevier
Page : 832 pages
File Size : 41,8 Mb
Release : 2013-08-31
Category : Technology & Engineering
ISBN : 9780857098764

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Handbook of Organic Materials for Optical and (Opto)Electronic Devices by Oksana Ostroverkhova Pdf

Small molecules and conjugated polymers, the two main types of organic materials used for optoelectronic and photonic devices, can be used in a number of applications including organic light-emitting diodes, photovoltaic devices, photorefractive devices and waveguides. Organic materials are attractive due to their low cost, the possibility of their deposition from solution onto large-area substrates, and the ability to tailor their properties. The Handbook of organic materials for optical and (opto)electronic devices provides an overview of the properties of organic optoelectronic and nonlinear optical materials, and explains how these materials can be used across a range of applications. Parts one and two explore the materials used for organic optoelectronics and nonlinear optics, their properties, and methods of their characterization illustrated by physical studies. Part three moves on to discuss the applications of optoelectronic and nonlinear optical organic materials in devices and includes chapters on organic solar cells, electronic memory devices, and electronic chemical sensors, electro-optic devices. The Handbook of organic materials for optical and (opto)electronic devices is a technical resource for physicists, chemists, electrical engineers and materials scientists involved in research and development of organic semiconductor and nonlinear optical materials and devices. Comprehensively examines the properties of organic optoelectronic and nonlinear optical materials Discusses their applications in different devices including solar cells, LEDs and electronic memory devices An essential technical resource for physicists, chemists, electrical engineers and materials scientists

Organic Semiconductors for Optoelectronics

Author : SachchidaNand Shukla
Publisher : Arcler Press
Page : 0 pages
File Size : 46,6 Mb
Release : 2022-12
Category : Electronic
ISBN : 1774695308

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Organic Semiconductors for Optoelectronics by SachchidaNand Shukla Pdf

"The book ""Organic Semiconductors for Optoelectronics"" provides a thorough analysis of the topic and illustrated examples of organic semiconductors in various applications. Organic semiconductors, which are composed of polymers or -bonded molecules, may conduct when charge carriers are inserted into them. The backbone of the polymeric chain containing the conjugated system of bonds enables charge transfer through the polymer chain.This textbook offers the teachers, researchers, and students an easy and thorough explanation of the principles, guidelines, and, particularly, the complicated instrumentation techniques used in optoelectronics. It discusses some recent advances in the study of the optoelectronic properties of organic semiconductors while also summarizing the fundamental ideas. Examples and applications of electronic and optoelectronic organic materials are also discussed in the book. This handbook thoroughly covers different aspects of organic semiconductors present today. Even a reader with no prior knowledge should be able to grasp the fundamental concepts of organic semiconductors after reading this book.

Interface Controlled Organic Thin Films

Author : Horst-Günter Rubahn,Helmut Sitter,Giles Horowitz,Katharina Al-Shamery
Publisher : Springer Science & Business Media
Page : 208 pages
File Size : 50,5 Mb
Release : 2009-06-12
Category : Technology & Engineering
ISBN : 9783540959304

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Interface Controlled Organic Thin Films by Horst-Günter Rubahn,Helmut Sitter,Giles Horowitz,Katharina Al-Shamery Pdf

Organic semiconductors are a central topic of advanced materials research. The book is aiming at bridging the gap between the development and production of devices and basic research on thin film characterisation using cutting-edge techniques in surface and interface science. Topics involve organic molecular-based sensors; interfaces in organic diodes and transistors; mobility in organic field effect transistors and space charge problems; integration of optoelectronic nanostructures; nonlinear optical properties of organic nanostructures; the wetting layer problem; how to get from functionalized molecules to nanoaggregates; optical, electrical and mechanical properties of organic nanofibers as well; as near field investigations of organic thin films.

World Scientific Handbook Of Organic Optoelectronic Devices (Volumes 1 & 2)

Author : Anonim
Publisher : World Scientific
Page : 908 pages
File Size : 47,5 Mb
Release : 2018-06-29
Category : Technology & Engineering
ISBN : 9789813239852

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World Scientific Handbook Of Organic Optoelectronic Devices (Volumes 1 & 2) by Anonim Pdf

Organic (opto)electronic materials have received considerable attention due to their applications in perovskite and flexible electronics, OPVs and OLEDs and many others. Reflecting the rapid growth in research and development of organic (opto)electronic materials over the last few decades, this book provides a comprehensive coverage of the state of the art in an accessible format. It presents the most widely recognized fundamentals, principles, and mechanisms along with representative examples, key experimental data, and over 200 illustrative figures.

Organic Semiconductor Heterojunctions and Its Application in Organic Light-Emitting Diodes

Author : Dongge Ma,Yonghua Chen
Publisher : Springer
Page : 153 pages
File Size : 49,6 Mb
Release : 2017-09-21
Category : Science
ISBN : 9783662536957

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Organic Semiconductor Heterojunctions and Its Application in Organic Light-Emitting Diodes by Dongge Ma,Yonghua Chen Pdf

This book systematically introduces the most important aspects of organic semiconductor heterojunctions, including the basic concepts and electrical properties. It comprehensively discusses the application of organic semiconductor heterojunctions as charge injectors and charge generation layers in organic light-emitting diodes (OLEDs). Semiconductor heterojunctions are the basis for constructing high-performance optoelectronic devices. In recent decades, organic semiconductors have been increasingly used to fabricate heterojunction devices, especially in OLEDs, and the subject has attracted a great deal of attention and evoked many new phenomena and interpretations in the field. This important application is based on the low dielectric constant of organic semiconductors and the weak non-covalent electronic interactions between them, which means that they easily form accumulation heterojunctions. As we know, the accumulation-type space charge region is highly conductive, which is an important property for highly efficient charge generation in their application as charge injector and charge generation layer in OLEDs. This book serves as a valuable reference for researchers and as a textbook for graduate students focusing on the study and development of OLED for display and lighting.

Optoelectronic Organic-Inorganic Semiconductor Heterojunctions

Author : Ye Zhou
Publisher : CRC Press
Page : 382 pages
File Size : 42,7 Mb
Release : 2021-01-19
Category : Technology & Engineering
ISBN : 9781000325713

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Optoelectronic Organic-Inorganic Semiconductor Heterojunctions by Ye Zhou Pdf

Optoelectronic Organic-Inorganic Semiconductor Heterojunctions summarizes advances in the development of organic-inorganic semiconductor heterojunctions, points out challenges and possible solutions for material/device design, and evaluates prospects for commercial applications. Introduces the concept and basic mechanism of semiconductor heterojunctions Describes a series of organic-inorganic semiconductor heterojunctions with desirable electrical and optical properties for optoelectronic devices Discusses typical devices such as solar cells, photo-detectors, and optoelectronic memories Outlines the materials and device challenges as well as possible strategies to promote the commercial translation of semiconductor heterojunctions-based optoelectronic devices Aimed at graduate students and researchers working in solid-state materials and electronics, this book offers a comprehensive yet accessible view of the state of the art and future directions.