Organic Catalysis For Polymerisation

Author : Andrew Dove,Haritz Sardon,Stefan Naumann
Publisher : Royal Society of Chemistry
Page : 648 pages
File Size : 54,9 Mb
Release : 2018-11-16
Category : Technology & Engineering
ISBN : 9781788011846

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Organic Catalysis for Polymerisation by Andrew Dove,Haritz Sardon,Stefan Naumann Pdf

In recent years polymerisation using organocatalysts has become an appealing alternative to more traditional metal-based catalysts. Conferring numerous advantages including low cost and ease of use, as well as the ability to precisely control the synthesis of advanced polymer structures, organocatalysts are increasingly used in polymer synthesis. Organic Catalysis for Polymerisation provides a holistic overview of the field, covering all process in the polymer synthesis pathway that are catalysed by organic catalysts. Sub-divided into two key sections for ease of use, the first focuses on recent developments in catalysis and the applications of catalysts to the full range of polymerisations that they have been utilised in; the second concerning monomers, arranges the field by monomer type and polymerisation mechanism. The book will therefore, provide a complimentary view of the field, providing both an overview of state-of-the-art catalyst development and also the best methodologies available to create specific polymer types. Edited by leading figures in the field and featuring contributions from researchers across the globe, this title will serve as an excellent reference for postgraduate students and researchers in both academia and industry interested in polymer chemistry, organic chemistry, catalysis and materials science.

Author : Andrew Dove,Haritz Sardon,Stefan Naumann
Publisher : Unknown
Page : 648 pages
File Size : 51,7 Mb
Release : 2019
Category : Catalysis
ISBN : 1523123095

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Organic Catalysis for Polymerisation by Andrew Dove,Haritz Sardon,Stefan Naumann Pdf

Author : Gian Paolo Chiusoli,Peter M Maitlis
Publisher : Royal Society of Chemistry
Page : 624 pages
File Size : 42,9 Mb
Release : 2019-04-05
Category : Science
ISBN : 9781788018418

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Metal-catalysis in Industrial Organic Processes by Gian Paolo Chiusoli,Peter M Maitlis Pdf

Catalysis underpins most modern industrial organic processes. It has become an essential tool in creating a 'greener' chemical industry by replacing more traditional stoichiometric reactions, which have high energy consumption and high waste production, with mild processes which increasingly resemble Nature's enzymes. Metal-Catalysis in Industrial Organic Processes considers the major areas of the field and discusses the logic of using catalysis in industrial processes. The book provides information on oxidation, hydrogenation, carbonylation, C-C bond formation, metathesis and polymerization processes, as well as on the mechanisms involved. In addition two appendices offer a concise treatment of homogeneous and heterogenous catalysis. Numerous exercises referring to problems of catalytic processes, and research perspectives complete the book. This definitive reference source, written by practising experts in the field, provides detailed and up-to-date information on key aspects of metal catalysis.

Author : V. Dragutan,R. Streck
Publisher : Elsevier
Page : 1292 pages
File Size : 45,5 Mb
Release : 2000-06-26
Category : Technology & Engineering
ISBN : 0080528627

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Catalytic Polymerization of Cycloolefins by V. Dragutan,R. Streck Pdf

This book covers the most important topics concerning cationic Ziegler-Natta and ring-opening metathesis polymerization of cycloolefins. The work describes the major pathways that cycloolefins can follow under the action of specific catalytic systems, essentially vinyl and ring-opening polymerization, both reaction types allowing the manufacture of distinct products with wide applicability in modern technologies. The comprehensive data available on this subject are logically and systematically selected and reviewed throughout 18 chapters, according to the basic catalytic processes involved, types of monomers and catalysts employed, reaction conditions and application fields. The modern trends in design of chiral metallocene catalysts, well-defined living metathesis catalysts, catalysts tolerant toward functionalities and water systems are highlighted. The book discusses in detail the relevant aspects of these processes including reaction thermodynamics, kinetics, mechanisms and stereochemistry and correlates the structure of produced polymers with their chemical and physical-mechanical properties. Related important topics include Ziegler-Natta polymerization of olefins and dienes, atom transfer radical polymerization of vinyl compounds, metathesis of olefins and acetylenes, acyclic diene metathesis reaction, carbonyl olefination reaction, metathesis polymerization of acetylenes, metathesis degradation of polymers and ring-opening polymerization of heterocycles. Special emphasis is laid upon the manufacture of commerical products, new polymers and copolymers of potential interest for industry and design and synthesis of speciality polymers with particular structures and architectures and desired properties. The book critically evaluates the most recent achievements reported in this field and outlines the modern trends on the research and application of the catalytic processes for cycloolefin polymerization. For the first time, comprehensive information about the published data on the subject up to now is provided for both academic and industrial researchers working in the areas of polymer chemistry, organic and organometallic chemistry, surface science and catalysis, petrochemistry and chemical engineering. This stimulating book offers an enlightening introduction and a quick documentation on the subject as well as a solid background in this field. Moreover, the work offers a wealth of useful information for specialists applying polymers in various scientific and industrial areas.

Author : Michael R. Buchmeiser
Publisher : John Wiley & Sons
Page : 582 pages
File Size : 53,8 Mb
Release : 2006-03-06
Category : Science
ISBN : 9783527605682

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Polymeric Materials in Organic Synthesis and Catalysis by Michael R. Buchmeiser Pdf

This is the first book to describe the synthesis and characterization of the materials used in polymer-supported synthesis. The authors cover not only the classical polymers and their use in homogeneous, heterogeneous and micellar catalysis, but also such new developments as "enzyme-labile linkers", illustrating how to simplify the purification process and avoid waste. The result is a wealth of useful information -- for beginners and experts alike - in one handy reference, removing the need for difficult and time-consuming research among the literature.

Author : Walter Kaminsky
Publisher : Springer Science & Business Media
Page : 674 pages
File Size : 53,6 Mb
Release : 2012-12-06
Category : Technology & Engineering
ISBN : 9783642601781

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Metalorganic Catalysts for Synthesis and Polymerization by Walter Kaminsky Pdf

45 years after the discovery of transition metals and organometallics as cocatalysts for the polymerization of olefins and for organic synthesis, these compounds have not lost their fascination. The birthday of Karl Ziegler, the great pioneer in this metalorganic catalysis, is now 100 years ago. Polyolefins and polydienes produced by Ziegler-Natta catalysis are the most important plastics and elastomers. New impulses for the polymerization of olefins have been brought about by highly active metallocenes and other single site catalysts. Just by changing the ligands of the organometallic compounds, the structure of the polymers produced can be tailored in a wide manner. In invited lectures and posters, relevant aspects of the metalorganic catalysts for synthesis and polymerization are discussed in this book. This includes mechanism and kinetics, stereochemistry, material properties, and industrial applications.

Author : Anatoly D. Pomogailo
Publisher : CRC Press
Page : 424 pages
File Size : 42,6 Mb
Release : 2020-08-18
Category : Science
ISBN : 9781000124712

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Catalysis by Polymer-Immobilized Metal Complexes by Anatoly D. Pomogailo Pdf

Deals with a new and promising field developed during the last two decades on the boundary between homogeneous and heterogeneous catalysis. This book presents general information on catalysis for a wide range of organic reactions, e.g., hydrogenation and oxidation reactions, and polymerization transformations. Special attention is paid to electro- and photochemical stimulation of catalytic processes in the presence of immobilized metal complexes. Other topics covered are the quantitative data on the comparison of catalyses by mobile and immobilized metal complexes; main factors affecting the activity of these catalytic systems and methods of optimizing their control; and specific problems of catalysis by fixed complexes (e.g., ligand exchange and electron transfer in metal polymer systems, macromolecular effects and polyfunctional catalysis).

Author : Walter Kaminsky
Publisher : Springer Science & Business Media
Page : 674 pages
File Size : 41,8 Mb
Release : 2012-12-06
Category : Technology & Engineering
ISBN : 9783642601781

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Metalorganic Catalysts for Synthesis and Polymerization by Walter Kaminsky Pdf

45 years after the discovery of transition metals and organometallics as cocatalysts for the polymerization of olefins and for organic synthesis, these compounds have not lost their fascination. The birthday of Karl Ziegler, the great pioneer in this metalorganic catalysis, is now 100 years ago. Polyolefins and polydienes produced by Ziegler-Natta catalysis are the most important plastics and elastomers. New impulses for the polymerization of olefins have been brought about by highly active metallocenes and other single site catalysts. Just by changing the ligands of the organometallic compounds, the structure of the polymers produced can be tailored in a wide manner. In invited lectures and posters, relevant aspects of the metalorganic catalysts for synthesis and polymerization are discussed in this book. This includes mechanism and kinetics, stereochemistry, material properties, and industrial applications.

Author : Shiro Kobayashi
Publisher : John Wiley & Sons
Page : 606 pages
File Size : 44,5 Mb
Release : 1997-08-15
Category : Science
ISBN : UOM:39015039915007

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Catalysis in Precision Polymerization by Shiro Kobayashi Pdf

This book provides a comprehensive survey of the entire field of catalysis in polymer synthesis covering the majority of essential aspects from basic organic, organometallic and bio-chemistry to industrial production. Particular emphasis is placed on "precision polymerization," where the catalyst plays a key role in the fabrication of innovative polymers. Precision polymerization enables the production of polymers with precisely controlled structures, molecular weight, distribution and stereochemistry, free from defects.

Author : Dave J. Adams,Paul J. Dyson,Stewart J. Tavener
Publisher : John Wiley & Sons
Page : 268 pages
File Size : 43,9 Mb
Release : 2005-09-01
Category : Science
ISBN : 9780470869659

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Chemistry In Alternative Reaction Media by Dave J. Adams,Paul J. Dyson,Stewart J. Tavener Pdf

At a time when environmental concerns are increasing, it's important that chemical processes are as environmentally friendly as possible. This book outlines various methods for producing inorganic and organic solvents without the use of traditional solvents that can have detrimental effects on the environment. This is the first book to give extensive and exclusive coverage to the topic Includes important environmental issues This book will appeal to anyone with an interest in organic synthesis; reaction chemistry; catalysis; and process development, and to undergraduate and graduate students of organic chemistry; catalysis; green chemistry; clean technology and environmental chemistry courses.

Author : Robert H. Grubbs,Daniel J. O'Leary
Publisher : John Wiley & Sons
Page : 744 pages
File Size : 45,9 Mb
Release : 2015-02-18
Category : Science
ISBN : 9783527694020

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Handbook of Metathesis, Volume 2 by Robert H. Grubbs,Daniel J. O'Leary Pdf

The second edition of the "go-to" reference in this field is completely updated and features more than 80% new content, with emphasis on new developments in the field, especially in industrial applications. No other book covers the topic in such a comprehensive manner and in such high quality. Edited by the Nobel laureate R. H. Grubbs and D. J. O´Leary, Volume 2 of the 3-volume work focusses on applications in organic synthesis. With a list of contributors that reads like a "Who's-Who" of metathesis, this is an indispensable one-stop reference for chemists in academia and industry. View the set here - http://www.wiley.com/WileyCDA/WileyTitle/productCd-3527334246.html Other available volumes: Volume 1: Catalyst Development and Mechanism, Editors: R. H. Grubbs and A. G. Wenzel - http://www.wiley.com/WileyCDA/WileyTitle/productCd-3527339485.html Volume 3: Polymer Synthesis, Editors: R. H. Grubbs and E. Khosravi - http://www.wiley.com/WileyCDA/WileyTitle/productCd-3527339507.html

Author : Robert W. Lenz
Publisher : Unknown
Page : 864 pages
File Size : 42,5 Mb
Release : 1967
Category : Chemistry, Organic
ISBN : STANFORD:36105006376375

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Organic Chemistry of Synthetic High Polymers by Robert W. Lenz Pdf

Author : M.S. Matar,M.J. Mirbach,H.A. Tayim
Publisher : Springer Science & Business Media
Page : 209 pages
File Size : 49,6 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789400911772

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Catalysis in Petrochemical Processes by M.S. Matar,M.J. Mirbach,H.A. Tayim Pdf

The field of petrochemicals started some years ago with the simple addition reaction of water to propylene for the production of isopropyl alcohol. Currently, the petrochemical industry has become a multi-billion dollar enterprise which encompasses a wide field of chemical products. Almost all the basic organic reactions such as hydrogenation, alkylation, substitution, polymerization, etc. are utilized for the production of these chemicals. It may not, however, have been possible to establish this huge industry without the use of different catalysts. In other words, the great advancements in the catalytic area have supported the vast developments in the petrochemical field. In this book, we have adopted the idea of discussing the petrochemical industry from the point of view of reactants' activities and susceptibilities toward different catalysts. The book is thus classified according to the reaction type. This will eriable students and other users of the book to base their understanding of the petrochemical field on the fundamental principles learned in chemistry. How ever, the first chapter is aimed at establishing some basic facts on the petro chemical industry and its major uses. It discusses, without going into details, the raw materials used, the intermediates and the downstream products. The next eight chapters discuss in some detail the main reactions and the catalysts used for the production of chemicals and polymers from petroleum. The last chapter is devoted to a discussion of some of the practical techniques used in the catalytic field.

Author : Yavuz Imamogammalu,Birgül Zümreogammalu-Karan,Allan J. Amass
Publisher : Springer Science & Business Media
Page : 567 pages
File Size : 41,6 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789401133289

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Olefin Metathesis and Polymerization Catalysts by Yavuz Imamogammalu,Birgül Zümreogammalu-Karan,Allan J. Amass Pdf

Olefin metathesis reaction can be considered as one of the most successful organic reactions with many applications in the low molecular weight range and also in the polymer field. The use of catalysts with their selective and effective transformation properties in olefin metathesis I polymerization systems is a growing interest. There has been great effort and competition in developing active and commercially useful catalysts. The main aim of this ASI was to gather several research groups and also the people from industry. to present existing knowledge and latest results in the field. A wide range of topics through homogeneous and heterogeneous aspects have been considered. Attention has been drawn to the metal-carbene and metallacyclobutane complexes as active species, the initiation mechanisms, the stereochemistry and thermodynamics of these reactions. New catalytic systems for the metathesis of alkenes and alkynes and fot' ring opening polymeriZation I block copolymerization reactions have been introduced. Spectroscopic studies for the characteriZation of catalysts, simulation studies explaining the function of chain carrier species and polymer degradation have also been covered. A detailed industrial report concerning the patents and applications in olefin metathesis I cyc1001efin polymerization area, fabrication and derivation has been presented. This volume contains the main lectures and seminars given at the NATO Advanced Study Institute on " Olefin Metathesis and Polymerization Catalysts: Synthesis, Mechanism and Utilization", held at Akcay. Babkesir. Turkey between 10th and 22nd September 1989.

Author : Ray Hoff,Robert T. Mathers
Publisher : John Wiley & Sons
Page : 599 pages
File Size : 49,6 Mb
Release : 2010-09-16
Category : Technology & Engineering
ISBN : 9780470504420

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Handbook of Transition Metal Polymerization Catalysts by Ray Hoff,Robert T. Mathers Pdf

A one-stop resource for understanding and applying polymerization catalysts An edited volume featuring contributions from leading researchers, the Handbook of Transition Metal Polymerization Catalysts covers the design and synthesis of catalysts, and their applications in synthesis of polymers. Dealing with those polymerization catalysts that afford commercially acceptable yields of polymer with respect to catalyst mass and promising newer catalysts, this practical reference provides polymer and organic chemists with a comprehensive overview of the known methods for developing and applying these important catalysts. With both recent advances and historically important catalysts, the subjects covered in this text include: Metal alkyls and other compounds that function as co-catalysts with a large number of catalysts The varieties of porous silica either necessary or valuable in certain catalyst formulations Catalyst scale-up and commercialization Copper catalysts for olefin polymerization Morphology control Along with the above topics, the Handbook of Transition Metal Polymerization Catalysts provides tables of valuable data to assist in reproducing a synthesis or applying the knowledge to a new problem. Polymerization reactivities, polymer properties, monomer and solvent purity requirements, molecular weights, distribution, and reactivity ratios are also covered. The Handbook of Transition Metal Polymerization Catalysts offers an excellent one-stop resource for understanding and applying polymerization catalysts.