Organic Reactions In Aqueous Media

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Comprehensive Organic Reactions in Aqueous Media

Chao-Jun Li,Tak-Hang Chan
Comprehensive Organic Reactions in Aqueous Media Book PDF

Author : Chao-Jun Li,Tak-Hang Chan
Publisher : John Wiley & Sons
Page : 435 pages
File Size : 47,7 Mb
Release : 2007-06-04
Category : Science
ISBN : 9780470131435

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Comprehensive Organic Reactions in Aqueous Media by Chao-Jun Li,Tak-Hang Chan Pdf

An extensive update of the classic reference on organic reactions in water Published almost a decade ago, the first edition has served as the guide for research in this burgeoning field. Due to the cost, safety, efficiency, and environmental friendliness of water as a solvent, there are many new applications in industry and academic laboratories. More than forty percent of this extensively updated second edition covers new reactions. For ease of reference, it is organized by functional groups. A core reference, Comprehensive Organic Reactions in Aqueous Media, Second Edition: * Provides the most comprehensive coverage of aqueous organicreactions available * Covers the basic principles and theory and progresses to applications * Includes alkanes, alkenes, aromatics, electrophilic substitutions, carbonyls, alpha, beta-unsaturated carbonyls, carbon-nitrogen bonds, organic halides, pericyclic reactions, photochemical reactions, click chemistry, and multi-step syntheses? * Provides examples of applications in industry This is the premier reference for chemists and chemical engineers in industry or research, as well as for students in advanced-level courses.

Organic Reactions in Water

U. Marcus Lindstrom
Organic Reactions in Water Book PDF

Author : U. Marcus Lindstrom
Publisher : John Wiley & Sons
Page : 424 pages
File Size : 40,5 Mb
Release : 2008-04-15
Category : Science
ISBN : 9780470994245

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Organic Reactions in Water by U. Marcus Lindstrom Pdf

Volatile organic solvents are the normal media used in both research scale and industrial scale synthesis of organic chemicals. Their environmental impact is significant, however, and so the development of alternative reaction media has become of great interest. Developments in the use of water as a solvent for organic synthesis have reached the point where it could now be considered a viable solvent for many organic reactions. Organic Reactions in Water demonstrates the underlying principles of using water as a reaction solvent and, by reference to a range of reaction types and systems, it’s effective use in synthetic organic chemistry. Written by an internationally respected team of contributors, and with a strong focus on the practical use of water as a reaction medium, this book illustrates the enormous potential of water for the development of new and unique chemistries and synthetic strategies, while at the same time offering a much reduced environmental impact.

Organic Reactions in Aqueous Media

Chao-Jun Li,Tak-Hang Chan
Organic Reactions in Aqueous Media Book PDF

Author : Chao-Jun Li,Tak-Hang Chan
Publisher : Wiley-Interscience
Page : 224 pages
File Size : 41,9 Mb
Release : 1997-08-19
Category : Science
ISBN : UCAL:B4378728

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Organic Reactions in Aqueous Media by Chao-Jun Li,Tak-Hang Chan Pdf

From cost and safety to synthetic efficiency and environmental friendliness, water has many potential advantages as a solvent for organic reactions. This book examines different aspects of organic reactions in water, enabling readers to gain an essential understanding of current thinking on a range of reaction types and techniques. Beginning with basic theory and progressing to synthetic applications, Organic Reactions in Aqueous Media is an ideal platform for both advanced-level study and practical research. It covers these key areas: * Fundamental properties of water * Pericyclic reactions-including Diels-Alder reactions * Nucleophilic additions and substitutions * Metal mediated reactions * Transition metal catalyzed reactions * Oxidations and reductions * Industrial applications

Organic Synthesis in Water

P.A. Grieco
Organic Synthesis in Water Book PDF

Author : P.A. Grieco
Publisher : Springer Science & Business Media
Page : 321 pages
File Size : 48,7 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789401149501

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Organic Synthesis in Water by P.A. Grieco Pdf

The use of water as a medium for promoting organic reactions has been rather neglected in the development of organic synthesis, despite the fact that it is the solvent in which almost all biochemical processes take place. Chemists have only recently started to appreciate the enormous potential water has to offer in the development of new synthetic reactions and strategies, where it can offer benefits in both unique chemistry and reduced environmental impact. In this new book, the editor, well known for his contribution to the development of water as a useful medium in synthetic organic chemistry, has assembled an international team of authors, themselves at the forefront of research into the use of the unique properties of water carrying out organic transformations, to provide a timely and concise overview of current research. By focusing on the practical use of water in synthetic organic chemistry, and with the concern for the use of solvents in organic chemistry, professional chemists, particularly those involved in industrial research and development, will find this book an essential guide to the current state of the art, and a useful starting point in their own research. Academic chemists, including postgraduate and advanced undergraduate students, will find this book an invaluable guide to this exciting and important area of chemistry.

Radical Reactions in Aqueous Media

V. Tamara Perchyonok
Radical Reactions in Aqueous Media Book PDF

Author : V. Tamara Perchyonok
Publisher : Royal Society of Chemistry
Page : 142 pages
File Size : 40,5 Mb
Release : 2010
Category : Science
ISBN : 9781849730006

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Radical Reactions in Aqueous Media by V. Tamara Perchyonok Pdf

Radical Reactions in Aqueous Media provides a step-wise introduction, taking students from the basic principles of radical reactions through to their applications in industry and their role in biological and environmental processes."--Jacket.

Chemistry In Alternative Reaction Media

Dave J. Adams,Paul J. Dyson,Stewart J. Tavener
Chemistry In Alternative Reaction Media Book PDF

Author : Dave J. Adams,Paul J. Dyson,Stewart J. Tavener
Publisher : John Wiley & Sons
Page : 268 pages
File Size : 52,5 Mb
Release : 2005-09-01
Category : Science
ISBN : 9780470869659

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Chemistry In Alternative Reaction Media by Dave J. Adams,Paul J. Dyson,Stewart J. Tavener Pdf

At a time when environmental concerns are increasing, it's important that chemical processes are as environmentally friendly as possible. This book outlines various methods for producing inorganic and organic solvents without the use of traditional solvents that can have detrimental effects on the environment. This is the first book to give extensive and exclusive coverage to the topic Includes important environmental issues This book will appeal to anyone with an interest in organic synthesis; reaction chemistry; catalysis; and process development, and to undergraduate and graduate students of organic chemistry; catalysis; green chemistry; clean technology and environmental chemistry courses.

Enzymatic Reactions in Organic Media

Ari Koskinen,A. Klibanov
Enzymatic Reactions in Organic Media Book PDF

Author : Ari Koskinen,A. Klibanov
Publisher : Springer Science & Business Media
Page : 338 pages
File Size : 50,9 Mb
Release : 1995-12-31
Category : Science
ISBN : 0751402591

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Enzymatic Reactions in Organic Media by Ari Koskinen,A. Klibanov Pdf

The outlook of organic synthesis has changed many times during its tractable history. The initial focus on the synthesis of substances typical of living matter, exemplified by the first examples of organic chemistry through the synthesis of urea from inorganic substances by Liebig, was accepted as the birth of organic chemistry, and thus also of organic synthesis. Although the early developments in organic synthesis closely followed the pursuit of molecules typical in nature, towards the end of the 19th century, societal pressures placed higher demands on chemical methods appropriate for the emerging age of industrialization. This led to vast amounts of information being generated through the discovery of synthetic reactions, spectroscopic techniques and reaction mechanisms. The basic organic functional group transformations were discovered and improved during the early part of this century. Reaction mechanisms were elucidated at a growing pace, and extremely powerful spectroscopic tools, such as infrared, nuclear magnetic resonance and mass spectrometry were introduced as everyday tools for a practising organic chemist. By the 1950s, many practitioners were ready to agree that almost every molecule could be syn thesized. Some difficult stereochemical problems were exceptions; for example Woodward concluded that erythromycin was a "hopelessly complex target". This frustration led to a hectic phase of development of new and increasingly more ingenious protecting group strategies and functional group transformations, and also saw the emergence of asymmetric synthesis.

Aqueous Organometallic Catalysis

Ferenc Joó
Aqueous Organometallic Catalysis Book PDF

Author : Ferenc Joó
Publisher : Springer Science & Business Media
Page : 302 pages
File Size : 40,8 Mb
Release : 2006-04-11
Category : Science
ISBN : 9780306475108

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Aqueous Organometallic Catalysis by Ferenc Joó Pdf

Over the past 20 years aqueous organometallic catalysis has found applications in small- scale organic synthesis in the laboratory, as well as in the industrial production of chemicals with a combined output close to one million tons per year. Aqueous/organic two-phase reactions allow easy product-catalyst separation and full catalyst recovery which mean clear benefits not only in economic but also in environmental and green chemistry contexts. Instead of putting together a series of expert reviews of specialized fields, this book attempts to give a comprehensive yet comprehensible description of the various catalytic transformations in aqueous systems as seen by an author who has been working on aqueous organometallic catalysis since its origin. Emphasis is put on the discussion of differences between related non-aqueous and aqueous processes due to the presence of water. The book will be of interest to experts and students working in catalysis, inorganic chemistry or organic synthesis, and may serve as a basis for advanced courses.

Organic Radical Reactions in Water and Alternative Media

J. Alberto Postigo
Organic Radical Reactions in Water and Alternative Media Book PDF

Author : J. Alberto Postigo
Publisher : Unknown
Page : 0 pages
File Size : 46,9 Mb
Release : 2011
Category : Chemical bonds
ISBN : 1612096484

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Organic Radical Reactions in Water and Alternative Media by J. Alberto Postigo Pdf

This book discusses and presents current research in the study of radical reactions of synthetic utility in water and non-conventional media. Emphasis is made throughout the book on synthetic methods, not covering other important aspects of radical chemistry in water, such as computational studies aimed at clarifying the powerful effect of water as a selective solvating media for radical chemistry, and reasons for the higher selectivity and reaction yields when water is employed as a solvent.

Green Organic Chemistry in Lecture and Laboratory

Andrew P. Dicks
Green Organic Chemistry in Lecture and Laboratory Book PDF

Author : Andrew P. Dicks
Publisher : CRC Press
Page : 298 pages
File Size : 45,7 Mb
Release : 2016-04-19
Category : Science
ISBN : 9781439840771

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Green Organic Chemistry in Lecture and Laboratory by Andrew P. Dicks Pdf

The last decade has seen a huge interest in green organic chemistry, particularly as chemical educators look to "green" their undergraduate curricula. Detailing published laboratory experiments and proven case studies, this book discusses concrete examples of green organic chemistry teaching approaches from both lecture/seminar and practical perspe

Modern Solvents in Organic Synthesis

Paul Knochel
Modern Solvents in Organic Synthesis Book PDF

Author : Paul Knochel
Publisher : Springer
Page : 210 pages
File Size : 54,8 Mb
Release : 2003-07-01
Category : Science
ISBN : 9783540486640

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Modern Solvents in Organic Synthesis by Paul Knochel Pdf

In recent years the choice of a given solvent for performing a reaction has become increasingly important. More and more, selective reagents are used for chemical transformations and the choice of the solvent may be determining for reaching high reaction rates and high selectivities. The toxicity and recycling considerations have also greatly influenced the nature of the solvents used for industrial reactions. Thus, the development of reactions in water is not only important on the laboratory scale but also for industrial applications. The p- formance of metal-catalyzed reactions in water for example has led to several new hydrogenation or hydroformylation procedures with important industrial applications. The various aspects of organic chemistry in water will be prese- ed in this book. Recently, novel reaction media such as perfluorinated solvents or supercritical carbon dioxide has proven to have unique advantages leading to more practical and more efficient reactions. Especially with perfluorinated solvents, new biphasic catalyses and novel approaches to perform organic reactions have been developed. These aspects will be examined in detail in this volume. Finally, the performance of reactions in the absence of solvents will show practical alternatives for many reactions. More than ever before, the choice of the solvent or the solvent system is ess- tial for realizing many chemical transformations with the highest efficiency. This book tries to cover the more recent and important new solvents or solvent systems for both academic and industrial applications.

The Diels-Alder Reaction

Francesco Fringuelli,Aldo Taticchi
The Diels Alder Reaction Book PDF

Author : Francesco Fringuelli,Aldo Taticchi
Publisher : John Wiley & Sons
Page : 364 pages
File Size : 44,9 Mb
Release : 2002-01-21
Category : Science
ISBN : 047180343X

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The Diels-Alder Reaction by Francesco Fringuelli,Aldo Taticchi Pdf

70 Jahre Forschung an der Diels-Alder-Reaktion: Dieses Buch fasst die wichtigsten und beeindruckendsten Ergebnisse in einzigartiger Weise zusammen! Zunächst werden die Grundprinzipien der Reaktion klar und verständlich anhand übersichtlicher Graphiken erläutert. Spezielle Vorschriften und gegebenenfalls ihre industrielle Umsetzung werden anschließend erklärt. Einen Schwerpunkt bilden auch physikalische und katalytische Verfahren zur Steigerung der Selektivität der Reaktion. Cycloadditionen in konventionellen und unkonventionellen Medien werden vorgestellt. Mit über 1.000 Literaturverweisen!

Solvents as Reagents in Organic Synthesis

Xiao-Feng Wu
Solvents as Reagents in Organic Synthesis Book PDF

Author : Xiao-Feng Wu
Publisher : John Wiley & Sons
Page : 552 pages
File Size : 40,5 Mb
Release : 2018-01-03
Category : Science
ISBN : 9783527341962

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Solvents as Reagents in Organic Synthesis by Xiao-Feng Wu Pdf

Written by highly renowned and experienced authors, this is the only reference on the application of solvents as reagents. Clearly structured, the text describes various methods for the activation and reaction of these small molecules, highlighting the synthetic opportunities as well as process-oriented advantages. To this end, all relevant types of solvents are covered separately and emphasized with numerous synthetic examples, while taking care to explain applications so as to avoid undesired side reactions. The result is a unique resource for every synthetic chemist and reaction engineer in industry and academia working on the methodical optimization of synthetic transformations.

Bismuth-Mediated Organic Reactions

Thierry Ollevier
Bismuth Mediated Organic Reactions Book PDF

Author : Thierry Ollevier
Publisher : Springer Science & Business Media
Page : 278 pages
File Size : 41,8 Mb
Release : 2012-01-10
Category : Science
ISBN : 9783642272394

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Bismuth-Mediated Organic Reactions by Thierry Ollevier Pdf

Bismuth Catalysts in Aqueous Media, by Shū Kobayashi, Masaharu Ueno and Taku Kitanosono.- Pentavalent Organobismuth Reagents in Organic Synthesis: Alkylation, Alcohol Oxidation and Cationic Photopolymerization , by Yoshihiro Matano.- Environmentally Friendly Organic Synthesis Using Bismuth(III) Compounds, by Scott W. Krabbe and Ram S. Mohan.- Bismuth-Catalyzed Addition of Silyl Nucleophiles to Carbonyl Compounds and Imines, by Thierry Ollevier.- Bismuth Salts in Catalytic Alkylation Reactions, by Magnus Rueping and Boris J. Nachtsheim.- New Applications for Bismuth(III) Salts in Organic Synthesis: From Bulk Chemicals to Steroid and Terpene Chemistry, by J. A. R. Salvador, S. M. Silvestre, R. M. A. Pinto, R. C. Santos and C. Le Roux.- Cationic Bismuth-Catalyzed Hydroamination and Direct Substitution of the Hydroxy Group in Alcohols with Amides, by Shigeki Matsunaga and Masakatsu Shibasaki.- Transition-Metal Catalyzed C–C Bond Formation Using Organobismuth Compounds, by Shigeru Shimada and Maddali L. N. Rao.- Bismuth(III) Salts as Synthetic Tools in Organic Transformations, by J. S. Yadav, Aneesh Antony and Basi V. Subba Reddy.

Science of Synthesis: Water in Organic Synthesis

Shu Kobayashi
Science of Synthesis Water in Organic Synthesis Book PDF

Author : Shu Kobayashi
Publisher : Thieme
Page : 1581 pages
File Size : 51,7 Mb
Release : 2014-05-14
Category : Science
ISBN : 9783131790415

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Science of Synthesis: Water in Organic Synthesis by Shu Kobayashi Pdf

Water in Organic Synthesis is essential for the organic chemist in helping gain a thorough appreciation of the latest and most reliable available methods for using water in organic synthesis. It illustrates how water can often be a viable and green solvent in the laboratory and provides a detailed introduction to the subject: background information, evaluated methods, practical applications, industrial applications, special techniques, and an overview of the latest trends. The reference work also helps in inspiring chemists worldwide to find new approaches and techniques for the application of water in organic synthesis. Comprehensive overview of a rapidly progressing field Critical review of aqueous reactions by 47 experts Covering almost all types of organic reactions Including special techniques with water and industrial applications Emphasis on environmental aspects