Organic Stereochemistry

Author : Sunil Kumar Talapatra,Bani Talapatra
Publisher : Springer Nature
Page : 266 pages
File Size : 45,8 Mb
Release : 2023-01-01
Category : Science
ISBN : 9783030959906

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Basic Concepts in Organic Stereochemistry by Sunil Kumar Talapatra,Bani Talapatra Pdf

This book discusses essential stereochemical concepts associated with organic molecules (natural or synthetic), as reflected in the course of their many reactions, their mechanisms, their asymmetric synthesis, biosynthesis, and biological activities. This treatise provides useful insights and understanding of the chiral/achiral designations (nomenclatures), the stereochemical features, and related properties of the natural and synthetic products. Without having an adequate knowledge of stereochemical concepts, it will not be possible to understand and appreciate the stereochemistry of natural or synthetic products. Thus, essential static and dynamic aspects of stereochemistry with sufficient illustrative examples along with discussions are presented. The structure of the monograph allows for easy selection of separate topics for reading and teaching. This book will also provide an idea of basic stereochemical concepts, as applied to organic molecules in general as well as to organic ligands in coordination complexes, and will, therefore, be valuable resources to teachers and students of advanced undergraduates and post-graduates, researchers, and professionals.

Author : Ernest L. Eliel,Samuel H. Wilen
Publisher : John Wiley & Sons
Page : 1296 pages
File Size : 48,6 Mb
Release : 1994-09-28
Category : Science
ISBN : 9780471016700

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Stereochemistry of Organic Compounds by Ernest L. Eliel,Samuel H. Wilen Pdf

Stereochemistry of Organic Compounds The first fully referenced, comprehensive book on this subject in more than thirty years, Stereochemistry of Organic Compounds contains up-to-date coverage and insightful exposition of all important new concepts, developments, and tools in the rapidly advancing field of stereochemistry, including: * Asymmetric and diastereoselective synthesis * Conformational analysis * Properties of enantiomers and racemates * Separation and analysis of enantiomers and diastereoisomers * Developments in spectroscopy (including NMR), chromatography, and molecular mechanics as applied to stereochemistry * Prostereoisomerism * Conceptual foundations of stereochemistry, including terminology and symmetry concepts * Chiroptical properties Written by the leading authorities in the field, the text includes more than 4,000 references, 1,000 illustrations, and a glossary of stereochemical terms.

Author : Hua-Jie Zhu
Publisher : John Wiley & Sons
Page : 336 pages
File Size : 41,6 Mb
Release : 2015-08-10
Category : Science
ISBN : 9783527338221

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Organic Stereochemistry by Hua-Jie Zhu Pdf

Adopting a novel approach to the topic by combining theoretical knowledge and practical results, this book presents the most popular and useful computational and experimental methods applied for studying the stereochemistry of chemical reactions and compounds. The text is clearly divided into three sections on fundamentals, spectroscopic and computational techniques, and applications in organic synthesis. The first part provides a brief introduction to the field of chirality and stereochemistry, while the second part covers the different methodologies, such as optical rotation, electronic circular dichroism, vibrational circular dicroism, and Raman spectroscopy. The third section then goes on to describe selective examples in organic synthesis, classified by reaction type, i.e. enantioselective, chemoselective and stereoselective reactions. A final chapter on total synthesis of natural products rounds off the book. A valuable reference for researchers in academia and industry working in the field of organic synthesis, computational chemistry, spectroscopy or medicinal chemistry.

Author : D. Nasipuri
Publisher : John Wiley & Sons
Page : 554 pages
File Size : 46,8 Mb
Release : 1991
Category : Science
ISBN : UOM:39015038998087

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Stereochemistry of Organic Compounds by D. Nasipuri Pdf

This text deals with the new concepts and terminology that have been introduced into the treatment of organic stereochemistry over the last decade. Organic reaction mechanisms, as they relate to stereochemistry, are included, and the pericyclic reaction using the frontier molecular orbital approach is explained. The text does not assume a strong grounding in organic chemistry and will therefore be useful to a broader spectrum of students - both graduate and undergraduate. The volume features numerous illustrations and programmed problems.

Author : Sheila R. Buxton,Stanley M. Roberts
Publisher : Prentice Hall
Page : 268 pages
File Size : 45,5 Mb
Release : 1996
Category : Science
ISBN : UOM:49015002477132

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Guide to Organic Stereochemistry by Sheila R. Buxton,Stanley M. Roberts Pdf

Takes the reader step-by-step from the structures of simple molecules, such as methane, to the basic shapes of biologically important macromolecules, such as proteins and nucleic acids. Deals with the concept of chirality, which is often overlooked by many texts. Chirality is approached by firstly explaining the stereochemistry of compounds with one stereogenic centre, then dealing with compounds having two or more stereogenic centres before focusing on compounds possessing axes of chirality. The importance of stereochemistry in a wide variety of transformations (for example addition reactions, eliminations, and cycloadditions), is discussed. The final chapters describe the application of stereocontrol in asymmetric synthesis, indicating the use of chiral auxiliaries and chiral catalysts in modern chemistry.

Author : Ernest L. Eliel,Samuel H. Wilen,Michael P. Doyle
Publisher : Wiley-Interscience
Page : 712 pages
File Size : 49,8 Mb
Release : 2001-04-11
Category : Science
ISBN : UOM:39015056628640

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Basic Organic Stereochemistry by Ernest L. Eliel,Samuel H. Wilen,Michael P. Doyle Pdf

A Practical Introduction to Stereochemistry Stereoisomers are compounds with the same chemical formula and connectivity but with different arrangements of their atoms in 3-dimensional space. Stereochemistry encompasses the study of stereoisomers and their properties. Despite having an identical chemical formula, stereoisomers can have drastically different biological, medicinal, and chemical properties. Basic Organic Stereochemistry explains in clear, concise terms the concepts and properties of stereoisomers. Ideal both as a text for advanced undergraduate or graduate students and as a handy guide for researchers in industry, this superb text covers: * Polarimetry and optical rotation * Internal coordinates, configuration, and conformation * Nature of stereoisomers * Barriers between stereoisomers and residual stereoisomers * Symmetry operators and symmetry point groups * Properties of stereoisomers and stereoisomer discrimination * Separation of stereoisomers, resolution, and racemization Suitable for students in organic and biological chemistry, Basic Organic Stereochemistry is unparalleled as a convenient text.

Author : Michael J. T. Robinson
Publisher : Oxford University Press on Demand
Page : 89 pages
File Size : 50,6 Mb
Release : 2000
Category : Science
ISBN : 0198792751

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Organic Stereochemistry by Michael J. T. Robinson Pdf

This book is an account for students of how the three-dimensional shapes of molecules influence their chemical and physical properties. It begins with the structures of molecules and then describes how such structures can be changed.

Author : M. Nógrádi
Publisher : Elsevier
Page : 300 pages
File Size : 55,8 Mb
Release : 2013-10-22
Category : Science
ISBN : 9781483278650

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Stereochemistry by M. Nógrádi Pdf

Stereochemistry: Basic Concepts and Applications is a three-chapter text that introduces the basic principles and concepts of stereochemistry, as well as its application to organic chemistry application. Chapter 1 describes first the stereochemistry of the ground state, specifically the configuration and conformation of organic compounds, as well as the most important methods for its investigation. This chapter also deals with the kinetics of conformational changes and provides an overview of the so-called "applied stereochemistry". Chapter 2 focuses on the analysis of the internal motions of the molecules and of the corresponding activation energies. This chapter also examines the principles of intramolecular symmetry. Chapter 3 considers the stereochemical aspect of several enzymic processes and the stereoisomerism of monotonic polymers and inorganic complexes. This book will be of great value to organic chemists and organic chemistry graduate students.

Author : D. Nasipuri
Publisher : New Age International
Page : 596 pages
File Size : 50,8 Mb
Release : 1994
Category : Science
ISBN : 8122405703

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Stereochemistry of Organic Compounds by D. Nasipuri Pdf

During Recent Years, Stereochemistry Has Undergone A Phenomenal Growth Both In Theory And Practice, With A Concomitant Increase Of Interest Among The Organic Chemists, Biological Chemists, Medicinal Chemists, And Pharmacologists. The Present Text Provides An Up-To-Date, Coherent; And Comprehensive Account Of The Subject Starting From The Fundamentals And Leading Up To The Latest Development As Far As Practicable. Emphasis Has Been Placed On Symmetry-Based Approach To Molecular Chirality, Stereochemical Terminologies (Modern Stereochemistry Is Replete, With Them), Topicity And Prostereoisomerism, Conformational Analysis, Dynamic Stereochemistry, Chiroptical Properties, And Assignment Of Absolute Configuration To Chiral Molecules.Dynamic Stereochemistry Has Been Discussed With Reference To Conformation-Reactivity Correlation, Stereoselective Syntheses, And Pericyclic Reactions. A Large Cross Section Of Organic Reactions With Stereochemical Implication Has Been Incorporated. Attempts Have Been Made To Familiarise The Readers With Modem Instrumental Techniques, Nuclear Magnetic Resonance In Particular, Used For Stereochemical Investigation. Each Chapter Is Provided With A Summary Which Highlights The Main Points Of The Text. Selective References, Mostly Of Textbooks, Monographs, Review Articles, And Significant Original Papers Have Been Given Extending Sometimes To Early 1991.The Book Is Expected To Fulfil The Long-Felt Need For A Comprehensive Text On Modern Organic Stereochemistry Which Is Conspicuously Absent Since The Publication Of Professor Eliels Book In 1962. The Text May Be Adopted At Any Stage Of The University Teaching And At The Same Time Be Useful To The Practising Organic Chemists.

Author : Dipak Kumar Mandal
Publisher : Academic Press
Page : 640 pages
File Size : 49,6 Mb
Release : 2021-04-21
Category : Science
ISBN : 9780128240939

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Stereochemistry and Organic Reactions by Dipak Kumar Mandal Pdf

Stereochemistry and Organic Reactions: Conformation, Configuration, Stereoelectronic Effects and Asymmetric Synthesis provides coverage on the stereochemistry of reactions of all mechanistic types, ranging from ionic, pericyclic and transition metal-catalyzed to radical and photochemical. Chapters cover acyclic molecules, cyclic molecules, the stereochemistry of organic reactions, the perturbation molecular orbital theory for the origin of stereoelectronic effects, and an introduction to the principles of stereoselectivity and hierarchical levels of asymmetric synthesis. Each chapter includes problems that reinforce main themes, making it valuable to students, teachers and researchers working in organic, biological and medicinal chemistry, as well as biologists, pharmacologists, polymer chemists and chemists. Presents a holistic and unified approach to stereochemical understanding and predictions, covering reactions of all mechanistic classes Includes two background chapters on perturbation theory and stereoselective principles, along with asymmetric designs Features novel rules and mnemonics to delineate product stereochemistry Includes up-to-date coverage with over 1300 selective references

Author : Bernard Testa
Publisher : Unknown
Page : 266 pages
File Size : 50,9 Mb
Release : 1979
Category : Science
ISBN : MINN:31951000024565X

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Principles of Organic Stereochemistry by Bernard Testa Pdf

Author : V.K. Ahluwalia
Publisher : Springer Nature
Page : 615 pages
File Size : 40,5 Mb
Release : 2022-01-04
Category : Science
ISBN : 9783030849610

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Stereochemistry of Organic Compounds by V.K. Ahluwalia Pdf

This textbook provides a simple approach to understand the various complex aspects of stereochemistry. It deals with basic static stereochemistry and gives an overview of the different isomeric forms and nomenclatures. With simple writing style and many examples, this book covers the topics such as stereochemistry of hydrocarbons, alkenes, cycloalkenes, optically active compounds, trivalent carbon, fused, bridged and caged rings and related compounds. This textbook also covers the additional topics such as optical rotatory dispersion and circular dichroism, steroechemistry of elimination reactions, substitution reactions, rearrangement reactions and pericyclic reactions. The book includes pedagogical features like end-of-chapter problems and key concepts to help students in self-learning. The textbook is extremely useful for the senior undergraduate and postgraduate students pursuing course in chemistry, especially organic chemistry. Besides, this book will also be a useful reference book for professionals working in various chemical industries, biotechnology, bioscience and pharmacy.

Author : Moses K. Kaloustian
Publisher : Elsevier
Page : 622 pages
File Size : 40,7 Mb
Release : 2004-07-21
Category : Science
ISBN : 0080472311

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Concepts and Terminology in Organic Stereochemistry by Moses K. Kaloustian Pdf

In the last quarter century there have been only two seminal contributions in the field of organic stereochemistry - both by Kurt Mislow and his coworkers - ones that have clarified the basic concepts of stereotopicity and chirotopicity. Not withstanding a few other sporadic contributions by others, to date there have been no systematic attempts to unify and develop the conceptual framework and terminology of organic stereochemistry. Existing terms are frequently misused or abused, needed terms - redundant, confusing or controversial - are invented randomly, and yet other needed terms have not seen the light of day. This three-part work presents the elements of a simple, uniform and comprehensive language of the stereochemical underpinnings of organic chemistry. It is essential reading for industrial chemists, graduate students, university professors and industrial researchers in the field of Organic Stereochemistry. * Presents the elements of a simple, uniform and comprehensive language of organic stereochemistry. * Unifies and develops a comprehensive language of organic stereochemistry * Presents concepts and classifications which are universal.

Author : P. S. Kalsi
Publisher : New Age International
Page : 41 pages
File Size : 52,7 Mb
Release : 2008
Category : Stereochemistry
ISBN : 9788122423563

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Stereochemistry Conformation and Mechanism by P. S. Kalsi Pdf

Stereochemistry has always occupied a central position and is pivotal to the practice of organic chemistry. A solid understanding of this subject is indeed critical to subsequent success in a science career. Stereochemistry is, therefore, a core constituent both at the undergraduate and postgraduate chemistry courses. This seventh edition is extensively revised and enlarged by adding new material to take account of recent developments and extensive amendments have been made to improve clarity. The key features of this new addition are: a brand new design. Incorporation of basic principles in boxes directly links the students to the main text;, and a large number of exercises with their solutions have been now added in each chapter. These exercises are set at appropriate places so that the students can test their command of a particular topic. New problems have been added at the end of each chapter. Chemical illustrations have been modified and developed for clarity and information. Generally the figures contain text as well, to decrease the need to refer back and forth to the text and for better understanding.

Author : David A. Lightner,Jerome E. Gurst
Publisher : John Wiley & Sons
Page : 508 pages
File Size : 50,7 Mb
Release : 2000-03-31
Category : Science
ISBN : 0471354058

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Organic Conformational Analysis and Stereochemistry from Circular Dichroism Spectroscopy by David A. Lightner,Jerome E. Gurst Pdf

Unter Zirkulardichroismus (CD) versteht man die spezifisch unterschiedliche Absorption von links- und rechtszirkular polarisiertem Licht durch bestimmte Moleküle. CD-Effekte lassen sich in Abhängigkeit von der Wellenlänge messen und spektroskopisch auswerten; sie geben beispielsweise Auskunft über die Konformation organischer Verbindungen. Dieses Buch richtet sich an den organischen Chemiker, der mit den Grundprinzipien der Stereochemie vertraut ist, und erläutert die Anwendung der CD-Spektroskopie zur Konformationsanalyse ausführlich und verständlich. (06/00)