Stereochemistry Of Organic Compounds

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Stereochemistry of Organic Compounds

Author : Ernest L. Eliel,Samuel H. Wilen
Publisher : John Wiley & Sons
Page : 1296 pages
File Size : 54,6 Mb
Release : 1994-09-28
Category : Science
ISBN : 9780471016700

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Stereochemistry of Organic Compounds by Ernest L. Eliel,Samuel H. Wilen Pdf

Stereochemistry of Organic Compounds The first fully referenced, comprehensive book on this subject in more than thirty years, Stereochemistry of Organic Compounds contains up-to-date coverage and insightful exposition of all important new concepts, developments, and tools in the rapidly advancing field of stereochemistry, including: * Asymmetric and diastereoselective synthesis * Conformational analysis * Properties of enantiomers and racemates * Separation and analysis of enantiomers and diastereoisomers * Developments in spectroscopy (including NMR), chromatography, and molecular mechanics as applied to stereochemistry * Prostereoisomerism * Conceptual foundations of stereochemistry, including terminology and symmetry concepts * Chiroptical properties Written by the leading authorities in the field, the text includes more than 4,000 references, 1,000 illustrations, and a glossary of stereochemical terms.

Stereochemistry of Organic Compounds

Author : D. Nasipuri
Publisher : John Wiley & Sons
Page : 554 pages
File Size : 46,9 Mb
Release : 1991
Category : Science
ISBN : UOM:39015038998087

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Stereochemistry of Organic Compounds by D. Nasipuri Pdf

This text deals with the new concepts and terminology that have been introduced into the treatment of organic stereochemistry over the last decade. Organic reaction mechanisms, as they relate to stereochemistry, are included, and the pericyclic reaction using the frontier molecular orbital approach is explained. The text does not assume a strong grounding in organic chemistry and will therefore be useful to a broader spectrum of students - both graduate and undergraduate. The volume features numerous illustrations and programmed problems.

Stereochemistry of Organic Compounds

Author : D. Nasipuri
Publisher : New Age International
Page : 596 pages
File Size : 41,9 Mb
Release : 1994
Category : Science
ISBN : 8122405703

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Stereochemistry of Organic Compounds by D. Nasipuri Pdf

During Recent Years, Stereochemistry Has Undergone A Phenomenal Growth Both In Theory And Practice, With A Concomitant Increase Of Interest Among The Organic Chemists, Biological Chemists, Medicinal Chemists, And Pharmacologists. The Present Text Provides An Up-To-Date, Coherent; And Comprehensive Account Of The Subject Starting From The Fundamentals And Leading Up To The Latest Development As Far As Practicable. Emphasis Has Been Placed On Symmetry-Based Approach To Molecular Chirality, Stereochemical Terminologies (Modern Stereochemistry Is Replete, With Them), Topicity And Prostereoisomerism, Conformational Analysis, Dynamic Stereochemistry, Chiroptical Properties, And Assignment Of Absolute Configuration To Chiral Molecules.Dynamic Stereochemistry Has Been Discussed With Reference To Conformation-Reactivity Correlation, Stereoselective Syntheses, And Pericyclic Reactions. A Large Cross Section Of Organic Reactions With Stereochemical Implication Has Been Incorporated. Attempts Have Been Made To Familiarise The Readers With Modem Instrumental Techniques, Nuclear Magnetic Resonance In Particular, Used For Stereochemical Investigation. Each Chapter Is Provided With A Summary Which Highlights The Main Points Of The Text. Selective References, Mostly Of Textbooks, Monographs, Review Articles, And Significant Original Papers Have Been Given Extending Sometimes To Early 1991.The Book Is Expected To Fulfil The Long-Felt Need For A Comprehensive Text On Modern Organic Stereochemistry Which Is Conspicuously Absent Since The Publication Of Professor Eliels Book In 1962. The Text May Be Adopted At Any Stage Of The University Teaching And At The Same Time Be Useful To The Practising Organic Chemists.

Stereochemistry

Author : M. Nógrádi
Publisher : Elsevier
Page : 300 pages
File Size : 43,7 Mb
Release : 2013-10-22
Category : Science
ISBN : 9781483278650

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Stereochemistry by M. Nógrádi Pdf

Stereochemistry: Basic Concepts and Applications is a three-chapter text that introduces the basic principles and concepts of stereochemistry, as well as its application to organic chemistry application. Chapter 1 describes first the stereochemistry of the ground state, specifically the configuration and conformation of organic compounds, as well as the most important methods for its investigation. This chapter also deals with the kinetics of conformational changes and provides an overview of the so-called "applied stereochemistry". Chapter 2 focuses on the analysis of the internal motions of the molecules and of the corresponding activation energies. This chapter also examines the principles of intramolecular symmetry. Chapter 3 considers the stereochemical aspect of several enzymic processes and the stereoisomerism of monotonic polymers and inorganic complexes. This book will be of great value to organic chemists and organic chemistry graduate students.

Stereochemistry of Organic Compounds

Author : V.K. Ahluwalia
Publisher : Springer Nature
Page : 615 pages
File Size : 41,6 Mb
Release : 2022-01-04
Category : Science
ISBN : 9783030849610

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Stereochemistry of Organic Compounds by V.K. Ahluwalia Pdf

This textbook provides a simple approach to understand the various complex aspects of stereochemistry. It deals with basic static stereochemistry and gives an overview of the different isomeric forms and nomenclatures. With simple writing style and many examples, this book covers the topics such as stereochemistry of hydrocarbons, alkenes, cycloalkenes, optically active compounds, trivalent carbon, fused, bridged and caged rings and related compounds. This textbook also covers the additional topics such as optical rotatory dispersion and circular dichroism, steroechemistry of elimination reactions, substitution reactions, rearrangement reactions and pericyclic reactions. The book includes pedagogical features like end-of-chapter problems and key concepts to help students in self-learning. The textbook is extremely useful for the senior undergraduate and postgraduate students pursuing course in chemistry, especially organic chemistry. Besides, this book will also be a useful reference book for professionals working in various chemical industries, biotechnology, bioscience and pharmacy.

Introduction to Stereochemistry

Author : Kurt Mislow
Publisher : Courier Corporation
Page : 210 pages
File Size : 47,6 Mb
Release : 2012-06-11
Category : Science
ISBN : 9780486151151

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Introduction to Stereochemistry by Kurt Mislow Pdf

Molecular shape, form, and symmetry play a central role in organic chemistry, and this text presents a brief introduction to the conceptual basis of stereochemistry. Its focus lies in the fundamentals of structural stereochemistry, rather than the dynamic aspects that are more relevant to reaction mechanisms. The three-part treatment deals with structure and symmetry, stereoisomerism, and the separation and configuration of stereoisomers. The first section reviews molecular architecture, relating empirical bonding geometries to the hybridization of the central carbon atom. Students receive a nonrigorous treatment of symmetry elements and point groups, with particular focus on the presence or absence of reflection symmetry. The second section classifies stereoisomers according to symmetry properties and to the nature of their barriers; it also discusses the dependence of optical activity on structure and concludes with an examination of topological isomerism. The third and final section explores the conceptual basis of asymmetric syntheses and kinetic resolutions. Each of the major sections features a series of exercises that reinforce and extend the preceding material, and answers are provided. Preface to the Dover edition. Answers to Exercises. Bibliography. Index.

Basic Concepts in Organic Stereochemistry

Author : Sunil Kumar Talapatra,Bani Talapatra
Publisher : Springer Nature
Page : 266 pages
File Size : 45,5 Mb
Release : 2023-01-01
Category : Science
ISBN : 9783030959906

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Basic Concepts in Organic Stereochemistry by Sunil Kumar Talapatra,Bani Talapatra Pdf

This book discusses essential stereochemical concepts associated with organic molecules (natural or synthetic), as reflected in the course of their many reactions, their mechanisms, their asymmetric synthesis, biosynthesis, and biological activities. This treatise provides useful insights and understanding of the chiral/achiral designations (nomenclatures), the stereochemical features, and related properties of the natural and synthetic products. Without having an adequate knowledge of stereochemical concepts, it will not be possible to understand and appreciate the stereochemistry of natural or synthetic products. Thus, essential static and dynamic aspects of stereochemistry with sufficient illustrative examples along with discussions are presented. The structure of the monograph allows for easy selection of separate topics for reading and teaching. This book will also provide an idea of basic stereochemical concepts, as applied to organic molecules in general as well as to organic ligands in coordination complexes, and will, therefore, be valuable resources to teachers and students of advanced undergraduates and post-graduates, researchers, and professionals.

Rules for the Nomenclature of Organic Chemistry

Author : L. C. Cross,W. Klyne
Publisher : Elsevier
Page : 21 pages
File Size : 50,6 Mb
Release : 2013-09-17
Category : Science
ISBN : 9781483284507

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Rules for the Nomenclature of Organic Chemistry by L. C. Cross,W. Klyne Pdf

Rules for the Nomenclature of Organic Chemistry: Section E: Stereochemistry (Recommendations 1974) deals with the main principles of stereochemistry. The rules discussed in this section have two main objects, namely, to prescribe, for basic views, terms that may provide a common language in all aspects of stereochemistry; and to define the ways in which these terms may be incorporated into the names of individual compounds. This book discusses the steric structure of a compound, which is denoted by an affix or affixes to the name that does not prescribe the stereochemistry. This text explains that isomers are termed stereoisomers when they differ only in the arrangement of the atoms in space. This book explains as well that the terms relative stereochemistry and relative configuration are used to describe the positions of substituents on different atoms in a molecule relative to one another. This book is a valuable resource for organic chemists.

Stereochemistry

Author : David G. Morris
Publisher : Royal Society of Chemistry
Page : 188 pages
File Size : 53,7 Mb
Release : 2001
Category : Education
ISBN : 085404602X

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Stereochemistry by David G. Morris Pdf

This text for undergraduate students presents an introduction to stereochemistry--the study of the three-dimensional structure of molecules--with a focus on organic chemistry. In eight chapters, Morris (U. of Glasgow) discusses topics such as the hybridization, conformation, and configuration of simple molecules; chiral molecules; molecules with two or more stereogenic centers; stereoisomerism in cyclic structures; and substitution reactions at saturated carbon. Coverage extends to the use of NMR spectroscopy in stereochemistry. c. Book News Inc.

Stereochemistry Conformation and Mechanism

Author : P. S. Kalsi
Publisher : New Age International
Page : 41 pages
File Size : 45,6 Mb
Release : 2008
Category : Stereochemistry
ISBN : 9788122423563

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Stereochemistry Conformation and Mechanism by P. S. Kalsi Pdf

Stereochemistry has always occupied a central position and is pivotal to the practice of organic chemistry. A solid understanding of this subject is indeed critical to subsequent success in a science career. Stereochemistry is, therefore, a core constituent both at the undergraduate and postgraduate chemistry courses. This seventh edition is extensively revised and enlarged by adding new material to take account of recent developments and extensive amendments have been made to improve clarity. The key features of this new addition are: a brand new design. Incorporation of basic principles in boxes directly links the students to the main text;, and a large number of exercises with their solutions have been now added in each chapter. These exercises are set at appropriate places so that the students can test their command of a particular topic. New problems have been added at the end of each chapter. Chemical illustrations have been modified and developed for clarity and information. Generally the figures contain text as well, to decrease the need to refer back and forth to the text and for better understanding.

Organic Stereochemistry

Author : Hua-Jie Zhu
Publisher : John Wiley & Sons
Page : 336 pages
File Size : 46,5 Mb
Release : 2015-08-10
Category : Science
ISBN : 9783527338221

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Organic Stereochemistry by Hua-Jie Zhu Pdf

Adopting a novel approach to the topic by combining theoretical knowledge and practical results, this book presents the most popular and useful computational and experimental methods applied for studying the stereochemistry of chemical reactions and compounds. The text is clearly divided into three sections on fundamentals, spectroscopic and computational techniques, and applications in organic synthesis. The first part provides a brief introduction to the field of chirality and stereochemistry, while the second part covers the different methodologies, such as optical rotation, electronic circular dichroism, vibrational circular dicroism, and Raman spectroscopy. The third section then goes on to describe selective examples in organic synthesis, classified by reaction type, i.e. enantioselective, chemoselective and stereoselective reactions. A final chapter on total synthesis of natural products rounds off the book. A valuable reference for researchers in academia and industry working in the field of organic synthesis, computational chemistry, spectroscopy or medicinal chemistry.

Computer Representation of the Stereochemistry of Organic Molecules

Author : DAVIS
Publisher : Birkhäuser
Page : 149 pages
File Size : 45,9 Mb
Release : 2013-11-11
Category : Science
ISBN : 9783034857888

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Computer Representation of the Stereochemistry of Organic Molecules by DAVIS Pdf

The role of the computer in the practice of organic chemistry has been firmly established over the past decade. Its uses as a large scale information storage and retrieval device in chemistry have been too numerous to mention. More recently, the applicability of computers to the problem of discovering valid and reasonable synthesis routes for organic molecules has been demonstrated. This has been both as an adjunct to the 1 chemist in the on-line interactive mode ,2,3 and also as a wholly computer-directed system seeking to simulate the intelligent prob- 4 lem-solving activity of the human organic synthetic chemist. ,5 In all of these computer applications to organic chemistry, it has been necessary to devise some computer-compatible repres- tation of an organic molecule that is both canonical and c- venient for table look-ups. This is in order that entities that have been constructed at different times under different circumstances can be identified and classified, with identical molecules being recognized as such even if their connection matrices list the elements of the molecule in different orders. E. J. Corey and W. T. Wipke, Science, 166, 178 (1969). 2 E. J. Corey, W. T. Wipke, R. D. Cramer III and W. J. Howe, J. Americ. Chern. Soc. , 94, 421 (1972) and 431 (1972). 3 E. J. Corey, R. D. Cramer III and W. J. Howe, ~. Americ. Chern. Soc. , 94, 440 (1972). 4 H. L. Gelernter, N. S. Sridharan and A. J.

Basic Organic Stereochemistry

Author : Ernest L. Eliel,Samuel H. Wilen,Michael P. Doyle
Publisher : Wiley-Interscience
Page : 712 pages
File Size : 54,5 Mb
Release : 2001-04-11
Category : Science
ISBN : UOM:39015056628640

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Basic Organic Stereochemistry by Ernest L. Eliel,Samuel H. Wilen,Michael P. Doyle Pdf

A Practical Introduction to Stereochemistry Stereoisomers are compounds with the same chemical formula and connectivity but with different arrangements of their atoms in 3-dimensional space. Stereochemistry encompasses the study of stereoisomers and their properties. Despite having an identical chemical formula, stereoisomers can have drastically different biological, medicinal, and chemical properties. Basic Organic Stereochemistry explains in clear, concise terms the concepts and properties of stereoisomers. Ideal both as a text for advanced undergraduate or graduate students and as a handy guide for researchers in industry, this superb text covers: * Polarimetry and optical rotation * Internal coordinates, configuration, and conformation * Nature of stereoisomers * Barriers between stereoisomers and residual stereoisomers * Symmetry operators and symmetry point groups * Properties of stereoisomers and stereoisomer discrimination * Separation of stereoisomers, resolution, and racemization Suitable for students in organic and biological chemistry, Basic Organic Stereochemistry is unparalleled as a convenient text.

Stereochemistry In Organic Compounds

Author : M.G. Arora
Publisher : Anmol Publications PVT. LTD.
Page : 96 pages
File Size : 40,5 Mb
Release : 1997-01-01
Category : Organic compounds
ISBN : 8174885595

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Stereochemistry In Organic Compounds by M.G. Arora Pdf

In Recent Years There Has Been No Death Of Elegant Books Dealing With The Subject Of Stereochemistry Of Organic Compounds At The Undergraduate And Postgraduate Levels. There Are, However, Very Few Books Which Hold The Interest Of The Inquisitive Students. The Present Book Has Been An Attempt To Hold The Interest Of The Inquisitive Students. Each Concept In This Book Has Been Self-Sufficient In Itself And Has Been Explained With A Large Number Of Illustrations In The Light Of Modern Development In A Simple Language And Elegant Style. Every Concept In This Book Can Do Full Justification For Most Of The Students.

Principles and Applications of Stereochemistry

Author : Michael North
Publisher : Routledge
Page : 269 pages
File Size : 46,7 Mb
Release : 2017-10-19
Category : Medical
ISBN : 9781351422055

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Principles and Applications of Stereochemistry by Michael North Pdf

A thorough understanding of stereochemistry is essential for the comprehension of almost all aspects of modern organic chemistry. It is also of great significance in many biochemical and medicinal disciplines, since the stereoisomers of a compound can have dramatically different biological properties. This text explains how the different properties of stereoisomers of a compound arise, and what processes can be used to prepare and analyze stereoisomerically pure compounds. It also presents prominent coverage of the stereochemistry of inorganic and organometallic compounds, which is likely to increase in importance, as these compounds are used as symmetric catalysts in asymmetric synthesis. Modern stereochemical terminology is used throughout, although reference is also made to older terms which are still widely used. A set of problems at the end of each chapter aims to further the reader's understanding of how the content can be applied. The book is designed mainly as a textbook for undergraduate students and as a reference source for more advanced levels, but is also intended for academic and professional organic chemists.