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Author : Jiro Tsuji
Publisher : Springer Science & Business Media
Page : 348 pages
File Size : 52,9 Mb
Release : 2005-07-06
Category : Science
ISBN : 3540239820
with contributions by numerous experts
Author : Jiro Tsuji
Publisher : Wiley
Page : 670 pages
File Size : 50,6 Mb
Release : 2004-06-25
Category : Science
ISBN : 0470850337
Jiro Tsuji, one of the pioneers in this field of organic synthesis, provides synthetic organic chemists with a remarkable overview of the many applications of organopalladium chemistry. Tsuji discusses the recent developments in the field as well as the explosive growth over the last five years. Highlighting the most recent discoveries in this rapidly expanding field, the book; Focuses on new aspects of organopalladium chemistry, putting emphasis on synthetic applications Investigates the new perspectives on the synthetic uses of contemporary organopalladium chemistry This volume, together with Innovations in Organic Synthesis, Tsuji's previous title, provides complete coverage of over 40 years of organopalladium chemistry. Palladium Reagents and Catalysts: New Perspectives for the 21st Century is an essential reference source and companion for students, and both industrial and academic research chemists working in organic synthesis, particularly on synthesis of natural products and medicinal compounds. Those studying development of new synthetic methodology and organometallic chemistry will also find this book valuable.
Author : Jiro Tsuji
Publisher : John Wiley & Sons
Page : 670 pages
File Size : 45,7 Mb
Release : 2006-02-08
Category : Science
ISBN : 9780470021194
Jiro Tsuji, one of the pioneers in this field of organic synthesis, provides synthetic organic chemists with a remarkable overview of the many applications of organopalladium chemistry. Tsuji discusses the recent developments in the field as well as the explosive growth over the last five years. Highlighting the most recent discoveries in this rapidly expanding field, the book; Focuses on new aspects of organopalladium chemistry, putting emphasis on synthetic applications Investigates the new perspectives on the synthetic uses of contemporary organopalladium chemistry This volume, together with Innovations in Organic Synthesis, Tsuji's previous title, provides complete coverage of over 40 years of organopalladium chemistry. Palladium Reagents and Catalysts: New Perspectives for the 21st Century is an essential reference source and companion for students, and both industrial and academic research chemists working in organic synthesis, particularly on synthesis of natural products and medicinal compounds. Those studying development of new synthetic methodology and organometallic chemistry will also find this book valuable.
Author : Navjeet Kaur
Publisher : CRC Press
Page : 432 pages
File Size : 43,8 Mb
Release : 2019-05-01
Category : Medical
ISBN : 9781351242608
This book is a compilation of the recent applications of palladium catalysts in organic synthesis. The book demonstrates that it is a highly dynamic research field. This methodology has emerged as a powerful tool for the efficient and chemoselective synthesis of heterocyclic molecules. In the past few years, several strategies have been pointed out to pursue more efficient, sustainable, and environment friendly chemical processes. Among those strategies, catalysis and the design of new processes that avoid the use of toxic reagents have been the focus of intense research.
Author : Stanley E. Livingstone
Publisher : Elsevier
Page : 224 pages
File Size : 48,5 Mb
Release : 2017-01-31
Category : Science
ISBN : 9781483158402
The Chemistry of Ruthenium, Rhodium, Palladium, Osmium, Iridium and Platinum
Author : Jie Jack Li,Gordon W. Gribble
Publisher : Elsevier
Page : 658 pages
File Size : 44,7 Mb
Release : 2006-10-20
Category : Science
ISBN : 9780080465845
Palladium chemistry, despite its immaturity, has rapidly become an indispensable tool for synthetic organic chemists. Heterocycles are of paramount importance in the pharmaceutical industry and palladium chemistry is one of the most novel and efficient ways of making heterocycles. Today, palladium-catalyzed coupling is the method of choice for the synthesis of a wide range of biaryls and heterobiaryls. The number of applications of palladium chemistry to the syntheses of heterocycles has grown exponentially. These developments highlight the need for a monograph dedicated solely to the palladium chemistry in heterocycles and this book provides a comprehensive explanation of the subject. The principal aim of the book is to highlight important palladium-mediated reactions of heterocycles with emphasis on the unique characteristics of individual heterocycles. 1. Palladium chemistry of heterocycles has its “idiosyncrasies stemming from their different structural properties from the corresponding carbocyclic aryl compounds. Even activated chloroheterocycles are sufficiently reactive to undergo Pd-catalyzed reactions. As a consequence of &agr and &bgr activation of heteroaryl halides, Pd-catalyzed chemistry may take place regioselectively at the activated positions, a phenomenon rarely seen in carbocyclic aryl halides. In addition, another salient peculiarity in palladium chemistry of heterocycles is the so-called "heteroaryl Heck reaction". For instance, while intermolecular palladium-catalyzed arylations of carbocyclic arenes are rare, palladium-catalyzed arylations of azoles and many other heterocycles readily take place. Therefore, the principal aim of this book is to highlight important palladium-mediated reactions of heterocycles with emphasis on the unique characteristics of individual heterocycles. 2. A myriad of heterocycles are biologically active and therefore of paramount importance to medicinal and agricultural chemists. Many heterocycle-containing natural products (they are highlighted in boxes throughout the text) have elicited great interest from both academic and industrial research groups. Recognizing the similarities between the palladium chemistry of arenes and heteroarenes, a critical survey of the accomplishments in heterocyclic chemistry will keep readers abreast of such a fast-growing field. We also hope this book will spur more interest and inspire ideas in such an extremely useful area. This book comprises a compilation of important preparations of heteroaryl halides, boranes and stannanes for each heterocycle. The large body of data regarding palladium-mediated polymerization of heterocycles in material chemistry is not focused here; neither is coordination chemistry involving palladium and heterocycles. Many heterocycle-containing natural products (highlighted throughout the text) have elicited great interest from both academic and industrial research groups. Recognizing the similarities between the palladium chemistry of arenes and heteroarenes, a critical survey of the accomplishments in heterocyclic chemistry keeps readers abreast of this fast-growing field. It is also hoped that this book will stimulate more interest and inspire new ideas in this exciting area. Contains the most up-to-date developments in this fast-moving field Includes 3 new chapters Incorporates material from selected well-respected authors on heterocyclic chemistry
Author : United States. Environmental Protection Agency. Office of Toxic Substances
Publisher : Unknown
Page : 808 pages
File Size : 54,5 Mb
Release : 1979
Category : Chemical industry
ISBN : MSU:31293011703190
Author : Ei-ichi Negishi,Armin de Meijere
Publisher : John Wiley & Sons
Page : 1657 pages
File Size : 42,5 Mb
Release : 2003-11-24
Category : Science
ISBN : 9780471473817
Organized to provide maximum utility to the bench synthetic chemist. The editor is well-known for his work in exploring, developing, and applying organopalladium chemistry. Contributors include over 24 world authorities in the field.
Author : Jiro Tsuji
Publisher : Springer Science & Business Media
Page : 221 pages
File Size : 42,5 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783642674754
Around 30 years ago the transition metal chemistry received great impulses. In the focus have been reactions of nickel and cobalt and herein especially their carbonyls. Also industrial processes have been developed. When the technical oxidation of ethylene with palladium chloride had been discovered, and a great number oflaboratory reactions, many groups have turned towards this subject. Apart from two important industrial processes - acetaldehyde and vinylacetate from ethylene - a great number of conversions and catalytic reactions with palladium compounds have been researched. Their mechanisms have been cleared up and have con tributed to a better understanding of the complex chemistry of palladium. Last but not least these reactions have also served for more understanding of organic transition metal compounds and catalyses in general. Numerous conventional reactions appear today in a different light. The effects of co-
Author : Henry Watts
Publisher : Unknown
Page : 886 pages
File Size : 52,6 Mb
Release : 1892
Category : Chemistry
ISBN : UCAL:B2933527
Author : Perrin Walker,William H. Tarn
Publisher : CRC Press
Page : 1434 pages
File Size : 49,9 Mb
Release : 1990-12-11
Category : Science
ISBN : 1439822530
This publication presents cleaning and etching solutions, their applications, and results on inorganic materials. It is a comprehensive collection of etching and cleaning solutions in a single source. Chemical formulas are presented in one of three standard formats - general, electrolytic or ionized gas formats - to insure inclusion of all necessary operational data as shown in references that accompany each numbered formula. The book describes other applications of specific solutions, including their use on other metals or metallic compounds. Physical properties, association of natural and man-made minerals, and materials are shown in relationship to crystal structure, special processing techniques and solid state devices and assemblies fabricated. This publication also presents a number of organic materials which are widely used in handling and general processing...waxes, plastics, and lacquers for example. It is useful to individuals involved in study, development, and processing of metals and metallic compounds. It is invaluable for readers from the college level to industrial R & D and full-scale device fabrication, testing and sales. Scientific disciplines, work areas and individuals with great interest include: chemistry, physics, metallurgy, geology, solid state, ceramic and glass, research libraries, individuals dealing with chemical processing of inorganic materials, societies and schools.
Author : A Doukelis,K Panopoulos,A Koumanakos,E Kakaras
Publisher : Elsevier
Page : 402 pages
File Size : 49,7 Mb
Release : 2014-10-20
Category : Technology & Engineering
ISBN : 9781782422419
Thanks to their outstanding hydrogen selectivity, palladium membranes have attracted extensive R&D interest. They are a potential breakthrough technology for hydrogen production and also have promising applications in the areas of thermochemical biorefining. This book summarises key research in palladium membrane technologies, with particular focus on the scale-up challenges. After an introductory chapter, Part one reviews the fabrication of palladium membranes. Part two then focuses on palladium membrane module and reactor design. The final part of the book reviews the operation of palladium membranes for synthesis gas/hydrogen production, carbon capture and other applications. Review of manufacture and design issues for palladium membranes Discussion of the applications of palladium membrane technology, including solar steam reforming, IGCC plants, NGCC plants, CHP plants and hydrogen production Examples of the technology in operation
Author : Anonim
Publisher : Unknown
Page : 556 pages
File Size : 44,7 Mb
Release : 1896
Category : Drugs
ISBN : UOM:39015069457722
Author : Hyung Yoon
Publisher : Springer Nature
Page : 236 pages
File Size : 54,9 Mb
Release : 2020-09-02
Category : Science
ISBN : 9783030540777
This book presents Pd- and Ni-catalyzed transformations generating functionalized heterocycles. Transition metal catalysis is at the forefront of synthetic organic chemistry since it offers new and powerful methods to forge carbon–carbon bonds in high atom- and step-economy. In Chapter 1, the author describes a Pd- and Ni-catalyzed cycloisomerization of aryl iodides to alkyl iodides, known as carboiodination. In the context of the Pd-catalyzed variant, the chapter explores the production of enantioenriched carboxamides through diastereoselective Pd-catalyzed carboiodination. It then discusses Ni-catalyzed reactions to generate oxindoles and an enantioselective variant employing a dual ligand system. Chapter 2 introduces readers to a Pd-catalyzed diastereoselective anion-capture cascade. It also examines diastereoselective Pd-catalyzed aryl cyanation to synthesize alkyl nitriles, a method that generates high yields of borylated chromans as a single diastereomer, and highlights its synthetic utility. Lastly, Chapter 3 presents a Pd-catalyzed domino process harnessing carbopalladation, C–H activation and π-system insertion (benzynes and alkynes) to generate spirocycles. It also describes the mechanistic studies performed on these reactions.
Author : Anonim
Publisher : Unknown
Page : 860 pages
File Size : 40,5 Mb
Release : 1964
Category : Aeronautics
ISBN : UOM:39015006086881