Organic Synthesis With Palladium Compounds

Author : Jiro Tsuji
Publisher : Springer Science & Business Media
Page : 221 pages
File Size : 49,7 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783642674754

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Organic Synthesis with Palladium Compounds by Jiro Tsuji Pdf

Around 30 years ago the transition metal chemistry received great impulses. In the focus have been reactions of nickel and cobalt and herein especially their carbonyls. Also industrial processes have been developed. When the technical oxidation of ethylene with palladium chloride had been discovered, and a great number oflaboratory reactions, many groups have turned towards this subject. Apart from two important industrial processes - acetaldehyde and vinylacetate from ethylene - a great number of conversions and catalytic reactions with palladium compounds have been researched. Their mechanisms have been cleared up and have con tributed to a better understanding of the complex chemistry of palladium. Last but not least these reactions have also served for more understanding of organic transition metal compounds and catalyses in general. Numerous conventional reactions appear today in a different light. The effects of co-

Author : Jiro Tsuji
Publisher : Springer Science & Business Media
Page : 348 pages
File Size : 42,5 Mb
Release : 2005-07-06
Category : Science
ISBN : 3540239820

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Palladium in Organic Synthesis by Jiro Tsuji Pdf

with contributions by numerous experts

Author : Ei-ichi Negishi,Armin de Meijere
Publisher : John Wiley & Sons
Page : 1697 pages
File Size : 41,6 Mb
Release : 2003-11-24
Category : Science
ISBN : 9780471461555

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Handbook of Organopalladium Chemistry for Organic Synthesis by Ei-ichi Negishi,Armin de Meijere Pdf

Organized to provide maximum utility to the bench synthetic chemist. The editor is well-known for his work in exploring, developing, and applying organopalladium chemistry. Contributors include over 24 world authorities in the field.

Author : Jiro Tsuji
Publisher : Unknown
Page : 596 pages
File Size : 40,8 Mb
Release : 1995
Category : Science
ISBN : UOM:39015055710860

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Palladium Reagents and Catalysts by Jiro Tsuji Pdf

Basic chemistry of organopalladium compounds; Classification of the reactions involving Pd(II) compounds and Pd(O) complexes.

Author : Jiro Tsuji
Publisher : Wiley
Page : 670 pages
File Size : 41,6 Mb
Release : 2004-06-25
Category : Science
ISBN : 0470850337

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Palladium Reagents and Catalysts by Jiro Tsuji Pdf

Jiro Tsuji, one of the pioneers in this field of organic synthesis, provides synthetic organic chemists with a remarkable overview of the many applications of organopalladium chemistry. Tsuji discusses the recent developments in the field as well as the explosive growth over the last five years. Highlighting the most recent discoveries in this rapidly expanding field, the book; Focuses on new aspects of organopalladium chemistry, putting emphasis on synthetic applications Investigates the new perspectives on the synthetic uses of contemporary organopalladium chemistry This volume, together with Innovations in Organic Synthesis, Tsuji's previous title, provides complete coverage of over 40 years of organopalladium chemistry. Palladium Reagents and Catalysts: New Perspectives for the 21st Century is an essential reference source and companion for students, and both industrial and academic research chemists working in organic synthesis, particularly on synthesis of natural products and medicinal compounds. Those studying development of new synthetic methodology and organometallic chemistry will also find this book valuable.

Author : Roderick Bates
Publisher : John Wiley & Sons
Page : 5 pages
File Size : 43,5 Mb
Release : 2012-04-12
Category : Science
ISBN : 9781118313664

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Organic Synthesis Using Transition Metals by Roderick Bates Pdf

Transition metals open up new opportunities for synthesis, because their means of bonding and their reaction mechanisms differ from those of the elements of the s and p blocks. In the last two decades the subject has mushroomed - established reactions are seeing both technical improvements and increasing numbers of applications, and new reactions are being developed. The practicality of the subject is demonstrated by the large number of publications coming from the process development laboratories of pharmaceutical companies, and its importance is underlined by the fact that three Nobel prizes have been awarded for discoveries in this field in the 21st Century already. Organic Synthesis Using Transition Metals, 2nd Edition considers the ways in which transition metals, as catalysts and reagents, can be used in organic synthesis, both for pharmaceutical compounds and for natural products. It concentrates on the bond-forming reactions that set transition metal chemistry apart from "classical" organic chemistry. Each chapter is extensively referenced and provides a convenient point of entry to the research literature. Topics covered include: introduction to transition metals in organic synthesis coupling reactions C-H activation carbonylative coupling reactions alkene and alkyne insertion reactions electrophilic alkene and alkyne complexes reactions of alkyne complexes carbene complexes h3- or p-allyl -allyl complexes diene, dienyl and arene complexes cycloaddition and cycloisomerisation reactions For this second edition the text has been extensively revised and expanded to reflect the significant improvements and advances in the field since the first edition, as well as the large number of new transition metal-catalysed processes that have come to prominence in the last 10 years – for example the extraordinary progress in coupling reactions using “designer” ligands, catalysis using gold complexes, new opportunities arising from metathesis chemistry, and C-H activation – without neglecting the well established chemistry of metals such as palladium. Organic Synthesis Using Transition Metals, 2nd Edition will find a place on the bookshelves of advanced undergraduates and postgraduates working in organic synthesis, catalysis, medicinal chemistry and drug discovery. It is also useful for practising researchers who want to refresh and enhance their knowledge of the field.

Author : Ei-ichi Negishi
Publisher : Wiley-Interscience
Page : 3424 pages
File Size : 45,5 Mb
Release : 2002-08-12
Category : Science
ISBN : 0471315060

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Handbook of Organopalladium Chemistry for Organic Synthesis, 2 Volume Set by Ei-ichi Negishi Pdf

Organized to provide maximum utility to the bench synthetic chemist. The editor is well-known for his work in exploring, developing, and applying organopalladium chemistry. Contributors include over 24 world authorities in the field.

Author : Jiro Tsuji
Publisher : John Wiley & Sons
Page : 670 pages
File Size : 41,5 Mb
Release : 2006-02-08
Category : Science
ISBN : 9780470021194

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Palladium Reagents and Catalysts by Jiro Tsuji Pdf

Jiro Tsuji, one of the pioneers in this field of organic synthesis, provides synthetic organic chemists with a remarkable overview of the many applications of organopalladium chemistry. Tsuji discusses the recent developments in the field as well as the explosive growth over the last five years. Highlighting the most recent discoveries in this rapidly expanding field, the book; Focuses on new aspects of organopalladium chemistry, putting emphasis on synthetic applications Investigates the new perspectives on the synthetic uses of contemporary organopalladium chemistry This volume, together with Innovations in Organic Synthesis, Tsuji's previous title, provides complete coverage of over 40 years of organopalladium chemistry. Palladium Reagents and Catalysts: New Perspectives for the 21st Century is an essential reference source and companion for students, and both industrial and academic research chemists working in organic synthesis, particularly on synthesis of natural products and medicinal compounds. Those studying development of new synthetic methodology and organometallic chemistry will also find this book valuable.

Author : L. Brandsma,S.F. Vasilevsky,H.D. Verkruijsse
Publisher : Springer Science & Business Media
Page : 349 pages
File Size : 49,5 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783642603280

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Application of Transition Metal Catalysts in Organic Synthesis by L. Brandsma,S.F. Vasilevsky,H.D. Verkruijsse Pdf

Homogeneous catalysis is an important strategy for the synthesis of high-valued chemicals. L. Brandsma has carefully selected and checked the experimental procedures illustrating the catalytic use of copper, nickel, and palladium compounds in organic synthesis. All procedures are on a preparative scale, make economic use of solvents and catalysts, avoid toxic substances and have high yields.

Author : Peter Maitlis
Publisher : Elsevier
Page : 336 pages
File Size : 49,7 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323155328

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Metal Complexes by Peter Maitlis Pdf

The Organic Chemistry of Palladium, Volume 1: Metal Complexes deals with the number of organic reactions that can be catalyzed by palladium, particularly as regards the structures bonding, and reactions of the metal complexes. The book discusses monodentate ligands which are either neutral (carbonyls, isonitriles, carbenes) or anionic (methyl, phenyl, ethynyl, hydride). The text also examines the complexes formed by 1,3-. 1,4-, and 1,5-diolefins where four carbon atoms are bound to the metal. Palladium (II) can undergo a reaction with the 1,3-dienes and results in a ?-allylic complexes where only three carbon atoms are coordinated to the metal. (The bonding situation in complexes 1,4- and 1,5-dienes, where no great interaction between the olefins are similar to that in monoolefin complexes, is straightforward), Olefins can also react with palladium chloride in protic solvents to produce ketones (or aldehydes) or organic coupling products. Some experiments conducted by Huttel et al shows that some palladium was precipitated from the reactions giving lower yields, resulting in various aldehydes and ketones as by products. The book also discusses cyclopentadienyl and benzene complexes. The text can prove beneficial for researchers, investigators and scientists whose works involve organic chemistry, analytical chemistry, physical chemistry and inorganic chemistry.

Author : P. Henry
Publisher : Springer Science & Business Media
Page : 449 pages
File Size : 43,6 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789400994461

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Palladium Catalyzed Oxidation of Hydrocarbons by P. Henry Pdf

The field of organometallic chemistry has emerged over the last twenty-five years or so to become one of the most important areas of chemistry, and there are no signs of abatement in the intense current interest in the subject, particularly in terms of its proven and potential application in catalytic reactions involving hydrocarbons. The development of the organometallic/ catalysis area has resulted in no small way from many contributions from researchers investigating palladium systems. Even to the well-initiated, there seems a bewildering and diverse variety of organic reactions that are promoted by palladium(II) salts and complexes. Such homogeneous reactions include oxidative and nonoxidative coupling of substrates such as olefins, dienes, acetylenes, and aromatics; and various isomerization, disproportionation, hydrogenation, dehydrogenation, car bonylation and decarbonylation reactions, as well as reactions involving formation of bonds between carbon and halogen, nitrogen, sulfur, and silicon. The books by Peter M. Maitlis - The Organic Chemistry of Palladium, Volumes I, II, Academic Press, 1971 - serve to classify and identify the wide variety of reactions, and access to the vast literature is available through these volumes and more recent reviews, including those of J. Tsuji [Accounts Chem. Res. , 6, 8 (1973); Adv. in Organometal. , 17, 141 (1979)], R. F. Heck [Adv. in Catat. , 26, 323 (1977)], and ones by Henry [Accounts Chem. Res. , 6, 16 (1973); Adv. in Organometal. , 13, 363 (1975)]. F. R. Hartley's book - The Chemistry of Platinum and Palladium, App!. Sci. Pub!.

Author : Manas Sutradhar
Publisher : MDPI
Page : 68 pages
File Size : 48,8 Mb
Release : 2021-08-30
Category : Science
ISBN : 9783036510620

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Metal-Based Catalysts in Organic Synthesis by Manas Sutradhar Pdf

Catalysts play a crucial role in the path towards the transformation of organic compounds. This book describes the recent development of metal-based catalysis in organic synthesis. Applications of various catalysts to interesting organic transformations are discussed. It covers important organic reactions such as cyclohexane oxidation under different energy stimuli, use of Pd-nanoparticles for carbonylation of aniline, ammoximation of methyl ethyl ketone by Ni-modified TS-1 and carbozincation of substituted 2-alkynylamines. This book will be a useful reference for researchers in the field of catalysis, organic chemistry and materials science. It is also intended to attract the attention of researchers with an industrial interest.

Author : Navjeet Kaur
Publisher : CRC Press
Page : 432 pages
File Size : 55,9 Mb
Release : 2019-05-01
Category : Medical
ISBN : 9781351242608

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Palladium Assisted Synthesis of Heterocycles by Navjeet Kaur Pdf

This book is a compilation of the recent applications of palladium catalysts in organic synthesis. The book demonstrates that it is a highly dynamic research field. This methodology has emerged as a powerful tool for the efficient and chemoselective synthesis of heterocyclic molecules. In the past few years, several strategies have been pointed out to pursue more efficient, sustainable, and environment friendly chemical processes. Among those strategies, catalysis and the design of new processes that avoid the use of toxic reagents have been the focus of intense research.

Author : Anthony J. Pearson
Publisher : Unknown
Page : 240 pages
File Size : 49,5 Mb
Release : 1994
Category : Science
ISBN : UOM:39015032425731

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Iron Compounds in Organic Synthesis by Anthony J. Pearson Pdf

Despite this, the use of organoiron complexes in organic synthesis has been somewhat restricted compared with, for example, palladium, rhodium and other metals that are mainly used in catalytic processes.

Author : Jiro Tsuji
Publisher : Unknown
Page : 199 pages
File Size : 41,6 Mb
Release : 1975
Category : Organic compounds
ISBN : 0387072276

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Organic Synthesis by Means of Transition Metal Complexes by Jiro Tsuji Pdf