Physical Chemistry Volume 1 Book in PDF, ePub and Kindle version is available to download in english. Read online anytime anywhere directly from your device. Click on the download button below to get a free pdf file of Physical Chemistry Volume 1 book. This book definitely worth reading, it is an incredibly well-written.
Author : Peter Atkins,Julio de Paula Publisher : W. H. Freeman Page : 0 pages File Size : 49,9 Mb Release : 2010-02-26 Category : Science ISBN : 1429231270
Physical Chemistry Volume 1: Thermodynamics and Kinetics by Peter Atkins,Julio de Paula Pdf
With its modern emphasis on the molecular view of physical chemistry, its wealth of contemporary applications, vivid full-color presentation, and dynamic new media tools, the thoroughly revised new edition is again the most modern, most effective full-length textbook available for the physical chemistry classroom. Volume 1 of Physical Chemistry, Ninth Edition, contains the new edition’s new Fundamentals chapters (Chapter 0), plus coverage of thermodynamics (Chapters 1-6) and kinetics (Chapters 20-23)
A Textbook of Physical Chemistry – Volume 1 by Mandeep Dalal Pdf
An advanced-level textbook of physical chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Physical Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Quantum Mechanics – I: Postulates of quantum mechanics; Derivation of Schrodinger wave equation; Max-Born interpretation of wave functions; The Heisenberg’s uncertainty principle; Quantum mechanical operators and their commutation relations; Hermitian operators (elementary ideas, quantum mechanical operator for linear momentum, angular momentum and energy as Hermition operator); The average value of the square of Hermitian operators; Commuting operators and uncertainty principle(x & p; E & t); Schrodinger wave equation for a particle in one dimensional box; Evaluation of average position, average momentum and determination of uncertainty in position and momentum and hence Heisenberg’s uncertainty principle; Pictorial representation of the wave equation of a particle in one dimensional box and its influence on the kinetic energy of the particle in each successive quantum level; Lowest energy of the particle. Chapter 2. Thermodynamics – I: Brief resume of first and second Law of thermodynamics; Entropy changes in reversible and irreversible processes; Variation of entropy with temperature, pressure and volume; Entropy concept as a measure of unavailable energy and criteria for the spontaneity of reaction; Free energy, enthalpy functions and their significance, criteria for spontaneity of a process; Partial molar quantities (free energy, volume, heat concept); Gibb’s-Duhem equation. Chapter 3. Chemical Dynamics – I: Effect of temperature on reaction rates; Rate law for opposing reactions of Ist order and IInd order; Rate law for consecutive & parallel reactions of Ist order reactions; Collision theory of reaction rates and its limitations; Steric factor; Activated complex theory; Ionic reactions: single and double sphere models; Influence of solvent and ionic strength; The comparison of collision and activated complex theory. Chapter 4. Electrochemistry – I: Ion-Ion Interactions: The Debye-Huckel theory of ion- ion interactions; Potential and excess charge density as a function of distance from the central ion; Debye Huckel reciprocal length; Ionic cloud and its contribution to the total potential; Debye - Huckel limiting law of activity coefficients and its limitations; Ion-size effect on potential; Ion-size parameter and the theoretical mean-activity coefficient in the case of ionic clouds with finite-sized ions; Debye - Huckel-Onsager treatment for aqueous solutions and its limitations; Debye-Huckel-Onsager theory for non-aqueous solutions; The solvent effect on the mobality at infinite dilution; Equivalent conductivity (Λ) vs. concentration c 1/2 as a function of the solvent; Effect of ion association upon conductivity (Debye- Huckel - Bjerrum equation). Chapter 5. Quantum Mechanics – II: Schrodinger wave equation for a particle in a three dimensional box; The concept of degeneracy among energy levels for a particle in three dimensional box; Schrodinger wave equation for a linear harmonic oscillator & its solution by polynomial method; Zero point energy of a particle possessing harmonic motion and its consequence; Schrodinger wave equation for three dimensional Rigid rotator; Energy of rigid rotator; Space quantization; Schrodinger wave equation for hydrogen atom, separation of variable in polar spherical coordinates and its solution; Principle, azimuthal and magnetic quantum numbers and the magnitude of their values; Probability distribution function; Radial distribution function; Shape of atomic orbitals (s,p & d). Chapter 6. Thermodynamics – II: Classius-Clayperon equation; Law of mass action and its thermodynamic derivation; Third law of thermodynamics (Nernest heat theorem, determination of absolute entropy, unattainability of absolute zero) and its limitation; Phase diagram for two completely miscible components systems; Eutectic systems, Calculation of eutectic point; Systems forming solid compounds Ax By with congruent and incongruent melting points; Phase diagram and thermodynamic treatment of solid solutions. Chapter 7. Chemical Dynamics – II: Chain reactions: hydrogen-bromine reaction, pyrolysis of acetaldehyde, decomposition of ethane; Photochemical reactions (hydrogen - bromine & hydrogen -chlorine reactions); General treatment of chain reactions (ortho-para hydrogen conversion and hydrogen - bromine reactions); Apparent activation energy of chain reactions, Chain length; Rice-Herzfeld mechanism of organic molecules decomposition(acetaldehyde); Branching chain reactions and explosions ( H2-O2 reaction); Kinetics of (one intermediate) enzymatic reaction : Michaelis-Menton treatment; Evaluation of Michaelis 's constant for enzyme-substrate binding by Lineweaver-Burk plot and Eadie-Hofstae methods; Competitive and non-competitive inhibition. Chapter 8. Electrochemistry – II: Ion Transport in Solutions: Ionic movement under the influence of an electric field; Mobility of ions; Ionic drift velocity and its relation with current density; Einstein relation between the absolute mobility and diffusion coefficient; The Stokes- Einstein relation; The Nernst -Einstein equation; Walden’s rule; The Rate-process approach to ionic migration; The Rate process equation for equivalent conductivity; Total driving force for ionic transport, Nernst - Planck Flux equation; Ionic drift and diffusion potential; the Onsager phenomenological equations; The basic equation for the diffusion; Planck-Henderson equation for the diffusion potential.
Author : Peter William Atkins,Julio De Paula Publisher : Oxford University Press, USA Page : 1149 pages File Size : 48,9 Mb Release : 2002 Category : Chemistry ISBN : 0198792859
Atkins' Physical Chemistry by Peter William Atkins,Julio De Paula Pdf
This major revision of the world's leading textbook of physical chemistry has maintained its tradition of accessibility but authority and has brought it thoroughly up to date. The new author team has introduced many innovations. There are new or rewritten chapters on the solid state, on molecular interactions, macromolecules, and electron transfer. Almost every chapter has at least one Box showing the relevance of the material to modern chemistry. All the chapters now conclude with a check list which includes definitions and key equations. The authors have paid special attention to the presentation of mathematical derivations and to the physical interpretation of equations. They have also ensured that the text is highly modular, so that it can be used in different sequences, either atoms first or thermodynamics first. The art program has been redrawn and extended, new Discussion questions have been added, and the Further Information sections have been recast to provide the necessary background in mathematics and physics. The text is fully geared to the web, with full media support. SUPPLEMENTS AND SUPPORT MATERIAL: 1. Web site featuring Living Graphs (about 150). Dynamic, interactive graphs that allow experimentation and hands-on learning. Web links to sources of data and other information, as referred to in the book. 2. Student's Solutions Manual containing worked solutions to half the end of chapter exercises and problems in the parenttext. 3. Instructor's Solutions Manual, FREE to adopters of the parent text, containing worked solutions to the other half of the end of chapter exercises and problems in the parent text. Contains a CD-ROM with all the illustrations from the text, for use in presentations. 4. MathCad/Mathematica supplement book with CD-ROM to take all living graphs further. NEW TO THIS EDITION: DT New co-author Julio de Paula, a biophysical chemist, strengthens the text's coverage of biologicalapplications. DT Margin notes provide help with mathematics just where it is needed. DT Boxes added to every chapter to cover biological applications, environmental, materials science and chemical engineering. Each box has two problems, and suggestions for further reading. DT Important equations and definitions added to the 'key concepts' section of every chapter. DT Microprojects used to be separate sections at end of every Part. These (most of them) have been integrated into the appropriate chapter's end-of-chapter exercises. DT More help with the mathematical development of derivations: marginal notes are provided, many derivations now include more steps (justifications), the section on mathematical techniques in Further Information sections has been rewritten, as has the Further Information section on concepts of physics. DT Fully integrated media support. The new feature of Living Graphs are flagged by an icon in the textbook, and marginal notes refer the reader to the weblinks to be found on the book's free web site. DT The chapters are modular so that they may be read in different orders for different courses. Road Maps are provided that suggest different routes through the text for the following types of course organizations: (a) thermodynamics first, (b) atoms first (quantum mechanics first). DT There is a separate section in of end-of-chapter exercises specifically for applications. DT End-of-chapter problems for which solutions are provided in the Student's Solutions Manual are now indicated by colour. MODERNIZATION DT More coverage of modern topics throughout the text. Some examples, by section of the book: PART 1: Illustrations of partial derivatives added Added Boxes, more practical and more biological applications PART 2: Chapter 14 includes computational chemistry Enhancements to quantum mechanics coverage: addition of materials science in Chapters 22 and 23 More modern spectroscopy, more computational chemistry Chapter 21: new chapter on molecular interactions Chapter 22 on macromolecules emphasizes polymers and biological polymers PART 3: Organized to make selective use easier (made more modular) Chapter 29: more modern treatment of electron transfer theory in solutions, biological systems, and solid state For a complete list of changes to the book since the last edition, see the web site at www.oup.com/pchem7
A Textbook of Physical Chemistry by Arthur Adamson Pdf
A Textbook of Physical Chemistry, Second Edition serves as an introductory text to physical chemistry. Topics covered range from wave mechanics and chemical bonding to molecular spectroscopy and photochemistry; ideal and nonideal gases; the three laws of thermodynamics; thermochemistry; and solutions of nonelectrolytes. The kinetics of gas-phase reactions; colloids and macromolecules; and nuclear chemistry and radiochemistry are also discussed. This edition is comprised of 22 chapters; the first of which introduces the reader to the behavior of ideal and nonideal gases, with particular emphasis on the van der Waals equation. The discussion then turns to the kinetic molecular theory of gases and the application of the Boltzmann principle to the treatment of molar polarization; dipole and magnetic moments; the phenomenology of light absorption; and classical and statistical thermodynamics. The chapters that follow focus on the traditional sequence of chemical and phase equilibria, electrochemistry, and chemical kinetics in gas phase and solution phase. This book also considers wave mechanics and its applications; molecular spectroscopy and photochemistry; and the excited state, and then concludes with an analysis of crystal structure, colloid and polymer chemistry, and radio and nuclear chemistry. This reference material is intended primarily as an introductory text for students of physical chemistry.
The Elements of Physical Chemistry by Peter William Atkins Pdf
This revision of the introductory textbook of physical chemistry has been designed to broaden its appeal, particularly to students with an interest in biological applications.
Author : Peter Atkins,Julio de Paula Publisher : W. H. Freeman Page : 0 pages File Size : 53,7 Mb Release : 2014-01-17 Category : Science ISBN : 1429290196
Physical Chemistry by Peter Atkins,Julio de Paula Pdf
Edition after edition, Atkins and de Paula's #1 bestseller remains the most contemporary, most effective full-length textbook for courses covering thermodynamics in the first semester and quantum mechanics in the second semester. Its molecular view of physical chemistry, contemporary applications, student friendly pedagogy, and strong problem-solving emphasis make it particularly well-suited for pre-meds, engineers, physics, and chemistry students. Now organized into briefer, more manageable topics, and featuring additional applications and mathematical guidance, the new edition helps students learn more effectively, while allowing instructors to teach the way they want. Available in Split Volumes For maximum flexibility in your physical chemistry course, this text is now offered as a traditional text or in two volumes: Volume 1: Thermodynamics and Kinetics: 1-4641-2451-5 Volume 2: Quantum Chemistry: 1-4641-2452-3
Physical Chemistry for the Biosciences by Raymond Chang Pdf
This book is ideal for use in a one-semester introductory course in physical chemistry for students of life sciences. The author's aim is to emphasize the understanding of physical concepts rather than focus on precise mathematical development or on actual experimental details. Subsequently, only basic skills of differential and integral calculus are required for understanding the equations. The end-of-chapter problems have both physiochemical and biological applications.
Molecular Physical Chemistry by José J. C. Teixeira-Dias Pdf
This is the physical chemistry textbook for students with an affinity for computers! It offers basic and advanced knowledge for students in the second year of chemistry masters studies and beyond. In seven chapters, the book presents thermodynamics, chemical kinetics, quantum mechanics and molecular structure (including an introduction to quantum chemical calculations), molecular symmetry and crystals. The application of physical-chemical knowledge and problem solving is demonstrated in a chapter on water, treating both the water molecule as well as water in condensed phases. Instead of a traditional textbook top-down approach, this book presents the subjects on the basis of examples, exploring and running computer programs (Mathematica®), discussing the results of molecular orbital calculations (performed using Gaussian) on small molecules and turning to suitable reference works to obtain thermodynamic data. Selected Mathematica® codes are explained at the end of each chapter and cross-referenced with the text, enabling students to plot functions, solve equations, fit data, normalize probability functions, manipulate matrices and test physical models. In addition, the book presents clear and step-by-step explanations and provides detailed and complete answers to all exercises. In this way, it creates an active learning environment that can prepare students for pursuing their own research projects further down the road. Students who are not yet familiar with Mathematica® or Gaussian will find a valuable introduction to computer-based problem solving in the molecular sciences. Other computer applications can alternatively be used. For every chapter learning goals are clearly listed in the beginning, so that readers can easily spot the highlights, and a glossary in the end of the chapter offers a quick look-up of important terms.
Atkins' Physical Chemistry 11e by Peter Atkins,Julio de Paula,James Keeler Pdf
Atkins' Physical Chemistry: Molecular Thermodynamics and Kinetics is designed for use on the second semester of a quantum-first physical chemistry course. Based on the hugely popular Atkins' Physical Chemistry, this volume approaches molecular thermodynamics with the assumption that students will have studied quantum mechanics in their first semester. The exceptional quality of previous editions has been built upon to make this new edition of Atkins' Physical Chemistry even more closely suited to the needs of both lecturers and students. Re-organised into discrete 'topics', the text is more flexible to teach from and more readable for students. Now in its eleventh edition, the text has been enhanced with additional learning features and maths support to demonstrate the absolute centrality of mathematics to physical chemistry. Increasing the digestibility of the text in this new approach, the reader is brought to a question, then the math is used to show how it can be answered and progress made. The expanded and redistributed maths support also includes new 'Chemist's toolkits' which provide students with succinct reminders of mathematical concepts and techniques right where they need them. Checklists of key concepts at the end of each topic add to the extensive learning support provided throughout the book, to reinforce the main take-home messages in each section. The coupling of the broad coverage of the subject with a structure and use of pedagogy that is even more innovative will ensure Atkins' Physical Chemistry remains the textbook of choice for studying physical chemistry.
Author : Peter Atkins,Julio De Paula Publisher : W H Freeman & Company Page : 128 pages File Size : 45,6 Mb Release : 2011-06-15 Category : Science ISBN : 1464104913
Physical Chemistry Vol 1, Student Solutions Manual + Access Card for Exploring Physical Chemistry by Peter Atkins,Julio De Paula Pdf
With its modern emphasis on the molecular view of physical chemistry, its wealth of contemporary applications, vivid full-color presentation, and dynamic new media tools, the thoroughly revised new edition is again the most modern, most effective full-length textbook available for the physical chemistry classroom. Volume 1 of "Physical Chemistry," Ninth Edition, contains the new edition's new Fundamentals chapters (Chapter 0), plus coverage of thermodynamics (Chapters 1-6) and kinetics (Chapters 20-23)
