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Author : Neil S. Isaacs
Publisher : John Wiley & Sons
Page : 572 pages
File Size : 49,6 Mb
Release : 1974
Category : Chemical reactions
ISBN : UCAL:B4476790
Author : Maya Shankar Singh
Publisher : John Wiley & Sons
Page : 296 pages
File Size : 46,5 Mb
Release : 2014-01-22
Category : Science
ISBN : 9783527678273
Most reactions in organic chemistry do not proceed in a single step but rather take several steps to yield the desired product. In the course of these multi-step reaction sequences, short-lived intermediates can be generated that quickly convert into other intermediates, reactants, products or side products. As these intermediates are highly reactive, they cannot usually be isolated, but their existence and structure can be proved by theoretical and experimental methods. Using the information obtained, researchers can better understand the underlying reaction mechanism of a certain organic transformation and thus develop novel strategies for efficient organic synthesis. The chapters are clearly structured and are arranged according to the type of intermediate, providing information on the formation, characterization, stereochemistry, stability, and reactivity of the intermediates. Additionally, representative examples and a problem section with different levels of difficulty are included for self-testing the newly acquired knowledge. By providing a deeper understanding of the underlying concepts, this is a musthave reference for PhD and Master Students in organic chemistry, as well as a valuable source of information for chemists in academia and industry working in the field. It is also ideal as primary or supplementary reading for courses on organic chemistry, physical organic chemistry or analytical chemistry.
Author : Curt Wentrup
Publisher : Wiley-Interscience
Page : 360 pages
File Size : 54,8 Mb
Release : 1984-03-21
Category : Science
ISBN : UCAL:B4476799
Designed for advanced undergraduate and graduate organic chemistry students, here's an up-to-date, in-depth textbook on the chemistry of neutral reactive intermediates--free radicals, diradicals, carbenes, nitrenes, strained rings, and antiaromatics. Includes numerous tables of physical data and extensive references to present day research in the field.
Author : Matthew S. Platz,Robert A. Moss,Maitland Jones, Jr.
Publisher : John Wiley & Sons
Page : 492 pages
File Size : 42,7 Mb
Release : 2007-04-20
Category : Science
ISBN : 9780470120811
The chemistry of reactive intermediates is central to a modern mechanistic and quantitative understanding of organic chemistry. Moreover, it underlies a significant portion of modern synthetic chemistry and is integral to a molecular view of biological chemistry. Reviews in Reactive Intermediate Chemistry presents an up-to-date, authoritative guide to this fundamental topic. Although it follows Reactive Intermediate Chemistry by the same authors, it serves as a free-standing resource for the entire chemical and biochemical community. The book includes: Relevant, practical applications Coverage of such topics as mass spectrometry methods, reactive intermediates in interstellar medium, quantum mechanical tunnelling, solvent effects, reactive intermediates in biochemical processes, and excited state surfaces Discussions of emerging areas, particularly those involving dynamics and theories Concluding sections identifying key directions for future research are provided at the end of each chapter
Author : Robert A. Moss,Matthew S. Platz,Maitland Jones, Jr.
Publisher : John Wiley & Sons
Page : 1088 pages
File Size : 44,9 Mb
Release : 2004-01-07
Category : Science
ISBN : 0471233242
Reactive Intermediate Chemistry presents a detailed and timely examination of key intermediates central to the mechanisms of numerous organic chemical transformations. Spectroscopy, kinetics, and computational studies are integrated in chapters dealing with the chemistry of carbocations, carbanions, radicals, radical ions, carbenes, nitrenes, arynes, nitrenium ions, diradicals, etc. Nanosecond, picosecond, and femtosecond kinetic realms are explored, and applications of current dynamics and electronic structure calculations are examined. Reactive Intermediate Chemistry provides a deeper understanding of contemporary physical organic chemistry, and will assist chemists in the design of new reactions for the efficient synthesis of pharmaceuticals, fine chemicals, and agricultural products. Among its features, this authoritative volume is: Edited and authored by world-renowned leaders in physical organic chemistry. Ideal for use as a primary or supplemental graduate textbook for courses in mechanistic organic chemistry or physical chemistry. Enhanced by supplemental reading lists and summary overviews in each chapter.
Author : Samuel McManus
Publisher : Elsevier
Page : 552 pages
File Size : 55,9 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323146272
Organic Chemistry: A Series of Monographs, Volume 26: Organic Reactive Intermediates focuses on the study of reactive intermediates. This book discusses the methods of formation and investigation, factors affecting the stability, and reactions of the intermediate. Other topics include the formation and reaction of free radicals; kinetic aspects of free-radical chain reactions; electronic states and structures of carbenes; and formation of transient carbenes and carbenoids in solution. The intermediacy of nitrenes in reactions; electronic structure and spectra; methods of investigating carbonium ions; and reactions of carbonium ions are also elaborated. This publication likewise covers the preparation of carbanions; factors affecting the stability of carbanions; reactions involving radical ions; and methods of investigating arynes. This volume serves as a textbook for the first graduate-level course, as well as a reference for industrial chemists interested in organic reaction mechanisms.
Author : Christopher J. Moody,Gordon Harlow Whitham
Publisher : Unknown
Page : 91 pages
File Size : 43,8 Mb
Release : 2006
Category : Intermediates (Chemistry)
ISBN : 0191848905
Neutral reactive intermediates play a key role in synthetic chemistry. This primer concentrates on this role; the important reactions of these electron-deficient species are laid out clearly and simply, with carefully chosen examples illustrating their use in organic synthesis. Each chapter includes a few problems as well as suggestions for further reading, and provides undergraduates with an invaluable summary of this important topic in organic chemistry.
Author : John E. Leffler
Publisher : Unknown
Page : 298 pages
File Size : 48,6 Mb
Release : 1956
Category : Chemical reactions
ISBN : STANFORD:36105006401330
Author : N. S. Isaacs
Publisher : Unknown
Page : 550 pages
File Size : 47,7 Mb
Release : 1979
Category : Electronic
ISBN : OCLC:1123525895
Author : R.A. Abramovitch
Publisher : Springer Science & Business Media
Page : 609 pages
File Size : 54,5 Mb
Release : 2012-12-06
Category : Science
ISBN : 9781461331926
The field of reactive intermediates has been blossoming at a rapid rate in recent years and its impact on chemistry, both "pure" and "applied," as well as on biology, astronomy, and other areas of science, is enormous. Several books have been published which cover the area; one, edited by McManus, * surveys the subject in general at the senior undergraduate or beginning graduate level. In addition, a number of monographs have appeared which deal with individual topics such as carbenes, nitrenes, free radicals, carbanions, carbenium ions, and so on, in great depth. Our objective is somewhat different. We hope that these Advances in . . . type of volumes will appear at irregular intervals of a year to 18 months each. We intend to publish up-to-date reviews in relatively new areas of the chemistry of reactive intermediates. These will be written by world authorities in the field, each one of whom will give the reader a current in-depth review of all aspects of the chemistry of each of these species. It is our plan that the subjects to be reviewed will cover not only organic chemistry but also inorganic, physical, bio-, industrial, and atmospheric chemistry. The volumes themselves, we hope, will end up being reasonably interdisciplinary, though this need not and probably will not be the case for the individual reviews.
Author : Jay Kochi
Publisher : Elsevier
Page : 642 pages
File Size : 41,7 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323144100
Organometallic Mechanisms and Catalysis: The Role of Reactive Intermediates in Organic Processes covers the mechanistic delineation of organometallic chemistry and catalysis. This book is organized into three parts encompassing 18 chapters. The first part describes first the oxidation-reduction process of organometals, followed by discussions on the catalytic reactions of peroxides, metal-catalyzed addition to olefins, and reduction of organic halides. This part also explores other reactions involving transition metal carbonyls and metal-catalyzed reactions of aromatic diazonium salts. The second part deals with some chemical aspects of organometals, such as their stability, thermochemistry, decomposition, hemolytic pathways, and the formation of carbon-carbon bonds. The third part examines the charge transfer processes and interactions of organometals with electron acceptors. This part further looks into the cleavage and insertion reactions of organometals with electrophiles, as well as the electrophilic and electron transfer mechanisms of organometals. Organic and inorganic chemists, teachers, and students will greatly benefit from this book.
Author : R.A. Abramovitch
Publisher : Springer Science & Business Media
Page : 640 pages
File Size : 40,5 Mb
Release : 2013-11-09
Category : Science
ISBN : 9781461334279
The field of reactive intermediates has been blossoming at a rapid rate in recent years and its impact on chemistry, both "pure" and "applied," as well as on biology, astronomy, and other areas of science, is enormous. Several books have been published which cover the area; one, edited by McManus, * surveys the subject in general at the senior undergraduate or beginning graduate level. In addition, a number of monographs have appeared which deal with individual topics such as carbenes, nitrenes, free radicals, carbanions, carbenium ions, and so on, in great depth. Our objective is somewhat different. We hope that these Advances in . . . type of volumes will appear at irregular intervals of a year to 18 months each. We intend to publish up-to-date reviews in relatively new areas of the chemistry of reactive intermediates. These will be written by world authorities in the field, each one of whom will give the reader a current in-depth review of all aspects of the chemistry of each of these species. It is our plan that the subjects to be reviewed will cover not only organic chemistry but also inorganic, physical, bio-, industrial, and atmospheric chemistry. The volumes themselves, we hope, will end up being reasonably interdisciplinary, though this need not and probably will not be the case for the individual reviews.
Author : John Edward Leffler
Publisher : Hassell Street Press
Page : 0 pages
File Size : 53,7 Mb
Release : 2021-09-09
Category : History
ISBN : 1014400686
This work has been selected by scholars as being culturally important and is part of the knowledge base of civilization as we know it. This work is in the public domain in the United States of America, and possibly other nations. Within the United States, you may freely copy and distribute this work, as no entity (individual or corporate) has a copyright on the body of the work. Scholars believe, and we concur, that this work is important enough to be preserved, reproduced, and made generally available to the public. To ensure a quality reading experience, this work has been proofread and republished using a format that seamlessly blends the original graphical elements with text in an easy-to-read typeface. We appreciate your support of the preservation process, and thank you for being an important part of keeping this knowledge alive and relevant.
Author : C. Chatgilialoglu,Klaus-Dieter Asmus
Publisher : Springer Science & Business Media
Page : 448 pages
File Size : 45,7 Mb
Release : 2013-03-08
Category : Science
ISBN : 9781468458749
A wonderfully successful NATO Advanced Study Institute on "Sulfur-Centered Reactive Intermediates in Chemistry and Biology" was held 18-30 June, 1989, at the Hotel Villa del Mare in Maratea, Italy. Despite the beautiful setting with mountains behind us and over looking the clear blue Mediterranean Sea under a cloudless sky (and with a private beach available), the lectures were extremely well attended. While some credit can go to the seriousness of the students, more must go to the calibre of speakers and the high quality of C. Chatgilialoglu, and Co-Director, Professor K. -D. their presentations. The Director, Dr. Asmus, are to be congratulated for putting together such an outstanding scientific program. Dr. Chatgilialoglu is also to be commended for arranging an equally stimulating social pro gram which included bus, train and boat trips to many local sites of interest. It was particularly fitting that a meeting on the chemistry and biochemistry of sulfur should be held in Italy since Italian chemists have made major contributions to our under standing of the organic chemistry of sulfur, including the chemistry of its reactive inter mediates. The early Italian interest in sulfur chemistry arose from the fact that Italy, or more specifically, Sicily, was a major world producer of sulfur prior to the development and exploitation of the Frasch process in Texas and Louisiana.
Author : Francis A. Carey,Richard J. Sundberg
Publisher : Springer Science & Business Media
Page : 1199 pages
File Size : 40,6 Mb
Release : 2007-06-27
Category : Science
ISBN : 9780387448992
The two-part, fifth edition of Advanced Organic Chemistry has been substantially revised and reorganized for greater clarity. The material has been updated to reflect advances in the field since the previous edition, especially in computational chemistry. Part A covers fundamental structural topics and basic mechanistic types. It can stand-alone; together, with Part B: Reaction and Synthesis, the two volumes provide a comprehensive foundation for the study in organic chemistry. Companion websites provide digital models for study of structure, reaction and selectivity for students and exercise solutions for instructors.