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Reactive Processing of Polymers by M.W.R. Brown,A. F. Johnson,P. D. Coates Pdf
Developments in machinery, materials and applications are outlined in the cond104 of commercial considerations and advances in fundamental understanding. The principles and benefits of polymer modification and blending via reactive extrusion are explained. A b257 of novel techniques which have developed out of the major reactive processes are also described. An additional indexed section containing several hundred abstracts from the Rapra Polymer Library database provides useful references for further reading.
Reactive Modifiers for Polymers by S. Al-Malaika Pdf
Chemical modification of polymers by reactive modifiers is no longer an academic curiosity but a commercial reality that has delivered a diverse range of speciality materials for niche markets: reactively grafted styrenic alloys, maleated polyolefins, super-tough nylons, silane modified and moisture-cured polyolefins, and thermoplastic elastomers, are but few exam ples of commercial successes. Although the approach of reactive modification of polymers has been largely achieved either in solution or in the solid state (through in situ reactions in polymer melts), it is the latter route that has attracted most attention in the last two decades owing to its flexibility and cost-effective ness. This route, referred to as reactive processing, focuses on the use of suitable reactive modifier(s) and the adoption of conventional polymer processing machinery, an extruder or a mixer, as a chemical reactor, to perform in situ targeted reactions for chemical modification of preformed polymers. This relatively simple, though scientifically highly challenging, approach to reactive modification offers unique opportunities in exploiting various reactive modifiers for the purpose of altering and transforming in a controlled manner the properties of preformed commercial polymers into new/speciality materials with tailor-made properties and custom-designed performance for target applications. Such an economically attractive route constitutes a radical diversion away from the traditional practices of manufacturing new polymers from monomers which involves massive in vestments in sophisticated technologies and chemical plants.
New Polymeric Materials by Ezio Martuscelli,Carlo Marchetta Pdf
The development of new polymeric materials has caused a considerable expansion in the field of reactive processing. These new materials are very competitive compared to the traditional ones with respect to production costs and performance. The reports published in this volume present the recent developments and emerging trends in the field of reactive processing and the physical properties of the resulting polymeric materials. Special attention is given to the chemical, kinetic and rheological aspects of reactive processing.
Reactive Processing of Polymers by V. P. Begishev,Aleksandr I︠A︡kovlevich Malkin Pdf
Discusses various technological methods of reactive processing of polymers with a special emphasis on production of large size articles. Also shows methods of scaling up from laboratory to production stage by a combination of process modeling and application of modern analytical techniques to evaluate similarity of production on different scales. This approach not only gives objective results required for precise evaluation of process kinetics, but it is applied in the book to real systems used as examples of model application. The book begins with a discussion of the chemistry of reactive processes that are then discussed from the point of view of their modeling. In the next section, analytical control methods are evaluated for their usefulness in process monitoring. The final chapter discusses details of various technological methods of reactive processing by means of 70 diagrams. It also describes how to control and introduce new processes without long trials, and design technology that is cost-efficient and environmentally friendly.
Reactive Extrusion by Günter Beyer,Christian Hopmann Pdf
This first comprehensive overview of reactive extrusion technology for over a decade combines the views of contributors from both academia and industry who share their experiences and highlight possible applications and markets. They also provide updated information on the underlying chemical and physical concepts, summarizing recent developments in terms of the material and machinery used. As a result, readers will find here a compilation of potential applications for reactive extrusion to access new and cost-effective polymeric materials, while using existing compounding machines.
Reactive Polymers: Fundamentals and Applications by Johannes Karl Fink Pdf
Reactive Polymers: Fundamentals and Applications: A Concise Guide to Industrial Polymers, Third Edition introduces engineers and scientists to a range of reactive polymers and then details their applications and performance benefits. Basic principles and industrial processes are described for each class of reactive resin (thermoset), as well as additives, the curing process, applications and uses. The initial chapters are devoted to individual resin types (e.g., epoxides, cyanacrylates), followed by more general chapters on topics such as reactive extrusion and dental applications. Injection molding of reactive polymers, radiation curing, thermosetting elastomers, and reactive extrusion equipment are covered as well. The use of reactive polymers enables manufacturers to make chemical changes at a late stage in the production process, which, in turn, cause changes in performance and properties. Material selection and control of the reaction are essential to achieve optimal performance. Material new to this edition includes the most recent developments, applications and commercial products for each chemical class of thermosets, as well as sections on fabrication methods, reactive biopolymers, recycling of reactive polymers and case studies. Covers the basics and most recent developments, including reactive biopolymers, recycling of reactive polymers, nanocomposites and fluorosilicones Offers an indispensable guide for engineers and advanced students alike Provides extensive literature and patent review Reflects a thorough review of all literature published in this area since 2014 Features revised and updated chapters to reflect the latest research in reactive polymers
Author : Peter J. Halley,Graeme A. George Publisher : Cambridge University Press Page : 445 pages File Size : 47,5 Mb Release : 2009-05-28 Category : Science ISBN : 9780521807197
Chemorheology of Polymers by Peter J. Halley,Graeme A. George Pdf
Understanding the dynamics of reactive polymer processes allows scientists to create new, high-value, high-performance polymers. This book is an indispensable resource for researchers and practitioners working in this area. It includes coverage of thermoplastics, thermoset and reactive polymers, together with practical industrial processes and modern chemorheological models and tools.
Reactive and Functional Polymers Volume One by Tomy J. Gutiérrez Pdf
Reactive and functional polymers are manufactured with the aim of improving the performance of unmodified polymers or providing functionality for different applications. These polymers are created mainly through chemical reactions, but there are other important modifications that can be carried out by physical alterations in order to obtain reactive and functional polymers. This volume presents a comprehensive analysis of these reactive and functional polymers. Reactive and Functional Polymers Volume One provides the principles and foundations for the design, development, manufacture and processing of reactive and functional polymers based primarily on biopolymers, polyesters and polyurenthanes. The text provides an in-depth review of updated sources on reactive resins and silicones. In this book, world-renowned researchers have participated, including Dr. Runcang Sun (Associate editor for the journal ‘Carbohydrate Polymers’). With its comprehensive scope and up-to-date coverage of issues and trends in Reactive and Functional Polymers, this is an outstanding book for students, professors, researchers and industrialists working in the field of polymers and plastic materials.
This is the first published book that combines the applied and fundamental aspects of reactive extrusion, a technology that has seen a tremendous growth in the past few years. It is based on a highly successful advanced technical course given by the authors at the Stevens Institute of Technology Polymer Processing Institute. The use of an extruder as a continuous reactor for processes such as polymerization, polymer modification, and blend compatibilization is gaining increasing popularity and competes with diluent-free operations with respect to efficiency and economics. The first part of the book emphasizes the technological aspects of reactive extrusion. It includes case histories of industrial applications, an analysis of existing continuous processes from reaction fundamentals and an extensive review of polymer modification reactions involving acid and anhydride functionalities and their applications. The second part of the monograph contains an exhaustive survey of virtually all chemical reactions that have been conducted in extruders; the important characteristics of over 600 processes listed in recent technical and patent literature are summarized. The engineering fundamentals of reactive extrusion are included in the third part of the book which features a full description and comparison of available extrusion equipment, heat transfer considerations and the application of polymerization engineering principles to extruder reactions. The book is intended for engineers and technologists involved in this industrially important sector of polymer processing.
Principles of Polymer Processing by Zehev Tadmor,Costas G. Gogos Pdf
Thoroughly revised edition of the classic text on polymer processing The Second Edition brings the classic text on polymer processing thoroughly up to date with the latest fundamental developments in polymer processing, while retaining the critically acclaimed approach of the First Edition. Readers are provided with the complete panorama of polymer processing, starting with fundamental concepts through the latest current industry practices and future directions. All the chapters have been revised and updated, and four new chapters have been added to introduce the latest developments. Readers familiar with the First Edition will discover a host of new material, including: * Blend and alloy microstructuring * Twin screw-based melting and chaotic mixing mechanisms * Reactive processing * Devolatilization--theory, mechanisms, and industrial practice * Compounding--theory and industrial practice * The increasingly important role of computational fluid mechanics * A systematic approach to machine configuration design The Second Edition expands on the unique approach that distinguishes it from comparative texts. Rather than focus on specific processing methods, the authors assert that polymers have a similar experience in any processing machine and that these experiences can be described by a set of elementary processing steps that prepare the polymer for any of the shaping methods. On the other hand, the authors do emphasize the unique features of particular polymer processing methods and machines, including the particular elementary step and shaping mechanisms and geometrical solutions. Replete with problem sets and a solutions manual for instructors, this textbook is recommended for undergraduate and graduate students in chemical engineering and polymer and materials engineering and science. It will also prove invaluable for industry professionals as a fundamental polymer processing analysis and synthesis reference.
Based on a highly successful PPI advanced technical course given by the author, this book combines the applied and fundamental aspects of reactive extrusion.
Polymer Reactive Processing, Stabilisation and Functionalisation by I. Meisel,C. S. Kniep,S. Spiegel,K. Grieve Pdf
In order to further develop the applications of polymers, it is necessary to control their useful life, i.e., we must know how to stabilise polymers effectively. We must therefore understand the mechanisms that cause polymers to degrade and the effects of processing and modifying the polymers on their stability. The 1st Conference on Polymer Modification, Degradation and Stabilisation (MoDeSt 2000) was held in Palermo, Italy in 2000. It brought together scientists and technologists from a range of academic and industrial backgrounds to discuss the topics in a dedicated environment. This volume of Macromolecular Symposia presents invited lectures from two of the sessions -- 'Processing and Melt Stabilisation' and 'Functionalisation and Reactive Processing'. It therefore represents a good sample of very recent work in these areas.
Major advancement has occurred in preparing useful polymer blends, in most cases using some form of compatibilization. While physical compatibilization using block copolymers was the technique of choice in the past, increasingly reactive approaches have been used. Much enabling technology is required to produce commercially viable blends including compatibilization chemistry, blend rheology, process equipment and morphology control. This volume is particularly suitable for students as a graduate level textbook and for practitioners trying to optimize these products and processes.
Processing-Structure-Properties Relationships in Polymers by Roberto Pantani Pdf
This collection of research and review papers is aimed at depicting the state of the art on the possible correlations between processing variables, obtained structure and special properties which this structure induces on the plastic part. The extraordinary capacity of plastics to modify their properties according to a particular structure is evidenced for several transformation processes and for many applications. The final common goal is to take profit of this peculiar capacity of plastics by inducing, through a suitable processing, a specific spatial organization.
Polymer Processing and Structure Development by Arthur N. Wilkinson,A.J. Ryan Pdf
Polymer science is fundamentally interdisciplinary, yet specialists in one aspect, such as chemistry or processing, frequently encounter difficulties in understanding the effects of other disciplines on their own. This book describes clearly how polymer chemistry and polymer processing interact to affect polymer properties. As such, specialists in both disciplines can gain a deeper understanding of how these subjects underpin each other. Coverage includes step-by-step introductions to polymer processing technologies; details of fluid flow and heat transfer behaviour; shaping methods and physical processes during cooking and curing, and analyses of moulding and extrusion processes.
