Recent Advances In Mechanistic And Synthetic Aspects Of Polymerization

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Recent Advances in Mechanistic and Synthetic Aspects of Polymerization

M. Fontanille,A. Guyot
Recent Advances in Mechanistic and Synthetic Aspects of Polymerization Book PDF

Author : M. Fontanille,A. Guyot
Publisher : Springer Science & Business Media
Page : 555 pages
File Size : 50,9 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789400939899

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Recent Advances in Mechanistic and Synthetic Aspects of Polymerization by M. Fontanille,A. Guyot Pdf

Due to their specific properties, polymers with well-defined structures have been receiving increasing attention over the last several years. Owing to the wide variability of their properties, these specialty polymers have been used in various areas from biomedical engineering to electronics or energy applications. The synthesis of such polymers necessi tates the use of new methods of polymerization which derived from an insight into the mechanism of polymerization reactions. A NATO Advanced Research Workshop on "Frontiers in Polymerization Catalysis and Polymer Synthesis" was held in BANDOl (FRANCE) in February 1987. Its aim was to assess the new polymerization methods, as well as the latest advances in the mechanisms of conventional polymerization reactions together with their applications to the synthesis of new macromolecular structures. The financial support from the NATO Scientific Affairs Division which covered the "lecturers' accomodation and travel expenses as well as the organization charges of this event gave it international scope. Several industrial companies participate at the meeting and contributed to it success. The organizors who are also editors of these proceedings, want to express their thanks to both NATO Scientific Affairs Division and the companies present at the meeting.

New Methods Polymer Synthesis

J. R. Ebdon
New Methods Polymer Synthesis Book PDF

Author : J. R. Ebdon
Publisher : Springer Science & Business Media
Page : 209 pages
File Size : 42,5 Mb
Release : 2012-12-06
Category : Science
ISBN : 9781468415308

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New Methods Polymer Synthesis by J. R. Ebdon Pdf

Most practitioners and students of polymer chemistry are familiar, in general terms at least, with the established methods of polymer synthesis - radical, anionic, cationic and coordination addition polymerization, and stepwise con densation and rearrangement polymerization. These methods are used to synthesize the majority of polymers used in the manufacture of commercially important plastics, fibres, resins and rubbers, and are covered in most introduc tory polymer chemistry textbooks and in most undergraduate and graduate courses on polymer science. Fewer polymer chemists, however, have much familiarity with more recent developments in methods of polymer synthesis, unless they have been specifically involved for some time in the synthesis of speciality polymers. These developments include not only refinements to established methods but also new mechanisms of polymerization, such as group transfer and metathesis polymerization and novel non-polymerization routes to speciality polymers involving, for example, the chemical modification of preformed polymers or the linking together of short terminally functionalized blocks.

New Methods of Polymer Synthesis

J.R. Ebdon
New Methods of Polymer Synthesis Book PDF

Author : J.R. Ebdon
Publisher : Springer Science & Business Media
Page : 209 pages
File Size : 47,6 Mb
Release : 2012-12-06
Category : Technology & Engineering
ISBN : 9789401095525

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New Methods of Polymer Synthesis by J.R. Ebdon Pdf

Most practitioners and students of polymer chemistry are familiar, in general terms at least, with the established methods of polymer synthesis - radical, anionic, cationic and coordination addition polymerization, and stepwise con densation and rearrangement polymerization. These methods are used to synthesize the majority of polymers used in the manufacture of commercially important plastics, fibres, resins and rubbers, and are covered in most introduc tory polymer chemistry textbooks and in most undergraduate and graduate courses on polymer science. Fewer polymer chemists, however, have much familiarity with more recent developments in methods of polymer synthesis, unless they have been specifically involved for some time in the synthesis of speciality polymers. These developments include not only refinements to established methods but also new mechanisms of polymerization, such as group transfer and metathesis polymerization and novel non-polymerization routes to speciality polymers involving, for example, the chemical modification of preformed polymers or the linking together of short terminally functionalized blocks.

Silicon in Polymer Synthesis

H.R. Kricheldorf
Silicon in Polymer Synthesis Book PDF

Author : H.R. Kricheldorf
Publisher : Springer Science & Business Media
Page : 507 pages
File Size : 49,6 Mb
Release : 2012-12-06
Category : Technology & Engineering
ISBN : 9783642791758

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Silicon in Polymer Synthesis by H.R. Kricheldorf Pdf

Silicon in Polymer Synthesis gives the first concise overview of silicon used for the synthesis and modification of polymers. The first section gives an introduction to the topic. The subsequent chapters detail the current status both from the basic research as well as from the industrial application points of view.

Anionic Polymerization

Henry Hsieh,Roderic P. Quirk
Anionic Polymerization Book PDF

Author : Henry Hsieh,Roderic P. Quirk
Publisher : CRC Press
Page : 748 pages
File Size : 54,8 Mb
Release : 1996-03-15
Category : Technology & Engineering
ISBN : 0824795237

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Anionic Polymerization by Henry Hsieh,Roderic P. Quirk Pdf

This work introduces the basic theories and experimental methods of anionic polymerization as well as the synthesis, analysis and characteristics of anionic polymerized products. It details the creation of linear and branched polymers, random and block copolymers, graft and macromonomers, and many other substances. The work emphasizes the relationship between fundamental principles and commercial applications.;College or university bookstores may purchase five or more copies at a special student price, available on request from Marcel Dekker, Inc.

Principles of Polymer Systems

Ferdinand Rodriguez,Claude Cohen,Christopher K. Ober,Lynden Archer
Principles of Polymer Systems Book PDF

Author : Ferdinand Rodriguez,Claude Cohen,Christopher K. Ober,Lynden Archer
Publisher : CRC Press
Page : 796 pages
File Size : 41,6 Mb
Release : 2014-12-09
Category : Science
ISBN : 9781482223798

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Principles of Polymer Systems by Ferdinand Rodriguez,Claude Cohen,Christopher K. Ober,Lynden Archer Pdf

Maintaining a balance between depth and breadth, the Sixth Edition of Principles of Polymer Systems continues to present an integrated approach to polymer science and engineering. A classic text in the field, the new edition offers a comprehensive exploration of polymers at a level geared toward upper-level undergraduates and beginning graduate stu

Functional Polymers

Raja Shunmugam
Functional Polymers Book PDF

Author : Raja Shunmugam
Publisher : CRC Press
Page : 327 pages
File Size : 43,7 Mb
Release : 2017-05-08
Category : Science
ISBN : 9781315342313

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Functional Polymers by Raja Shunmugam Pdf

This new book covers the synthetic as well application aspects of functional polymers. It highlights modern trends in the field and showcases the recent characterization techniques that are being employed in the field of polymer science. The chapters are written by top-notch scientists who are internationally recognized in the field. The chapters will highlight the modern trend in the field.

Controlled and Living Polymerizations

Krzysztof Matyjaszewski,Axel H. E. Müller
Controlled and Living Polymerizations Book PDF

Author : Krzysztof Matyjaszewski,Axel H. E. Müller
Publisher : John Wiley & Sons
Page : 634 pages
File Size : 41,8 Mb
Release : 2009-12-23
Category : Science
ISBN : 3527629106

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Controlled and Living Polymerizations by Krzysztof Matyjaszewski,Axel H. E. Müller Pdf

Written by a highly prestigious and knowledgeable team of top scientists in the field, this book provides an overview of the current status of controlled/living polymerization, combining the synthetic, mechanistic and application-oriented aspects. From the contents: * Anionic Vinyl Polymerization * Carbocationic Polymerization * Radical Polymerization * Coordinative Polymerization of Olefins * Ring-Opening Polymerization of Heterocycles * Ring-Opening Metathesis Polymerization * Macromolecular Architectures * Complex Functional Macromolecules * Synthesis of Block and Graft Copolymers * Bulk and Solution Structures of Block Copolymers * Industrial Applications While some of the material is based on chapters taken from the four-volume work "Macromolecular Engineering", it is completely updated and rewritten to reflect the focus of this monograph. Must-have knowledge for polymer and organic chemists, plastics technologists, materials scientists and chemical engineers.

Ionomers

M.R. Tant,K.A. Mauritz,G.L. Wilkes
Ionomers Book PDF

Author : M.R. Tant,K.A. Mauritz,G.L. Wilkes
Publisher : Springer Science & Business Media
Page : 524 pages
File Size : 40,8 Mb
Release : 2012-12-06
Category : Technology & Engineering
ISBN : 9789400914612

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Ionomers by M.R. Tant,K.A. Mauritz,G.L. Wilkes Pdf

Polymers have achieved an enviable position as the class of materials having the highest volume of production, exceeding that of both metals and ceramics. The meteoric rise in the production and utilization of polymers has been due to advances in polymer synthesis which allow the creation of specific and well-defined molecular structures, to new knowledge concerning the relationships between polymer structure and properties, and to an improved understanding of how processing can be used as a tool to develop morphological features which result in desired properties. Polymers have truly become 'engineered materials' in every sense of the term. Polymer scientists and engineers are forever seeking to modify and improve the properties of synthetic polymeric systems for use in specific applications. Towards this end they have often looked to nature for advice on how to design molecules for specific needs. An excellent illustration of this is the use of noncovalent bonding (ionic, hydrogen, and van der Waals) in lipids, proteins, and nucleic acids, where these noncovalent bonds, acting both intra and intermolecularly, precisely control the structure and thus the function of the entire system. The utilization of ionic bonding, in particular in man-made polymers has attracted widespread interest in recent years, since ionic interactions exert a similar strong influence on the structure and properties of these synthetic systems.

New Methods for Polymer Synthesis

W.J. Mijs
New Methods for Polymer Synthesis Book PDF

Author : W.J. Mijs
Publisher : Springer Science & Business Media
Page : 327 pages
File Size : 45,9 Mb
Release : 2013-06-29
Category : Science
ISBN : 9781489923561

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New Methods for Polymer Synthesis by W.J. Mijs Pdf

The art and science of macromolecular architecture is based on synthesis, analysis, processing, and evaluation of physical properties of polymers. The growing specificity of available synthetic methods and the increasing refinement of analytical and physical analysis are gradually providing a deeper insight into structure-property relationships of polymers, upon which many applications can be based. This book deals with recent methods for polymer synthesis. Those that lead to specific structures have been selected especially. Background, mechanism scope and limitations, and illustrative procedures are given for each method. With this layout the editor hopes that the book will provide a practical guideline, for the synthetic polymer chemist in industry or at a university graduate school, on how to apply the methods in the design of new polymer structures. The editor is grateful to the authors not only for their contributions containing interesting new developments in polymer synthesis, but also for the way they have fitted their text into the general framework of the book. The elegant chemistry described in the following chapters will, it is hoped, inspire more organic chemists to apply their skills to polymer synthesis, where the beauty of organic chemistry in terms of structural control and reactivity may be even more apparent than in the low molecular field.

Handbook of Polymer Synthesis

Hans R. Kricheldorf
Handbook of Polymer Synthesis Book PDF

Author : Hans R. Kricheldorf
Publisher : CRC Press
Page : 830 pages
File Size : 40,5 Mb
Release : 1991-12-23
Category : Technology & Engineering
ISBN : 0824785150

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Handbook of Polymer Synthesis by Hans R. Kricheldorf Pdf

A compact but comprehensive review of the most important preparative methods for the synthesis and chemical modification of polymers. The contents of the two-volume handbook (Part A was cited in the May 1992 SciTech Book News) are subdivided according to the chemical structure of the polymer backbone on the one hand (Chapters 1-14 of Part A and 15-18 of Part B) and special properties and applications of polymers regardless of their chemical structure on the other hand (Chapters 19-27 of Part B). The latter chapters deal with, for instance, electroconductive polymers, polymeric reagents, and models of bio-polymers. Includes some 11,000 references to the original literature. Annotation c. by Book News, Inc., Portland, Or.

Novel Biodegradable Microbial Polymers

E.A. Dawes
Novel Biodegradable Microbial Polymers Book PDF

Author : E.A. Dawes
Publisher : Springer Science & Business Media
Page : 473 pages
File Size : 49,7 Mb
Release : 2012-12-06
Category : Nature
ISBN : 9789400921290

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Novel Biodegradable Microbial Polymers by E.A. Dawes Pdf

The NATO Advanced Research Workshop from which this book derives was conceived during Biotec-88, the Second Spanish Conference on Biotechnology, held at Barcelona in June 1988. The President of the Conference, Dr. Ricardo Guerrero, had arranged sessions on bacterial polymers which included lectures by five invited participants who, together with Dr. Guerrero, became the Organizing Committee for a projected meeting that would focus attention upon the increasing international importance of novel biodegradable polymers. The proposal found favour with the NATO Science Committee and, with Dr. R. Clinton Fuller and Dr. Robert W. Lenz as the co-Directors, Dr. Edwin A. Dawes as the Proceedings Editor, and Dr. Hans G. Schlegel, Dr. Alexander J.B. Zehnder and Dr. Ricardo Guerrero as members of the Organizing Committee, the meeting quickly took shape. To Dr. Guerrero we owe the happy choice of Sitges for the venue, a pleasant coastal resort 36 kilometres from Barcelona, which proved ideal. The sessions were held at the Palau de Maricel in appropriately impressive surroundings, and invaluable local support was provided by Mr. Jordi Mas-Castella and by Ms. Merce Piqueras. Much of the preparatory work fell upon the broad shoulders of Mr. Edward Knee, whose efforts are deeply appreciated. The Organizing Committee hopes that this Workshop will prove to be the first of a series which will aim to keep abreast of a rapidly expanding and exciting area of research that is highly relevant to environmental and industrial interests.

Olefin Metathesis and Polymerization Catalysts

Yavuz Imamogammalu,Birgül Zümreogammalu-Karan,Allan J. Amass
Olefin Metathesis and Polymerization Catalysts Book PDF

Author : Yavuz Imamogammalu,Birgül Zümreogammalu-Karan,Allan J. Amass
Publisher : Springer Science & Business Media
Page : 567 pages
File Size : 44,6 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789401133289

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Olefin Metathesis and Polymerization Catalysts by Yavuz Imamogammalu,Birgül Zümreogammalu-Karan,Allan J. Amass Pdf

Olefin metathesis reaction can be considered as one of the most successful organic reactions with many applications in the low molecular weight range and also in the polymer field. The use of catalysts with their selective and effective transformation properties in olefin metathesis I polymerization systems is a growing interest. There has been great effort and competition in developing active and commercially useful catalysts. The main aim of this ASI was to gather several research groups and also the people from industry. to present existing knowledge and latest results in the field. A wide range of topics through homogeneous and heterogeneous aspects have been considered. Attention has been drawn to the metal-carbene and metallacyclobutane complexes as active species, the initiation mechanisms, the stereochemistry and thermodynamics of these reactions. New catalytic systems for the metathesis of alkenes and alkynes and fot' ring opening polymeriZation I block copolymerization reactions have been introduced. Spectroscopic studies for the characteriZation of catalysts, simulation studies explaining the function of chain carrier species and polymer degradation have also been covered. A detailed industrial report concerning the patents and applications in olefin metathesis I cyc1001efin polymerization area, fabrication and derivation has been presented. This volume contains the main lectures and seminars given at the NATO Advanced Study Institute on " Olefin Metathesis and Polymerization Catalysts: Synthesis, Mechanism and Utilization", held at Akcay. Babkesir. Turkey between 10th and 22nd September 1989.

Stereoselective Polymerization with Single-Site Catalysts

Lisa S. Baugh,Jo Ann M. Canich
Stereoselective Polymerization with Single Site Catalysts Book PDF

Author : Lisa S. Baugh,Jo Ann M. Canich
Publisher : CRC Press
Page : 698 pages
File Size : 50,6 Mb
Release : 2007-11-29
Category : Science
ISBN : 9781420017083

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Stereoselective Polymerization with Single-Site Catalysts by Lisa S. Baugh,Jo Ann M. Canich Pdf

New synthetic techniques allow chemists to modify polymer microstructures more precisely than ever, making it possible to design materials that meet increasingly demanding performance requirements. Written and edited by experts in the field, Stereoselective Polymerization with Single-Site Catalysts reviews how the relative stereochemistry of

Catalytic Olefin Polymerization

T. Keii,K. Soga
Catalytic Olefin Polymerization Book PDF

Author : T. Keii,K. Soga
Publisher : Elsevier
Page : 573 pages
File Size : 54,5 Mb
Release : 1990-09-12
Category : Technology & Engineering
ISBN : 0080887546

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Catalytic Olefin Polymerization by T. Keii,K. Soga Pdf

Recent development of a new generation of Ziegler-Natta Catalysts using either magnesium dichloride as carrier or methylaluminoxane as cocatalyst has markedly stimulated the research activity in the field of olefin polymerization. These discoveries have not only yielded economical processes for polyolefin production but also opened the way to a new generation of novel polymers. Moreover, the nature of active species is being clarified well by the effort to simplify catalyst systems. The present volume includes 38 papers from the 31 lectures and 18 posters presented at the symposium on `Recent Developments in Olefin Polymerization Catalysts', which covered the following topics: Overview of super-active homogeneous and heterogeneous catalysts, kinetic profile of olefin polymerization including copolymerization, characterization of catalysts and polymers, methods for the determination of active center concentration, role of Lewis bases on the catalysts isospecificity, polymerization mechanisms, and synthetic pathways for functionalized polyolefins. The contents are well balanced between fundamental research and application as well as between homogeneous and heterogeneous catalyst systems.