Ring Opening Metathesis Polymerisation And Related Chemistry

Author : Ezat Khosravi,T. Szymanska-Buzar
Publisher : Springer Science & Business Media
Page : 489 pages
File Size : 53,6 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789401003735

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Ring Opening Metathesis Polymerisation and Related Chemistry by Ezat Khosravi,T. Szymanska-Buzar Pdf

Since the last ASI in Turkey in Sept. 1995, the olefin metathesis has made remarkable strong developments with an incredible speed in various directions. New catalyst systems have been developed which have resulted in the synthesis of novel materials. Other fascinating developments have been the new catalysts for stereoselective metathesis and catalysts with considerable functional group tolerance. These new catalysts in addition to Ring Opening Metathesis Polymerisation (ROMP) and Acyclic Diene Metathesis (ADMET) are now powerful tools for Ring Closing Metathesis (RCM) and have found many applications in the synthesis of natural products. A lot of information has been established about all aspects of the olefin metathesis and there is a vast literature concerning the process, covering the initiators, mechanistic features and applications of this reaction in organic and polymer synthesis. The NATO ASI on rd th ROMP and Related Chemistry took place in Polanica-Zdroj, Poland during 3 to 15 Sept. 2000, to highlight the developments in this area and to discuss the prospects and visions for the year 2000 and beyond. The aims of the ASI were: to provide a platform for dissemination of knowledge; to promote communication between people who have a serious interest in this field of chemistry; to help establishing international scientific contacts and to provide an opportunity for the scientists with an appropriate scientific background to learn of recent developments in this field of science. There were 15 lecturers and 67 participants in this NATO ASI.

Author : V. Dragutan,R. Streck
Publisher : Elsevier
Page : 1292 pages
File Size : 44,8 Mb
Release : 2000-06-26
Category : Technology & Engineering
ISBN : 0080528627

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Catalytic Polymerization of Cycloolefins by V. Dragutan,R. Streck Pdf

This book covers the most important topics concerning cationic Ziegler-Natta and ring-opening metathesis polymerization of cycloolefins. The work describes the major pathways that cycloolefins can follow under the action of specific catalytic systems, essentially vinyl and ring-opening polymerization, both reaction types allowing the manufacture of distinct products with wide applicability in modern technologies. The comprehensive data available on this subject are logically and systematically selected and reviewed throughout 18 chapters, according to the basic catalytic processes involved, types of monomers and catalysts employed, reaction conditions and application fields. The modern trends in design of chiral metallocene catalysts, well-defined living metathesis catalysts, catalysts tolerant toward functionalities and water systems are highlighted. The book discusses in detail the relevant aspects of these processes including reaction thermodynamics, kinetics, mechanisms and stereochemistry and correlates the structure of produced polymers with their chemical and physical-mechanical properties. Related important topics include Ziegler-Natta polymerization of olefins and dienes, atom transfer radical polymerization of vinyl compounds, metathesis of olefins and acetylenes, acyclic diene metathesis reaction, carbonyl olefination reaction, metathesis polymerization of acetylenes, metathesis degradation of polymers and ring-opening polymerization of heterocycles. Special emphasis is laid upon the manufacture of commerical products, new polymers and copolymers of potential interest for industry and design and synthesis of speciality polymers with particular structures and architectures and desired properties. The book critically evaluates the most recent achievements reported in this field and outlines the modern trends on the research and application of the catalytic processes for cycloolefin polymerization. For the first time, comprehensive information about the published data on the subject up to now is provided for both academic and industrial researchers working in the areas of polymer chemistry, organic and organometallic chemistry, surface science and catalysis, petrochemistry and chemical engineering. This stimulating book offers an enlightening introduction and a quick documentation on the subject as well as a solid background in this field. Moreover, the work offers a wealth of useful information for specialists applying polymers in various scientific and industrial areas.

Author : Anonim
Publisher : Wiley-VCH
Page : 0 pages
File Size : 47,6 Mb
Release : 2000-09-12
Category : Technology & Engineering
ISBN : 3527301321

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Advances in Ring Opening (Metathesis) Polymerization by Anonim Pdf

This volume of Macromolecular Symposia contains contributions presented at the RO(M)P'99 International Symposium in Mons, Belgium. At this meeting, over one hundred chemists, physico-chemists, chemical engineers from the world of academia and industry, as well as students, discussed recent developments in mechanisms and kinetics in RO(M)P, synthesis and characterization of new macromolecular architectures, and new materials and applications via RO(M)P.

Author : Yavuz Imamogammalu
Publisher : Springer Science & Business Media
Page : 443 pages
File Size : 47,8 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789401151887

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Metathesis Polymerization of Olefins and Polymerization of Alkynes by Yavuz Imamogammalu Pdf

The first NATO Advanced Study Institute on Olefin Metathesis and Polymerization Catalysts was held on September 10-22, 1989 in Akcay, Turkey. Based on the fundamental research of RRSchrock, RGrubbs and K.B.Wagener in the field of ring opening metathesis polymerization (ROMP), acyclic diene metathesis (ADMET) and alkyne polymerization, these areas gained growing interest within the last years. Therefore the second NATO-ASI held on metathesis reactions was on Ring Opening Metathesis Po lymerization of Olefins and Polymerization of Alkynes on September 3-16, 1995 in Akcay, Turkey. The course joined inorganic, organic and polymer chemists to exchange their knowledge in this field. This volume contains the main and short lectures held in Akcay. To include ADMET reactions better into the title of this volume we changed it into: Metathesis Polymerization of Olefins and Alkyne Polymerization. This volume is addressed to research scientists, but also to those who start to work in the area of olefin metathesis and alkyne polymerization. The topics of the course were: mechanism of ROMP reactions/ new catalysts for ROMP/ new products by ROMP/ new catalysts for ADMET/ new products by ADMETI degradation of polymer by metathesis reactions/ alkyne polymerization and metathesis/ industrial application of metathesis reactions. The Advanced Study Institute was generously sponsored by the Scientific Affairs Division of NATO and the editor gratefully acknowledges this sponsorship. We also thank the Members of the Local Organizing Committee for their engagement on a successful NATO-AS!.

Author : K. J. Ivin,J. C. Mol
Publisher : Elsevier
Page : 489 pages
File Size : 43,7 Mb
Release : 1997-01-07
Category : Technology & Engineering
ISBN : 9780080537979

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Olefin Metathesis and Metathesis Polymerization by K. J. Ivin,J. C. Mol Pdf

This book is a follow-up to Ivins Olefin Metathesis, (Academic Press, 1983). Bringing the standard text in the field up to date, this Second Edition is a result of rapid growth in the field, sparked by the discovery of numerous well-defined metal carbene complexes that can act as very efficient initiators of all types of olefin metathesis reaction, including ring-closing metathesis of acyclic dienes, enynes, and dienynes; ring-opening metathesis polymerizationof cycloalkenes, acyclic diene metathesis polymerization; and polymerization of alkynes, as well as simple olefin metathesis. Olefin Metathesis and Metathesis Polymerization provides a broad, up-to-date account of the subject from its beginnings in 1957 to the latest applications in organic synthesis. The book follows the same format as the original, making it useful toteachers and to researchers, and will be of particular interest to those working in the fields of organic chemistry, polymer chemistry, organometallic chemistry, catalysis, materials science and chemical engineering. Discusses different classes of olefin metathesis and the choice of reaction conditions and catalyst Considers commercial processes with examples from existing and new technologies Provides a complete overview of the subject from its beginning to the present day

Author : Philippe Dubois,Olivier Coulembier,Jean-Marie Raquez
Publisher : John Wiley & Sons
Page : 427 pages
File Size : 42,9 Mb
Release : 2009-03-02
Category : Technology & Engineering
ISBN : 9783527319534

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Handbook of Ring-Opening Polymerization by Philippe Dubois,Olivier Coulembier,Jean-Marie Raquez Pdf

This comprehensive, truly one-stop reference discusses monomers, methods, stereochemistry, industrial applications and more. Chapters written by internationally acclaimed experts in their respective fields cover both basic principles and up-to-date information, ranging from the controlled ring-opening polymerization methods to polymer materials of industrial interest. All main classes of monomers including heterocyclics, cyclic olefins and alkynes, and cycloalkanes, are discussed separately as well as their specificities regarding the ring-opening polymerization techniques, the mechanisms, the degree of control, the properties of the related polymers and their applications. The two last chapters are devoted to the implementation of green chemistry in ring-opening polymerization processes. Of much interest to chemists in academia and industry.

Author : Charles E. Jr. Carraher
Publisher : Elsevier
Page : 368 pages
File Size : 48,5 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323153904

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Organometallic Polymers by Charles E. Jr. Carraher Pdf

Organometallic Polymers focuses on the synthesis, characterization, and potential applications of organometallic polymers. The discussion is organized around seven themes: vinyl polymerization of organometallic monomers; condensation polymerization of organometallic monomers; polymer-bound catalysts; applications of organotin polymers; developments in organosilicon polymers; phosphonitrile and sulfur nitride polymers; and coordination polymers. This book is comprised of 33 chapters and begins with a general review of polymerized vinyl monomers containing transition metals, as well as the reactivity of such monomers in addition to homo- and copolymerizations. The following chapters explore the participation of the ferrocene nucleus in the polymerization of vinylferrocene and its effect on polymer properties; thermomechanical transitions of ferrocene-containing polymers; photocrosslinkable organometallic polyesters; and supported catalysts for ethylene polymerization. The remaining sections discuss antifouling applications of various tin-containing organometallic polymers; structure and applications of polyphosphazenes and polymeric sulfur nitride; and coordination of inorganic ions to polymers. This monograph will be a useful resource for organic chemists and research workers in the field.

Author : Ray Hoff
Publisher : John Wiley & Sons
Page : 696 pages
File Size : 49,8 Mb
Release : 2018-05-08
Category : Technology & Engineering
ISBN : 9781119242130

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Handbook of Transition Metal Polymerization Catalysts by Ray Hoff Pdf

Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity. • Contains the valuable data needed to reproduce syntheses or use the catalyst for new applications • Offers a guide to the design and synthesis of catalysts, and their applications in synthesis of polymers • Includes the information essential for choosing the appropriate reactions to maximize yield of polymer synthesized • Presents new chapters on vanadium catalysts, Ziegler catalysts, laboratory homopolymerization, and copolymerization

Author : Yavuz Imamoglu,Valerian Dragutan
Publisher : Springer Science & Business Media
Page : 506 pages
File Size : 53,5 Mb
Release : 2007-07-04
Category : Technology & Engineering
ISBN : 9781402060908

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Metathesis Chemistry by Yavuz Imamoglu,Valerian Dragutan Pdf

Discover why olefin metathesis has asserted itself as a powerful strategy for obtaining fine chemicals, biologically active compounds, architecturally complex assemblies, new materials, and functionalized polymers. This volume compiles all the latest trends in olefin metathesis. In particular, you’ll learn how olefin metathesis has growing potential for the development of sustainable technologies with many possible industrial applications.

Author : Robert H. Grubbs,Anna G. Wenzel,Daniel J. O'Leary,Ezat Khosravi
Publisher : John Wiley & Sons
Page : 1639 pages
File Size : 43,7 Mb
Release : 2015-05-26
Category : Science
ISBN : 9783527334247

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Handbook of Metathesis, 3 Volume Set by Robert H. Grubbs,Anna G. Wenzel,Daniel J. O'Leary,Ezat Khosravi Pdf

Covering the complete breadth of the olefin metathesis reaction. The second edition of the ultimate reference in this field is completely updated and features more than 80% new content, with the focus on new developments in the field, especially in industrial applications. No other book covers the topic in such a comprehensive manner and in such high quality, and this new edition retains the three-volume format: Catalyst Development, Applications in Organic Synthesis and Polymer Synthesis. Edited by a Nobel laureate in the field, and with a list of contributors that reads like a "Who's-Who" of metathesis, this is an indispensable one-stop reference for organic, polymer and industrial chemists, as well as chemists working with organometallics. Individual volumes also available separately to purchase Volume 1: Catalyst Development - http://www.wiley.com/WileyCDA/WileyTitle/productCd-3527339485.html Volume 2: Applications in Organic Synthesis - http://www.wiley.com/WileyCDA/WileyTitle/productCd-3527339493.html Volume 3: Polymer Synthesis - http://www.wiley.com/WileyCDA/WileyTitle/productCd-3527339507.html

Author : Valerian Drăguțan,Alexandru T. Balaban,Mihai Dimonie
Publisher : Unknown
Page : 554 pages
File Size : 54,7 Mb
Release : 1985
Category : Science
ISBN : STANFORD:36105032919586

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Olefin Metathesis and Ring-opening Polymerization of Cyclo-olefins by Valerian Drăguțan,Alexandru T. Balaban,Mihai Dimonie Pdf

Author : Krzysztof Matyjaszewski,Axel H. E. Müller
Publisher : John Wiley & Sons
Page : 640 pages
File Size : 51,5 Mb
Release : 2009-09-28
Category : Science
ISBN : 3527324925

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Controlled and Living Polymerizations by Krzysztof Matyjaszewski,Axel H. E. Müller Pdf

Written by a highly prestigious and knowledgeable team of top scientists in the field, this book provides an overview of the current status of controlled/living polymerization, combining the synthetic, mechanistic and application-oriented aspects. From the contents: * Anionic Vinyl Polymerization * Carbocationic Polymerization * Radical Polymerization * Coordinative Polymerization of Olefins * Ring-Opening Polymerization of Heterocycles * Ring-Opening Metathesis Polymerization * Macromolecular Architectures * Complex Functional Macromolecules * Synthesis of Block and Graft Copolymers * Bulk and Solution Structures of Block Copolymers * Industrial Applications While some of the material is based on chapters taken from the four-volume work "Macromolecular Engineering", it is completely updated and rewritten to reflect the focus of this monograph. Must-have knowledge for polymer and organic chemists, plastics technologists, materials scientists and chemical engineers.

Author : Yavuz Imamogammalu,Birgül Zümreogammalu-Karan,Allan J. Amass
Publisher : Springer Science & Business Media
Page : 567 pages
File Size : 51,9 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789401133289

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Olefin Metathesis and Polymerization Catalysts by Yavuz Imamogammalu,Birgül Zümreogammalu-Karan,Allan J. Amass Pdf

Olefin metathesis reaction can be considered as one of the most successful organic reactions with many applications in the low molecular weight range and also in the polymer field. The use of catalysts with their selective and effective transformation properties in olefin metathesis I polymerization systems is a growing interest. There has been great effort and competition in developing active and commercially useful catalysts. The main aim of this ASI was to gather several research groups and also the people from industry. to present existing knowledge and latest results in the field. A wide range of topics through homogeneous and heterogeneous aspects have been considered. Attention has been drawn to the metal-carbene and metallacyclobutane complexes as active species, the initiation mechanisms, the stereochemistry and thermodynamics of these reactions. New catalytic systems for the metathesis of alkenes and alkynes and fot' ring opening polymeriZation I block copolymerization reactions have been introduced. Spectroscopic studies for the characteriZation of catalysts, simulation studies explaining the function of chain carrier species and polymer degradation have also been covered. A detailed industrial report concerning the patents and applications in olefin metathesis I cyc1001efin polymerization area, fabrication and derivation has been presented. This volume contains the main lectures and seminars given at the NATO Advanced Study Institute on " Olefin Metathesis and Polymerization Catalysts: Synthesis, Mechanism and Utilization", held at Akcay. Babkesir. Turkey between 10th and 22nd September 1989.

Author : John W Nicholson
Publisher : Royal Society of Chemistry
Page : 204 pages
File Size : 54,5 Mb
Release : 2007-10-31
Category : Science
ISBN : 9781847552075

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The Chemistry of Polymers by John W Nicholson Pdf

"The Chemistry of Polymers is a concise, easy-to-read, inexpensive introduction to the subject and fulfils the need for a polymer text written from an applied angle. It covers the basics of polymer chemistry while emphasising the practical applications and is essential for those who wish to acquire a rapid overview of the field. This book covers the basics of polymer synthesis, characterisation, reaction kinetics and materials science, as well as important specialised topics such as polymer degradation, polymers and pollution, and a variety of technological developments. Now in its second edition, the book has been revised and expanded to reflect recent developments in the subject. There are, for example, extensive updates to the ""Special topics in polymer chemistry"" section, with an additional section on optically active polymers, expanded sections on ionic and co-ordination polymerisations, and copolymerisation, and additional examples of new environmental legislation are outlined wherever appropriate."

Author : Broja Mohan Mandal
Publisher : World Scientific
Page : 468 pages
File Size : 41,6 Mb
Release : 2013
Category : Science
ISBN : 9789814322461

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Fundamentals of Polymerization by Broja Mohan Mandal Pdf

Over the last twenty years, the field of the chemistry of polymerization witnessed enormous growth through the development of new concepts, catalysts, processes etc. Examples are: non classical living polymerizations (group transfer polymerization, living carbocationic polymerization, living radical polymerization and living ring-opening metathesis polymerization (ROMP)); new catalysts (metallocenes and late transition metal catalysts for stereospecific polymerization, Schrock and Grubbs catalyst for ROMP among others) and new processes such as miniemulsion, microemulsion polymerization and dispersion polymerization (in polar solvents). Apart from the developments in the chemistry of polymerization, methods have been developed for the evaluation of highly reliable rate constants of propagation in radical as well as cationic polymerization. All these have revolutionized the field of synthetic polymer chemistry. In the book, fundamentals of both the new and old polymerization chemistry have been dealt with. The new chemistry has been given nearly equal space along with the old.