Selected Topics In High Temperature Chemistry

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Selected Topics in High Temperature Chemistry

Author : Ø. Johannesen,A.G. Andersen
Publisher : Elsevier
Page : 412 pages
File Size : 54,7 Mb
Release : 2017-01-31
Category : Technology & Engineering
ISBN : 9781483291017

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Selected Topics in High Temperature Chemistry by Ø. Johannesen,A.G. Andersen Pdf

The properties of materials at high temperature play a vital role in their processing and practical use. The real properties of materials at elevated temperatures are very often governed by defects in their structure. Lattice defects may consist of point defects like vacancies, interstitial atoms or substituted atoms. These classes are discussed in general and specifically for oxides, nitrides, carbides and sulfides. Defect aggregates, shear structures and adaptive structures are also described. Special attention is paid to hydrogen defects which seem to play an important role in several materials.Defects in solids lead to transport properties such as diffusion and conductivity. These themes are thoroughly treated in this book, with examples from various materials being provided. Special attention is paid to the transport properties of grain boundaries. In high temperature corrosion and other types of oxidation, the diffusion of atoms through the reaction products is often the rate limiting step of the reaction. This book takes the reader from the theoretical treatment of defects to applications in high temperature corrosion. Reactions between metals and pure oxygen lead to the formation of oxides on the surface, and the reaction rates may often be related to the diffusion coefficients of the oxide. However, in practical use alloys are subjected to other severe gaseous atmospheres which may often lead to accelerated attack on the material. The severest condition, namely where a salt deposit is combined with oxidizing gases, is called hot corrosion. This and other types of corrosion are also covered. Finally, a chapter is devoted to the prevention of corrosive attack on materials by the addition of rare earth metals.The book has been published in honour of Professor Per Kofstad on the occasion of his 60th birthday. Professor Kofstad has for many years been active in the field of high temperature chemistry in all its aspects, from basic and theoretical work to its application in high temperature corrosion of metals and alloys. The various chapters have been contributed by his friends and colleagues, all of whom are international experts in the field.

Selected Topics in High Temperature Chemistry

Author : Tormod Førland
Publisher : Unknown
Page : 226 pages
File Size : 47,6 Mb
Release : 1966
Category : Chemistry
ISBN : UCAL:B4163986

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Selected Topics in High Temperature Chemistry by Tormod Førland Pdf

Advances in High Temperature Chemistry

Author : Leroy Eyring
Publisher : Elsevier
Page : 349 pages
File Size : 51,9 Mb
Release : 2013-10-22
Category : Science
ISBN : 9781483224343

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Advances in High Temperature Chemistry by Leroy Eyring Pdf

Advances in High Temperature Chemistry, Volume 1 describes the complexities and special and changing characteristics of high temperature chemistry. After providing a brief definition of high temperature chemistry, this nine-chapter book goes on describing the experiments and calculations of diatomic transition metal molecules, as well as the advances in applied wave mechanics that may contribute to an understanding of the bonding, structure, and spectra of the molecules of high temperature interest. The next chapter provides a summary of gaseous ternary compounds of the alkali metals used in high temperature chemistry. This topic is followed by discussions on the thermochemical properties of some simple solids in terms of valence states of the metallic elements and of the electrons in metals, on anions, and in aqueous solutions. Other chapters are concerned with the stepwise bond dissociation energies in a number of polyvalent metal fluorides and the unique possibilities for chemical syntheses, which are available through high temperature species. The final chapters are devoted to the techniques, temperature ranges, and accuracy of high temperature calorimetry. These chapters also include surveys on the nature of thermal plasmas for high temperature chemistry. This book is of benefit to high temperature chemists and specialized engineers.

Developments in High Temperature Corrosion and Protection of Materials

Author : W Gao
Publisher : Elsevier
Page : 677 pages
File Size : 40,9 Mb
Release : 2008-04-09
Category : Technology & Engineering
ISBN : 9781845694258

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Developments in High Temperature Corrosion and Protection of Materials by W Gao Pdf

High temperature corrosion is a phenomenon that occurs in components that operate at very high temperatures, such as gas turbines, jet engines and industrial plants. Engineers are constantly striving to understand and prevent this type of corrosion. This book examines the latest developments in the understanding of high temperature corrosion processes and protective oxide scales and coatings. Part one looks at high temperature corrosion. Chapters cover diffusion and solid state reactions, external and internal oxidation of alloys, metal dusting corrosion, tribological degradation, hot corrosion, and oxide scales on hot-rolled steel strips. Modern techniques for analysing high temperature oxidation and corrosion are also discussed. Part two discusses methods of protection using ceramics, composites, protective oxide scales and coatings. Chapters focus on layered ternary ceramics, alumina scales, Ti-Al intermetallic compounds, metal matrix composites, chemical vapour deposited silicon carbide, nanocrystalline coatings and thermal barrier coatings. Part three provides case studies illustrating some of the challenges of high temperature corrosion to industry and how they can be overcome. Case studies include the petrochemical industry, modern incinerators and oxidation processing of electronic materials. This book is a valuable reference tool for engineers who develop heat resistant materials, mechanical engineers who design and maintain high temperature equipment and plant, and research scientists and students who study high temperature corrosion and protection of materials. Describes the latest developments in understanding high temperature corrosion Presents the latest research by the leading innovators from around the globe Case studies are provided to illustrate key points

High Temperature Experiments in Chemistry and Materials Science

Author : Ketil Motzfeldt
Publisher : John Wiley & Sons
Page : 364 pages
File Size : 49,9 Mb
Release : 2012-12-04
Category : Science
ISBN : 9781118457788

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High Temperature Experiments in Chemistry and Materials Science by Ketil Motzfeldt Pdf

Cutting edge high temperature materials include high temperature superconductors, solid oxide fuel cells, thermoelectric materials and ultrahigh temperature construction materials (including metals, cermets and ceramics) and have applications in key areas such as energy, transportation and space technologies. This book introduces the concepts which underpin research into these critical materials including thermodynamics, kinetics and various physical, chemical and modelling techniques with a focus on practical “how to” methods and covers: Introduction to High Temperature Research Basic Design of High Temperature Furnaces Temperature Measurement Radiation Pyrometry Refractory Materials in the Laboratory Vacuum in Theory and Practice The Design of Vacuum Furnaces and Thermobalances With highly detailed instrument illustrations and an emphasis on the control and measurement of the fundamental properties of temperature, pressure and mass, High Temperature Experiments in Chemistry and Materials Science provides a practical reference on high temperature measurements, for researchers, advanced students and those working in academic or industrial laboratories. Introduction to High Temperature Research Basic Design of High Temperature Furnaces Temperature Measurement Radiation Pyrometry Refractory Materials in the Laboratory Vacuum in Theory and Practice The Design of Vacuum Furnaces and Thermobalances

Ultra-High Temperature Materials II

Author : Igor L. Shabalin
Publisher : Springer
Page : 755 pages
File Size : 50,5 Mb
Release : 2019-04-24
Category : Technology & Engineering
ISBN : 9789402413021

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Ultra-High Temperature Materials II by Igor L. Shabalin Pdf

This exhaustive work in three volumes and over 1300 pages provides a thorough treatment of ultra-high temperature materials with melting points over 2500 °C. The first volume focuses on Carbon and Refractory Metals, whilst the second and third are dedicated solely to Refractory compounds and the third to Refractory Alloys and Composites respectively. Topics included are physical (crystallographic, thermodynamic, thermo physical, electrical, optical, physico-mechanical, nuclear) and chemical (solid-state diffusion, interaction with chemical elements and compounds, interaction with gases, vapours and aqueous solutions) properties of the individual physico-chemical phases of carbon (graphite/graphene), refractory metals (W, Re, Os, Ta, Mo, Nb, Ir) and compounds (oxides, nitrides, carbides, borides, silicides) with melting points in this range. It will be of interest to researchers, engineers, postgraduate, graduate and undergraduate students alike. The reader is provided with the full qualitative and quantitative assessment for the materials, which could be applied in various engineering devices and environmental conditions at ultra-high temperatures, on the basis of the latest updates in the field of physics, chemistry, materials science and engineering.

Selected Topics in Chemistry

Author : Dr. A.Abdul Jameel,Dr. M.Syed Ali Padusha
Publisher : Vandana Publications
Page : 208 pages
File Size : 55,8 Mb
Release : 2024-07-01
Category : Science
ISBN : 9788193284339

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Selected Topics in Chemistry by Dr. A.Abdul Jameel,Dr. M.Syed Ali Padusha Pdf

While searching the syllabi for the spectral aspects of Inorganic compounds and metal complexes, we come across some important chapters in chemistry in almost all Universities in India and abroad. Laser Raman spectroscopy, Supramolecular chemistry, Nanochemistry and Sonochemistry are found either as separate papers or as chapters in a paper in B.Sc., M.Sc. and M.Phil. syllabi. So we thought of including these chapters along with the inorganic aspects of spectroscopy like Nuclear Quadrupole spectroscopy, ORD and CD of Inorganic compounds, Mass spectra of inorganic compounds and Photoelectron spectroscopy. The limited knowledge of Laser chemistry and Raman spectroscopy leads to the less understanding of Laser Raman spectroscopy. Hence chapters on Laser chemistry and Fundamentals of Raman spectroscopy are included in this book. These chapters were once considered as specialization in chemistry but due to advancement in chemistry, they find place in the regular curriculum. The book is written in a simple language with more advanced and latest informations. Diagrams and tables are given for the better understanding of the subject matter. The book provides a comprehensive and indepth coverage of the subject. There is a shortage of suitable text books for these chapters and this book may fill the gap and will mostly be useful to all the B.Sc. and M.Sc. students and M.Phil. Scholars globally. This book is an outcome of very long teaching and research experience of the authors in the field of Inorganic chemistry. Apart from the subject study, this book may also be used for writing the competitive examinations like UGC–NET, Civil Services Examination and so on. This book is also useful for the interdisciplinary students studying physics and biological sciences.

High Temperature Corrosion

Author : César A. C. Sequeira
Publisher : John Wiley & Sons
Page : 656 pages
File Size : 52,5 Mb
Release : 2019-01-23
Category : Science
ISBN : 9780470119884

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High Temperature Corrosion by César A. C. Sequeira Pdf

Reviews the science and engineering of high-temperature corrosion and provides guidelines for selecting the best materials for an array of system processes High-temperature corrosion (HTC) is a widespread problem in an array of industries, including power generation, aerospace, automotive, and mineral and chemical processing, to name a few. This book provides engineers, physicists, and chemists with a balanced presentation of all relevant basic science and engineering aspects of high-temperature corrosion. It covers most HTC types, including oxidation, sulfidation, nitridation, molten salts, fuel-ash corrosion, H2S/H2 corrosion, molten fluoride/HF corrosion, and carburization. It also provides corrosion data essential for making the appropriate choices of candidate materials for high-temperature service in process conditions. A form of corrosion that does not require the presence of liquids, high-temperature corrosion occurs due to the interaction at high temperatures of gases, liquids, or solids with materials. HTC is a subject is of increasing importance in many areas of science and engineering, and students, researchers, and engineers need to be aware of the nature of the processes that occur in high-temperature materials and equipment in common use today, especially in the chemical, gas, petroleum, electric power, metal manufacturing, automotive, and nuclear industries. Provides engineers and scientists with the essential data needed to make the most informed decisions on materials selection Includes up-to-date information accompanied by more than 1,000 references, 80% of which from within the past fifteen years Includes details on systems of critical engineering importance, especially the corrosion induced by low-energy radionuclides Includes practical guidelines for testing and research in HTC, along with both the European and International Standards for high-temperature corrosion engineering Offering balanced, in-depth coverage of the fundamental science behind and engineering of HTC, High Temperature Corrosion: Fundamentals and Engineering is a valuable resource for academic researchers, students, and professionals in the material sciences, solid state physics, solid state chemistry, electrochemistry, metallurgy, and mechanical, chemical, and structural engineers.

High Temperature Oxidation and Corrosion of Metals

Author : David John Young
Publisher : Elsevier
Page : 758 pages
File Size : 48,7 Mb
Release : 2016-05-12
Category : Technology & Engineering
ISBN : 9780081001196

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High Temperature Oxidation and Corrosion of Metals by David John Young Pdf

High Temperature Oxidation and Corrosion of Metals, Second Edition, provides a high level understanding of the fundamental mechanisms of high temperature alloy oxidation. It uses this understanding to develop methods of predicting oxidation rates and the way they change with temperature, gas chemistry, and alloy composition. The book focuses on the design and selection of alloy compositions which provide optimal resistance to attack by corrosive gases, providing a rigorous treatment of the thermodynamics and kinetics underlying high temperature alloy corrosion. In addition, it emphasizes quantitative calculations for predicting reaction rates and the effects of temperature, oxidant activities, and alloy compositions. Users will find this book to be an indispensable source of information for researchers and students who are dealing with high temperature corrosion. Emphasizes quantitative calculations for predicting reaction rates and the effects of temperature, oxidant activities, and alloy compositions Uses phase diagrams and diffusion paths to analyze and interpret scale structures and internal precipitation distributions Presents a detailed examination of corrosion in industrial gases (water vapor effects, carburization and metal dusting, sulphidation) Contains numerous micrographs, phase diagrams, and tabulations of relevant thermodynamic and kinetic data Combines physical chemistry and materials science methodologies Provides two completely new chapters (chapters 11 and 13), and numerous other updates throughout the text

High-Temperature Oxidation and Sulphidation Processes

Author : J. D. Embury
Publisher : Elsevier
Page : 360 pages
File Size : 55,5 Mb
Release : 2016-01-21
Category : Technology & Engineering
ISBN : 9781483287409

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High-Temperature Oxidation and Sulphidation Processes by J. D. Embury Pdf

This book deals with the fundamental description of the thermodynamics and kinetics of high temperature oxidation of sulphidation of metals and intermetallic compounds. It is a comprehensive account of a large amount of new work in the field including modelling, analysis and a range of experimental methods. The text deals with both basic materials, and some current high temperature structural materials.

Selected Topics in the Chemistry of Natural Products

Author : Raphael Ikan
Publisher : World Scientific
Page : 625 pages
File Size : 53,7 Mb
Release : 2008
Category : Science
ISBN : 9789812790781

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Selected Topics in the Chemistry of Natural Products by Raphael Ikan Pdf

Labor is the most important of the three traditional factors of production (land, labor and capital), accounting for some 75 per cent of the GDP. It is therefore important to focus on issues of labor economics. In this book the approach taken will be that of the free market philosophy of libertarianism, the perspective that allows the maximum of freedom, consistent with the responsibility of all to respect the equal rights of all others. The position of this book on unions is unique outside of the libertarian movement, and this is indicative of its analysis of several other issues, such as minimum wages. For scholars on the left, it is almost true that unions can do no wrong (for Marxists, they do not do enough, but that is another story). Their role is to raise wages for the workingman, and this task is almost unstintingly applauded. Conservatives, on the other hand, oppose unions root and branch (except for their support of foreign wars, which is also another story). To this end they support a welter of regulations, designed to reduce their power: limitations of check offs, forced secret ballots, etc. For libertarians, the analysis depends, intimately, on whether or not these are voluntary organizations. If they are, there is no more justification for imposing secret ballots on them than to do so for the chess or garden club. If they are not, they should not be weakened by restrictions, but, rather, banned, and their leaders imprisoned.

Electrochemistry

Author : G J Hills
Publisher : Royal Society of Chemistry
Page : 284 pages
File Size : 45,7 Mb
Release : 2007-10-31
Category : Science
ISBN : 9781847557216

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Electrochemistry by G J Hills Pdf

Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued.

Ultra-High Temperature Materials III

Author : Igor L. Shabalin
Publisher : Springer Nature
Page : 797 pages
File Size : 41,9 Mb
Release : 2020-07-07
Category : Technology & Engineering
ISBN : 9789402420395

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Ultra-High Temperature Materials III by Igor L. Shabalin Pdf

This exhaustive work in several volumes and over 2500 pages provides a thorough treatment of ultra-high temperature materials (with melting points around or over 2500 °C). The first volume focuses on carbon (graphene/graphite) and refractory metals (W, Re, Os, Ta, Mo, Nb and Ir), whilst the second and third are dedicated to refractory transition metal 4-5 groups carbides. Topics included are physical (structural, thermal, electro-magnetic, optical, mechanical, nuclear) and chemical (more than 3000 binary, ternary and multi-component systems, including those used for materials design, data on solid-state diffusion, wettability, interaction with various elements and compounds in solid and liquid states, gases and chemicals in aqueous solutions) properties of these materials. It will be of interest to researchers, engineers, postgraduate, graduate and undergraduate students alike. The readers/users are provided with the full qualitative and quantitative assessment, which is based on the latest updates in the field of fundamental physics and chemistry, nanotechnology, materials science, design and engineering.