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Author : R.G. Compton,C.H. Bamford,C.F.H. Tipper†
Publisher : Elsevier
Page : 435 pages
File Size : 45,6 Mb
Release : 1984-07-01
Category : Science
ISBN : 0080868134
Simple Processes at the Gas-Solid Interface
Author : Anonim
Publisher : Unknown
Page : 0 pages
File Size : 47,7 Mb
Release : 1984
Category : Electronic
ISBN : 0444422870
Author : R.W. Carr
Publisher : Elsevier
Page : 317 pages
File Size : 55,7 Mb
Release : 2007-09-04
Category : Science
ISBN : 9780080546179
Modeling of Chemical Reactions covers detailed chemical kinetics models for chemical reactions. Including a comprehensive treatment of pressure dependent reactions, which are frequently not incorporated into detailed chemical kinetic models, and the use of modern computational quantum chemistry, which has recently become an extraordinarily useful component of the reaction kinetics toolkit. It is intended both for those who need to model complex chemical reaction processes but have little background in the area, and those who are already have experience and would benefit from having a wide range of useful material gathered in one volume. The range of subject matter is wider than that found in many previous treatments of this subject. The technical level of the material is also quite wide, so that non-experts can gain a grasp of fundamentals, and experts also can find the book useful. A solid introduction to kinetics Material on computational quantum chemistry, an important new area for kinetics Contains a chapter on construction of mechanisms, an approach only found in this book
Author : V.P. Zhdanov
Publisher : Springer Science & Business Media
Page : 324 pages
File Size : 47,9 Mb
Release : 2013-11-11
Category : Science
ISBN : 9781489923738
vi industrial process or a class of catalysts forms the basis of other books, with information on: fundamental science of the topic, the use of the pro cess or catalysts, and engineering aspects. Single topics in catalysis are also treated in the series, with books giving the theory of the underlying science, and relating it to catalytic practice. We believe that this approach is giving a collection of volumes that is of value to both academic and industrial workers. The series editors welcome comments on the series and suggestions of topics for future volumes. Martyn Twigg Michael Spencer Billingham and Cardiff Contents Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . 1 . . . . . . . . Chapter 1. Vibrational Relaxation of Adsorbed Particles . . . .. . 5 1.1. General Approach to Describing Vibrational Relaxation ..... 5 1.2. Phonon Mechanism of Relaxation .................... 8 1.2.1. Relationship between the Simple Perturbation Theory and the Adiabatic Approximation .. . . . . . . . . . .. . . 9 . 1.2.2. One-Mode Approximation .................. . .. 11 1.2.3. Relaxation Caused by Correlation Potential Proportional to Displacement of Adsorbed Particle from Equilibrium ........................... 12 1.2.4. Relaxation Caused by Correlation Potential Proportional to Displacement of Surface Atom from Equilibrium ........................... 14 1.2.5. Results and Discussion ....................... 15 1.3. Vibrational Relaxation via Interaction with Conduction Electrons . . . . . . . . . . . . . . . . . . . . . . . . . .. . . 18 . . . . . . . . . 1.3.1. Dipole Approximation ......... '.' . . . . . . . . .. . . 18 .
Author : C.H. Bamford,R.G. Compton,C.F.H. Tipper†
Publisher : Elsevier
Page : 236 pages
File Size : 43,7 Mb
Release : 1984-09-01
Category : Science
ISBN : 0080868150
Reactions of Solids with Gases
Author : Klaus Wandelt
Publisher : John Wiley & Sons
Page : 1532 pages
File Size : 55,6 Mb
Release : 2016-03-14
Category : Science
ISBN : 9783527411580
In eight volumes, Surface and Interface Science covers all fundamental aspects and offers a comprehensive overview of this research area for scientists working in the field, as well as an introduction for newcomers. Volume 5: Solid-Gas Interfaces I Topics covered: Basics of Adsorption and Desorption Surface Microcalorimetry Adsorption of Rare Gases Adsorption of Alkali and Other Electro-Positive Metals Halogen adsorption on metals Adsorption of Hydrogen Adsorption of Water Adsorption of (Small) Molecules on Metal Surfaces Surface Science Approach to Catalysis Adsorption, Bonding and Reactivity of Unsaturated and Multifunctional Molecules Volume 6: Solid-Gas Interfaces II Topics covered: Adsorption of Large Organic Molecules Chirality of Adsorbates Adsorption on Semiconductor Surfaces Adsorption on Oxide Surfaces Oscillatory Surface Reactions Statistical Surface Thermodynamics Theory of the Dynamics at Surfaces Atomic and Molecular Manipulation
Author : C.H. Bamford,R.G. Compton,C.F.H. Tipper†
Publisher : Elsevier
Page : 527 pages
File Size : 40,7 Mb
Release : 1983-01-01
Category : Science
ISBN : 0080868185
Modern Methods in Kinetics
Author : Kenneth Sing,Jean Rouquerol
Publisher : Elsevier
Page : 525 pages
File Size : 49,8 Mb
Release : 2009-06-04
Category : Technology & Engineering
ISBN : 9780080960470
Adsorption at the Gas-Solid and Liquid-Solid Interface
Author : Friedrich G. Helfferich
Publisher : Elsevier
Page : 508 pages
File Size : 50,8 Mb
Release : 2004-09-15
Category : Science
ISBN : 9780080473185
This book addresses primarily the engineer in industrial process development, the research chemist in academia and industry, and the graduate student intending to become a reaction engineer. In industry, competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such development should be based on "fundamental" kinetics that reflect the elementary steps of which the reaction consists. The book forges fundamental kinetics into a practical tool by presenting new, effective methods for elucidation of mechanisms and reduction of complexity without unacceptable sacrifice in accuracy: fewer equations (lesser computational load), fewer coefficients (fewer experiment to determine them). For network elucidation, new rules relating network configurations to observable kinetic behaviour allow incorrect networks to be ruled out by whole classes instead of one by one. For modelling, general equations and algorithms are given from which equations for specific networks can be recovered by simple substitutions. The procedures are illustrated with examples of industrial reactions including, among others, paraffin oxidation, ethoxylation, hydroformylation, hydrocyanation, shape-selective catalysis, ethane pyrolysis, styrene polymerization, and ethene oligomerization. Many of the rate equations have not been published before. The expanded edition of the 2001 title, Kinetics of Homogeneous Multistep Reactions includes new chapters on heterogeneous catalysis and periodic and chaotic re-actions; new sections on adsorption, statistical methods, and lumping; and other new detail. Contains new chapters on heterogeneous catalysis, oscillations and chaos Includes new sections on statistical methods, lumping adsorption and software and databases Provides a better understanding of complex reaction mechanisms
Author : Nicholas Green
Publisher : Elsevier
Page : 263 pages
File Size : 48,7 Mb
Release : 2003-11-21
Category : Science
ISBN : 9780080543444
Unimolecular reactions are in principle the simplest chemical reactions, because they only involve one molecule. The basic mechanism, in which the competition between the chemical reaction step and a collisional deactivation leads to a pressure-dependent coefficient, has been understood for a long time. However, this is a rapidly developing field, and many new and important discoveries have been made in the past decade.This First Part Part of Two CCK Volumes dealing with Unimolecular Rections, deals with the Reaction Step. The first chapter is an introduction to the whole project, aiming to cover the material necessary to understand the content of the detailed chapters, as well as the history of the development of the area. Chapter 2 is a review of the modern view of the statistical theories, as embodied in the various forms of RRKM theory. Chapter 3 deals with the fully quantum mechanical view of reactive states as resonances. . Presents considerable advances in the field made during the last decade.. Treats both the statistical as well as the fully quantum mechanical view.
Author : Friedrich G. Helfferich
Publisher : Elsevier
Page : 427 pages
File Size : 40,7 Mb
Release : 2001-01-25
Category : Technology & Engineering
ISBN : 9780080535265
This book addresses primarily the chemist and engineer in industrial research and process development, where competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such scale-up should be based on "fundamental" kinetics, that is, mathematics that reflect the elementary steps of which the reactions consist. The book forges fundamental kinetics into a practical tool by presenting new effective methods for elucidation of mechanisms and reduction of mathematical complexity without unacceptable sacrifice in accuracy.
Author : Victor L. Cherginets
Publisher : Elsevier
Page : 401 pages
File Size : 46,6 Mb
Release : 2005-02-15
Category : Science
ISBN : 9780080455242
The generally accepted definitions of acids and bases together with the generalized definition for the solvent system introduced by the author for the description of both molecular and ionic solvents are discussed. The oxobasicity index introduced as a measure of relative oxoacidic properties of ionic melts (pIL) and methods of its determination are presented. Moreover, the oxoacidity scales of ionic melts based on alkali metal halides at different temperatures are constructed. The sequential addition method (SAM), proposed by the author to investigate the effect of oxide particle size on oxide solubilities is presented. This book is meant for specialists developing theoretical and applied aspects of molten salt chemistry, acid-base theories and solubility phenomena. It will also be useful for those chemists who wish to extend their knowledge of physical and solution chemistry. First book devoted to oxoacids and oxobases Aimed at specialists developing theoretical and applied aspects of molten salt chemistry, acid-base theories and solubility phenomena The perfect handbook for beginners looking for preliminary knowledge about methods of investigation
Author : David S. Wilkinson
Publisher : Cambridge University Press
Page : 292 pages
File Size : 49,6 Mb
Release : 2000-11-02
Category : Science
ISBN : 0521624940
The field of matter transport is central to understanding the processing of materials and their subsequent mechanical properties. While thermodynamics determines the final state of a material system, it is the kinetics of mass transport that governs how it gets there. This book, first published in 2000, gives a solid grounding in the principles of matter transport and their application to a range of engineering problems. The author develops a unified treatment of mass transport applicable to both solids and liquids. Traditionally matter transport in fluids is considered as an extension of heat transfer and can appear to have little relationship to diffusion in solids. This unified approach clearly makes the connection between these important fields. This book is aimed at advanced undergraduate and beginning graduate students of materials science and engineering and related disciplines. It contains numerous worked examples and unsolved problems. The material can be covered in a one semester course.
Author : R.G. Compton
Publisher : Elsevier
Page : 367 pages
File Size : 53,7 Mb
Release : 1987-12-01
Category : Science
ISBN : 0080868215
Volumes 26 and 27 are both concerned with reactions occurring at electrodes arising through the passage of current. They provide an introduction to the study of electrode kinetics. The basic ideas and experimental methodology are presented in Volume 26, whilst Volume 27 deals with reactions at particular types of electrodes. Chapter 1 of the present volume deals with redox reactions at metal electrodes, Chapter 2 with semiconducting electrodes and Chapter 3 with reactions at metal oxide electrodes. Both theoretical aspects and experimental results are covered.
Author : S.A. Rice
Publisher : Elsevier
Page : 403 pages
File Size : 51,6 Mb
Release : 1985-03-01
Category : Science
ISBN : 0080868193
Diffusion-Limited Reactions
