Spectra And Energy Levels Of Rare Earth Ions In Crystals

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Spectroscopy of Crystals Containing Rare Earth Ions

Author : A.A. Kaplyanskii,R.M. McFarlane
Publisher : Elsevier
Page : 767 pages
File Size : 49,5 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780444598271

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Spectroscopy of Crystals Containing Rare Earth Ions by A.A. Kaplyanskii,R.M. McFarlane Pdf

``Spectroscopy of Crystals Containing Rare Earth Ions'' contains chapters on some key problems selected from a broad range of spectroscopic studies of RE-activated solids including both crystalline and glassy materials. Progress in crystal field theory is surveyed, an area which is basic to our understanding of the energy levels. The treatment of dynamical properties includes studies of coherence phenomena in isolated ions, energy transfer between ions and co-operative phenomena associated with ion-ion and ion-lattice interactions. In addition, the role of electron spins and nuclear spins is studied by light scattering and double resonance techniques. The presence of inhomogeneous broadening of spectral lines is observed and studied in many contexts, leading to new insights into general problems of the disordered state. Considerable attention is devoted to describing new experimental techniques whose development is of prime importance for progress in the spectroscopy of RE-activated solids. Many of these rely on the development and application of tunable lasers. At the moment this is a very active field of spectroscopy with more exciting developments likely to occur in the future.

Spectroscopy of Solids Containing Rare Earth Ions

Author : A. A. Kapli͡anskiĭ,Roger M. Macfarlane
Publisher : North Holland
Page : 776 pages
File Size : 43,8 Mb
Release : 1987
Category : Science
ISBN : UVA:X001401612

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Spectroscopy of Solids Containing Rare Earth Ions by A. A. Kapli͡anskiĭ,Roger M. Macfarlane Pdf

Spectroscopy of Crystals Containing Rare Earth Ions'' contains chapters on some key problems selected from a broad range of spectroscopic studies of RE-activated solids including both crystalline and glassy materials. Progress in crystal field theory is surveyed, an area which is basic to our understanding of the energy levels. The treatment of dynamical properties includes studies of coherence phenomena in isolated ions, energy transfer between ions and co-operative phenomena associated with ion-ion and ion-lattice interactions. In addition, the role of electron spins and nuclear spins is studied by light scattering and double resonance techniques. The presence of inhomogeneous broadening of spectral lines is observed and studied in many contexts, leading to new insights into general problems of the disordered state. Considerable attention is devoted to describing new experimental techniques whose development is of prime importance for progress in the spectroscopy of RE-activated solids. Many of these rely on the development and application of tunable lasers. At the moment this is a very active field of spectroscopy with more exciting developments likely to occur in the future.

Theoretical Spectroscopy of Transition Metal and Rare Earth Ions

Author : Mikhail G. Brik,Ma Chong-Geng
Publisher : CRC Press
Page : 209 pages
File Size : 47,5 Mb
Release : 2019-12-11
Category : Science
ISBN : 9781000007572

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Theoretical Spectroscopy of Transition Metal and Rare Earth Ions by Mikhail G. Brik,Ma Chong-Geng Pdf

This book describes in detail the main concepts of theoretical spectroscopy of transition metal and rare-earth ions. It shows how the energy levels of different electron configurations are formed and calculated for the ions in a free state and in crystals, how group theory can help in solving main spectroscopic problems, and how the modern DFT-based methods of calculations of electronic structure can be combined with the semi-empirical crystal field models. The style of presentation makes the book helpful for a wide audience ranging from graduate students to experienced researchers. Performance of optical materials crucially depends on the impurity ions intentionally introduced into the crystalline host materials. The color of these materials, their emission and absorption spectra can be understood by analyzing the relations between the electronic properties of impurity ions and host crystal structure, which constitutes the main content of this book. It describes in detail the main concepts of theoretical spectroscopy of transition metal and rare earth ions.

Theoretical Spectroscopy of Transition Metal and Rare Earth Ions

Author : Mikhail G. Brik,Ma Chong-Geng
Publisher : CRC Press
Page : 462 pages
File Size : 49,7 Mb
Release : 2019-12-11
Category : Science
ISBN : 9781000000733

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Theoretical Spectroscopy of Transition Metal and Rare Earth Ions by Mikhail G. Brik,Ma Chong-Geng Pdf

This book describes in detail the main concepts of theoretical spectroscopy of transition metal and rare-earth ions. It shows how the energy levels of different electron configurations are formed and calculated for the ions in a free state and in crystals, how group theory can help in solving main spectroscopic problems, and how the modern DFT-based methods of calculations of electronic structure can be combined with the semi-empirical crystal field models. The style of presentation makes the book helpful for a wide audience ranging from graduate students to experienced researchers. Performance of optical materials crucially depends on the impurity ions intentionally introduced into the crystalline host materials. The color of these materials, their emission and absorption spectra can be understood by analyzing the relations between the electronic properties of impurity ions and host crystal structure, which constitutes the main content of this book. It describes in detail the main concepts of theoretical spectroscopy of transition metal and rare earth ions.

Physics of Laser Crystals

Author : Jean-Claude Krupa,Nicolay A. Kulagin
Publisher : Springer Science & Business Media
Page : 276 pages
File Size : 48,5 Mb
Release : 2003-11-30
Category : Technology & Engineering
ISBN : 140201676X

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Physics of Laser Crystals by Jean-Claude Krupa,Nicolay A. Kulagin Pdf

Physics of laser crystals has been constantly developing since the invention of the laser in 1960. Nowadays, more than 1500 wide-band-gap and semiconductors crystals are suitable for the production of the laser effect. Different laser devices are widely used in science, medicine and communication systems according to the progress achieved in the development of laser crystal physics. Scintillators for radiation detection also gained benefit from these developments. Most of the optically active materials offer laser radiations within the 500 to 3000 nm region with various quantum efficiency which fit the usual applications. However, new crystals for laser emissions are needed either in the blue, UV and VUV - region or far IR- region, especially for medicine, computer microchip production and for undiscovered practical uses. Scientific problems of the growth and properties of laser crystals are discussed in numerous books and scientific journals by many scientists working in the field. Therefore, we thought that joint discussions of the scientific and technical problems in laser physics will be useful for further developments in this area. We have proposed to held a Workshop on Physics of Laser Crystals for attempting to induce additional advances especially in solid state spectroscopy. This NATO Advanced Research Workshop (ARW) was hold in Kharkiv • Stary Saltov th nd (Ukraine) on august 26 - September 2 , 2002, and was mainly devoted to the consideration 0 f modem approaches and Iast results in physics of laser crystals.

Optical Spectra of Transparent Rare Earth Compounds

Author : S. Hufner
Publisher : Elsevier
Page : 252 pages
File Size : 48,7 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323158985

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Optical Spectra of Transparent Rare Earth Compounds by S. Hufner Pdf

Optical Spectra of Transparent Rare Earth Compounds investigates the optical spectra of transparent rare earth (RE) compounds such as europium chalcogenides. Emphasis is placed on the underlying physics in selected examples, and theoretical results are usually presented without proof in a form that allows their application to the interpretation of experimental data. This book is comprised of 11 chapters and begins with an overview of the spectra of RE ions in ionic crystals, paying particular attention to the sharpness of many lines in the absorption and emission spectra. How these very narrow lines arise, what interactions determine their energy, and how they can be used to investigate particular properties of the solid state are explained in detail. Subsequent chapters explore the energy structure of RE free ions in solids; trivalent RE ions in a static crystal field and in a phonon field; magnetic interactions and hyperfine interactions; and Jahn-Teller systems. The absorption spectra of europium chalcogenides are also considered, along with REs in glasses and RE lasers. This monograph is written primarily for solid state physicists and those who need an overall view of the basic features of rare earth spectra in transparent solids, such as new workers.

Nanostructured and Advanced Materials for Applications in Sensor, Optoelectronic and Photovoltaic Technology

Author : Ashok K. Vaseashta,D. Dimova-Malinovska,J.M. Marshall
Publisher : Springer Science & Business Media
Page : 432 pages
File Size : 42,8 Mb
Release : 2007-04-29
Category : Technology & Engineering
ISBN : 9781402035623

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Nanostructured and Advanced Materials for Applications in Sensor, Optoelectronic and Photovoltaic Technology by Ashok K. Vaseashta,D. Dimova-Malinovska,J.M. Marshall Pdf

The principal aim of this NATO Advanced Study Institute (ASI) "Nanostructured and Advanced Materials for Applications in Sensor, Optoelectronic and Photovoltaic Technology" was to present a contemporary overview of the field of nanostructured and advanced electronic materials. Nanotechnology is an emerging scientific field receiving significant worldwide attention. On a nanometer scale, materials or structures may possess new and unique physical properties. Some of these are now known to the scientific community, but there may well be many properties not yet known to us, rendering it as a fascinating area of research and a suitable subject for a NATO ASI. Yet another aspect of the field is the possibility for creating meta-stable phases with unconventional properties and the ultra-miniaturization of current devices, sensors, and machines. Such nanotechnological and related advanced materials have an extremely wide range of potential applications, viz. nanoscale electronics, sensors, optoelectronics, photonics, nano-biological systems, na- medicine, energy storage systems, etc. This is a wide-ranging subject area and therefore requires the formation of multi-disciplinary teams of physicists, chemists, materials scientists, engineers, molecular biologists, pharmacologists, and others to work together on the synthesis and processing of materials and structures, the understanding of their physical properties, the design and fabrication of devices, etc. Hence, in formulating our ASI, we adopted an int- disciplinary approach, bringing together recognised experts in the various fields while retaining a level of treatment accessible to those active in specific individual areas of research and development.

Atomic Energy Levels in Crystals

Author : John L. Prather
Publisher : Unknown
Page : 96 pages
File Size : 49,5 Mb
Release : 1961
Category : Crystallography, Mathematical
ISBN : UOM:39015012332568

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Atomic Energy Levels in Crystals by John L. Prather Pdf

Physics of Solid-State Laser Materials

Author : Zundu Luo,Yidong Huang
Publisher : Springer Nature
Page : 470 pages
File Size : 52,9 Mb
Release : 2020-04-07
Category : Science
ISBN : 9789813296688

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Physics of Solid-State Laser Materials by Zundu Luo,Yidong Huang Pdf

This book discusses the spectral properties of solid-state laser materials, including emission and absorption of light, the law of radiative and nonradiative transitions, the selection rule for optical transitions, and different calculation methods of the spectral parameters. The book includes a systematic presentation of the authors' own research works in this field, specifically addressing the stimulated nonradiative transition theory and the apparent crystal field model. This volume is helpful resource for researchers and graduate students in the fields of solid spectroscopy and solid-state laser material physics, while also serving as a valuable reference guide for instructors and advanced students of physics.

Rare-Earth-Doped Fiber Lasers and Amplifiers, Revised and Expanded

Author : Michel J.F. Digonnet
Publisher : CRC Press
Page : 956 pages
File Size : 42,6 Mb
Release : 2001-05-31
Category : Technology & Engineering
ISBN : 9780824741648

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Rare-Earth-Doped Fiber Lasers and Amplifiers, Revised and Expanded by Michel J.F. Digonnet Pdf

A discussion of the theories, operating characteristics, and current technology of main fiber laser and amplifier devices based on rare-earth-doped silica and fluorozirconate fibers. It describes the principles, designs, and properties of the erbium-doped fiber amplifier and its role as the cornerstone component in optical communication systems. This second edition contains new and revised material reflecting major developments in academia and industry.

Magnetooptical Spectroscopy of the Rare-Earth Compounds: Development and Application

Author : Uygun V. Valiev ,John B. Gruber ,Gary. W. Burdick
Publisher : Scientific Research Publishing, Inc. USA
Page : 146 pages
File Size : 40,5 Mb
Release : 2012-01-05
Category : Science
ISBN : 9781618960542

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Magnetooptical Spectroscopy of the Rare-Earth Compounds: Development and Application by Uygun V. Valiev ,John B. Gruber ,Gary. W. Burdick Pdf

A comparison of theory with experiment is made for rare-earth compounds with garnet structure and orthoaluminate whose optical, magnetic and magnetooptical features have been studied sufficiently well by now.

Lanthanide-Doped Luminescent Nanomaterials

Author : Xueyuan Chen,Yongsheng Liu,Datao Tu
Publisher : Springer Science & Business Media
Page : 217 pages
File Size : 47,5 Mb
Release : 2013-11-04
Category : Technology & Engineering
ISBN : 9783642403644

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Lanthanide-Doped Luminescent Nanomaterials by Xueyuan Chen,Yongsheng Liu,Datao Tu Pdf

Lanthanide-Doped Luminescent Nanomaterials reviews the latest advances in the development of lanthanide-doped luminescent inorganic nanoparticles for potential bioapplications. This book covers the chemical and physical fundamentals of these nanoparticles, such as the controlled synthesis methodology, surface modification chemistry, optical physics, and their promising applications in diverse bioassays, with an emphasis on heterogeneous and homogeneous in-vitro biodetection of tumor biomarkers. This book is intended for those readers who are interested in systematically understanding the materials design strategy, optical behavior of lanthanide ions, and practical bioapplications of lanthanide nanoparticles. It primarily focuses on the interdisciplinary frontiers in chemistry, physics and biological aspects of luminescent nanomaterials. All chapters were written by scientists active in this field and for a broad audience, providing both beginners and advanced researchers with comprehensive information on the subject. Xueyuan Chen is a Professor at Fujian Institute of Research on the Structure of Matter (FJIRSM), Chinese Academy of Sciences. Yongsheng Liu is a Research Associate Professor at FJIRSM, Chinese Academy of Sciences. Datao Tu is a Research Assistant Professor at FJIRSM, Chinese Academy of Sciences.

Lasers and Excited States of Rare Earths

Author : Renata Reisfeld,Christian K. Jorgensen
Publisher : Springer Science & Business Media
Page : 235 pages
File Size : 55,9 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783642666964

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Lasers and Excited States of Rare Earths by Renata Reisfeld,Christian K. Jorgensen Pdf

The possibility of stimulated light emission was discussed by Einstein in 1917, eight years before the quantum-mechanical description of energy levels of many-electron systems. Though it is imperative to use samples having optical properties greatly different from the stan dard continuous spectrum of opaque objects ("black body" radia tion) it is not always necessary to restrict the study to monatomic entities. Thus, spectral lines can be obtained (in absorption and in emission) from lanthanide compounds, containing from one to thir teen 4f electrons going from trivalent cerium to ytterbium, that are nearly as sharp as the ones from gaseous atoms. However, the presence of adjacent atoms modifies the simple picture of an isolated electron configuration, and in particular, it is possible to pump excited levels efficiently by energy transfer from species with intense absorption bands, such as the inter-shell transitions of other lanthanides and of thallium(I), lead(II) and bismuth(III) or the electron transfer bands of the uranyl ion or other complexes. On the other hand, it is possible to diminuish the mUlti-phonon relaxation (competing with sharp line luminescence) by selecting vitreous or crystalline materials with low phonon energies. Obviously, one cannot circumvent the conservation of energy by lasers, but they may have unprecedented consequences for the future by allowing nuclear fusion of light elements, effects of non-linear optics and time-resolved spectroscopy, besides the more conventional applications of coherent light beams with negligible angular extension.

Magnetic Properties of Rare Earth Metals

Author : R. Elliott
Publisher : Springer Science & Business Media
Page : 425 pages
File Size : 46,8 Mb
Release : 2013-06-29
Category : Technology & Engineering
ISBN : 9781475756913

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Magnetic Properties of Rare Earth Metals by R. Elliott Pdf

The rare earths have a unique place among the elements. Although very much alike chemically and in most phy~ical properties they each have very different and striking magnetic properties. The reason, of course, lies in their 4f electrons which determine the magnetic properties but have little effect on other chemical and physical behaviour. Although they are not rare, some indeed are among the more common heavy elements in the earth's crust, the difficulty of separation has meant that their intricate magnetic properties have only recently been unravelled. Now, however, the general pattern of their magnetism is well charted and the underlying theory is well understood. Both are thoroughly summarised in this book. It provides an excellent example of the kind of extensive synthesis which is possible with modem solid state physics. it represents only a high plateau in the ascent to complete understanding. But It will become clear to the reader that while the overall position is satisfactory there are many details still to be elucidated experimentally and much to be done theoretically before all the underlying forces are identified and estimated from a priori calculations. It is hoped that the book will provide a useful stimulus in this direction. It should also be of use to those who are interested in related disciplines, for example the rare earth compounds, or the transition metals. In addition rare earths promise to be important technologically as alloy constituents.