Statistical Mechanics Of Liquids And Solutions

Author : Roland Kjellander
Publisher : CRC Press
Page : 424 pages
File Size : 46,6 Mb
Release : 2019-07-30
Category : Science
ISBN : 9781482244045

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Statistical Mechanics of Liquids and Solutions by Roland Kjellander Pdf

The statistical mechanical theory of liquids and solutions is a fundamental area of physical sciences with important implications for many industrial applications. This book shows how you can start from basic laws for the interactions and motions of microscopic particles and calculate how macroscopic systems of these particles behave, thereby explaining properties of matter at the scale that we perceive. Using this microscopic, molecular approach, the text emphasizes clarity of physical explanations for phenomena and mechanisms relevant to fluids, addressing the structure and behavior of liquids and solutions under various conditions. A notable feature is the author’s treatment of forces between particles that include nanoparticles, macroparticles, and surfaces. The book also provides an expanded, in-depth treatment of polar liquids and electrolytes.

Author : Walter Schirmacher
Publisher : Springer
Page : 167 pages
File Size : 42,7 Mb
Release : 2014-08-19
Category : Science
ISBN : 9783319069500

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Theory of Liquids and Other Disordered Media by Walter Schirmacher Pdf

This set of lectures provides an introduction to the structure, thermodynamics and dynamics of liquids, binary solutions and polymers at a level that will enable graduate students and non-specialist researchers to understand more specialized literature and to possibly start their own work in this field. Part I starts with the introduction of distribution functions, which describe the statistical arrangements of atoms or molecules in a simple liquid. The main concepts involve mean field theories like the Perkus-Yevick theory and the random phase approximation, which relate the forces to the distribution functions. In order to provide a concise, self-contained text, an understanding of the general statistical mechanics of an interacting many-body system is assumed. The fact that in a classic liquid the static and dynamic aspects of such a system can be discussed separately forms the basis of the two-fold structure of this approach. In order to allow polymer melts and solutions to be discussed, a short chapter acquaints readers with scaling concepts by discussing random walks and fractals. Part II of the lecture series is essentially devoted to the presentation of the dynamics of simple and complex liquids in terms of the generalized hydrodynamics concept, such as that introduced by Mori and Zwanzig. A special topic is a comprehensive introduction of the liquid-glass transition and its discussion in terms of a mode-coupling theory.

Author : Jean-Pierre Hansen,I.R. McDonald
Publisher : Academic Press
Page : 637 pages
File Size : 48,8 Mb
Release : 2013-08-12
Category : Science
ISBN : 9780123870339

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Theory of Simple Liquids by Jean-Pierre Hansen,I.R. McDonald Pdf

Comprehensive coverage of topics in the theory of classical liquids Widely regarded as the standard text in its field, Theory of Simple Liquids gives an advanced but self-contained account of liquid state theory within the unifying framework provided by classical statistical mechanics. The structure of this revised and updated Fourth Edition is similar to that of the previous one but there are significant shifts in emphasis and much new material has been added. Major changes and Key Features in content include: Expansion of existing sections on simulation methods, liquid-vapour coexistence, the hierarchical reference theory of criticality, and the dynamics of super-cooled liquids. New sections on binary fluid mixtures, surface tension, wetting, the asymptotic decay of pair correlations, fluids in porous media, the thermodynamics of glasses, and fluid flow at solid surfaces. An entirely new chapter on applications to 'soft matter' of a combination of liquid state theory and coarse graining strategies, with sections on polymer solutions and polymer melts, colloidal dispersions, colloid-polymer mixtures, lyotropic liquid crystals, colloidal dynamics, and on clustering and gelation. Expansion of existing sections on simulation methods, liquid-vapour coexistence, the hierarchian reference of criticality, and the dynamics of super-cooled liquids. New sections on binary fluid mixtures, surface tension, wetting, the asymptotic decay of pair correlations, fluids in porous media, the thermodynamics of glasses, and fluid flow at solid surfaces. An entirely new chapter on applications to 'soft matter' of a combination of liquid state theory and coarse graining strategies, with sections on polymer solutions and polymer melts, colloidal dispersions, colloid-polymer mixtures, lyotropic liquid crystals, colloidal dynamics, and on clustering and gelation.

Author : Jean-Louis Bretonnet
Publisher : Cambridge Scholars Publishing
Page : 582 pages
File Size : 43,8 Mb
Release : 2020-09-18
Category : Science
ISBN : 9781527559707

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Statistical Mechanics for the Liquid State by Jean-Louis Bretonnet Pdf

In a simple and accessible form, this book presents a unified approach to the physics of the liquid state, both in and out of equilibrium. It discerns, behind the seemingly anarchistic proliferation of phenomena observable in the liquid state, the sequence of causes and effects and, where appropriate, the underlying rules that preside over the general principles. The book begins by introducing the fundamental concepts of statistical mechanics, such as classical and quantum mechanics, probability theory, and the kinetic theory of gases, before moving on to discuss theoretical methods in order to contextualise the study of liquids. The last final section is devoted to ordering in complex fluids. It includes detailed technical notes and explicit calculations, and will appeal to graduate students in physics and chemistry. It will also be of interest the reader interested in statistical mechanics and their application to the physics of dense matter. This book will certainly become an indispensable reference for students and researchers who wish to become familiar with a multifaceted process looking towards new horizons.

Author : Arieh Ben-Naim
Publisher : Springer
Page : 474 pages
File Size : 50,6 Mb
Release : 2013-02-17
Category : Science
ISBN : 1461587042

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Water and Aqueous Solutions by Arieh Ben-Naim Pdf

The molecular theory of water and aqueous solutions has only recently emerged as a new entity of research, although its roots may be found in age-old works. The purpose of this book is to present the molecular theory of aqueous fluids based on the framework of the general theory of liquids. The style of the book is introductory in character, but the reader is presumed to be familiar with the basic properties of water [for instance, the topics reviewed by Eisenberg and Kauzmann (1969)] and the elements of classical thermodynamics and statistical mechanics [e.g., Denbigh (1966), Hill (1960)] and to have some elementary knowledge of probability [e.g., Feller (1960), Papoulis (1965)]. No other familiarity with the molecular theory of liquids is presumed. For the convenience of the reader, we present in Chapter 1 the rudi ments of statistical mechanics that are required as prerequisites to an under standing of subsequent chapters. This chapter contains a brief and concise survey of topics which may be adopted by the reader as the fundamental "rules of the game," and from here on, the development is very slow and detailed.

Author : Denis J. Evans,Gary P. Morriss
Publisher : ANU E Press
Page : 318 pages
File Size : 51,9 Mb
Release : 2007-08-01
Category : Science
ISBN : 9781921313233

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Statistical Mechanics of Nonequilibrium Liquids by Denis J. Evans,Gary P. Morriss Pdf

"There is a symbiotic relationship between theoretical nonequilibrium statistical mechanics on the one hand and the theory and practice of computer simulation on the other. Sometimes, the initiative for progress has been with the pragmatic requirements of computer simulation and at other times, the initiative has been with the fundamental theory of nonequilibrium processes. This book summarises progress in this field up to 1990"--Publisher's description.

Author : J. R. Solana
Publisher : CRC Press
Page : 400 pages
File Size : 49,7 Mb
Release : 2013-03-22
Category : Science
ISBN : 9781439807767

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Perturbation Theories for the Thermodynamic Properties of Fluids and Solids by J. R. Solana Pdf

This book, Perturbation Theories for the Thermodynamic Properties of Fluids and Solids, provides a comprehensive review of current perturbation theories-as well as integral equation theories and density functional theories-for the equilibrium thermodynamic and structural properties of classical systems. Emphasizing practical applications, the text

Author : Max Born,Herbert S. Green
Publisher : CUP Archive
Page : 116 pages
File Size : 46,9 Mb
Release : 2024-06-23
Category : Electronic
ISBN : 8210379456XXX

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A General Kinetic Theory of Liquids by Max Born,Herbert S. Green Pdf

Author : W. Ronald Fawcett
Publisher : Oxford University Press on Demand
Page : 638 pages
File Size : 54,6 Mb
Release : 2004-07
Category : Language Arts & Disciplines
ISBN : 9780195094329

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Liquids, Solutions, and Interfaces by W. Ronald Fawcett Pdf

Fawcett (chemistry, University of California-Davis) introduces modern topics in solution chemistry to senior undergraduates and graduate students who have completed two semesters or three quarters of chemical thermodynamics and statistical mechanics.

Author : George D.J. Phillies
Publisher : Springer Science & Business Media
Page : 441 pages
File Size : 43,8 Mb
Release : 2012-12-06
Category : Science
ISBN : 9781461212645

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Elementary Lectures in Statistical Mechanics by George D.J. Phillies Pdf

This textbook for graduates and advanced undergraduates in physics and physical chemistry covers the major areas of statistical mechanics and concludes with the level of current research. It begins with the fundamental ideas of averages and ensembles, focusing on classical systems described by continuous variables such as position and momentum, and using the ideal gas as an example. It then turns to quantum systems, beginning with diatomic molecules and working up through blackbody radiation and chemical equilibria. The discussion of equilibrium properties of systems of interacting particles includes such techniques as cluster expansions and distribution functions and uses non-ideal gases, liquids, and solutions. Dynamic behavior -- treated here more extensively than in other texts -- is discussed from the point of view of correlation functions. The text concludes with the problem of diffusion in a suspension of interacting hard spheres and what can be learned about such a system from scattered light. Intended for a one-semester course, the text includes several "asides" on topics usually omitted from introductory courses, as well as numerous exercises.

Author : Prof. Jan Hermans,Barry Lentz
Publisher : John Wiley & Sons
Page : 411 pages
File Size : 48,7 Mb
Release : 2013-10-22
Category : Science
ISBN : 9781118733776

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Equilibria and Kinetics of Biological Macromolecules by Prof. Jan Hermans,Barry Lentz Pdf

Progressively builds a deep understanding of macromolecular behavior Based on each of the authors' roughly forty years of biophysics research and teaching experience, this text instills readers with a deep understanding of the biophysics of macromolecules. It sets a solid foundation in the basics by beginning with core physical concepts such as thermodynamics, quantum chemical models, molecular structure and interactions, and water and the hydrophobic effect. Next, the book examines statistical mechanics, protein-ligand binding, and conformational stability. Finally, the authors address kinetics and equilibria, exploring underlying theory, protein folding, and stochastic models. With its strong emphasis on molecular interactions, Equilibria and Kinetics of Biological Macromolecules offers new insights and perspectives on proteins and other macromolecules. The text features coverage of: Basic theory, applications, and new research findings Related topics in thermodynamics, quantum mechanics, statistical mechanics, and molecular simulations Principles and applications of molecular simulations in a dedicated chapter and interspersed throughout the text Macromolecular binding equilibria from the perspective of statistical mechanics Stochastic processes related to macromolecules Suggested readings at the end of each chapter include original research papers, reviews and monographs, enabling readers to explore individual topics in greater depth. At the end of the text, ten appendices offer refreshers on mathematical treatments, including probability, computational methods, Poisson equations, and defining molecular boundaries. With its classroom-tested pedagogical approach, Equilibria and Kinetics of Biological Macromolecules is recommended as a graduate-level textbook for biophysics courses and as a reference for researchers who want to strengthen their understanding of macromolecular behavior.

Author : Stuart Alan Rice,Peter Gray
Publisher : Unknown
Page : 608 pages
File Size : 47,8 Mb
Release : 1965
Category : Kinetic theory of liquids
ISBN : MSU:31293002380115

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The Statistical Mechanics of Simple Liquids by Stuart Alan Rice,Peter Gray Pdf

Author : G. A. Martynov
Publisher : CRC Press
Page : 500 pages
File Size : 41,8 Mb
Release : 1992-03-26
Category : Art
ISBN : UOM:39015028471434

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Fundamental Theory of Liquids, Method of Distribution Functions by G. A. Martynov Pdf

This monograph concentrates on the statistical mechanics of fluid systems in equilibrium. The approach is classical. It shows how macroscopic properties of matter (structure, thermodynamic) can be calculated ab initio from knowledge of a few microscopic quantities. Dealing predominantly with liquids, the treatment of gases is included as a specific example. Accessible to both experimentalists & theorists, chapters can be referred to independently making this a useful handbook. A valuable monograph for postgraduate students & researchers in the fields of statistical physics, physical chemistry, chemical engineering & theoretical chemistry.

Author : Fumio Hirata
Publisher : CRC Press
Page : 288 pages
File Size : 47,9 Mb
Release : 2020
Category : Molecular Conformation
ISBN : 1138563889

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Exploring Life Phenomena with Statistical Mechanics of Molecular Liquids by Fumio Hirata Pdf

In a living body, a variety of molecules are working in a concerted manner to maintain its life, and to carry forward the genetic information from generation to generation. A key word to understand such processes is "water," which plays an essential role in life phenomena. This book sheds light on life phenomena, which are woven by biomolecules as warp and water as weft, by means of statistical mechanics of molecular liquids, the RISM and 3D-RISM theories, both in equilibrium and non-equilibrium. A considerable number of pages are devoted to basics of mathematics and physics, so that students who have not majored in physics may be able to study the book by themselves. The book will also be helpful to those scientists seeking better tools for the computer-aided-drug-discovery. Explains basics of the statistical mechanics of molecular liquids, or RISM and 3D-RISM theories, and its application to water. Provides outline of the generalized Langevin theory and the linear response theory, and its application to dynamics of water. Applies the theories to functions of biomolecular systems. Applies the theories to the computer aided drug design. Provides a perspective for future development of the method.

Author : Jean-Pierre Hansen,Ian R. McDonald
Publisher : Elsevier
Page : 569 pages
File Size : 46,8 Mb
Release : 1990-09-24
Category : Science
ISBN : 9780080571010

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Theory of Simple Liquids by Jean-Pierre Hansen,Ian R. McDonald Pdf

This book gives a comprehensive and up-to-date treatment of the theory of "simple" liquids. The new second edition has been rearranged and considerably expanded to give a balanced account both of basic theory and of the advances of the past decade. It presents the main ideas of modern liquid state theory in a way that is both pedagogical and self-contained. The book should be accessible to graduate students and research workers, both experimentalists and theorists, who have a good background in elementary mechanics. Compares theoretical deductions with experimental results Molecular dynamics Monte Carlo computations Covers ionic, metallic, and molecular liquids