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There are a lot of books available about the chemistry and biology of sulfur. However, this is the first book with a compilation of all relevant Sulfur containing reagents. Synthetic chemists, most particularly in the medicinal and pharmaceutical chemists, are often called upon to prepare compounds that contain Sulfur as a key structural feature. In the past, this seemed to be a domain for specialists; today every synthetic chemist working in these area is expected to synthesize compounds containing sulfides, sulfates, sulfones, etc. This book offers an important source of information for the selection and handling of the right reagents.
Sulfur Reagents in Organic Synthesis by Patrick Metzner,Andre Thuillier Pdf
Designed for the practising organic chemist, this book details over a hundred experimental procedures using sulfer compounds in organic synthesis. Many of these methods are new to the literature, having been published since 1991, and illustrate the striking versatility of the use of sulfur reagents. Examples are simple to perform and extremely useful, and as such this book will be an invaluable aid to all involved in synthetic organic chemistry, whether in academic or industrial laboratories.
An Introduction to Organosulfur Chemistry by R. J. Cremlyn Pdf
Sulfur chemistry is becoming increasingly important as the role of this element is explored in both biological and environmental fields. After the initial chapters have discussed the synthesis, reactivity, and properties of the compounds in general, each of the next nine chapters takes a specific sulfur containing functional group and expands the discussion on synthetic procedures. The final chapter looks at the major uses of organo-sulfur compounds and their impact on biological and environmental areas.
Chiral Sulfur Reagents by Marian Mikolajczyk,Jozef Drabowicz,Piotr Kielbasinski Pdf
Over the last three decades, more than 40 different classes of chiral (mirror-image) sulfur compounds have been described, and a number of useful procedures and applications have been developed for their use. Emphasizing modern methodologies, Chiral Sulfur Reagents demonstrates the great potential of enantionmerically pure sulfur reagents in transmitting chirality to other centers. Each chapter highlights the synthesis and synthetic uses of a particular class of chiral sulfur reagent, followed by examples of the most important experimental procedures.
In recent years organic sulfur chemistry has been growing at an even faster pace than the very rapid development in other fields of chemistry. This phenomenal growth is undoubtedly a reflection of industrial and public demands: not only was sulfur recently in overall surplus for the first time in the history of the chemical industry but it has now become a prin cipal environmental hazard in the form of sulfur dioxide, sulfuric acid and hydrogen sulfide. Another reason, discernible in the last fifteen years, has been the desire, on the part of individual chemists and all types of research managers, to move away from the established chemistry of carbon into the less well understood and sometimes virgin chemistries of the other elements which form covalent bonds. As a result of this movement the last decade has seen the development of sulfur chemistry into a well-organized and now much better understood branch of organic chemistry. Enough of the detail has become clear to see mechanistic interrelationships between previously unconnected reactions and with this clarification the whole subject has in tum become systema tized and subdivided. The divalent sulfur chemistry of thiols, monosulfides, disulfides and polysulfides is a large area in itself, much of it devoted to oxidation-reduction and the breakage and formation of sulfur-sulfur bonds, although interesting discoveries are now being made about the reac tivity of certain sulfur-carbon bonds. Of course, this area has its own mas sive biochemical branch involving enzymes and proteins.
Organic Sulfur Compounds, Volume I deals with the chemistry of organic sulfur compounds such as disulfides, polysulfides, olefins, acetylenes, and chloroethylenes. Topics covered range from the inorganic acids of sulfur and the thermodynamics of organic sulfur compounds to some applications of isotopic sulfur and the stereochemistry of disulfides and polysulfides. The mechanism of oxidation of thiols to disulfides is also discussed. Comprised of 40 chapters, this volume first considers the precise structures of elemental sulfur in relation to the reactions of sulfur compounds, followed by an analysis of the inorganic acids of sulfur. The reader is then introduced to the thermodynamics of organic sulfur compounds and the bonding characteristics of the sulfur atom, as well as the infrared spectra of organosulfur compounds. Subsequent chapters focus on the ionic scission of the sulfur-sulfur bond; nucleophilic reactions of thiols with acetylene and chloroethylene; reactions of sulfur with olefins; and the chemistry of isothiocyanates. This book should prove useful to advanced students, practitioners, and research workers in the field of organic chemistry.
Reactions of Organosulfur Compounds by Eric Block Pdf
Organic Chemistry, Volume 37: Reactions of Organosulfur Compounds covers the basics of organosulfur chemistry and the characteristics of organically bound sulfur, with an emphasis on reactions, particularly those of synthetic utility. The book discusses the preparation, nature, stereochemical aspects, reactions, and the kinetic and thermodynamic assessment of the stability of sulfur-containing carbanions; the preparation and reactions of sulfur ylides; and the preparation, assessment of stability, and reactions of sulfur-containing carbocations. The text also describes preparation, assessment of stability, nature, and reactions of sulfur-containing radicals, organosulfur carbenes, and carbenoids; as well as the the pericyclic reactions of organosulfur compounds. Chemists, biochemists, and students taking related courses will find the book useful.
This volume contains fundamental knowledge regarding the structure and mechanisms of organic sulfur chemistry. Topics include sulfur bondings, effects of sulfur groups, stereochemistry around sulfur, substitution, ligand coupling within s-sulfurane, oxidation, reduction and rearrangement. References in this work total over 2,300. Anyone with an interest in organic sulfur chemistry will find this book to be fascinating reading.
Reactions of Sulfur with Organic Compounds by Mikhail Grigorʹevich Voronkov Pdf
This book, written by the eminent Russian organic chemist Professor M. G. Voronkov, exhaustively deals with the reactions of sulfur with organic compounds. It is the only book on the subject which covers both work readily available to Western scientists and research carried out by Russian workers. Since much of the work discussed in this volume is not readily accessible to Western scien tists, it will enable them to find hitherto "unpublished" research. In addition, Professor Voronkov has dealt with many reactions and processes of interest to the industrial chemist; e.g., there is an interesting section on sulfur dyes and related compounds, and the chemistry of vulcanization is lucidly discussed. Hence this book should be of value to both academic and industrial chemists inter ested in the chemistry and reactions of sulfur, and also to those synthetic chemists studying new pathways to organic compounds. The text has recently been updated and revised, and there are numerous references to publications up to and including 1980. An exhaustive index is provided to enable the reader to refer rapidly to any of the compounds, reactions, or processes discussed in the text.
Advances in Sulfur Chemistry, Volume 1 provides information pertinent to the four key aspects of sulfur chemistry. This book illustrates the great utility of sulfur in organic synthesis as applied to the synthesis of cyclic compounds, most of which serve as intermediates in the total synthesis of natural products. Organized into five chapters, this volume begins with an overview of desulfurization using Raney nickel. This text then highlights the extensive research done on compounds containing both phosphorus and sulfur attached to the same carbon atom, revealing synergism involving these adjacent second row heteroatoms. Other chapters consider the significant class of thiaheterocycles and include a discussion of the chemistry of disulfur. The final chapter deals with the chemistry of metal complexes of thiols, with focus on the chemistry, structure, and chemical modeling of the nitrogenase enzyme system, whereby dinitrogen is ultimately reduced to ammonia. This book is a valuable resource for graduate students, postdoctoral fellows, industrial chemists, and those teaching specialized topics to graduate students.
The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.
Chemistry of Organosulfur Compounds by Leonid Isaakovich Belenʹkiĭ Pdf
A review of the major methods of producing sulfur-organic compounds, which presents data related to their applications and methods of catalytic synthesis. There is also a discussion on the conversion of compounds which have applications in the processes of polymerization and vulcanization.
The Organic Chemistry of Sulfur, Tetracovalent Sulfur Compounds by Chester Merle Suter Pdf
Esters of sulfuric acid; Aliphatic sulfonic acids; The preparation of aromatic sulfonic acids; The properties and reactions of aromatic sulfonic acids; Derivatives of aromatic sulfonic acids. 1. Sulfonyl halides, esters, and anhydrides; Derivatives of aromatic sulfonic acids. 2. Sulfonamides and related compounds; Sulfones.
Handbook of Reagents, 4 Volume Set by Gary A. Molander Pdf
EROS has become a brand name for high quality information on organic reagents. For chemists at the bench we have developed the series of Handbooks of Reagents for Organic Synthesis, which contain all the necessary information in focused volumes. All content has been expertly collected and presented by an internationally recognised and respected editorial board. This four-volume set comprises of: Fluorine-Containing Reagents Today every synthetic chemist working in medicinal and pharmaceutical areas are expected to synthesize compounds containing Fluorides. This book will be an important source of information for the selection and handling of the right reagents. Catalyst Components for Coupling Reactions Compiles all major catalyst components in use in the area, and is intended to guide the experimentalist and facilitate choice among the numerous reagents available for any one purpose. The Handbook details pre-catalysts, catalysts, and ligands prominently employed in coupling reactions, broadly defined. Reagents for Radical and Radical Ion Chemistry Concentrates on reagents for the creation and use of radicals and radical ions, reflecting the enormous growth of radical chemistry over the past ten years. Includes coverage of reagents used in the preparation of key radical and radical ion precursors, reagents for the generation of radical and radical ions themselves, initiators, and radical traps. Sulfur-Containing Reagents Sulfur containing molecules are essential in a wide range of applications, such as drugs, pesticides and polymers and “Sulfur bridges” are important in peptide and protein chemistry. This handbook provides a compilation of all relevant Sulfur containing reagents and how to select and handle the right reagents. This set is intended for chemists in industry and academia, especially in the areas of medicinal chemistry, drug development, pharmaceutical chemistry, biological chemistry, biochemistry, bioorganic chemistry, agricultural and food industries, plastics, polymers, dyes, cosmetics, detergents and novel materials. They are ideal for use in the laboratory.