Sulfur Dioxide Insertion Reactions For Organic Synthesis

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Sulfur Dioxide Insertion Reactions for Organic Synthesis

Author : Danqing Zheng,Jie Wu
Publisher : Springer
Page : 80 pages
File Size : 55,8 Mb
Release : 2017-04-04
Category : Science
ISBN : 9789811042027

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Sulfur Dioxide Insertion Reactions for Organic Synthesis by Danqing Zheng,Jie Wu Pdf

This brief summarizes the most commonly used sulfur dioxide surrogates and also shows the diverse reactivities to highlight the advances made in the development of synthetic methods through the insertion of sulfur dioxide. Depending on the nature of the transformation, these reactions are classified into four types: (i) pericyclic reactions; (ii) nucleophilic addition with organometallic reagents; (iii) transition metal catalysis; and (iv) free radical reactions. Highlighting recent advances in the insertion of sulfur dioxide, providing detailed descriptions of the experimental procedures for these valuable reactions, and discussing the remaining challenges in this field, the brief offers an appealing and highly useful guide for a wide readership in organic chemistry and medicinal chemistry from both academia and industry.

Advances in Organometallic Chemistry

Author : Anonim
Publisher : Academic Press
Page : 456 pages
File Size : 50,5 Mb
Release : 1974-06-28
Category : Science
ISBN : 0080580130

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Advances in Organometallic Chemistry by Anonim Pdf

Advances in Organometallic Chemistry

Comprehensive Organic Synthesis

Author : Barry M. Trost
Publisher : Elsevier
Page : 1174 pages
File Size : 51,9 Mb
Release : 1991
Category : Science
ISBN : 0080405991

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Comprehensive Organic Synthesis by Barry M. Trost Pdf

Volume 8.

Comprehensive Organic Functional Group Transformations: Synthesis: carbon with one heteroatom attached by a single bond

Author : Alan R. Katritzky,Otto Meth-Cohn,Charles Wayne Rees
Publisher : Elsevier
Page : 1474 pages
File Size : 55,9 Mb
Release : 1995-12-29
Category : Science
ISBN : 008042323X

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Comprehensive Organic Functional Group Transformations: Synthesis: carbon with one heteroatom attached by a single bond by Alan R. Katritzky,Otto Meth-Cohn,Charles Wayne Rees Pdf

Organomercury Compounds in Organic Synthesis

Author : R.C. Larock
Publisher : Springer Science & Business Media
Page : 432 pages
File Size : 41,6 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783642700040

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Organomercury Compounds in Organic Synthesis by R.C. Larock Pdf

The field of organometallic chemistry has enjoyed explosive growth in recent years. During this time a rapidly increasing number of metals have found utility in organic synthesis as the corresponding organometallic compounds. The sub ject of "Organic Synthesis by Means of Transition Metal Complexes" was reviewed in the first volume of this series of monographs. This volume deals primarily with the appli cation of organomercury compounds in organic synthesis (exclusive of solvomercuration-demercuration reactions), but will of necessity involve a number of reactions of other organometallics as well. Organomercurials are among the oldest known organo metallics and were perhaps the first to have an entire book devoted to their chemistry, when Whitmore wrote an American Chemical Society monograph on the subject in 1921. Subsequently, two very detailed monographs on the subject have appeared. In 1967 "The Organic Compounds of Mercury", volume 4 in the series "Methods of Elemento Organic Chemistry" appeared and this was followed in 1974 by Houben Weyl's full volume, Band XIII/2b, devoted entirely to the organometallic compounds of mercury. These books cover the entire field of organomercury chemistry.

Stereoselective Synthesis of Drugs and Natural Products

Author : Vasyl Andrushko,Natalia Andrushko
Publisher : John Wiley & Sons
Page : 1836 pages
File Size : 43,6 Mb
Release : 2013-08-16
Category : Science
ISBN : 9781118628331

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Stereoselective Synthesis of Drugs and Natural Products by Vasyl Andrushko,Natalia Andrushko Pdf

Brings together the best tested and proven stereoselective synthetic methods Both the chemical and pharmaceutical industries are increasingly dependent on stereoselective synthetic methods and strategies for the generation of new chiral drugs and natural products that offer specific 3-D structures. With the publication of Stereoselective Synthesis of Drugs and Natural Products, researchers can turn to this comprehensive two-volume work to guide them through all the core methods for the synthesis of chiral drugs and natural products. Stereoselective Synthesis of Drugs and Natural Products features contributions from an international team of synthetic chemists and pharmaceutical and natural product researchers. These authors have reviewed the tremendous body of literature in the field in order to compile a set of reliable, tested, and proven methods alongside step-by-step guidance. This practical resource not only explores synthetic methodology, but also reaction mechanisms and applications in medicinal chemistry and drug discovery. The publication begins with an introductory chapter covering general principles and methodologies, nomenclature, and strategies of stereoselective synthesis. Next, it is divided into three parts: Part One: General Methods and Strategies Part Two: Stereoselective Synthesis by Bond Formation including C-C bond formation C-H bond formation C-O bond formation C-N bond formation Other C-heteroatom formation and other bond formation Part Three: Methods of Analysis and Chiral Separation References in every chapter serve as a gateway to the literature in the field. With this publication as their guide, chemists involved in the stereoselective synthesis of drugs and natural products now have a single, expertly edited source for all the methods they need.

Cumulative Indexes

Author : Barry M. Trost
Publisher : Elsevier
Page : 828 pages
File Size : 43,8 Mb
Release : 1992-09-08
Category : Science
ISBN : 9780080912523

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Cumulative Indexes by Barry M. Trost Pdf

Cumulative Indexes

The Lightest Metals

Author : Timothy P. Hanusa
Publisher : John Wiley & Sons
Page : 496 pages
File Size : 42,6 Mb
Release : 2015-10-12
Category : Science
ISBN : 9781118751435

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The Lightest Metals by Timothy P. Hanusa Pdf

The first seven metals in the periodic table are lithium, beryllium, sodium, magnesium, aluminium, potassium and calcium, known collectively as the “lightest metals”. The growing uses of these seven elements are enmeshing them ever more firmly into critical areas of 21st century technology, including energy storage, catalysis, and various applications of nanoscience. This volume provides comprehensive coverage of the fundamentals and recent advances in the science and technology of the lightest metals. Opening chapters of the book describe major physical and chemical properties of the metals, their occurrence and issues of long-term availability. The book goes on to disucss a broad range of chemical features, including low oxidation state chemistry, organometallics, metal-centered NMR spectroscopy, and cation-π interactions. Current and emerging applications of the metals are presented, including lithium-ion battery technology, hydrogen storage chemistry, superconductor materials, transparent ceramics, nano-enhanced catalysis, and research into photosynthesis and photoelectrochemical cells. The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry: http://www.wileyonlinelibrary.com/ref/eibc

Green Solvents in Organic Synthesis

Author : Xiao-Feng Wu,Zhiping Yin,Liang-nian He,Feng Wang
Publisher : John Wiley & Sons
Page : 469 pages
File Size : 52,5 Mb
Release : 2024-03-11
Category : Science
ISBN : 9783527352005

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Green Solvents in Organic Synthesis by Xiao-Feng Wu,Zhiping Yin,Liang-nian He,Feng Wang Pdf

Green Solvents in Organic Synthesis Essential reference on replacing conventional solvents with greener alternatives in industrial chemicals synthesis and production A well-timed book promoting sustainability in synthesis and production of chemicals, Green Solvents in Organic Synthesis details various green solvents, solvent systems, and solubilization techniques, including their chemistry, physiochemical properties, performance, and distinct applications, presenting a greener approach to conventional solvents by replacing them with sustainable alternatives that have similarities in their reaction mechanisms. Edited by four highly qualified academics with significant research experience in the field, Green Solvents in Organic Synthesis includes information on: Water and liquid polymers (Polyethylene glycol PEG), Acetonitrile, DMSO, Dimethyl carbonate, Ionic liquids, and Supercritical fluids) Bio-based solvents (Cyrene, γ-Valerolactone (GVL), Lactic acid, 2-MeTHF) and deep eutectic solvents (DESs) Alcohols (MeOH, EtOH, i-PrOH, n-BuOH, t-BuOH, Ethylene glycol), ketones (Acetones, MEK, MIBK, Cyclohexanone), and esters (Methyl acetate, Ethyl acetate, i-PrOAc, n-BuOAc) Technical, economic, and environmental aspects of green solvents and how to maximize their reuse and recycling to alleviate pollution and reduce energy consumption For chemists in a variety of disciplines, Green Solvents in Organic Synthesis is an essential reference that provides foundational knowledge of green solvents, along with key features of each class of green solvent within the context of organic reactions for industrial and laboratory synthesis.

Reduction

Author : Barry M. Trost
Publisher : Elsevier
Page : 1166 pages
File Size : 49,7 Mb
Release : 1992-09-08
Category : Science
ISBN : 9780080912516

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Reduction by Barry M. Trost Pdf

This volume contains 37 chapters on methods for reducing functional groups, organized into four main parts. (i) Reduction of C=X systems, where X is an electronegative heteroatom, divided into 14 chapters based on the degree of reduction, the oxidation level of the C=X substrate, and on the nature of the reagent. (ii) Reduction of X=Y systems, divided into three chapters, covering the reduction of such groups as nitro, azo, and the various kinds of P=O and S=O groups. (iii) Reduction of C=C and C≡C, divided into 12 chapters based on the method of reduction, with aromatic, heteroaromatic, and conjugated systems treated separately, and including an extensive discussion of hydrometallation. (iv) Reduction of single bonds, C-X to C-H, in eight chapters, including the hydrogenolysis of the various kinds of C-X bonds, the reduction of epoxides, and the reduction of vinyl derivatives to alkenes. Each chapter includes a discussion of chemoselectivity, regioselectivity, and stereoselectivity, wherever it is appropriate, and most include advice on the reagent of choice, and the mechanistic basis of the various methods of reduction. In short, it is, within the space available, as near to a comprehensive account of reduction in organic chemistry as one could hope for.

Transition Metals in Organic Synthesis

Author : Rolf Scheffold
Publisher : Unknown
Page : 450 pages
File Size : 52,8 Mb
Release : 1983
Category : Science
ISBN : PURD:32754002308561

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Transition Metals in Organic Synthesis by Rolf Scheffold Pdf

Comprehensive Organometallic Chemistry II, Volume 14

Author : Edward W. Abel
Publisher : Elsevier
Page : 399 pages
File Size : 55,5 Mb
Release : 2002-09-10
Category : Science
ISBN : 9780080912745

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Comprehensive Organometallic Chemistry II, Volume 14 by Edward W. Abel Pdf

Since the publication Comprehensive Organometallic Chemistry in 1982, studies on the chemistry of molecules with carbon-metal bonds have continued to expand rapidly. This is due to many factors, ranging from the sheer intellectual challenge and excitement provided by the continuing production of novel results, which demand new ideas, through to the successful application of organometallic species in organic syntheses, the generation of living catalysts for polymerization, and the synthesis of precursors for materials employed in the electronic and ceramic industries. These factors led to the publication of the updated Comprehensive Organometallic Chemistry II. The original work serves as a basis for new volumes, focusing on organometallic chemistry reported since 1982, with reference back to the original work when necessary. For ease of use the new volumes maintain the same general structure as employed previously but reflect the changes in substance and direction the field has undergone in the last ten years. This book will serve as a pivotal reference point for new work and will function to generate new ideas and perceptions for the continued advance of what will surely continue as a vibrant area of chemistry.

Catalysis of Organic Reactions

Author : Mike G. Scaros
Publisher : Routledge
Page : 566 pages
File Size : 43,6 Mb
Release : 2017-11-22
Category : Science
ISBN : 9781351462341

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Catalysis of Organic Reactions by Mike G. Scaros Pdf

Based on the papers and posters presented at the 15th Conference on Catalysis of Organic Reactions, this work covers developments in the study of catalysis as it relates to organic synthesis, emphasizing applications in industrial processes. Over 1000 bibliographic citations and over 250 tables, drawings, and photographs are provided. Theoretical and practical aspects of the field are highlighted.