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The monograph is concerned with the results of examination of the properties of superionic conductors and their heterostructures with different electrode materials. Special attention is given to the problems of changes in the characteristics of impedance in a wide frequency range. The author presents theoretical and experimental data on the properties of ionic, ionic-electronic conductors, reversible and polarised interfaces. The directions and specific examples of practical application of superionic conductors and heterostructures based on them are also discussed.
A hundred and eighty five chemists, physicists, and engineers met in Schenectady, New York, for the three days May 10-12, 1976, to discuss the subject of Superionic Conductors. This International Conference was held at the Research and Development Center of the General Electric Company. The subject of the Conference was fast ion transport in solids. These materials have potential application in new types of batteries, fuel cells, and sensors. Some like beta alumina are under active development in nov'el new systems. Their study has also become a popular area of scientific investigation. One objective of the Conference was to provide a forum for interdisciplinary communication between chemists, physicists, and engineers. The Conference was an attempt to bring these groups together, in order to listen to each others problems and progress. We began organizing the Conference in the spring of 1975. It was suggested to General Electric managers Drs. Craig S. Tedmon, Jr. and Roland W. Schmitt. They provided immediate and enthusiastic support. They also provided the advice, staff, and backup which were necessary at all points in the planning and duration of the Conference. We were also pleased that they could participate in the Conference: Dr. Tedmon welcomed the participants and officially opened the Conference, and Dr. Schmitt gave the after banquet address. We thank them. Additional and invaluable help, and advice, were also provided by Drs. D. Chatterji, J. B. Bush, G. W. Ludwig, and J. B. Comly. We were joined on the program committee by Drs.
Physics of Superionic Conductors by M.B. Salamon Pdf
Superionic conductors are solids whose ionic conductivities approach, and in some cases exceed, those of molten salts and electrolyte solutions. This implies an un usual state of matter in which some atoms have nearly liquidlike mobility while others retain their regular crystalline arrangement. This liquid-solid duality has much appeal to condensed matter physicists, and the coincident development of powerful new methods for studying disordered solids and interest in superionic conductors for technical applications has resulted in a new surge of activity in this venerable field. It is the purpose of this book to summarize the current re search in the physics of superionic conduction. with special emphasis on those aspects which set these materials apart from other solids. The volume is aimed to wards the materials community and will, we expect, stimulate further research on these potentially useful substances. The usual characterization of the superionic phase lists high ionic conductivity; low activation energy; and the open structure of the crystal, with its interconne ted network of vacant sites available to one ionic species. To these, as we demon strate in this volume, should be added important dynami~ and collective effect~: the absence of well-defined optical lattice modes, the presence of a pervasive, low-energy excitation, an infrared peak in the frequency-dependent conductivity, unusual NMR prefactors, phase transitions, and a strong tendency for the mobile ion to be found between allowed sites.
The Physics of Superionic Conductors and Electrode Materials by John W. Perram Pdf
The following chapters present most of the lectures delivered at the NATO Advanced Studies Institute on "The Physics of Super ionic Conductors and Electrode Materials", held at Odense Univer sity's Mathematics Department between the 4th and 22nd of August, 1980. The aim of the organizing committee was to present in a rather detailed fashion the most recent advances in the computa tional mathematics and physics of condensed matter physics and to see how these advances could be applied to the study of ionically conducting solids. The first half of the meeting was mainly taken up with lectures. In the second week, working groups on the various aspects were set up, the students joining these groups being helped in the implementation of the lecture material. The leaders of these groups deserve special mention for the tremendous effort they put into this aspect of the meeting, particularly: Dr. Aneesur Rahman (Molecular Dynamics group) Dr. Fred Horne (Ion Transport group) Drs. Nick Quirke and David Adams (Monte Carlo methods) Dr. Heinz Schulz (Diffraction group) Dr. John Harding (Defect Calculations group) The Molecular Dynamics group achieved a certain amount of notoriety within the University by appearing to live in the terminal room.
Uses an integrated, scientists' approach to the principles regulating the synthesis, structure and physical characteristics of crystalline solids. Mathematical derivations are kept to a minimum. Covers electrical properties of metals and band semiconductors, superionic conductors, ferrites and solid electrolytes. Features end-of-chapter problem sets.
International Symposium On Solid Ionic and Ionic-Electronic Conductors by R. D. Armstrong Pdf
Solid Ionic and Ionic-Electronic Conductors presents a selection of papers gathered from the International Conference on Solid Ionic and Ionic-Electronic Conductors, held in Rome in September 1976. The collection emphasizes studies on lithium ion conductors and solid electrolytes. The conference covers a broad range of topics on solid ionic and ionic-electronic conductors. A considerable amount of papers are written on Li-ion conductors, where topics on conductivity data for several lithium ion conductors; new Li-ion conductors with several different structure types; and the crystal structure of a group of ternary copper compounds of the composition CuTeX are presented. Papers dealing with investigations and applications of solid electrolytes are also substantial and cover topics on iodine diffusion and gettering in solid electrolyte batteries; the application of solid electrolytes to the thermodynamic study of some alkaline earths silicates; and properties and applications of sulfate-based solid electrolytes. Electronics engineers, physicists, researchers, materials engineers, and businessmen in the electronics industry will find the contents of the book insightful.
Solid State Electrochemistry I by Vladislav V. Kharton Pdf
The only comprehensive handbook on this important and rapidly developing topic combines fundamental information with a brief overview of recent advances in solid state electrochemistry, primarily targeting specialists working in this scientific field. Particular attention is focused on the most important developments performed during the last decade, methodological and theoretical aspects of solid state electrochemistry, as well as practical applications. The highly experienced editor has included chapters with critical reviews of theoretical approaches, experimental methods and modeling techniques, providing definitions and explaining relevant terminology as necessary. Several other chapters cover all the key groups of the ion-conducting solids important for practice, namely cationic, protonic, oxygen-anionic and mixed conductors, but also conducting polymer and hybrid materials. Finally, the whole is rounded off by brief surveys of advances in the fields of fuel cells, solid-state batteries, electrochemical sensors, and other applications of ion-conducting solids. Due to the very interdisciplinary nature of this topic, this is of great interest to material scientists, polymer chemists, physicists, and industrial scientists, too.
Phonons: Theory and Experiments III by Peter Brüesch Pdf
The first volume of this treatment, Phonons: Theory and Experiments I, was devoted to the basic concepts of the physics of phonons and to a study of models for interatomic forces. The second volume, Phonons: Theory and Experiments II, contains a study of experimental techniques and the inter pretation of experimental results. In the present third volume we treat a number of phenomena which are directly related to phonons. The aim of this book is to bridge the gap between theory and experi ment. An attempt has been made to present the descriptive as well as the analytical aspects of the topics. Although emphasis is placed on the role of phonons in the different topics, most chapters also contain a general intro duction into the specific subject. The book is addressed to experimentalists and to theoreticians working in the vast field of dynamical properties of solids. It will also prove useful to graduate students starting research in this or related fields. The choice of the topics treated was partly determined by the author's own activity in these areas. This is particularly the case for the chapters dealing with phonons in one-dimensional metals, disordered systems, super ionic conductors and certain newer aspects of ferroelectricity and melting. I am very grateful to my colleagues J. Bernasconi, V.T. Hochli and 1.
Fast Ionic Conductors and Solid-Solid Interfaces Designed for Next Generation Solid-State Batteries by Fuminori Mizuno,Jeff Sakamoto,Shyue Ping Ong Pdf