Surface Organometallic Chemistry Molecular Approaches To Surface Catalysis

Author : Jean-Marie Basset,Bruce C. Gates,Jean-Pierre Candy,Agnès Choplin,Michel Leconte,Françoise Quignard,Cathérine Santini
Publisher : Springer Science & Business Media
Page : 340 pages
File Size : 43,8 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789400929715

Get Book

Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis by Jean-Marie Basset,Bruce C. Gates,Jean-Pierre Candy,Agnès Choplin,Michel Leconte,Françoise Quignard,Cathérine Santini Pdf

Surface organometallic chemistry is a new field bringing together researchers from organometallic, inorganic, and surface chemistry and catalysis. Topics ranging from reaction mechanisms to catalyst preparation are considered from a molecular basis, according to which the "active site" on a catalyst surface has a supra-molecular character. This. the first book on the subject, is the outcome of a NATO Workshop held in Le Rouret. France, in May. 1986. It is our hope that the following chapters and the concluding summary of recommendations for research may help to provide a definition of surface organometallic chemistry. Besides catalysis. the central theme of the Workshop, four main topics are considered: 1) Reactions of organometallics with surfaces of metal oxides, metals. and zeolites; 2) Molecular models of surfaces, metal oxides, and metals; 3) Molecular approaches to the mechanisms of surface reactions; 4) Synthesis and modification of zeolites and related microporous solids. Most surface organometallic chemistry has been carried out on amorphous high-surf ace-area metal oxides such as silica. alumina. magnesia, and titania. The first chapter. contributed by KNOZINGER. gives a short summary of the structure and reactivity of metal oxide surfaces. Most of our understanding of these surfaces is based on acid base and redox chemistry; this chemistry has developed from X-ray and spectroscopic data, and much has been inferred from the structures and reactivities of adsorbed organic probe molecules. There are major opportunities for extending this understanding by use of well-defined (single crystal) oxide surfaces and organometallic probe molecules.

Author : Anonim
Publisher : Unknown
Page : 52 pages
File Size : 42,9 Mb
Release : 1987
Category : Catalysis
ISBN : CHI:37716564

Get Book

Surface Organometallic Chemistry by Anonim Pdf

Author : Jean-Marie Basset,Rinaldo Psaro,Dominique Roberto,Renato Ugo
Publisher : Wiley-VCH
Page : 725 pages
File Size : 46,7 Mb
Release : 2009-08-10
Category : Science
ISBN : 3527319727

Get Book

Modern Surface Organometallic Chemistry by Jean-Marie Basset,Rinaldo Psaro,Dominique Roberto,Renato Ugo Pdf

Covering everything from the basics to recent applications, this monograph represents an advanced overview of the field. Edited by internationally acclaimed experts respected throughout the community, the book is clearly divided into sections on fundamental and applied surface organometallic chemistry. Backed by numerous examples from the recent literature, this is a key reference for all chemists.

Author : C. Copéret,Bruno Chaudret
Publisher : Springer Science & Business Media
Page : 312 pages
File Size : 55,7 Mb
Release : 2005-11-03
Category : Science
ISBN : 3540264965

Get Book

Surface and Interfacial Organometallic Chemistry and Catalysis by C. Copéret,Bruno Chaudret Pdf

With contributions by numerous experts

Author : Jean-Marie Basset,Rinaldo Psaro,Dominique Roberto,Renato Ugo
Publisher : John Wiley & Sons
Page : 725 pages
File Size : 51,5 Mb
Release : 2009-07-10
Category : Science
ISBN : 9783527627103

Get Book

Modern Surface Organometallic Chemistry by Jean-Marie Basset,Rinaldo Psaro,Dominique Roberto,Renato Ugo Pdf

Covering everything from the basics to recent applications, this monograph represents an advanced overview of the field. Edited by internationally acclaimed experts respected throughout the community, the book is clearly divided into sections on fundamental and applied surface organometallic chemistry. Backed by numerous examples from the recent literature, this is a key reference for all chemists.

Author : Sophie Hermans,Thierry Visart de Bocarme
Publisher : Royal Society of Chemistry
Page : 318 pages
File Size : 51,6 Mb
Release : 2015
Category : Science
ISBN : 9781849738293

Get Book

Atomically-Precise Methods for Synthesis of Solid Catalysts by Sophie Hermans,Thierry Visart de Bocarme Pdf

With techniques bridging the gap between surface science and heterogeneous catalysis the book presents a tool-kit for anyone wishing to prepare and define solid catalysts.

Author : Gabor A. Somorjai,Yimin Li
Publisher : John Wiley & Sons
Page : 804 pages
File Size : 41,6 Mb
Release : 2010-06-08
Category : Science
ISBN : 9780470508237

Get Book

Introduction to Surface Chemistry and Catalysis by Gabor A. Somorjai,Yimin Li Pdf

Now updated-the current state of development of modern surface science Since the publication of the first edition of this book, molecular surface chemistry and catalysis science have developed rapidly and expanded into fields where atomic scale and molecular information were previously not available. This revised edition of Introduction to Surface Chemistry and Catalysis reflects this increase of information in virtually every chapter. It emphasizes the modern concepts of surface chemistry and catalysis uncovered by breakthroughs in molecular-level studies of surfaces over the past three decades while serving as a reference source for data and concepts related to properties of surfaces and interfaces. The book opens with a brief history of the evolution of surface chemistry and reviews the nature of various surfaces and interfaces encountered in everyday life. New research in two crucial areas-nanomaterials and polymer and biopolymer interfaces-is emphasized, while important applications in tribology and catalysis, producing chemicals and fuels with high turnover and selectivity, are addressed. The basic concepts surrounding various properties of surfaces such as structure, thermodynamics, dynamics, electrical properties, and surface chemical bonds are presented. The techniques of atomic and molecular scale studies of surfaces are listed with references to up-to-date review papers. For advanced readers, this book covers recent developments in in-situ surface analysis such as high- pressure scanning tunneling microscopy, ambient pressure X-ray photoelectron spectroscopy, and sum frequency generation vibrational spectroscopy (SFG). Tables listing surface structures and data summarizing the kinetics of catalytic reactions over metal surfaces are also included. New to this edition: A discussion of new physical and chemical properties of nanoparticles Ways to utilize new surface science techniques to study properties of polymers, reaction intermediates, and mobility of atoms and molecules at surfaces Molecular-level studies on the origin of the selectivity for several catalytic reactions A microscopic understanding of mechanical properties of surfaces Updated tables of experimental data A new chapter on "soft" surfaces, polymers, and biointerfaces Introduction to Surface Chemistry and Catalysis serves as a textbook for undergraduate and graduate students taking advanced courses in physics, chemistry, engineering, and materials science, as well as researchers in surface science, catalysis science, and their applications.

Author : R. Ugo
Publisher : Springer Science & Business Media
Page : 122 pages
File Size : 52,7 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789400921139

Get Book

Aspects of Homogeneous Catalysis by R. Ugo Pdf

The literature contains tens of thousands of publications and patents devoted to the synthesis, characterization and processing of polymers. Despite the fact that there are more than one hundred elements, the majority of these publications and patents concern polymers with carbon backbones. Furthermore, the limited (by comparison) number of publications on polymers that contain elements other than carbon in their backbones are typically devoted to polymers based on silicon, especially those with Si-O bonds. This disparity is partially a consequence of the dearth of low cost organometallic feedstock chemicals potentially useful for polymer synthesis. It also derives from the lack of general synthetic techniques for the preparation of organometallic polymers. That is, by comparison with the numerous synthetic strategies available for the preparation of organic polymers, there are few such strategies available for synthesizing tractable, organometallic polymers. In recent years, commerical and military performance requirements have begun to challenge the performance limits of organic polymers. As such, researchers have turned to organometallic polymers as a possible means of exceeding these limits for a wide range of applications that include: (1) microelectronics processing (e.g. photoresists) [1]; (2) light weight batteries (conductors and semi-conductors) [2]; (3) non-linear optical devices [3] and, (4) high temperature structural materials (e.g. ceramic fiber processing) [4,5].

Author : Ryan Richards
Publisher : CRC Press
Page : 555 pages
File Size : 42,7 Mb
Release : 2006-05-25
Category : Science
ISBN : 9781420015751

Get Book

Surface and Nanomolecular Catalysis by Ryan Richards Pdf

Using new instrumentation and experimental techniques that allow scientists to observe chemical reactions and molecular properties at the nanoscale, the authors of Surface and Nanomolecular Catalysis reveal new insights into the surface chemistry of catalysts and the reaction mechanisms that actually occur at a molecular level during catalys

Author : Rutger A. van Santen,Matthew Neurock
Publisher : John Wiley & Sons
Page : 488 pages
File Size : 40,5 Mb
Release : 2009-06-10
Category : Science
ISBN : 9783527608348

Get Book

Molecular Heterogeneous Catalysis by Rutger A. van Santen,Matthew Neurock Pdf

An integrated approach to the molecular theory of reaction mechanism in heterogeneous catalysis, largely based on the knowledge among the growing theoretical catalysis community over the past half century, and covering all major catalytic systems. The authors develop a general conceptual framework, including in-depth comparisons with enzyme catalysis, biomineralisation, organometallic and coordination chemistry. A chapter dedicated to molecular electrocatalysis addresses the molecular description of reactions at the liquid-solid interphase, while studies range from a quantum-chemical treatment of individual molecular states to dynamic Monte-Carlo simulations, including the full flexibility of the many-particle systems. Complexity in catalysis is explained in chapters on self-organization and self-assembly of catalysts, and other sections are devoted to evolutionary, combinatorial techniques as well as artificial chemistry.

Author : Anonim
Publisher : Elsevier
Page : 677 pages
File Size : 50,9 Mb
Release : 2001-05-21
Category : Science
ISBN : 9780080538310

Get Book

Oxide Surfaces by Anonim Pdf

The book is a multi-author survey (in 15 chapters) of the current state of knowledge and recent developments in our understanding of oxide surfaces. The author list includes most of the acknowledged world experts in this field. The material covered includes fundamental theory and experimental studies of the geometrical, vibrational and electronic structure of such surfaces, but with a special emphasis on the chemical properties and associated reactivity. The main focus is on metal oxides but coverage extends from 'simple' rocksalt materials such as MgO through to complex transition metal oxides with different valencies.

Author : Graham Hutchings,Matthew Davidson,Richard Catlow,Christopher Hardacre,Nicholas Turner,Paul Collier
Publisher : World Scientific
Page : 348 pages
File Size : 49,6 Mb
Release : 2016-11-14
Category : Science
ISBN : 9781786341235

Get Book

Modern Developments in Catalysis by Graham Hutchings,Matthew Davidson,Richard Catlow,Christopher Hardacre,Nicholas Turner,Paul Collier Pdf

The UK Catalysis Hub is a consortium of universities working together on fundamental and applied research to find out how catalysts work and to improve their effectiveness. The contribution of catalysis to manufacturing contributes to almost 40% of global GDP, making development and innovation within the field integral to industry. Modern Developments in Catalysis provides a review of current research and practise on catalysis, focussing on five main themes: catalysis design, environmental catalysis, catalysis and energy, chemical transformation and biocatalysis and biotransformations. Topics range from complex reactions to the intricacies of catalyst preparation for supported nanoparticles, while chapters illustrate the challenges facing catalytic science and the directions in which the field is developing. Editor leaders of the UK Hub, this book provides insight into one of the most important areas of modern chemistry — it represents a unique learning opportunity for students and professionals studying and working towards speeding-up, improving and increasing the rate of catalytic reactions in science and industry.

Author : Albert F. Carley,Philip R. Davies,Graham J. Hutchings,Michael S. Spencer
Publisher : Springer Science & Business Media
Page : 392 pages
File Size : 40,5 Mb
Release : 2013-04-18
Category : Science
ISBN : 9781475766370

Get Book

Surface Chemistry and Catalysis by Albert F. Carley,Philip R. Davies,Graham J. Hutchings,Michael S. Spencer Pdf

In 2001 Wyn Roberts celebrated both his 70th birthday and 50 years of working in surface science, to use the term "surface science" in its broadest meaning. This book aims to mark the anniversary with a contribution of lasting value, something more than the usual festschrift issue of a relevant journal. The book is divided into three sections: Surface Science, Model Catalysts and Catalysis, topics in which Wyn has always had interests. The authors for each chapter were chosen from some of the many eminent scientists who have worked with Wyn in various ways and are all internationally acknowledged as leaders in their field. The authors have produced authoritative reviews of their own specialties which together result in a book with an unrivalled combination of breadth and depth exploring the most recent developments in surface chemistry and catalysis.

Author : Gianfranco Pacchioni,Paul S. Bagus,Fulvio Parmigiani
Publisher : Springer Science & Business Media
Page : 683 pages
File Size : 44,6 Mb
Release : 2013-03-08
Category : Science
ISBN : 9781468460216

Get Book

Cluster Models for Surface and Bulk Phenomena by Gianfranco Pacchioni,Paul S. Bagus,Fulvio Parmigiani Pdf

It is widely recognized that an understanding of the physical and chemical properties of clusters will give a great deal of important information relevant to surface and bulk properties of condensed matter. This relevance of clusters for condensed matter is one of the major motivations for the study of atomic and molecular clusters. The changes of properties with cluster size, from small clusters containing only a few atoms to large clusters containing tens of thousands of atoms, provides a unique way to understand and to control the development of bulk properties as separated units are brought together to form an extended system. Another important use of clusters is as theoretical models of surfaces and bulk materials. The electronic wavefunctions for these cluster models have special advantages for understanding, in particular, the local properties of condensed matter. The cluster wavefunctions, obtained with molecular orbital theory, make it possible to relate chemical concepts developed to describe chemical bonds in molecules to the very closely related chemical bonding at the surface and in the bulk of condensed matter. The applications of clusters to phenomena in condensed matter is a cross-disciplinary activity which requires the interaction and collaboration of researchers in traditionally separate areas. For example, it is necessary to bring together workers whose background and expertise is molecular chemistry with those whose background is solid state physics. It is also necessary to bring together experimentalists and theoreticians.

Author : R.M. Lambert,Gianfranco Pacchioni
Publisher : Springer Science & Business Media
Page : 534 pages
File Size : 52,9 Mb
Release : 2013-04-17
Category : Science
ISBN : 9789401589116

Get Book

Chemisorption and Reactivity on Supported Clusters and Thin Films: by R.M. Lambert,Gianfranco Pacchioni Pdf

Heterogeneous catalysis provides the backbone of the world's chemical and oil industries. The innate complexity of practical catalytic systems suggests that useful progress should be achievable by investigating key aspects of catalysis by experimental studies on idealised model systems. Thin films and supported clusters are two promising types of model system that can be used for this purpose, since they mimic important aspects of the properties of practical dispersed catalysts. Similarly, appropriate theoretical studies of chemisorption and surface reaction clusters or extended slab systems can provide valuable information on the factors that underlie bonding and catalytic activity. This volume describes such experimental and theoretical approaches to the surface chemistry and catalytic behaviour of metals, metal oxides and metal/metal oxide systems. An introduction to the principles and main themes of heterogeneous catalysis is followed by detailed accounts of the application of modern experimental and theoretical techniques to fundamental problems. The application of advanced experimental methods is complemented by a full description of theoretical procedures, including Hartree-Fock, density functional and similar techniques. The relative merits of the various approaches are considered and directions for future progress are indicated.