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Excluding the biological polymers proteins, lipids and nucleic acids, modified tetrapyrroles are the biological molecules that have had the greatest impact on the evolution of life over the past 4 billion years. They are involved in a wide variety of fundamental processes that underpin central primary metabolism in all kingdoms of life, from photosynthesis to methanogenesis. Moreover, they bring colour into the world and it is for this reason that these compounds have been appropriately dubbed the ‘pigments of life’. To understand how and why these molecules have been so universally integrated into the life processes one has to appreciate the chemical properties of the tetrapyrrole scaffold and, where appropriate, the chemical characteristics of the centrally chelated metal ion. This book addresses why these molecules are employed in Nature, how they are made and what happens to them after they have finished their usefulness.
The study of the structure and function of tetrapyrrolic compounds has excited the interests of organic chemists, biochemists, botanists and biologists for more than a hundred years. Scientific analysis began with the first descriptions of naturally occurring porphyrins, and progress was made towards understanding the structure of chlorophyll. This was followed by the use of newly available isotopes of carbon and nitrogen to investigate the formation of porphyrins in biological systems. Further discoveries led to the elucidation of the atoms in protoporphyrin IX, made possible by the application of physical methods, such as NMR spectroscopy and recombinant DNA technology. The present volume discusses many more exciting and unexpected developments which have been made in the field over the last ten to fifteen years. While not all questions have yet been answered, the forum is set for a great scope of further research in the study of tetrapyrroles. • Of interest to biochemists, organic chemists and plant scientists • The book focusses on the exciting and unexpected developments in the field of tetrapyrolles over the last ten years • It paves the way for future research in this area
Metabolism, Structure and Function of Plant Tetrapyrroles: Introduction, Microbial and Eukaryotic Chlorophyll Synthesis and Catabolism by Anonim Pdf
Metabolism, Structure and Function of Plant Tetrapyrroles, Volume 90, the latest release in the Advances in Botanical Research series is a compilation of the current state-of-the-art on the topic. Chapters in this new release cover Tetrapyrrole Pigments of Photosynthetic Antennae and Reaction Centers of Higher Plants: Biochemistry, Biophysics, Functions, Molecular Mechanism of Antenna Regulation, Applications, Chlorophyll c: Synthesis, Occurrence, Light-Harvesting, Absorbance, Excitation Properties, Pigment Organization in Chlorophyll-Binding Proteins (FCP), Chlorophyll d and f: Synthesis, Occurrence, Light-harvesting, Absorbance, Excitation Properties, Pigment Organization in Chlorophyll-Binding Protein Complexes, Analysis of Chlorophyll, Precursors and Derivatives by New High-Performance Liquid Chromatography and Mass Spectrometry, and much more. Presents the latest release in the Advances in Botanical Research series Provides an Ideal resource for post-graduates and researchers in the plant sciences, including botany, plant biochemistry, plant pathology and plant physiology Contains contributions from internationally recognized authorities in their respective fields
Metabolism, Structure and Function of Plant Tetrapyrroles: Control Mechanisms of Chlorophyll Biosynthesis and Analysis of Chlorophyll-Binding Proteins by Anonim Pdf
Metabolism, Structure and Function of Plant Tetrapyrroles, Volume 91, the latest release in the Advances in Botanical Research series is a compilation of the current state-of-the-art on the topic. Chapters in this new release cover Tetrapyrrole Pigments of Photosynthetic Antennae and Reaction Centers of Higher Plants: Biochemistry, Biophysics, Functions, Molecular Mechanism of Antenna Regulation, Applications, Chlorophyll c: Synthesis, Occurrence, Light-Harvesting, Absorbance, Excitation Properties, Pigment Organization in Chlorophyll-Binding Proteins (FCP), Chlorophyll d and f: Synthesis, Occurrence, Light-harvesting, Absorbance, Excitation Properties, Pigment Organization in Chlorophyll-Binding Protein Complexes, Analysis of Chlorophyll, Precursors and Derivatives by New High-Performance Liquid Chromatography and Mass Spectrometry, and much more. Presents the latest release in the Advances in Botanical Research series Provides an Ideal resource for post-graduates and researchers in the plant sciences, including botany, plant biochemistry, plant pathology and plant physiology Contains contributions from internationally recognized authorities in their respective fields
Metabolic Pathways: Amino acids and tetrapyrroles by David Morris Greenberg,Henry James Vogel,Lowell E. Hokin Pdf
Surveys the existing knowledge of the chemical steps in the metabolism of the constituents of major importance in living organisms -- Preface volume 1.
Heme, Chlorophyll, and Bilins by Alison Smith,Michael Witty Pdf
In Heme, Chlorophyll, and Bilins: Methods and Protocols, an interdisciplinary panel of hands-on investigators describe in detail how to work successfully with chlorophyll, heme, and bilins in biological, medical, chemical, and biochemical research. Each method is presented by a researcher who actually uses it on a daily basis and includes step-by-step instructions and pertinent tricks-of-the-trade that often make the difference between laboratory success and failure. Topics range from methods for the analysis of tetrapyrroles,heme, and hemoproteins, to the biosynthesis and analysis of chlorophyll and bilins.
Handbook of Porphyrin Science (Volumes 16 – 20): With Applications to Chemistry, Physics, Materials Science, Engineering, Biology and Medicine by Karl M Kadish,Kevin M Smith,Roger Guilard Pdf
This is the fourth set of Handbook of Porphyrin Science.Porphyrins, phthalocyanines and their numerous analogues and derivatives are materials of tremendous importance in chemistry, materials science, physics, biology and medicine. They are the red color in blood (heme) and the green in leaves (chlorophyll); they are also excellent ligands that can coordinate with almost every metal in the Periodic Table. Grounded in natural systems, porphyrins are incredibly versatile and can be modified in many ways; each new modification yields derivatives, demonstrating new chemistry, physics and biology, with a vast array of medicinal and technical applications.As porphyrins are currently employed as platforms for study of theoretical principles and applications in a wide variety of fields, the Handbook of Porphyrin Science represents a timely ongoing series dealing in detail with the synthesis, chemistry, physicochemical and medical properties and applications of polypyrrole macrocycles. Professors Karl Kadish, Kevin Smith and Roger Guilard are internationally recognized experts in the research field of porphyrins, each having his own separate area of expertise in the field. Between them, they have published over 1500 peer-reviewed papers and edited more than three dozen books on diverse topics of porphyrins and phthalocyanines. In assembling the new volumes of this unique handbook, they have selected and attracted the very best scientists in each sub-discipline as contributing authors.This handbook will prove to be a modern authoritative treatise on the subject as it is a collection of up-to-date works by world-renowned experts in the field. Complete with hundreds of figures, tables and structural formulas, and thousands of literature citations, all researchers and graduate students in this field will find the Handbook of Porphyrin Science an essential, major reference source for many years to come.
Chlorophyll Biosynthesis and Technological Applications by Constantin A. Rebeiz Pdf
Heme and chlorophyll (Chl) are porphyrins. Porphyrins (also referred to as tetrapyrroles) are essential for life in the biosphere. Chlorophyll catalyzes the conversion of solar energy to chemical energy via the process of photosynthesis. Organic life in the biosphere is made possible by consumption of the chemical energy generated by photosynthesis. Hemes are the prosthetic groups of cytochromes which are involved in electron transport during oxidative phosphorylation and photosynthetic phosphorylation which generate ATP and NADPH. The latter are essential for many cellular functions. Chlorophyll on the other hands catalyzes the process of photosynthesis. Indeed, life in the biosphere depends on the process of photosynthesis which converts light energy, carbon dioxide and water into the chemical energy, required for the formation of food and fiber. Photosynthetic efficiency is controlled by extrinsic factors such as the availability of water, CO2, inorganic nutrients, ambient temperature and the metabolic and developmental state of the plant, as well as by intrinsic factors (Lien and San Pietro, 1975). The most important intrinsic factor is the efficiency of the photosynthetic electron transport system (PETS). Conventional agriculture is one of the few human activities that have not undergone a revolution to join other activities such as overcoming gravity by flying, and landing on the moon, crossing underwater the polar cap, and communicating wirelessly over long distances via electromagnetic waves. We now feel that enough biochemical and molecular biological knowledge has accumulated to render this dream amenable to experimentation. We believe that the time has come to bioengineer chloroplasts capable of synthesizing a short chain carbohydrate such as glycerol at rates that approach the upper theoretical limits of photosynthesis [Rebeiz, C. A. (2010) Investigations of possible relationships between the chlorophyll biosynthetic pathway and the assembly of chlorophyll-protein complexes and photosynthetic efficiency. In: Rebeiz, C. A. Benning, C., Bohnert, H.J., Daniell, H., Hoober J. K., Lichtenthaler, H. K., Portis , A. R., and Tripathy, B. C. eds. The chloroplast: Basics and Applications. Springer. The Netherlands, p 1-24]. In order to achieve this goal a thorough knowledge of the Chl biosynthetic pathway is needed along with knowledge in other domains (Rebeiz 2010). In this context, this monograph is devoted to an in depth discussion of our present knowledge of the Chl biosynthetic pathway. The complexity and biochemical heterogeneity of the Chl biosynthetic pathway and the relationship of this complexity to the structural and biosynthetic complexity of photosynthetic membranes will be emphasized. We will also emphasize in historical perspective, key stages in our understanding of the Chl biosynthetic heterogeneity. The reader should keep in mind that a complex biosynthetic process is only fully understood when it becomes possible to reconstitute in vitro every step of the process. We are not yet at this stage of understanding of thylakoid membrane biogenesis. Considerable progress has been achieved however, in the understanding of numerous facets of the Chl biosynthetic pathway, namely (a) detection and identification of various major and minor metabolic intermediates (b) precursor-product relationships between various intermediates, (c) structure and regulation of many enzymes of the pathway, and (d) the relationship of the Chl biosynthetic heterogeneity to the structural and functional heterogeneity of thylakoid membranes. In addition topics related to the development of Analytical techniques, Cell-free systems, Herbicides, Insecticides, and Cancericides are also discussed.
Pseudomonas comprises three volumes covering the biology of pseudomonads in a wide context, including the niches they inhabit, the taxonomic relations among members of this group, the molecular biology of gene expression in different niches and under different environmental conditions, the analysis of virulence traits in plants, animals and human pathogens as well as the determinants that make some strains useful for biotechnological applications and promotion of plant growth. There has been growing interest in pseudomonads and a particular urge to understand the biology underlying the complex metabolism of these ubiquitous microbes. These bacteria are capable of colonizing a wide range of niches, including the soil, the plant rhizosphere and phylosphere, and animal tissues; more recently they have attracted attention because of their capacity to form biofilms, a characteristic with potentially important medical and environmental implications. The three volumes cover the following topics: - Taxonomy, - Genomics, - Life styles, - Cell Architecture, - Virulence, - Regulation, - Macromolecules, - Alternative Respiratory Substrates, - Catabolism and Biotransformations. Pseudomonas will be of use to all researchers working on these bacteria, particularly those studying microbiology, plant crops, pathogenesis, and chemical engineering. Advanced students in biology, medicine and agronomy will also find these three volumes a valuable reference during their studies.
