The Fundamentals Of Chemical Thermodynamics

Author : Themis Matsoukas
Publisher : Prentice Hall
Page : 719 pages
File Size : 47,6 Mb
Release : 2012-10-02
Category : Science
ISBN : 9780132693189

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Fundamentals of Chemical Engineering Thermodynamics by Themis Matsoukas Pdf

The Clear, Well-Organized Introduction to Thermodynamics Theory and Calculations for All Chemical Engineering Undergraduate Students This text is designed to make thermodynamics far easier for undergraduate chemical engineering students to learn, and to help them perform thermodynamic calculations with confidence. Drawing on his award-winning courses at Penn State, Dr. Themis Matsoukas focuses on “why” as well as “how.” He offers extensive imagery to help students conceptualize the equations, illuminating thermodynamics with more than 100 figures, as well as 190 examples from within and beyond chemical engineering. Part I clearly introduces the laws of thermodynamics with applications to pure fluids. Part II extends thermodynamics to mixtures, emphasizing phase and chemical equilibrium. Throughout, Matsoukas focuses on topics that link tightly to other key areas of undergraduate chemical engineering, including separations, reactions, and capstone design. More than 300 end-of-chapter problems range from basic calculations to realistic environmental applications; these can be solved with any leading mathematical software. Coverage includes • Pure fluids, PVT behavior, and basic calculations of enthalpy and entropy • Fundamental relationships and the calculation of properties from equations of state • Thermodynamic analysis of chemical processes • Phase diagrams of binary and simple ternary systems • Thermodynamics of mixtures using equations of state • Ideal and nonideal solutions • Partial miscibility, solubility of gases and solids, osmotic processes • Reaction equilibrium with applications to single and multiphase reactions

Author : J. Bevan Ott,Juliana Boerio-Goates
Publisher : Elsevier
Page : 465 pages
File Size : 47,9 Mb
Release : 2000-06-16
Category : Science
ISBN : 9780080500997

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Chemical Thermodynamics: Advanced Applications by J. Bevan Ott,Juliana Boerio-Goates Pdf

This book is an excellent companion to Chemical Thermodynamics: Principles and Applications. Together they make a complete reference set for the practicing scientist. This volume extends the range of topics and applications to ones that are not usually covered in a beginning thermodynamics text. In a sense, the book covers a "middle ground" between the basic principles developed in a beginning thermodynamics textbook, and the very specialized applications that are a part of an ongoing research project. As such, it could prove invaluable to the practicing scientist who needs to apply thermodynamic relationships to aid in the understanding of the chemical process under consideration. The writing style in this volume remains informal, but more technical than in Principles and Applications. It starts with Chapter 11, which summarizes the thermodynamic relationships developed in this earlier volume. For those who want or need more detail, references are given to the sections in Principles and Applications where one could go to learn more about the development, limitations, and conditions where these equations apply. This is the only place where Advanced Applications ties back to the previous volume. Chapter 11 can serve as a review of the fundamental thermodynamic equations that are necessary for the more sophisticated applications described in the remainder of this book. This may be all that is necessary for the practicing scientist who has been away from the field for some time and needs some review. The remainder of this book applies thermodynamics to the description of a variety of problems. The topics covered are those that are probably of the most fundamental and broadest interest. Throughout the book, examples of "real" systems are used as much as possible. This is in contrast to many books where "generic" examples are used almost exclusively. A complete set of references to all sources of data and to supplementary reading sources is included. Problems are given at the end of each chapter. This makes the book ideally suited for use as a textbook in an advanced topics course in chemical thermodynamics. An excellent review of thermodynamic principles and mathematical relationships along with references to the relevant sections in Principles and Applications where these equations are developed Applications of thermodynamics in a wide variety of chemical processes, including phase equilibria, chemical equilibrium, properties of mixtures, and surface chemistry Case-study approach to demonstrate the application of thermodynamics to biochemical, geochemical, and industrial processes Applications at the "cutting edge" of thermodynamics Examples and problems to assist in learning Includes a complete set of references to all literature sources

Author : Leonard K. Nash
Publisher : Courier Corporation
Page : 271 pages
File Size : 52,7 Mb
Release : 2013-02-20
Category : Science
ISBN : 9780486151847

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Elements of Chemical Thermodynamics by Leonard K. Nash Pdf

This text addresses the use of purely thermal data in calculating the position of equilibrium in a chemical reaction. Its argument highlights the physical content of thermodynamics, as distinct from purely mathematical aspects. Methods are limited to a very few of the most elementary operations of the calculus, all of which are explained in an appendix. Readers need no more than a sound background in high school mathematics and physics, as well as some familiarity with the leading quantitative concepts of an introductory college chemistry course. An introduction establishes the fundamentals of temperature, heat and work, reversibility, and pressure-volume work. The first principle of thermodynamics is explored in terms of energy, enthalpy, thermochemistry and Hess's Law, heat capacity, Kirchhoff's equations, and adiabatic processes. Considerations of the second principle of thermodynamics encompass the Carnot cycle, the concept of entropy, and evaluation of entropy changes. The consequences of thermodynamic principles are examined in chapters on the free energies, the Clapeyron equation, ideal solutions and colligative properties, and the equilibrium state and equilibrium constant. Numerous problems appear throughout the text, in addition to 30 fully worked illustrative examples.

Author : John Alfred Valentine Butler
Publisher : Unknown
Page : 128 pages
File Size : 47,5 Mb
Release : 1942
Category : Chemistry, Physical
ISBN : OCLC:219531462

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The Fundamentals of Chemical Thermodynamics by John Alfred Valentine Butler Pdf

Author : Peter A. Rock
Publisher : University Science Books
Page : 576 pages
File Size : 43,9 Mb
Release : 2013-06-19
Category : Science
ISBN : 1891389327

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Chemical Thermodynamics by Peter A. Rock Pdf

This textbook is a general introduction to chemical thermodynamics.

Author : John H. S. Lee,K. Ramamurthi
Publisher : CRC Press
Page : 139 pages
File Size : 49,8 Mb
Release : 2022-01-26
Category : Science
ISBN : 9781000533200

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Fundamentals of Thermodynamics by John H. S. Lee,K. Ramamurthi Pdf

A concise treatment of the fundamentals of thermodynamics is presented in this book. In particular, emphasis is placed on discussions of the second law, a unique feature of thermodynamics, which states the limitations of converting thermal energy into mechanical energy. The entropy function that permits the loss in the potential of a real thermodynamic process to be assessed, the maximum possible work in a process, and irreversibility and equilibrium are deduced from the law through physical and intuitive considerations. They are applicable in mitigating waste heat and are useful for solving energy, power, propulsion and climate-related issues. The treatment is not restricted to properties and functions of ideal gases. The ideal gas assumption is invoked as a limiting case. Reversible paths between equilibrium states are obtained using reversible heat engines and reversible heat pumps between environment and systems to determine the entropy changes and the maximum work. The conditions of thermodynamic equilibrium comprising mechanical, thermal, chemical and phase equilibrium are addressed and the species formed at equilibrium in a chemical reaction at a given temperature and pressure are obtained. The molecular basis for the laws of thermodynamics, temperature, internal energy changes, entropy, reversibility and equilibrium are briefly discussed. The book serves as a reference for undergraduate and graduate students alongside thermodynamics textbooks.

Author : Milo D. Koretsky
Publisher : John Wiley & Sons
Page : 724 pages
File Size : 50,8 Mb
Release : 2012-12-17
Category : Technology & Engineering
ISBN : 9780470259610

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Engineering and Chemical Thermodynamics by Milo D. Koretsky Pdf

Chemical engineers face the challenge of learning the difficult concept and application of entropy and the 2nd Law of Thermodynamics. By following a visual approach and offering qualitative discussions of the role of molecular interactions, Koretsky helps them understand and visualize thermodynamics. Highlighted examples show how the material is applied in the real world. Expanded coverage includes biological content and examples, the Equation of State approach for both liquid and vapor phases in VLE, and the practical side of the 2nd Law. Engineers will then be able to use this resource as the basis for more advanced concepts.

Author : John Alfred Valentine Butler
Publisher : Unknown
Page : 271 pages
File Size : 44,6 Mb
Release : 1942
Category : Chemistry, Physical and theoretical
ISBN : OCLC:15104366

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The Fundamentals of Chemical Thermodynamics by John Alfred Valentine Butler Pdf

Author : E Brian Smith
Publisher : World Scientific Publishing Company
Page : 228 pages
File Size : 43,5 Mb
Release : 2013-10-04
Category : Science
ISBN : 9781783263387

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Basic Chemical Thermodynamics by E Brian Smith Pdf

This widely acclaimed text, now in its sixth edition and translated into many languages, continues to present a clear, simple and concise introduction to chemical thermodynamics. An examination of equilibrium in the everyday world of mechanical objects provides a starting point for an accessible account of the factors that determine equilibrium in chemical systems. This straightforward approach leads students to a thorough understanding of the basic principles of thermodynamics, which are then applied to a wide range of physical chemical systems. The book also discusses the problems of non-ideal solutions and the concept of activity, and provides an introduction to the molecular basis of thermodynamics. Over six editions, the views of teachers of the subject and their students have been incorporated. Reference to the phase rule has been included in this edition and the notation has been revised to conform to current IUPAC recommendations. Students taking courses in thermodynamics will continue to find this popular book an excellent introductory text.

Author : Ingo Müller,Wolfgang H. Müller
Publisher : Springer Science & Business Media
Page : 404 pages
File Size : 46,5 Mb
Release : 2009-03-12
Category : Science
ISBN : 9783540746485

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Fundamentals of Thermodynamics and Applications by Ingo Müller,Wolfgang H. Müller Pdf

Thermodynamics is the much abused slave of many masters • physicists who love the totally impractical Carnot process, • mechanical engineers who design power stations and refrigerators, • chemists who are successfully synthesizing ammonia and are puzzled by photosynthesis, • meteorologists who calculate cloud bases and predict föhn, boraccia and scirocco, • physico-chemists who vulcanize rubber and build fuel cells, • chemical engineers who rectify natural gas and distil f- mented potato juice, • metallurgists who improve steels and harden surfaces, • - trition counselors who recommend a proper intake of calories, • mechanics who adjust heat exchangers, • architects who construe – and often misconstrue – ch- neys, • biologists who marvel at the height of trees, • air conditioning engineers who design saunas and the ventilation of air plane cabins, • rocket engineers who create supersonic flows, et cetera. Not all of these professional groups need the full depth and breadth of ther- dynamics. For some it is enough to consider a well-stirred tank, for others a s- tionary nozzle flow is essential, and yet others are well-served with the partial d- ferential equation of heat conduction. It is therefore natural that thermodynamics is prone to mutilation; different group-specific meta-thermodynamics’ have emerged which serve the interest of the groups under most circumstances and leave out aspects that are not often needed in their fields.

Author : E. N. Yeremin
Publisher : Firebird Publications
Page : 128 pages
File Size : 44,7 Mb
Release : 1978-06-01
Category : Electronic
ISBN : 0828532133

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Fundamentals of Chemical Thermodynamics by E. N. Yeremin Pdf

Author : Bruce H. Mahan
Publisher : Courier Corporation
Page : 178 pages
File Size : 55,9 Mb
Release : 2013-02-13
Category : Science
ISBN : 9780486151236

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Elementary Chemical Thermodynamics by Bruce H. Mahan Pdf

This straightforward presentation emphasizes chemical applications of thermodynamics as well as physical interpretations, offering students an introduction that's both interesting and coherent. It considers chemical behavior in terms of energy and entropy, and it explains the ways in which the magnitude of energy and entropy changes are dictated by atomic properties. All concepts are presented in a simplified mathematical context, making this an ideal text for a beginning course in thermodynamics. The author considers the first and second laws of thermodynamics in turn, after which he proceeds to applications of thermodynamic principles. He devotes considerable attention to the concept of entropy, emphasizing the interpretation of entropy changes and chemical behavior in terms of qualitative molecular properties. Students gain a familiarity with the entropy concept that will form a solid foundation for later courses and more formal thermodynamic treatments.

Author : Michael Grätzel,Pierre Infelta
Publisher : Universal-Publishers
Page : 300 pages
File Size : 40,7 Mb
Release : 2000-01-01
Category : Science
ISBN : 9781581127720

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The Bases of Chemical Thermodynamics: Volume 1 by Michael Grätzel,Pierre Infelta Pdf

In this volume (volume 1), the fundamental aspects of thermodynamics are presented. The first & second laws of thermodynamics are illustrated. The need to define thermodynamic temperature & the nature of entropy are explained. The book explores the meaning of auxiliary thermodynamic functions, the origin, usefulness & use of partial molar quantities. Gaseous systems & phase equilibrium, in systems where chemical reactions do not take place, are described In volume 2, the tools necessary to study & understand systems in which chemical reactions can take place are developed. The variables of reaction are the keys to understanding. Criteria for chemical equilibrium are established. It is shown how chemical reactions can provide work, as for example, in batteries. For complex systems, the number of independent reactions & their nature have to be determined systematically. The effect of external factors on chemical equilibria is analyzed & illustrated. The formalism necessary to study ideal & real solutions is provided. The various standard states in use & the corresponding activity coefficients are clearly defined. The statistical aspect of thermodynamics is best understood once students are familiar with the rest of the book, for this reason, is treated in the last chapter. Both volumes comply with the latest IUPC recommendations for symbols. Most of the specific mathematical tools are presented either directly in the text if they are used mostly in one chapter, while the others are included in an appendix. A primarily phenomenological approach has been selected to keep chemical thermodynamics easily accessible to beginners. Intermediate steps in the derivations have been kept to enhance the clarity of the presentation. A large number of problems, most of them original, will with complete solutions, are provided. They give this textbook a great pedagogical value. This book is primarily destined to students, graduate students & practicing scientists in the fields of Chemistry, Chemical Engineering & Material Sciences.

Author : Miguel T. Fleischer,H. William Prengle
Publisher : Cognella Academic Publishing
Page : 128 pages
File Size : 42,7 Mb
Release : 2012-10-31
Category : Electronic
ISBN : 1621316432

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Thermodynamics by Miguel T. Fleischer,H. William Prengle Pdf

Author : J. Richard Elliott,Carl T. Lira
Publisher : Prentice Hall
Page : 912 pages
File Size : 43,6 Mb
Release : 2012-02-06
Category : Science
ISBN : 9780132901093

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Introductory Chemical Engineering Thermodynamics by J. Richard Elliott,Carl T. Lira Pdf

A Practical, Up-to-Date Introduction to Applied Thermodynamics, Including Coverage of Process Simulation Models and an Introduction to Biological Systems Introductory Chemical Engineering Thermodynamics, Second Edition, helps readers master the fundamentals of applied thermodynamics as practiced today: with extensive development of molecular perspectives that enables adaptation to fields including biological systems, environmental applications, and nanotechnology. This text is distinctive in making molecular perspectives accessible at the introductory level and connecting properties with practical implications. Features of the second edition include Hierarchical instruction with increasing levels of detail: Content requiring deeper levels of theory is clearly delineated in separate sections and chapters Early introduction to the overall perspective of composite systems like distillation columns, reactive processes, and biological systems Learning objectives, problem-solving strategies for energy balances and phase equilibria, chapter summaries, and “important equations” for every chapter Extensive practical examples, especially coverage of non-ideal mixtures, which include water contamination via hydrocarbons, polymer blending/recycling, oxygenated fuels, hydrogen bonding, osmotic pressure, electrolyte solutions, zwitterions and biological molecules, and other contemporary issues Supporting software in formats for both MATLAB® and spreadsheets Online supplemental sections and resources including instructor slides, ConcepTests, coursecast videos, and other useful resources