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The VSEPR Model of Molecular Geometry by Ronald J Gillespie,Istvan Hargittai Pdf
Valence Shell Electron Pair Repulsion (VSEPR) theory is a simple technique for predicting the geometry of atomic centers in small molecules and molecular ions. This authoritative reference was written by Istvan Hartiggai and the developer of VSEPR theory, Ronald J. Gillespie. In addition to its value as a text for courses in molecular geometry and chemistry, it constitutes a classic reference for professionals. Starting with coverage of the broader aspects of VSEPR, this volume narrows its focus to a succinct survey of the methods of structural determination. Additional topics include the applications of the VSEPR model and its theoretical basis. Helpful data on molecular geometries, bond lengths, and bond angles appear in tables and other graphics.
The VSEPR Model of Molecular Geometry by Ronald J. Gillespie,Istvan Hargittai Pdf
" Valence Shell Electron Pair Repulsion (VSEPR) theory is a simple technique for predicting the geometry of atomic centers in small molecules and molecular ions. This authoritative reference, written by the developer of VSEPR theory features extensive coverage of structural information as well as theory and applications. Helpful data on molecular geometries, bond lengths, and band angles appear in tables and other graphics. 1991 edition"--
Molecular Geometry by Alison Rodger,Mark Rodger Pdf
Molecular Geometry discusses topics relevant to the arrangement of atoms. The book is comprised of seven chapters that tackle several areas of molecular geometry. Chapter 1 reviews the definition and determination of molecular geometry, while Chapter 2 discusses the unified view of stereochemistry and stereochemical changes. Chapter 3 covers the geometry of molecules of second row atoms, and Chapter 4 deals with the main group elements beyond the second row. The book also talks about the complexes of transition metals and f-block elements, and then covers the organometallic compounds and transition metal clusters. The last chapter tackles the consequences of small, local variations in geometry. The text will be of great use to chemists who primarily deal with the properties of molecules and atoms.
Emphasises on contemporary applications and an intuitive problem-solving approach that helps students discover the exciting potential of chemical science. This book incorporates fresh applications from the three major areas of modern research: materials, environmental chemistry, and biological science.
A Textbook of Inorganic Chemistry – Volume 1 by Mandeep Dalal Pdf
An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Chemistry 2e by Paul Flowers,Richard Langely,William R. Robinson,Klaus Hellmut Theopold Pdf
Chemistry 2e is designed to meet the scope and sequence requirements of the two-semester general chemistry course. The textbook provides an important opportunity for students to learn the core concepts of chemistry and understand how those concepts apply to their lives and the world around them. The book also includes a number of innovative features, including interactive exercises and real-world applications, designed to enhance student learning. The second edition has been revised to incorporate clearer, more current, and more dynamic explanations, while maintaining the same organization as the first edition. Substantial improvements have been made in the figures, illustrations, and example exercises that support the text narrative. Changes made in Chemistry 2e are described in the preface to help instructors transition to the second edition.
Concept Development Studies in Chemistry by John S. Hutchinson Pdf
This is an on-line textbook for an Introductory General Chemistry course. Each module develops a central concept in Chemistry from experimental observations and inductive reasoning. This approach complements an interactive or active learning teaching approach. Additional multimedia resources can be found at: http: //cnx.org/content/col10264/1.5
A Chemist's Guide to Valence Bond Theory by Sason S. Shaik,Philippe C. Hiberty Pdf
This reference on current VB theory and applications presents a practical system that can be applied to a variety of chemical problems in a uniform manner. After explaining basic VB theory, it discusses VB applications to bonding problems, aromaticity and antiaromaticity, the dioxygen molecule, polyradicals, excited states, organic reactions, inorganic/organometallic reactions, photochemical reactions, and catalytic reactions. With a guide for performing VB calculations, exercises and answers, and numerous solved problems, this is the premier reference for practitioners and upper-level students.
William (Beloit College) Brown,Shawn (Olympic Training Center) Farrell,Frederick (Adelphi University) Bettelheim,Mary (Mount Holyoke College) Campbell,Omar (College of the Canyons) Torres
Author : William (Beloit College) Brown,Shawn (Olympic Training Center) Farrell,Frederick (Adelphi University) Bettelheim,Mary (Mount Holyoke College) Campbell,Omar (College of the Canyons) Torres Publisher : Unknown Page : 128 pages File Size : 40,5 Mb Release : 2020-10 Category : Electronic ISBN : 0357671066
Introduction to General, Organic and Biochemistry by William (Beloit College) Brown,Shawn (Olympic Training Center) Farrell,Frederick (Adelphi University) Bettelheim,Mary (Mount Holyoke College) Campbell,Omar (College of the Canyons) Torres Pdf
Gain a comprehensive understanding of chemistry and see how it relates to health science with INTRODUCTION TO GENERAL, ORGANIC, AND BIOCHEMISTRY. This bestseller features dynamic art, interesting examples, coverage of the latest issues, and a wide variety of medical and biological applications. As you explore topics such as botulin toxin as a cosmetic agent, implications for the use of antibiotics, the Atkins diet, and ultraviolet sunscreen, you will see how useful the study of chemistry is to so many aspects of your life. The book's built-in integration with OWLv2 (Online Web-based Learning) turns your chemistry study time into active experiences that build your comprehension and bring concepts to life.
Electrons, Atoms, and Molecules in Inorganic Chemistry by Joseph J. Stephanos,Anthony W. Addison Pdf
Electrons, Atoms, and Molecules in Inorganic Chemistry: A Worked Examples Approach builds from fundamental units into molecules, to provide the reader with a full understanding of inorganic chemistry concepts through worked examples and full color illustrations. The book uniquely discusses failures as well as research success stories. Worked problems include a variety of types of chemical and physical data, illustrating the interdependence of issues. This text contains a bibliography providing access to important review articles and papers of relevance, as well as summaries of leading articles and reviews at the end of each chapter so interested readers can readily consult the original literature. Suitable as a professional reference for researchers in a variety of fields, as well as course use and self-study. The book offers valuable information to fill an important gap in the field. Incorporates questions and answers to assist readers in understanding a variety of problem types Includes detailed explanations and developed practical approaches for solving real chemical problems Includes a range of example levels, from classic and simple for basic concepts to complex questions for more sophisticated topics Covers the full range of topics in inorganic chemistry: electrons and wave-particle duality, electrons in atoms, chemical binding, molecular symmetry, theories of bonding, valence bond theory, VSEPR theory, orbital hybridization, molecular orbital theory, crystal field theory, ligand field theory, electronic spectroscopy, vibrational and rotational spectroscopy
In this invaluable book, 36 famous chemists, including 18 Nobel laureates, tell the reader about their lives in science, the beginnings of their careers, their aspirations, and their hardships and triumphs. The reader will learn about their seminal discoveries, and the conversations in the book bring out the humanity of these great scientists. Highlighted in the stories are the discovery of new elements and compounds, the VSEPR model, computational chemistry, organic synthesis, natural products, polysaccharides, supramolecular chemistry, peptide synthesis, combinatorial chemistry, X-ray crystallography, the reaction mechanism and kinetics, electron transfer in small and large systems, non-equilibrium systems, oscillating reactions, atmospheric chemistry, chirality, and the history of chemistry. Contents: Glenn T SeaborgWilliam N LipscombNeil BartlettRonald J GillespieLawrence S BartellPaul von Rague SchleyerAlbert EschenmoserGilbert StorkEndre A BalazsAlfred BaderJacquelin K BartonAd BaxDonald J CramJean-Marie LehnBruce MerrifieldArpad FurkaGuy OurissonMildred CohnPaul D BoyerJohn E WalkerHerbert A HauptmanJack D DunitzHartmut MichelJohann DeisenhoferRobert HuberManfred EigenJohn C PolanyiDudley R HerschbachHenry TaubeRudolph A MarcusIlya PrigogineAnatol M ZhabotinskyRichard N ZarePaul J CrutzenReiko KurodaStephen Mason Readership: Chemists and other scientists. Keywords:Chemistry;Nobel Prize;History of Chemistry;Famous ChemistsReviews:“This book makes interesting light reading, especially for chemists who have watched the field develop over the past 30 to 60 years … it makes a worthwhile contribution to the oral history of science, and I recommend it for both libraries and individuals.”Nature “István Hargittai's interviews with eminent scientists are a lively and important way of entering the minds of prominent chemists … this makes a wonderful bedside book that attractively opens up a gallery of people, and a window onto the development of science.”Chemistry & Industry “I have come back to these interviews time after time after my first read through. It's always inspiring to read about people who are good at what they do. To paraphrase Jack Dunitz, if you want value for your money in a predictable way, I think Hargittai's book is a good value. I strongly recommend it.”Southwest Retort “Hargittai has done a superb job in selecting both chemical topics and appropriate interview subjects who know the topics first-hand … Candid Science III is an interesting source of information on both current and recent chemistry and its practitioners, from a first-hand perspective of those practitioners. It also promises to be a valuable sourcebook for historians of the chemistry of this time.”The Alchemist, The ChemWeb Magazine “I recommend this useful volume, suitable for complete reading or browsing, not only to historians of chemistry and science but also to practicing chemists and students, who will benefit from these inspiring stories by some of chemistry's most eminent contributors.”Chemical Heritage “I recommend this handy volume, admirably suited for complete reading or browsing, not only to historians of chemistry and of science but also to practicing scientists, especially beginning ones, as well as to students, who will surely benefit from these inspiring stories by some of chemistry's leading luminaries.”The Chemical Educator
The Chemical Bond by Gernot Frenking,Sason Shaik Pdf
This is the perfect complement to "Chemical Bonding - Across the Periodic Table" by the same editors, who are two of the top scientists working on this topic, each with extensive experience and important connections within the community. The resulting book is a unique overview of the different approaches used for describing a chemical bond, including molecular-orbital based, valence-bond based, ELF, AIM and density-functional based methods. It takes into account the many developments that have taken place in the field over the past few decades due to the rapid advances in quantum chemical models and faster computers.
The Quantum Theory of Atoms in Molecules by Chérif F. Matta,Russell J. Boyd Pdf
This book distills the knowledge gained from research into atoms in molecules over the last 10 years into a unique, handy reference. Throughout, the authors address a wide audience, such that this volume may equally be used as a textbook without compromising its research-oriented character. Clearly structured, the text begins with advances in theory before moving on to theoretical studies of chemical bonding and reactivity. There follow separate sections on solid state and surfaces as well as experimental electron densities, before finishing with applications in biological sciences and drug-design. The result is a must-have for physicochemists, chemists, physicists, spectroscopists and materials scientists.
