Adsorption Of Gases On Heterogeneous Surfaces

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Adsorption of Gases on Heterogeneous Surfaces

Author : W. Rudzinski,D. H. Everett
Publisher : Academic Press
Page : 619 pages
File Size : 50,9 Mb
Release : 2012-12-02
Category : Technology & Engineering
ISBN : 9780080984360

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Adsorption of Gases on Heterogeneous Surfaces by W. Rudzinski,D. H. Everett Pdf

All real solid surfaces are heterogeneous to a greater or lesser extent and this book provides a broad yet detailed survey of the present state of gas adsorption. Coverage is comprehensive and extends from basic principles to computer simulation of adsorption. Underlying concepts are clarified and the strengths and weaknesses of the various methods described are discussed. Adsorption isotherm equations for various types of heterogeneous solid surfaces Methods of determining the nature of surface heterogeneity and porosity from experimental data Studies of phase behavior of gases absorbed on heterogeneous solid surfaces Computer simulation of adsorption on heterogeneous solid surfaces

Equilibria and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces

Author : W.A. Steele,G. Zgrablich,W. Rudzinski
Publisher : Elsevier
Page : 883 pages
File Size : 51,7 Mb
Release : 1996-12-17
Category : Technology & Engineering
ISBN : 0080531199

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Equilibria and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces by W.A. Steele,G. Zgrablich,W. Rudzinski Pdf

The fact that the surfaces of real solids are geometrically distorted and chemically non-uniform has long been realized by the scientists investigating various phenomena occurring on solid surfaces. Even in the case when diffraction experiments show a well-organized bulk solid structure, the surface atoms or molecules will usually exhibit a much smaller degree of surface organization. In addition to the results obtained from electron diffraction, this can be seen in the impressive images obtained from STM and AFM microscopies. This geometric and chemical disorder is the source of the energetic heterogeneity for molecules adsorbing on real solid surfaces. Hundreds of papers have been published showing that this heterogeneity is a major factor in determining the behaviour of real adsorption systems. Studies of adsorption on energetically heterogeneous surfaces have proceeded along three somewhat separate paths, with only minor coupling of ideas. One was the study of adsorption equilibria on heterogeneous solid surfaces. The second path was the study of time evolution of adsorption processes such as surface diffusion or adsorption-desorption kinetics on heterogeneous surfaces, and the third was the study of adsorption in porous solids, or more generally, adsorption in systems with limited dimensions. The present monograph is a first attempt to provide a synthesis of the ways that surface geometric and energetic heterogeneities affect both the equilibria and the time evolution of adsorption on real solids. The book contains 17 chapters written by a team of internationally recognized specialists, some of whom have already published books on adsorption.

Physical Adsorption on Heterogeneous Solids

Author : M. Jaroniec,R. Madey
Publisher : Elsevier Publishing Company
Page : 376 pages
File Size : 41,8 Mb
Release : 1988
Category : Science
ISBN : STANFORD:36105032444916

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Physical Adsorption on Heterogeneous Solids by M. Jaroniec,R. Madey Pdf

This book presents a unified description of physical adsorption on heterogeneous solids from both the gas and liquid phases. All solid adsorbents of great practical importance, such as activated carbons, silica gels, aluminium oxides, zeolites, etc., possess surface and structural heterogeneities, which play a dominant role in the adsorption process especially at low pressures. The assumption of adsorbent heterogeneity in studies of physical adsorption introduces considerable difficulties in the theoretical description of this phenomenon. To overcome this problem, the authors have presented a relatively simple theory of physical adsorption on heterogeneous solids, which provides a quantitative description of this phenomenon and simultaneously permits elaboration of methods for characterizing adsorbent heterogeneity. The chapter on single-gas adsorption on heterogeneous surfaces is the most extensive one in the book because there is a great deal of scientific literature concerning this problem. Moreoever, the theory of single-gas adsorption provides foundations for deriving equations that apply to adsorption from multicomponent gas and liquid mixtures.

Adsorption

Author : Jozsef Toth
Publisher : CRC Press
Page : 904 pages
File Size : 54,6 Mb
Release : 2002-05-10
Category : Science
ISBN : 0824707478

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Adsorption by Jozsef Toth Pdf

Offers an overview of the recent theoretical and practical results achieved in gas-solid (G/S), liquid-solid (L/S), and gas-liquid (G/L) adsorption research.

The Interaction of Gases with Solid Surfaces

Author : William Arthur Steele
Publisher : Pergamon
Page : 372 pages
File Size : 54,7 Mb
Release : 1974
Category : Science
ISBN : UCSD:31822013048202

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The Interaction of Gases with Solid Surfaces by William Arthur Steele Pdf

The Chemical Physics of Solid Surfaces and Heterogeneous Catalysis

Author : David Anthony King,D. P. Woodruff
Publisher : Unknown
Page : 404 pages
File Size : 42,5 Mb
Release : 1983
Category : Science
ISBN : UOM:39015016011127

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The Chemical Physics of Solid Surfaces and Heterogeneous Catalysis by David Anthony King,D. P. Woodruff Pdf

This series of volumes is a unique summary of the present state of understanding of solid surfaces. The physical basis of chemisorption and heterogeneous catalysis is presented as a well-developed science with contributions from an international panel of chemists, physicists and metallurgists. The books are destined to become a fundamental and indispensable reference source for all those studying the nature of solid surfaces and catalysis.

Adsorption by Powders and Porous Solids

Author : Jean Rouquerol,Françoise Rouquerol,Philip Llewellyn,Guillaume Maurin,Kenneth Sing
Publisher : Academic Press
Page : 647 pages
File Size : 44,5 Mb
Release : 2013-09-06
Category : Technology & Engineering
ISBN : 9780080970363

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Adsorption by Powders and Porous Solids by Jean Rouquerol,Françoise Rouquerol,Philip Llewellyn,Guillaume Maurin,Kenneth Sing Pdf

The declared objective of this book is to provide an introductory review of the various theoretical and practical aspects of adsorption by powders and porous solids with particular reference to materials of technological importance. The primary aim is to meet the needs of students and non-specialists who are new to surface science or who wish to use the advanced techniques now available for the determination of surface area, pore size and surface characterization. In addition, a critical account is given of recent work on the adsorptive properties of activated carbons, oxides, clays and zeolites. Provides a comprehensive treatment of adsorption at both the gas/solid interface and the liquid/solid interface Includes chapters dealing with experimental methodology and the interpretation of adsorption data obtained with porous oxides, carbons and zeolites Techniques capture the importance of heterogeneous catalysis, chemical engineering and the production of pigments, cements, agrochemicals, and pharmaceuticals

Interactions at the Soil Colloid

Author : G.H. Bolt,M.F. de Boodt,Michael H.B. Hayes,M.B. McBride,E.B.A. de Strooper
Publisher : Springer Science & Business Media
Page : 605 pages
File Size : 42,8 Mb
Release : 2013-11-11
Category : Nature
ISBN : 9789401719094

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Interactions at the Soil Colloid by G.H. Bolt,M.F. de Boodt,Michael H.B. Hayes,M.B. McBride,E.B.A. de Strooper Pdf

About 20 years ago the emphasis in soil chemistry research switched from studies of problems related to scarcities of plant nutrients to those arising from soil pollutants. The new problems have come about because of the excessive uses of fertilizers, the inputs from farm and industrial wastes, the widespread applications of anthropogenie xenobiotic chemicals, and the deterioration of soil structure resulting from certain modern agriculture practises. The International Society of Soil Science (ISSS) recognized these problems and challenges. A provisional Working Group was set up in 1978 to focus attention on soil colloids with a view to understanding better the interactions wh ich take place at their surfaces. It was recognized that these interactions are fundamental to problems of soil fertility, as weIl as to those of soil pollution. After the group had received the official support of ISSS at its 12th International Congress in New Delhi in 1982 it set as its priority the assembling and evaluation of information, relevant to the soil and environmental sciences, concerning the composition and structure of soil colloids. Prior to that aseries of Position Papers were published in the Bulletin of the International Society of Soil Science (Vol. 61, 1981) outlining the state of knowledge about the composition and properties of soil colloids.

Adsorption by Carbons

Author : Eduardo J. Bottani,Juan M.D. Tascón
Publisher : Elsevier
Page : 776 pages
File Size : 43,9 Mb
Release : 2011-10-10
Category : Technology & Engineering
ISBN : 0080559425

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Adsorption by Carbons by Eduardo J. Bottani,Juan M.D. Tascón Pdf

Adsorption by Carbons covers the most significant aspects of adsorption by carbons, attempting to fill the existing gap between the fields of adsorption and carbonaceous materials. Both basic and applied aspects are presented. The first section of the book introduces physical adsorption and carbonaceous materials, and is followed by a section concerning the fundamentals of adsorption by carbons. This leads to development of a series of theoretical concepts that serve as an introduction to the following section in which adsorption is mainly envisaged as a tool to characterize the porous texture and surface chemistry of carbons. Particular attention is paid to some novel nanocarbons, and the electrochemistry of adsorption by carbons is also addressed. Finally, several important technological applications of gas and liquid adsorption by carbons in areas such as environmental protection and energy storage constitute the last section of the book. The first book to address the interplay between carbonaceous materials and adsorption Includes important environmental applications, such as the removal of volatile organic compounds from polluted atmospheres Covers both gas-solid and liquid-solid adsorption

Interaction of Gases with Surfaces

Author : Alexander V. Bogdanov,German V. Dubrovskiy,Michael P. Krutikov,Dmitry V. Kulginov,Victor M. Strelchenya
Publisher : Springer Science & Business Media
Page : 140 pages
File Size : 42,8 Mb
Release : 2008-09-11
Category : Science
ISBN : 9783540491071

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Interaction of Gases with Surfaces by Alexander V. Bogdanov,German V. Dubrovskiy,Michael P. Krutikov,Dmitry V. Kulginov,Victor M. Strelchenya Pdf

Interface phenomena are most fascinating because of the mixing of different scales and the interference of diverse physical processes. This makes it necessary to use different levels of description: microscopic, kinetic, and gas-dynamical. A unified quasiclassical approach is used to answer practical questions dealing with inelastic gas-surface scattering, the kinetics of adsorption layers, the evolution of inhomogeneities and defects at the surface, the Knudsen layer, the development of boundary conditions on the kinetic and gas-dynamical levels, the determination of exchange and slip coefficients, and so on.

Encyclopedia of Surface and Colloid Science

Author : P. Somasundaran
Publisher : CRC Press
Page : 1148 pages
File Size : 47,8 Mb
Release : 2006
Category : Colloids
ISBN : 0849396042

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Encyclopedia of Surface and Colloid Science by P. Somasundaran Pdf

Physical Adsorption

Author : L.W. Bruch,Milton W. Cole,Eugene Zaremba
Publisher : Courier Dover Publications
Page : 354 pages
File Size : 54,6 Mb
Release : 2007-03-29
Category : Science
ISBN : 9780486457673

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Physical Adsorption by L.W. Bruch,Milton W. Cole,Eugene Zaremba Pdf

A comprehensive account of the phenomena that occur when simple gases interact with surfaces, this text takes a fundamental perspective. Physical adsorption involves atomic or molecular films bound to surfaces by less than 0.5 eV per particle. Physically absorbed thin films exhibit remarkably diverse properties and behave in a manner characteristic of two-dimensional matter. This exploration focuses on monolayer physics, emphasizing atomic rather than molecular adsorption. The phase diagrams of physically absorbed films are diverse and rich in structure because of the subtle and varied competition between the two interactions: the mutual interaction between adsorbed molecules, and the force binding each molecule to the surface. The authors explain the microscopic origin of these forces in terms of constituent electrons and nuclei. They then examine the structural and dynamical properties of these films in the context of atomic and solid-state physics, statistical mechanics, and computer simulations. This text will be of interest to research chemists, physicists, and engineers alike, as well as students in these fields. Key literature citations allow readers to trace important developments, and thought-provoking problems are addressed in detail.