Equilibria And Dynamics Of Gas Adsorption On Heterogeneous Solid Surfaces

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Equilibria and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces

Author : W.A. Steele,G. Zgrablich,W. Rudzinski
Publisher : Elsevier
Page : 883 pages
File Size : 52,9 Mb
Release : 1996-12-17
Category : Technology & Engineering
ISBN : 0080531199

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Equilibria and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces by W.A. Steele,G. Zgrablich,W. Rudzinski Pdf

The fact that the surfaces of real solids are geometrically distorted and chemically non-uniform has long been realized by the scientists investigating various phenomena occurring on solid surfaces. Even in the case when diffraction experiments show a well-organized bulk solid structure, the surface atoms or molecules will usually exhibit a much smaller degree of surface organization. In addition to the results obtained from electron diffraction, this can be seen in the impressive images obtained from STM and AFM microscopies. This geometric and chemical disorder is the source of the energetic heterogeneity for molecules adsorbing on real solid surfaces. Hundreds of papers have been published showing that this heterogeneity is a major factor in determining the behaviour of real adsorption systems. Studies of adsorption on energetically heterogeneous surfaces have proceeded along three somewhat separate paths, with only minor coupling of ideas. One was the study of adsorption equilibria on heterogeneous solid surfaces. The second path was the study of time evolution of adsorption processes such as surface diffusion or adsorption-desorption kinetics on heterogeneous surfaces, and the third was the study of adsorption in porous solids, or more generally, adsorption in systems with limited dimensions. The present monograph is a first attempt to provide a synthesis of the ways that surface geometric and energetic heterogeneities affect both the equilibria and the time evolution of adsorption on real solids. The book contains 17 chapters written by a team of internationally recognized specialists, some of whom have already published books on adsorption.

Gas Adsorption Equilibria

Author : Jürgen U. Keller,Reiner Staudt
Publisher : Springer Science & Business Media
Page : 430 pages
File Size : 43,9 Mb
Release : 2006-06-23
Category : Science
ISBN : 9780387235981

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Gas Adsorption Equilibria by Jürgen U. Keller,Reiner Staudt Pdf

This book is intended to present for the first time experimental methods to measure equilibria states of pure and mixed gases being adsorbed on the surface of solid materials. It has been written for engineers and scientists from industry and academia who are interested in adsorption based gas separation processes and/or in using gas adsorption for characterization of the porosity of solid materials. This book is the result of a fruitful collaboration of a theoretician (JUK) and an experimentalist (RS) over more than twelve years in the field of gas adsorption systems at the Institute of Fluid- and Thermodynamics (IFT) at the University of Siegen, Siegen, Germany. This collaboration resulted in the development of several new methods to measure not only pure gas adsorption, but gas mixture or coadsorption equilibria on inert porous solids. Also several new theoretical results could be achieved leading to new types of so-called adsorption isotherms based on the concepts of molecular association and – phenomenologically speaking – on that of thermodynamic phases of fractal dimension. Naturally, results of international collaboration of the authors over the years (1980-2000) also are included.

Adsorption by Carbons

Author : Eduardo J. Bottani,Juan M.D. Tascón
Publisher : Elsevier
Page : 776 pages
File Size : 52,8 Mb
Release : 2011-10-10
Category : Technology & Engineering
ISBN : 0080559425

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Adsorption by Carbons by Eduardo J. Bottani,Juan M.D. Tascón Pdf

Adsorption by Carbons covers the most significant aspects of adsorption by carbons, attempting to fill the existing gap between the fields of adsorption and carbonaceous materials. Both basic and applied aspects are presented. The first section of the book introduces physical adsorption and carbonaceous materials, and is followed by a section concerning the fundamentals of adsorption by carbons. This leads to development of a series of theoretical concepts that serve as an introduction to the following section in which adsorption is mainly envisaged as a tool to characterize the porous texture and surface chemistry of carbons. Particular attention is paid to some novel nanocarbons, and the electrochemistry of adsorption by carbons is also addressed. Finally, several important technological applications of gas and liquid adsorption by carbons in areas such as environmental protection and energy storage constitute the last section of the book. The first book to address the interplay between carbonaceous materials and adsorption Includes important environmental applications, such as the removal of volatile organic compounds from polluted atmospheres Covers both gas-solid and liquid-solid adsorption

Surfaces of Nanoparticles and Porous Materials

Author : James A. Schwarz,Cristian I. Contescu
Publisher : CRC Press
Page : 814 pages
File Size : 48,9 Mb
Release : 1999-01-21
Category : Science
ISBN : 0824746686

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Surfaces of Nanoparticles and Porous Materials by James A. Schwarz,Cristian I. Contescu Pdf

This innovative reference collects state-of-the-art procedures for the construction and design of nanoparticles and porous material while suggesting appropriate areas of application. Presenting both synthesis and characterization protocols, Surfaces of Nanoparticles and Porous Materials contains over 3000 references, tables, equations, drawings, and photographs. It examines the thermodynamics and kinetics of adsorption involving organic and inorganic liquids, solids, and gaseous media.. Topics include characterization, transport processes, diffusion, and the adsorption of heavy metals, ions, proteins, and pharmaceutical organics.

Adsorption Science and Technology

Author : Duong D Do
Publisher : World Scientific
Page : 756 pages
File Size : 43,7 Mb
Release : 2000-04-06
Category : Technology & Engineering
ISBN : 9789814493376

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Adsorption Science and Technology by Duong D Do Pdf

This book presents the latest research on adsorption science and technology. It covers various aspects of materials, solid characterization, equilibria, kinetics determination and new processes. Contents:Cluster Mediated Filling of Water and Alcohol on Microporous Carbon Alloys (K Kaneko et al.)Direct Measurement of Transient Concentration Profiles in Molecular Sieve Particles and Columns by MRI (N Karsten-Bär et al.)Computer Simulation Studies of Wetting on Heterogeneous Surfaces (S Curtarolo et al.)New Adsorbents for Gas Separation by Weak Chemical Bonds (R T Yang)Measurement of Adsorbate Density Profiles in Activated Carbon with the Aid of 1H-MRI (F B Aarden et al.)Interaction Between Adsorption and Condensation Processes in a Pore-Relation Between Condensation Pressure and Pore Width (C Aharoni)Isosteric Heat: A Criterion for Equilibrium Model Selection (A Ahmadpour & D D Do)Adsorption Characteristics and Isotherm Relationships of Activated Carbons Developed from Lignite and Peat (S J Allen et al.)and other papers Readership: Engineers and scientists working in adsorption and separation science and engineering, as well as research students in chemical engineering and physical chemistry. Keywords:

Adsorption

Author : Jozsef Toth
Publisher : CRC Press
Page : 904 pages
File Size : 41,8 Mb
Release : 2002-05-10
Category : Science
ISBN : 0824707478

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Adsorption by Jozsef Toth Pdf

Offers an overview of the recent theoretical and practical results achieved in gas-solid (G/S), liquid-solid (L/S), and gas-liquid (G/L) adsorption research.

Adsorption Science and Technology

Author : D. Do Duong
Publisher : World Scientific
Page : 764 pages
File Size : 46,9 Mb
Release : 2000
Category : Science
ISBN : 9810242638

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Adsorption Science and Technology by D. Do Duong Pdf

This book is the proceedings of the second Pacific Basin Conference on Adsorption Science and Technology that was held May 14-18, 2000 in Brisbane, Australia.

Characterisation of Porous Solids V

Author : G. Kreysa,J.P. Baselt,KK Unger
Publisher : Elsevier
Page : 700 pages
File Size : 43,7 Mb
Release : 2000-04-11
Category : Science
ISBN : 0080528899

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Characterisation of Porous Solids V by G. Kreysa,J.P. Baselt,KK Unger Pdf

The Fifth International Symposium on the Characterisation of Porous Solids (COPS-V) was held at Heidelberg, Germany, from May 30 to June 2, 1999. About 220 participants from 25 countries enjoyed a very successful meeting with 32 lectures and 155 poster presentations. The Symposium started with a highly stimulating lecture by Sir John Meurig Thomas, Cambridge, highlighting the recent developments in engineering of new catalysts. The following two full sessions were devoted to theory, modelling and simulation which provide the basis for the interpretation of pore structural data of adsorbents and finely dispersed solids. Sessions 2 and 3 focused on the advances in the synthesis and characterisation of highly ordered inorganic adsorbents and carbons. Sessions 4 and 5 addressed important questions with respect to the characterisation of porous solids by sorption measurement and other related techniques. The intensive three-day programme provided a stimulating forum for the exchange of novel research findings, concepts, techniques and materials which are collected in this volume.

Adsorption of Gases on Heterogeneous Surfaces

Author : W. Rudzinski,D. H. Everett
Publisher : Academic Press
Page : 624 pages
File Size : 46,9 Mb
Release : 2012-12-02
Category : Technology & Engineering
ISBN : 9780080984360

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Adsorption of Gases on Heterogeneous Surfaces by W. Rudzinski,D. H. Everett Pdf

All real solid surfaces are heterogeneous to a greater or lesser extent and this book provides a broad yet detailed survey of the present state of gas adsorption. Coverage is comprehensive and extends from basic principles to computer simulation of adsorption. Underlying concepts are clarified and the strengths and weaknesses of the various methods described are discussed. Adsorption isotherm equations for various types of heterogeneous solid surfaces Methods of determining the nature of surface heterogeneity and porosity from experimental data Studies of phase behavior of gases absorbed on heterogeneous solid surfaces Computer simulation of adsorption on heterogeneous solid surfaces

Microporous Media

Author : Freddy Romm
Publisher : CRC Press
Page : 363 pages
File Size : 49,8 Mb
Release : 2004-03-29
Category : Science
ISBN : 9780824758080

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Microporous Media by Freddy Romm Pdf

Microporous Media presents new developments from nearly a decade of advancement. Written by a leading researcher in the field, this reference provides examples of the most original scientific and technical research impacting studies in porosity and microporosity, and illustrates methods to forecast the properties of microporous structures for improved electronic, construction, electrical, chemical, and medical applications. The book outlines new results in fractal, self-organization, and polymer theories; pore aging, and percolation; and their various engineering applications, and considers the impact of preparation conditions on the structure and properties of microporous materials.

Encyclopedia of Surface and Colloid Science -

Author : Arthur T. Hubbard
Publisher : CRC Press
Page : 1580 pages
File Size : 47,6 Mb
Release : 2002-07-18
Category : Science
ISBN : 0824707575

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Encyclopedia of Surface and Colloid Science - by Arthur T. Hubbard Pdf

This comprehensive reference collects fundamental theories and recent research from a wide range of fields including biology, biochemistry, physics, applied mathematics, and computer, materials, surface, and colloid science-providing key references, tools, and analytical techniques for practical applications in industrial, agricultural, and forensic processes, as well as in the production of natural and synthetic compounds such as foods, minerals, paints, proteins, pharmaceuticals, polymers, and soaps.

Physical Adsorption

Author : Jacques P. Fraissard
Publisher : Springer Science & Business Media
Page : 642 pages
File Size : 53,9 Mb
Release : 1997
Category : Science
ISBN : 0792345479

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Physical Adsorption by Jacques P. Fraissard Pdf

The study of physical adsorption has economic and technical value, while continuing to present scientific challenges. During recent years three significant trends have become manifest: significant theoretical advances; instrumental developments allowing detailed characterization of materials, including microporous solids; and the realization that closer coupling of scientific and technological lines of enquiry can lead to both greater scientific understanding and better technology.

The Molecular Theory of Adsorption in Porous Solids

Author : Yury Konstantinovich Tovbin
Publisher : CRC Press
Page : 780 pages
File Size : 47,8 Mb
Release : 2017-10-17
Category : Science
ISBN : 9781351652889

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The Molecular Theory of Adsorption in Porous Solids by Yury Konstantinovich Tovbin Pdf

In the adsorption phenomenon the substances from the external environment the gas or liquid are absorbed by a solid surface (adsorbent). Adsorption is used to separate gaseous and liquid mixtures, for drying and purification of gases and liquids. This reference broadly explores the calculation of the equilibrium and dynamic characteristics of adsorption in porous bodies at the molecular level. Two new theories of statistical physics are presented, both developed by the author for the consistent description of the equilibrium distribution of molecules and dynamics of flows in complex porous materials to be able to solve a wide range of practical tasks in the development of new technologies.

Applications in Industry

Author : Anonim
Publisher : Elsevier
Page : 1064 pages
File Size : 48,9 Mb
Release : 1998-12-17
Category : Technology & Engineering
ISBN : 0080557201

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Applications in Industry by Anonim Pdf

Volume I contains a brief review of adsorption history and its development for practical purposes up until now. It also presents some important information on adsorbents and catalysts as well as on the methods of their characterization. The part of this volume dealing with practical industrial applications includes chapters presenting advanced technical tools for high capacity adsorption separation of liquid and gas mixtures, development of new adsorbents for removal of hazardous contaminants from combustion flue gases and wastewaters, degasification of coal seams and fabrication of inorganic membranes and their applications. A comprehensive review is also included on contemporary utility of self-assembled monolayers, adsorption proteins and their role in modern industry, adsorption methods in technology of optical fibre glasses, sol-gel technology, solid desiccant dehumidification systems, etc. The articles give both the scientific backgrounds of the phenomena discussed and emphasize their practical aspects. The chapters give not only brief current knowledge about the studied problems, but are also a source of topical literature on the subject. A comprehensive bibliography on adsorption principles, design data and adsorbent materials for industrial applications for the period 1967-1997 concludes the book.