Aromatic C Sp2 H Dehydrogenative Coupling Reactions

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Aromatic C(sp2)−H Dehydrogenative Coupling Reactions

Bagher Eftekhari-Sis
Aromatic C sp2 H Dehydrogenative Coupling Reactions Book PDF

Author : Bagher Eftekhari-Sis
Publisher : CRC Press
Page : 310 pages
File Size : 46,7 Mb
Release : 2019-10-31
Category : Science
ISBN : 9781000733570

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Aromatic C(sp2)−H Dehydrogenative Coupling Reactions by Bagher Eftekhari-Sis Pdf

This comprehensive text covers the research and development trends in the growing field of aromatic C–H dehydrogenative coupling reactions, leading to different types of heterocycles. The author provides answers to how these coupling reactions occur, what kinds of heterocycles are synthesized, and what their advantages are. The palladium-, rhodium-, iridium-, copper-, cobalt-, ruthenium-, and ferric-catalyzed aromatic C(sp2)–H dehydrogenative cross-coupling reactions are described in detail. A useful reference source for researchers and graduates in the field of heterocyclic chemistry and transition-metal-catalyzed dehydrogenative coupling reactions. Features: Comprehensive volume on the synthesis of benzo-heterocycles via aromatic C(sp2)–H bond activation. Heterocycles are of paramount importance to medicinal chemistry and drug discovery. Provides a comprehensive literature survey on the construction of heterocycles. Reaction procedures and mechanistic explanations are included, which will appeal to those in fine chemicals and pharmaceutical companies.

Aromatic C(sp2)-H Dehydrogenative Coupling Reactions

Bagher Eftekhari-Sis
Aromatic C sp2 H Dehydrogenative Coupling Reactions Book PDF

Author : Bagher Eftekhari-Sis
Publisher : CRC Press
Page : 310 pages
File Size : 47,8 Mb
Release : 2019
Category : Aromatic compounds
ISBN : 0367347296

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Aromatic C(sp2)-H Dehydrogenative Coupling Reactions by Bagher Eftekhari-Sis Pdf

This comprehensive text covers the research and development trends in the growing field of aromatic C-H dehydrogenative coupling reactions, leading to different types of heterocycles. The author provides answers to how these coupling reactions occur, what kinds of heterocycles are synthesized, and what their advantages are. The palladium-, rhodium-, iridium-, copper-, cobalt-, ruthenium-, and ferric-catalyzed aromatic C(sp2)-H dehydrogenative cross-coupling reactions are described in detail. A useful reference source for researchers and graduates in the field of heterocyclic chemistry and transition-metal-catalyzed dehydrogenative coupling reactions. Features: Comprehensive volume on the synthesis of benzo-heterocycles via aromatic C(sp2)-H bond activation. Heterocycles are of paramount importance to medicinal chemistry and drug discovery. Provides a comprehensive literature survey on the construction of heterocycles. Reaction procedures and mechanistic explanations are included, which will appeal to those in fine chemicals and pharmaceutical companies.

Aromatic C(sp2)−H Dehydrogenative Coupling Reactions

Bagher Eftekhari-Sis
Aromatic C sp2 H Dehydrogenative Coupling Reactions Book PDF

Author : Bagher Eftekhari-Sis
Publisher : CRC Press
Page : 290 pages
File Size : 49,9 Mb
Release : 2019-10-31
Category : Science
ISBN : 9781000733914

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Aromatic C(sp2)−H Dehydrogenative Coupling Reactions by Bagher Eftekhari-Sis Pdf

This comprehensive text covers the research and development trends in the growing field of aromatic C–H dehydrogenative coupling reactions, leading to different types of heterocycles. The author provides answers to how these coupling reactions occur, what kinds of heterocycles are synthesized, and what their advantages are. The palladium-, rhodium-, iridium-, copper-, cobalt-, ruthenium-, and ferric-catalyzed aromatic C(sp2)–H dehydrogenative cross-coupling reactions are described in detail. A useful reference source for researchers and graduates in the field of heterocyclic chemistry and transition-metal-catalyzed dehydrogenative coupling reactions. Features: Comprehensive volume on the synthesis of benzo-heterocycles via aromatic C(sp2)–H bond activation. Heterocycles are of paramount importance to medicinal chemistry and drug discovery. Provides a comprehensive literature survey on the construction of heterocycles. Reaction procedures and mechanistic explanations are included, which will appeal to those in fine chemicals and pharmaceutical companies.

From C-H to C-C Bonds

Chao-Jun Li
From C H to C C Bonds Book PDF

Author : Chao-Jun Li
Publisher : Royal Society of Chemistry
Page : 330 pages
File Size : 42,8 Mb
Release : 2014-09-30
Category : Science
ISBN : 9781849737975

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From C-H to C-C Bonds by Chao-Jun Li Pdf

This book examines the first ten years of this rapidly-expanding field, providing the reader with the knowledge to develop new syntheses in keeping with the principles of Green Chemistry.

Heterocycles via Cross Dehydrogenative Coupling

Ananya Srivastava,Chandan K. Jana
Heterocycles via Cross Dehydrogenative Coupling Book PDF

Author : Ananya Srivastava,Chandan K. Jana
Publisher : Springer Nature
Page : 494 pages
File Size : 48,5 Mb
Release : 2019-08-23
Category : Science
ISBN : 9789811391446

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Heterocycles via Cross Dehydrogenative Coupling by Ananya Srivastava,Chandan K. Jana Pdf

This book discusses the developments in the synthesis and functionalization of different heterocycles based on the formation of carbon-carbon (C-C) and carbon-heteroatom (C-X) bonds using cross-dehydrogenative coupling (CDC). Consisting of 13 chapters, the book systematically describes the advances in the synthesis and functionalization of nitrogen, oxygen, and sulfur-containing heterocycles. It also discusses the various mechanistic pathways to help readers gain an in-depth understanding of the CDC reactions of heterocycles. Lastly, in order to promote green chemistry, it addresses a range of metal-free CDC reactions of heterocycles – an area that has attracted significant attention in both academic and industrial research.

Science of Synthesis: Cross-Dehydrogenative Coupling

Debabrata Maiti
Science of Synthesis Cross Dehydrogenative Coupling Book PDF

Author : Debabrata Maiti
Publisher : Georg Thieme Verlag
Page : 686 pages
File Size : 55,8 Mb
Release : 2023-09-06
Category : Science
ISBN : 9783132455252

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Science of Synthesis: Cross-Dehydrogenative Coupling by Debabrata Maiti Pdf

Comprehensive overview of strategies and applications of cross-dehydrogenative coupling methods Cross-Dehydrogenative Coupling (CDC) represents a type of coupling reaction for the construction of a C−C bond or C−heteroatom (C–X) bond directly from C−H and X−H bonds present in the precursors. Since this genre of coupling reaction obviates the need for substrate prefunctionalization, it has an added advantage of high efficiency, atom economy, and environmental friendliness. CDC reactions are triggered by transition-metal catalysts or simply by an oxidants, or by either photocatalysis or electrocatalysis, leading to a hetero- or homo-coupled products with the removal of two hydrogens. Over the years, several CDC strategies have been developed that has made it possible to construct bonds between carbon-hydrogen (C–H) bonds of diverse hybridization. CDC has also streamlined the synthesis and functionalization of various nitrogen, oxygen, and sulfur-containing heterocycles. This volume features a series of chapters systematically covering methods and strategies in CDC, organized primarily on the type of bond being formed. In addition, particular aspects of CDC are highlighted in devoted chapters on topics such as mechanistic aspects, electrochemical and flow methods, transformations in water, natural product synthesis, and enantioselective protocols.

Economic Synthesis of Heterocycles

Xiao-Feng Wu,Matthias Beller
Economic Synthesis of Heterocycles Book PDF

Author : Xiao-Feng Wu,Matthias Beller
Publisher : Royal Society of Chemistry
Page : 522 pages
File Size : 52,9 Mb
Release : 2014-05-01
Category : Science
ISBN : 9781782620839

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Economic Synthesis of Heterocycles by Xiao-Feng Wu,Matthias Beller Pdf

Heterocycle synthesis is one of the largest areas of modern organic chemistry. Heterocycles have a broad range of applications including pharmaceuticals, agrochemicals and dyes, and are the core structure to around 90% of naturally-occurring molecules. Transition metal catalysts have become favoured in heterocycle synthesis, not least because of their low cost, but also due to their relatively low environmental toxicity and biocompatibility. This book presents an overview of the state-of-the-art in transition metal catalysis for heterocycle synthesis. Each metal is discussed in turn, presenting a comprehensive source of information on the use of zinc, iron, copper, cobalt, manganese, and nickel in a sustainable and economic manner. Referencing the latest primary literature, and authored by active researchers in the field, this book is a must-have resource for anyone wishing to undertake an economic and sustainable approach to heterocycle synthesis.

Transition-Metal-Mediated Aromatic Ring Construction

Ken Tanaka
Transition Metal Mediated Aromatic Ring Construction Book PDF

Author : Ken Tanaka
Publisher : John Wiley & Sons
Page : 785 pages
File Size : 52,5 Mb
Release : 2013-07-09
Category : Science
ISBN : 9781118629994

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Transition-Metal-Mediated Aromatic Ring Construction by Ken Tanaka Pdf

State-of-the-science methods, synthetic routes, and strategies to construct aromatic rings The development of new reactions for the synthesis of aromatic compounds is a highly active research area in organic synthesis, providing new functional organic materials, functional reagents, and biologically active compounds. Recently, significant advances in transition-metal-mediated reactions have enabled the efficient and practical construction of new aromatic rings with useful properties and applications. This book draws together and reviews all the latest discoveries and methods in transition-metal-mediated reactions, offering readers promising new routes to design and construct complex aromatic compounds. Integrating metal catalysis with aromatic compound synthesis, Transition-Metal-Mediated Aromatic Ring Construction offers a practical guide to the methods, synthetic routes, and strategies for constructing aromatic compounds. The book's five parts examine: [2+2+2], [2+2+1], and related cycloaddition reactions [4+2], [3+2], and related cycloaddition reactions Electrocyclization reactions Coupling and addition reactions Other important transformations, including methathesis reactions and skeletal rearrangement reactions Edited by Ken Tanaka, an internationally recognized expert in the field of transition-metal catalysis, the book features authors who are leading pioneers and researchers in synthetic reactions. Their contributions reflect a thorough review and analysis of the literature as well as their own firsthand laboratory experience developing new aromatic compounds. All chapters end with a summary and outlook, setting forth new avenues of research and forecasting new discoveries. There are also references at the end of each chapter, guiding readers to important original research reports and reviews. In summary, Transition-Metal-Mediated Aromatic Ring Construction offers synthetic chemists a promising new avenue for the development of important new aromatic compounds with a broad range of applications.

Advances in Heterocyclic Chemistry

Anonim
Advances in Heterocyclic Chemistry Book PDF

Author : Anonim
Publisher : Elsevier
Page : 430 pages
File Size : 41,6 Mb
Release : 2024-03-01
Category : Science
ISBN : 9780443237744

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Advances in Heterocyclic Chemistry by Anonim Pdf

Advances in Heterocyclic Chemistry, Volume 142, the latest release in this definitive series, combines descriptive synthetic chemistry and mechanistic insight to yield an understanding of how chemistry drives the preparation and useful properties of heterocyclic compounds. Chapters in this new release include Recent advances in the Synthesis of Benzo[b]furans, Recent Advances in the Synthesis of 6-Membered Heterocycles via Domino and Multicomponent Reactions (from 2017-2022), Multi-component synthesis of isatin based bioactive heterocycles, Recent advances in the chemistry of pyrazolo[1,5-a]pyrimidines, The Literature of Heterocyclic Chemistry, Part XXI, 2021, and much more. Additional sections present the latest Advances in applications of dihydropyridines in organic chemistry and Strategies for the annulation of five-membered sulfur-nitrogen rings to benzene and heterocycles. Considered the definitive serial in the field of heterocyclic chemistry Serves as the go-to reference for organic chemists, polymer chemists, and many biological scientists Provides the latest comprehensive reviews written by established authorities in the field Combines descriptive synthetic chemistry and mechanistic insights to enhance understanding on how chemistry drives the preparation and useful properties of heterocyclic compounds

Advances in Heterocyclic Chemistry

Eric F.V. Scriven,Christopher A. Ramsden
Advances in Heterocyclic Chemistry Book PDF

Author : Eric F.V. Scriven,Christopher A. Ramsden
Publisher : Elsevier
Page : 296 pages
File Size : 52,8 Mb
Release : 2023-02-07
Category : Science
ISBN : 9780443193156

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Advances in Heterocyclic Chemistry by Eric F.V. Scriven,Christopher A. Ramsden Pdf

Advances in Heterocyclic Chemistry, Volume 139, the latest release in this definitive series on the field of heterocyclic chemistry, combines descriptive synthetic chemistry and mechanistic insights to yield an understanding on how chemistry drives the preparation and useful properties of heterocyclic compounds. Topics in this new release include Application of the Fischer indole synthesis in medicinal chemistry, Oxindole Synthesis via C-H Activation Methods, Ring-Closing Metathesis in the Synthesis of Fused Indole Structures, Synthesis of fuller heterocycles, The Literature of Heterocyclic Chemistry, Part XX, 2020, and Heterocyclic Zwitterions Based on Coupled Polymethines. Presents what is considered to be the definitive serial in the field of heterocyclic chemistry Serves as the go-to reference for organic chemists, polymer chemists and many biological scientists Provides the latest comprehensive reviews written by established authorities in the field Combines descriptive synthetic chemistry and mechanistic insights to enhance understanding on how chemistry drives the preparation and useful properties of heterocyclic compounds

Catalytic Asymmetric Synthesis

Takahiko Akiyama,Iwao Ojima
Catalytic Asymmetric Synthesis Book PDF

Author : Takahiko Akiyama,Iwao Ojima
Publisher : John Wiley & Sons
Page : 798 pages
File Size : 55,8 Mb
Release : 2022-05-27
Category : Science
ISBN : 9781119736417

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Catalytic Asymmetric Synthesis by Takahiko Akiyama,Iwao Ojima Pdf

Catalytic Asymmetric Synthesis Seminal text presenting detailed accounts of the most important catalytic asymmetric reactions known today This book covers the preparation of enantiomerically pure or enriched chemical compounds by use of chiral catalyst molecules. While reviewing the most important catalytic methods for asymmetric organic synthesis, this book highlights the most important and recent developments in catalytic asymmetric synthesis. Edited by two well-qualified experts, sample topics covered in the work include: Metal catalysis, organocatalysis, photoredox catalysis, enzyme catalysis C–H bond functionalization reactions Carbon–carbon bond formation reactions, carbon–halogen bond formation reactions, hydrogenations, polymerizations, flow reactions Axially chiral compounds Retaining the best of its predecessors but now thoroughly up to date with the important and recent developments in catalytic asymmetric synthesis, the 4th edition of Catalytic Asymmetric Synthesis serves as an excellent desktop reference and text for researchers and students, from upper-level undergraduates all the way to experienced professionals in industry or academia.

Ruthenium in Organic Synthesis

Shun-Ichi Murahashi
Ruthenium in Organic Synthesis Book PDF

Author : Shun-Ichi Murahashi
Publisher : John Wiley & Sons
Page : 398 pages
File Size : 48,8 Mb
Release : 2006-03-06
Category : Science
ISBN : 9783527605798

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Ruthenium in Organic Synthesis by Shun-Ichi Murahashi Pdf

In this comprehensive book, one of the leading experts, Shun-Ichi Murahashi, presents all the important facets of modern synthetic chemistry using Ruthenium, ranging from hydrogenation to metathesis. In 14 contributions, written by an international authorship, readers will find all the information they need about this fascinating and extraordinary chemistry. The result is a high quality information source and a indispensable reading for everyone working in organometallic chemistry. From the contents: Introduction (S.-I. Murahashi) Hydrogenation and Transfer Hydrogenation (M. Kitamura and R. Noyori) Oxidations (S.-I. Murahashi and N. Komiya) Carbon-Carbon Bond Formations via Ruthenacycle Intermediates (K. Itoh) Carbon-Carbon Bond Formation via pi-Allylruthenium Intermediates (T. Mitsudo) Olefin Metathesis (R. H. Grubbs) Cyclopropanation (H. Nishiyama) Nucleophilic Addition to Alkynes and Reactions via Vinylidene Intermediates (P. Dixneuf) Reactions via C-H Activation (N. Chatani) Lewis Acid Reactions (E. P. Kundig) Reactions with CO and CO2 (T. Mitsudo) Isomerization of Organic Substrates Catalyzed by Ruthenium Complexes (H. Suzuki) Radical Reactions (H. Nagashima) Bond Cleavage Reactions (S. Komiya)

C-C Cross Couplings with 3d Base Metal Catalysts

Xiao-Feng Wu
C C Cross Couplings with 3d Base Metal Catalysts Book PDF

Author : Xiao-Feng Wu
Publisher : Springer Nature
Page : 403 pages
File Size : 47,9 Mb
Release : 2023-06-13
Category : Science
ISBN : 9783031328671

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C-C Cross Couplings with 3d Base Metal Catalysts by Xiao-Feng Wu Pdf

This volume presents recent progress on 3d base metal catalyzed C-C cross coupling reactions. The contributions provide detailed discussions on the use of cheap metal catalysts such as Cr, Mn, Fe, Co, Ni, Cu, and Zn to construct Csp2-Csp2, Csp2-Csp3 and Csp3-Csp3 bonds with a variety of substrates. These non-noble metal catalyst have many advantages such as being inexpensive, having low toxicity and are environmentally benign. Therefore the use of cheap metal catalysts in organic synthesis has gained much attention in efforts to develop more sustainable synthetic green chemistry. Each chapter is written by international experts in the field and is a great resource for students, researchers and chemists working in industry to gain an overview on the latest developments.

Organic Chemistry

Pierre Vogel,Kendall N. Houk
Organic Chemistry Book PDF

Author : Pierre Vogel,Kendall N. Houk
Publisher : John Wiley & Sons
Page : 1382 pages
File Size : 43,6 Mb
Release : 2019-10-07
Category : Science
ISBN : 9783527345328

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Organic Chemistry by Pierre Vogel,Kendall N. Houk Pdf

Provides the background, tools, and models required to understand organic synthesis and plan chemical reactions more efficiently Knowledge of physical chemistry is essential for achieving successful chemical reactions in organic chemistry. Chemists must be competent in a range of areas to understand organic synthesis. Organic Chemistry provides the methods, models, and tools necessary to fully comprehend organic reactions. Written by two internationally recognized experts in the field, this much-needed textbook fills a gap in current literature on physical organic chemistry. Rigorous yet straightforward chapters first examine chemical equilibria, thermodynamics, reaction rates and mechanisms, and molecular orbital theory, providing readers with a strong foundation in physical organic chemistry. Subsequent chapters demonstrate various reactions involving organic, organometallic, and biochemical reactants and catalysts. Throughout the text, numerous questions and exercises, over 800 in total, help readers strengthen their comprehension of the subject and highlight key points of learning. The companion Organic Chemistry Workbook contains complete references and answers to every question in this text. A much-needed resource for students and working chemists alike, this text: -Presents models that establish if a reaction is possible, estimate how long it will take, and determine its properties -Describes reactions with broad practical value in synthesis and biology, such as C-C-coupling reactions, pericyclic reactions, and catalytic reactions -Enables readers to plan chemical reactions more efficiently -Features clear illustrations, figures, and tables -With a Foreword by Nobel Prize Laureate Robert H. Grubbs Organic Chemistry: Theory, Reactivity, and Mechanisms in Modern Synthesis is an ideal textbook for students and instructors of chemistry, and a valuable work of reference for organic chemists, physical chemists, and chemical engineers.

Noncovalent Interactions in Catalysis

Kamran T Mahmudov,Maximilian N Kopylovich,M Fatima C Guedes da Silva,Armando J L Pombeiro
Noncovalent Interactions in Catalysis Book PDF

Author : Kamran T Mahmudov,Maximilian N Kopylovich,M Fatima C Guedes da Silva,Armando J L Pombeiro
Publisher : Royal Society of Chemistry
Page : 676 pages
File Size : 46,7 Mb
Release : 2019-03-04
Category : Science
ISBN : 9781788017510

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Noncovalent Interactions in Catalysis by Kamran T Mahmudov,Maximilian N Kopylovich,M Fatima C Guedes da Silva,Armando J L Pombeiro Pdf

Noncovalent interactions often provide the spine of biomolecular and material structures, and can therefore play a key role in biological and catalytic processes. Selectivity in chemical reactions, particularly in catalytic processes, is often an orchestral action of various noncovalent interactions occurring in intermediates and transition states. Although the role of hydrogen bonding is well explored in catalysis, the other types of weak interactions, namely cation–π, anion–π, π–π stacking, pseudo-agostic, halogen, chalcogen, pnictogen, tetrel and icosagen bonds, must also be considered. Naturally, the chemo-, regio- or stereoselectivity of a reaction depends on the stability of such noncovalent-interaction-supported species in catalytic systems. Therefore, an in-depth understanding of these weak interactions may be the key to designing new catalytic materials. Providing an overview of the role of these different types of noncovalent interactions in both homogenous and heterogeneous catalysis, this book is a valuable resource for synthetic chemists who are interested in exploring and further developing noncovalent-interaction-assisted synthesis and catalysis.