Catalysis By Di And Polynuclear Metal Cluster Complexes

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Catalysis by Di- and Polynuclear Metal Cluster Complexes

Author : Richard D. Adams,F. Albert Cotton
Publisher : Wiley-VCH
Page : 586 pages
File Size : 47,5 Mb
Release : 1998-03-16
Category : Science
ISBN : UOM:39015040163183

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Catalysis by Di- and Polynuclear Metal Cluster Complexes by Richard D. Adams,F. Albert Cotton Pdf

A pioneer work on catalysis of organic chemical reactions involving multinuclear metal complexes. Catalysis by Di- and Polynuclear Metal Cluster Complexes surveys the latest developments at the frontier of this exciting field, combining theory with new and original examples of catalytic processes produced by polynuclear metal complexes. An invaluable resource for inorganic and organometallic chemists in industry and R&D, it contains chapters from world experts and scholars on: Concepts and models for characterizing homogeneous reactions catalyzed by transition metal cluster complexes Activation of ruthenium clusters for use in catalysis Catalysis by mixed metal clusters containing gold phosphine groupings Catalysis by sulfido bridged dimolybdenum complexes Dimolybdenum and ditungsten complexes Synthesis of organic compounds catalyzed by transition metal clusters Catalysis with dirhodium (II) complexes Catalytic synthesis of polythioether macrocycles Catalysis of Rh, Rh-Co, and Ir-Co multinuclear complexes and its applications to organic syntheses Bimetallic hydroformylation catalysis Catalysis by colloids Catalysis with palladium clusters Heterometallic clusters for heterogeneous catalysis Supported clusters in catalysis.

Organometallic Chemistry

Author : M Green
Publisher : Royal Society of Chemistry
Page : 566 pages
File Size : 41,8 Mb
Release : 2007-10-31
Category : Science
ISBN : 9781847554178

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Organometallic Chemistry by M Green Pdf

Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Metal Clusters in Chemistry

Author : Pierre Braunstein,Luis A. Oro,Paul R. Raithby
Publisher : Wiley-VCH
Page : 710 pages
File Size : 41,8 Mb
Release : 2000-01-11
Category : Science
ISBN : UCLA:L0080295116

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Metal Clusters in Chemistry by Pierre Braunstein,Luis A. Oro,Paul R. Raithby Pdf

Metal cluster chemistry is at the cutting edge between molecular and solid-state chemistry and has therefore had a great impact on the researchers working on organic, coordination, and solid-state chemistry, catalysis, physics, and materials science. The development of new sophisticated synthetic techniques has led to enormous progress in the synthesis of this diverse class of compounds. The number of clusters is growing rapidly, since the possible variations in the metal and ligand sphere are numerous. Modern bonding theories, such as the isolobal principle, have allowed a better understanding of the structures and properties of metal clusters, and thus paved the way for the usage of these versatile materials. Catalysis and nanomaterials are just two of the very promising application-oriented fields. Seventy six contributions, written by world experts in this research field, provide extensive coverage of different aspects of cluster chemistry, ranging from synthesis, structure determination, and dynamics to applications. Up-to-date information, including an impressive collection of structural data and illustrations, extensive coverage of the most important publications of the last decade, and many more features make this three-volume set a complete single-source guide for all researchers working in the area of cluster chemistry.

Homogeneous Catalysis with Metal Complexes

Author : Oleg N. Temkin
Publisher : John Wiley & Sons
Page : 963 pages
File Size : 51,7 Mb
Release : 2012-02-08
Category : Science
ISBN : 9781119966821

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Homogeneous Catalysis with Metal Complexes by Oleg N. Temkin Pdf

Homogeneous catalysis by soluble metal complexes has gained considerable attention due to its unique applications and features such as high activity and selectivity. Catalysis of this type has demonstrated impressive achievements in synthetic organic chemistry and commercial chemical technology. Homogeneous Catalysis with Metal Complexes: Kinetic Aspects and Mechanisms presents a comprehensive summary of the results obtained over the last sixty years in the field of the kinetics and mechanisms of organic and inorganic reactions catalyzed with metal complexes. Topics covered include: Specific features of catalytic reaction kinetics in the presence of various mono- and polynuclear metal complexes and nanoclusters Multi-route mechanisms and the methods of their identification, as well as approaches to the kinetics of polyfunctional catalytic systems Principles and features of the dynamic behavior of nonlinear kinetic models The potential, achievements, and limitations of applying the kinetic approach to the identification of complex reaction mechanisms The development of a rational strategy for designing kinetic models The kinetic models and mechanisms of many homogeneous catalytic processes employed in synthetic and commercial chemistry Written for specialists in the field of kinetics and catalysis, this book is also relevant for post-graduates engaged in the study

Catalysis

Author : James J. Spivey
Publisher : Royal Society of Chemistry
Page : 218 pages
File Size : 52,6 Mb
Release : 2005
Category : Reference
ISBN : 0854042342

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Catalysis by James J. Spivey Pdf

Catalysis will be of interest to anyone working in academia and industry that needs an up-to-date critical analysis and summary of catalysis research and applications.

The Chemistry of Metal Cluster Complexes

Author : Duward F. Shriver,Herbert D. Kaesz,Richard D. Adams
Publisher : Wiley-VCH
Page : 456 pages
File Size : 45,7 Mb
Release : 1990
Category : Science
ISBN : UOM:39015021543395

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The Chemistry of Metal Cluster Complexes by Duward F. Shriver,Herbert D. Kaesz,Richard D. Adams Pdf

Seven chapters summarize the current status of organometallic cluster chemistry from the viewpoints of synthesis, structure and bonding, ligand substitution reactions, ligand transformations, polyhedral rearrangement, cluster fragmentation reactions, and metal clusters as homogeneous catalysts. An eighth provides an extensive bibliography of reviews for the period from 1965 to 1988. Annotation copyrighted by Book News, Inc., Portland, OR

Organometallic Chemistry and Catalysis

Author : Karl Kirchner,Walter Weissensteiner
Publisher : Springer Science & Business Media
Page : 165 pages
File Size : 45,5 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783709162743

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Organometallic Chemistry and Catalysis by Karl Kirchner,Walter Weissensteiner Pdf

From the beginning of chemistry as an exact (natural) science - almost 200 years ago - there was a more or less distinct differentiation between its various branches such as organic, inorganic, physical, analytical, or biochemistry. With the increasing insight into the connections and governing laws it soon became obvious, however, that such a clear separation could be regarded as more or less obsolete; within almost any field of chemical research one has to deal with most of the branches mentioned. Especially organic and inorganic chemistry are significant examples for this statement, overlapping considerably within the important field of organome tallic chemistry. This regime of chemistry started its advance with the discovery of dimethylzinc 150 years ago, had a highlight with the introduction of Grignard reagents around 1900, developed further with the start of lithium organyls in 1925 and literally exploded after the discovery of the first transition metal cyclopenta dienyl complex ferrocene half a century ago. The chronological sequence of the important steps, i. e. 1850 (Zn) - 1900 (Mg) - 1925 (Li) - 1950 (Fe), seems rather remarkable. The increasing group of metallocenes is not only of high theoretical and, due to the potential chirality of its members, stereochemical interest, but offers also a wide variety of extremely useful catalysts, especially for stereoselective reactions. The Austrian Chemical Society took this development into account by organizing the Twelfth International Conference on Organometallic Chemistry held in Vienna in 1985.

Nanostructured Materials

Author : Anonim
Publisher : Elsevier
Page : 222 pages
File Size : 55,5 Mb
Release : 2001-12-18
Category : Technology & Engineering
ISBN : 9780080493503

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Nanostructured Materials by Anonim Pdf

This thematic volume of Advances in Chemical Engineering presents the latest advances in the exciting interdisciplinary field of nanostructured materials. Written by chemical engineers, chemists, physicists, materials scientists, and bioengineers, this volume focuses on the molecular engineering of materials at the nanometer scale for unique size-dependent properties. It describes a "bottom-up" approach to designing nanostructured systems for a variety of chemical, physical, and biological applications.

Advances in Catalytic Activation of Dioxygen by Metal Complexes

Author : László I. Simándi
Publisher : Springer Science & Business Media
Page : 349 pages
File Size : 40,7 Mb
Release : 2006-04-11
Category : Science
ISBN : 9780306478161

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Advances in Catalytic Activation of Dioxygen by Metal Complexes by László I. Simándi Pdf

The subject of dioxygen activation and homogeneous catalytic oxidation by metal complexes has been in the focus of attention over the last 20 years. The widespread interest is illustrated by its recurring presence among the sessions and subject areas of important international conferences on various aspects of bioinorganic and coordination chemistry as well as catalysis. The most prominent examples are ICCC, ICBIC, EUROBIC, ISHC, and of course the ADHOC series of meetings focusing on the subject itself. Similarly, the number of original and review papers devoted to various aspects of dioxygen activation are on the rise. This trend is due obviously to the relevance of catalytic oxidation to biological processes such as dioxygen transport, and the action of oxygenase and oxidase enzymes related to metabolism. The structural and functional modeling of metalloenzymes, particularly of those containing iron and copper, by means of low-molecular complexes of iron, copper, ruthenium, cobalt, manganese, etc., have provided a wealth of indirect information helping to understand how the active centers of metalloenzymes may operate. The knowledge gained from the study of metalloenzyme models is also applicable in the design of transition metal complexes as catalytsts for specific reactions. This approach has come to be known as biomimetic or bioinspired catalysis and continues to be a fruitful and expanding area of research.

Handbook Of Boron Science: With Applications In Organometallics, Catalysis, Materials And Medicine (In 4 Volumes)

Author : Narayan S Hosmane,Robert D Eagling
Publisher : World Scientific
Page : 1051 pages
File Size : 44,6 Mb
Release : 2018-08-07
Category : Science
ISBN : 9781786344434

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Handbook Of Boron Science: With Applications In Organometallics, Catalysis, Materials And Medicine (In 4 Volumes) by Narayan S Hosmane,Robert D Eagling Pdf

Boron science features in numerous fields including organic chemistry, organometallic chemistry and medicine. Boron is unique in all aspects of science and engineering and has made a significant impact in our daily lives through its use in fertilizers, germicides, fungicides, soaps, detergents, cancer drugs as well as many household glassware utensils, ceramics and cell phone windows. These volumes bring together an array of internationally renowned scientists to discuss the very latest developments in the application of boron in a broad range of disciplines. This multi-reference work describes the topic by appointing leading researchers to write on current developments in boron science, showcasing its importance to the four separate areas described in each volume: Organometallic Chemistry, Catalysis, Materials Chemistry and Medicine.Written to cover the full range of applications and innovations in boron science, this all-encompassing work offers us a one-stop reference compiled by world-leading researchers and practitioners of the subject, making it perfect for undergraduate and graduate students of chemistry, and researchers and practitioners interested in their professional development.

Organometallics

Author : Christoph Elschenbroich
Publisher : John Wiley & Sons
Page : 839 pages
File Size : 42,6 Mb
Release : 2006-03-10
Category : Science
ISBN : 9783527293902

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Organometallics by Christoph Elschenbroich Pdf

THE textbook on organometallic chemistry. Comprehensive and up-to-date, the German original is already a classic, making this third completely revised and updated English edition a must for graduate students and lecturers in chemistry, inorganic chemists, chemists working with/on organometallics, bioinorganic chemists, complex chemists, and libraries. Over one third of the chapters have been expanded to incorporate developments since the previous editions, while the chapter on organometallic catalysis in synthesis and production appears for the first time in this form. From the reviews of the first English editions: 'The selection of material and the order of its presentation is first class ... Students and their instructors will find this book extraordinarily easy to use and extraordinarily useful.' -Chemistry in Britain 'Elschenbroich and Salzer have written the textbook of choice for graduate or senior-level courses that place an equal emphasis on main group element and transition metal organometallic chemistry. ... this book can be unequivocally recommended to any teacher or student of organometallic chemistry.' - Angewandte Chemie International Edition 'The breadth and depth of coverage are outstanding, and the excitement of synthetic organometallic chemistry comes across very strongly.' - Journal of the American Chemical Society

Nanoparticles and Catalysis

Author : Didier Astruc
Publisher : John Wiley & Sons
Page : 663 pages
File Size : 46,6 Mb
Release : 2008-06-25
Category : Science
ISBN : 9783527621330

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Nanoparticles and Catalysis by Didier Astruc Pdf

Written by international experts, this monograph combines two of the most important aspects of modern chemistry, presenting the latest knowledge on these environmental friendly applications. This result is a comprehensive overview of the application of nanoparticles in catalysis, focusing on synthesis and the most important reaction types, providing all the information needed by catalytic, organic and solid state chemists, as well as those working with or on organometallics, materials scientists, and chemists in industry.

Advanced Inorganic Chemistry

Author : F. Albert Cotton,Geoffrey Wilkinson,Carlos A. Murillo,Manfred Bochmann
Publisher : John Wiley & Sons
Page : 1380 pages
File Size : 42,9 Mb
Release : 1999-04-13
Category : Science
ISBN : 9780471199571

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Advanced Inorganic Chemistry by F. Albert Cotton,Geoffrey Wilkinson,Carlos A. Murillo,Manfred Bochmann Pdf

For more than a quarter century, Cotton and Wilkinson's Advanced Inorganic Chemistry has been the source that students and professional chemists have turned to for the background needed to understand current research literature in inorganic chemistry and aspects of organometallic chemistry. Like its predecessors, this updated Sixth Edition is organized around the periodic table of elements and provides a systematic treatment of the chemistry of all chemical elements and their compounds. It incorporates important recent developments with an emphasis on advances in the interpretation of structure, bonding, and reactivity.“/p> From the reviews of the Fifth Edition: "The first place to go when seeking general information about the chemistry of a particular element, especially when up-to-date, authoritative information is desired." —Journal of the American Chemical Society "Every student with a serious interest in inorganic chemistry should have [this book]." —Journal of Chemical Education "A mine of information . . . an invaluable guide." —Nature "The standard by which all other inorganic chemistry books are judged." —Nouveau Journal de Chimie "A masterly overview of the chemistry of the elements." —The Times of London Higher Education Supplement "A bonanza of information on important results and developments which could otherwise easily be overlooked in the general deluge of publications." —Angewandte Chemie

Coordination Chemistry of Silicon

Author : Prof. Dr. Shigeyoshi Inoue
Publisher : MDPI
Page : 228 pages
File Size : 52,6 Mb
Release : 2019-03-04
Category : Science
ISBN : 9783038976387

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Coordination Chemistry of Silicon by Prof. Dr. Shigeyoshi Inoue Pdf

The chemistry of silicon has always been a field of major concern due to its proximity to carbon on the periodic table. From the molecular chemist’s viewpoint, one of the most interesting differences between carbon and silicon is their divergent coordination behavior. In fact, silicon is prone to form hyper-coordinate organosilicon complexes, and, as conveyed by reports in the literature, highly sophisticated ligand systems are required to furnish low-coordinate organosilicon complexes. Tremendous progress in experimental, as well as computational, techniques has granted synthetic access to a broad range of coordination numbers for silicon, and the scientific endeavor, which was ongoing for decades, was rewarded with landmark discoveries in the field of organosilicon chemistry. Molecular congeners of silicon(0), as well as silicon oxides, were unveiled, and the prominent group 14 metalloid proved its applicability in homogenous catalysis as a supportive ligand or even as a center of catalytic activity. This book focuses on the most recent advances in the coordination chemistry of silicon with transition metals as well as main group elements, including the stabilization of low-valent silicon species through the coordination of electron donor ligands. Therefore, this book is associated with the development of novel synthetic methodologies, structural elucidations, bonding analysis, and also possible applications in catalysis or chemical transformations using related organosilicon compounds.

Multimetallic Catalysts in Organic Synthesis

Author : Masakatsu Shibasaki,Yoshinori Yamamoto
Publisher : John Wiley & Sons
Page : 310 pages
File Size : 44,5 Mb
Release : 2006-03-06
Category : Science
ISBN : 9783527604326

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Multimetallic Catalysts in Organic Synthesis by Masakatsu Shibasaki,Yoshinori Yamamoto Pdf

This first book to comprehensively cover this hot topic presents the information hitherto scattered throughout smaller reviews or single book chapters to provide an introduction to this rapidly expanding field. In ten chapters, the international team of expert authors treats asymmetric syntheses, new transformations, and organometallic reactions using homo- and hetero-bimetallic catalysts. Written for advanced researchers, this very timely publication is of significant benefit to organic and organometallic chemists in both academia and industry.