Chemical Kinetics And Catalysis

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Chemical Kinetics and Catalysis

Author : R.A. van Santen,Hans (J.)W. Niemantsverdriet
Publisher : Springer Science & Business Media
Page : 290 pages
File Size : 43,7 Mb
Release : 2013-06-29
Category : Science
ISBN : 9781475796438

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Chemical Kinetics and Catalysis by R.A. van Santen,Hans (J.)W. Niemantsverdriet Pdf

to the Fundamental and Applied Catalysis Series Catalysis is important academically and industrially. It plays an essential role in the manufacture of a wide range of products, from gasoline and plastics to fertilizers and herbicides, which would otherwise be unobtainable or prohibitively expensive. There are few chemical-or oil-based material items in modem society that do not depend in some way on a catalytic stage in their manufacture. Apart from manu facturing processes, catalysis is finding other important and ever-increasing uses; for example, successful applications of catalysis in the control of pollution and its use in environmental control are certain to increase in the future. The commercial importance of catalysis and the diverse intellectual challenges of catalytic phenomena have stimulated study by a broad spectrum of scientists, including chemists, physicists, chemical engineers, and material scientists. Increas ing research activity over the years has brought deeper levels of understanding, and these have been associated with a continually growing amount of published material. As recently as sixty years ago, Rideal and Taylor could still treat the subject comprehensively in a single volume, but by the 1950s Emmett required six volumes, and no conventional multivolume text could now cover the whole of catalysis in any depth. In view of this situation, we felt there was a need for a collection of monographs, each one of which would deal at an advanced level with a selected topic, so as to build a catalysis reference library.

Kinetics of Chemical Reactions

Author : Guy B. Marin,Gregory S. Yablonsky,Denis Constales
Publisher : John Wiley & Sons
Page : 462 pages
File Size : 43,9 Mb
Release : 2019-04-29
Category : Science
ISBN : 9783527342952

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Kinetics of Chemical Reactions by Guy B. Marin,Gregory S. Yablonsky,Denis Constales Pdf

This second, extended and updated edition presents the current state of kinetics of chemical reactions, combining basic knowledge with results recently obtained at the frontier of science. Special attention is paid to the problem of the chemical reaction complexity with theoretical and methodological concepts illustrated throughout by numerous examples taken from heterogeneous catalysis combustion and enzyme processes. Of great interest to graduate students in both chemistry and chemical engineering.

Chemical Kinetics and Catalysis

Author : Richard I. Masel
Publisher : Wiley-Interscience
Page : 0 pages
File Size : 46,9 Mb
Release : 2001-04-13
Category : Technology & Engineering
ISBN : 0471241970

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Chemical Kinetics and Catalysis by Richard I. Masel Pdf

Provides a thorough and up-to-date treatment of chemical kinetics and catalysis, combining traditional background information with the latest computational methods for fitting data to appropriate rate equations. Demonstrates how the vastly improved computational tools now available allow application of kinetic concepts to understanding and predicting the behavior of diverse and complex phenomena, including biological systems, semiconductor growth, and corrosion. * Contains chapters reviewing of kinetic concepts, introducing kinetics via rate equations and mechanisms, explaining the theory of reaction rates (a section on trajectory calculations to simulate reactions), predicting potential energy surfaces (methods for directing the reaction rate), and discussing catalysis with a focus on modifying the reaction rate. * A useful reference guide, providing the essential basics along with numerous solved examples, problems, and illustrative computer programs.

Catalytic Kinetics

Author : Dmitry Yu Murzin,Tapio Salmi
Publisher : Elsevier
Page : 752 pages
File Size : 52,6 Mb
Release : 2016-06-04
Category : Technology & Engineering
ISBN : 9780444634634

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Catalytic Kinetics by Dmitry Yu Murzin,Tapio Salmi Pdf

Catalytic Kinetics: Chemistry and Engineering, Second Edition offers a unified view that homogeneous, heterogeneous, and enzymatic catalysis form the cornerstone of practical catalysis. The book has an integrated, cross-disciplinary approach to kinetics and transport phenomena in catalysis, but still recognizes the fundamental differences between different types of catalysis. In addition, the book focuses on a quantitative chemical understanding and links the mathematical approach to kinetics with chemistry. A diverse group of catalysts is covered, including catalysis by acids, organometallic complexes, solid inorganic materials, and enzymes, and this fully updated second edition contains a new chapter on the concepts of cascade catalysis. Finally, expanded content in this edition provides more in-depth discussion, including topics such as organocatalysis, enzymatic kinetics, nonlinear dynamics, solvent effects, nanokinetics, and kinetic isotope effects. Fully revised and expanded, providing the latest developments in catalytic kinetics Bridges the gaps that exist between hetero-, homo- and enzymatic-catalysis Provides necessary tools and new concepts for researchers already working in the field of catalytic kinetics Written by internationally-renowned experts in the field Examples and exercises following each chapter make it suitable as an advanced course book

Kinetics of Chemical Reactions

Author : Guy B. Marin,Gregory S. Yablonsky
Publisher : John Wiley & Sons
Page : 451 pages
File Size : 43,6 Mb
Release : 2011-08-29
Category : Science
ISBN : 9783527317639

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Kinetics of Chemical Reactions by Guy B. Marin,Gregory S. Yablonsky Pdf

This systematic presentation covers both experimental and theoretical kinetic methods, as well as fundamental and applied. The identification of dominant reaction paths, reaction intermediates and rate-determining steps allows a quantification of the effects of reaction conditions and catalyst properties, providing guidelines for catalyst optimization. In addition, the form in which the equations are presented allows for their straightforward implementation for scale-up and chemical reactor design purposes. Throughout, the methodologies given are illustrated by many examples.

Chemical Kinetics and Reaction Dynamics

Author : Santosh K. Upadhyay
Publisher : Springer Science & Business Media
Page : 256 pages
File Size : 49,5 Mb
Release : 2007-04-29
Category : Science
ISBN : 9781402045479

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Chemical Kinetics and Reaction Dynamics by Santosh K. Upadhyay Pdf

Chemical Kinetics and Reaction Dynamics brings together the major facts and theories relating to the rates with which chemical reactions occur from both the macroscopic and microscopic point of view. This book helps the reader achieve a thorough understanding of the principles of chemical kinetics and includes: Detailed stereochemical discussions of reaction steps Classical theory based calculations of state-to-state rate constants A collection of matters on kinetics of various special reactions such as micellar catalysis, phase transfer catalysis, inhibition processes, oscillatory reactions, solid-state reactions, and polymerization reactions at a single source. The growth of the chemical industry greatly depends on the application of chemical kinetics, catalysts and catalytic processes. This volume is therefore an invaluable resource for all academics, industrial researchers and students interested in kinetics, molecular reaction dynamics, and the mechanisms of chemical reactions.

Kinetics of Chemical Processes

Author : Michel Boudart
Publisher : Elsevier
Page : 263 pages
File Size : 54,9 Mb
Release : 2014-05-16
Category : Science
ISBN : 9781483183978

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Kinetics of Chemical Processes by Michel Boudart Pdf

Kinetics of Chemical Processes details the concepts associated with the kinetic study of the chemical processes. The book is comprised of 10 chapters that present information relevant to applied research. The text first covers the elementary chemical kinetics of elementary steps, and then proceeds to discussing catalysis. The next chapter tackles simplified kinetics of sequences at the steady state. Chapter 5 deals with coupled sequences in reaction networks, while Chapter 6 talks about autocatalysis and inhibition. The seventh chapter describes the irreducible transport phenomena in chemical kinetics. The next two chapters discuss the correlations in homogenous kinetics and heterogeneous catalysis, respectively. The last chapter covers the analysis of reaction networks. The book will be of great use to students, researchers, and practitioners of scientific disciplines that deal with chemical reaction, particularly chemistry and chemical engineering.

Kinetics of Catalytic Reactions

Author : M. Albert Vannice
Publisher : Springer Science & Business Media
Page : 257 pages
File Size : 40,6 Mb
Release : 2006-04-09
Category : Science
ISBN : 9780387259727

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Kinetics of Catalytic Reactions by M. Albert Vannice Pdf

Describes how to conduct kinetic experiments with heterogeneous catalysts, analyze and model the results, and characterize the catalysts Detailed analysis of mass transfer in liquid phase reactions involving porous catalysts. Important to the fine chemicals and pharmaceutical industries so it has appeal to many researchers in both industry and academia (chemical engineering and chemistry departments

An Introduction to Chemical Kinetics

Author : Michel Soustelle
Publisher : John Wiley & Sons
Page : 484 pages
File Size : 50,9 Mb
Release : 2013-02-07
Category : Science
ISBN : 9781118604229

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An Introduction to Chemical Kinetics by Michel Soustelle Pdf

This book is a progressive presentation of kinetics of the chemical reactions. It provides complete coverage of the domain of chemical kinetics, which is necessary for the various future users in the fields of Chemistry, Physical Chemistry, Materials Science, Chemical Engineering, Macromolecular Chemistry and Combustion. It will help them to understand the most sophisticated knowledge of their future job area. Over 15 chapters, this book present the fundamentals of chemical kinetics, its relations with reaction mechanisms and kinetic properties. Two chapters are then devoted to experimental results and how to calculate the kinetic laws in both homogeneous and heterogeneous systems. The following two chapters describe the main approximation modes to calculate these laws. Three chapters are devoted to elementary steps with the various classes, the principles used to write them and their modeling using the theory of the activated complex in gas and condensed phases. Three chapters are devoted to the particular areas of chemical reactions, chain reactions, catalysis and the stoichiometric heterogeneous reactions. Finally the non-steady-state processes of combustion and explosion are treated in the final chapter.

Chemical Kinetics

Author : Luis G Arnaut,Sebastiao Jose Formosinho,Hugh Burrows
Publisher : Elsevier
Page : 562 pages
File Size : 40,9 Mb
Release : 2006-12-21
Category : Science
ISBN : 0080469345

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Chemical Kinetics by Luis G Arnaut,Sebastiao Jose Formosinho,Hugh Burrows Pdf

Chemical Kinetics bridges the gap between beginner and specialist with a path that leads the reader from the phenomenological approach to the rates of chemical reactions to the state-of-the-art calculation of the rate constants of the most prevalent reactions: atom transfers, catalysis, proton transfers, substitution reactions, energy transfers and electron transfers. For the beginner provides the basics: the simplest concepts, the fundamental experiments, and the underlying theories. For the specialist shows where sophisticated experimental and theoretical methods combine to offer a panorama of time-dependent molecular phenomena connected by a new rational. Chemical Kinetics goes far beyond the qualitative description: with the guidance of theory, the path becomes a reaction path that can actually be inspected and calculated. But Chemical Kinetics is more about structure and reactivity than numbers and calculations. A great emphasis in the clarity of the concepts is achieved by illustrating all the theories and mechanisms with recent examples, some of them described with sufficient detail and simplicity to be used in general chemistry and lab courses. * Looking at atoms and molecules, and how molecular structures change with time. * Providing practical examples and detailed theoretical calculations * Of special interest to Industrial Chemistry and Biochemistry

Catalysis and Kinetics: Molecular Level Considerations

Author : Guy B. Marin
Publisher : Academic Press
Page : 254 pages
File Size : 52,9 Mb
Release : 2013-12-24
Category : Technology & Engineering
ISBN : 9780124199941

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Catalysis and Kinetics: Molecular Level Considerations by Guy B. Marin Pdf

Advances in Chemical Engineering was established in 1960 and is the definitive serial in the area. It is one of great importance to organic chemists, polymer chemists, and many biological scientists. Written by established authorities in the field, the comprehensive reviews combine descriptive chemistry and mechanistic insight and yield an understanding of how the chemistry drives the properties. This volume covers the topic of catalysis and kinetics and aspects in chemical engineering. Control and optimization of process systems Polyelectrolytes Propane dehydrogenation and selective oxidation of hydrogen Chromium catalysts for ethylene polymerization and oligomerization Computational simulation of rare Earth catalysis

Chemical Kinetics

Author : Praveen Tyagi
Publisher : Discovery Publishing House
Page : 380 pages
File Size : 53,9 Mb
Release : 2006
Category : Electronic
ISBN : 8183561594

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Chemical Kinetics by Praveen Tyagi Pdf

Contents: Chemical Kinetics, Determination of Order of Reaction, Activation Energy and Chemical Reactions, KineticsofFastReactions, Photo chemistry, Kineticsof Homogeneous Reactions and Catalysis.

Kinetics of Multistep Reactions

Author : Friedrich G. Helfferich
Publisher : Elsevier
Page : 508 pages
File Size : 41,7 Mb
Release : 2004-09-15
Category : Science
ISBN : 9780080473185

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Kinetics of Multistep Reactions by Friedrich G. Helfferich Pdf

This book addresses primarily the engineer in industrial process development, the research chemist in academia and industry, and the graduate student intending to become a reaction engineer. In industry, competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such development should be based on "fundamental" kinetics that reflect the elementary steps of which the reaction consists. The book forges fundamental kinetics into a practical tool by presenting new, effective methods for elucidation of mechanisms and reduction of complexity without unacceptable sacrifice in accuracy: fewer equations (lesser computational load), fewer coefficients (fewer experiment to determine them). For network elucidation, new rules relating network configurations to observable kinetic behaviour allow incorrect networks to be ruled out by whole classes instead of one by one. For modelling, general equations and algorithms are given from which equations for specific networks can be recovered by simple substitutions. The procedures are illustrated with examples of industrial reactions including, among others, paraffin oxidation, ethoxylation, hydroformylation, hydrocyanation, shape-selective catalysis, ethane pyrolysis, styrene polymerization, and ethene oligomerization. Many of the rate equations have not been published before. The expanded edition of the 2001 title, Kinetics of Homogeneous Multistep Reactions includes new chapters on heterogeneous catalysis and periodic and chaotic re-actions; new sections on adsorption, statistical methods, and lumping; and other new detail. Contains new chapters on heterogeneous catalysis, oscillations and chaos Includes new sections on statistical methods, lumping adsorption and software and databases Provides a better understanding of complex reaction mechanisms

Catalytic Kinetics

Author : Dmitry Yu Murzin,Tapio Salmi
Publisher : Elsevier
Page : 492 pages
File Size : 45,7 Mb
Release : 2005-11-07
Category : Technology & Engineering
ISBN : 0080455468

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Catalytic Kinetics by Dmitry Yu Murzin,Tapio Salmi Pdf

Chemistry and chemical technology have been at the heart of the revolutionary developments of the 20th century. The chemical industry has a long history of combining theory (science) and practice (engineering) to create new and useful products. Worldwide, the process industry (which includes chemicals, petrochemicals, petroleum refining, and pharmaceuticals) is a huge, complex, and interconnected global business with an annual production value exceeding 4 trillion dollars. Although in industry special focus is in heterogeneous catalysis, homogeneous, enzymatic, photochemical and electrochemical catalysis should not be overlooked; as the major aim is to produce certain chemicals in the best possible way, applying those types of catalysis, which suit a particular process in the most optimal way. Catalysis according to the very definition of it deals with enhancement of reaction rates, that is, with catalytic kinetics. This book unifies the main sub disciplines forming the cornerstone of catalytic kinetics. * Provides a broad overview catalytic kinetics * Bridges the gaps that exist between hetero-, homo- and bio-catalysis * Written by internationally renowned experts in this field

Principles of Chemical Kinetics

Author : Gorden Hammes
Publisher : Elsevier
Page : 281 pages
File Size : 48,8 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323157964

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Principles of Chemical Kinetics by Gorden Hammes Pdf

Principles of Chemical Kinetics is devoted to the principles and applications of chemical kinetics. The phenomenology and commonly used theories of chemical kinetics are presented in a critical manner, with particular emphasis on collision dynamics. How and what mechanistic information can be obtained from various experimental approaches is stressed throughout this book. Comprised of nine chapters, this text opens with an overview of reaction rates and their empirical analysis, along with theories of chemical kinetics. The following chapters consider reactions and unimolecular decompositions in the gas phase; chemical reactions in molecular beams; and energy transfer and partitioning in chemical reactions. Kinetics in liquid solutions and fast reactions in liquids are also described. The final chapter looks at the kinetics of enzymes, with particular reference to steady state and transient state kinetics, the pH and temperature dependence of kinetic parameters, and the mechanism underlying enzymatic action. This monograph is intended for students with a general college background in chemistry, physics, and mathematics, and with a typical undergraduate course in physical chemistry.