Conformation Dependent Design Of Sequences In Copolymers Ii
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Conformation-Dependent Design of Sequences in Copolymers II by Alexei R. Khokhlov Pdf
1 V.O. Aseyev, H. Tenhu, F. Winnik: Temperature Dependence of the Colloidal Stability of Neutral Amphiphilic Polymers in Water.- 2 V.I. Lozinsky: Approaches to Chemical Synthesis of Protein-Like Copolymers.- 3 S.I. Kuchanov, A.R. Khokhlov: Role of Physical Factors in the Processes of Obtaining of Copolymers.- 4 A.Y. Grosberg, A.R. Khokhlov: "After-Action" of the Ideas of O.M. Lifshitz in Polymer and Biopolymer Physics.-
. A.J. M ller, V. Balsamo, M.L. Arnal: Nucleation and Crystallization in Diblock and Triblock Copolymers.- 2 J.-F. Gohy: Block Copolymer Micelles.- 3 M.A. Hillmyer: Nanoporous Materials from Block Copolymer Precursors.- 4 M. Li, C. Coenjarts, C.K. Ober: Patternable Block Copolymers.-
This book has the Highest Impact Factor of all publications ranked by ISI within Polymer Science. It contains short and concise reports on physics and chemistry of polymers, each written by the world renowned experts. The book is still valid and useful after 5 or 10 years. The electronic version is available free of charge for standing order customers at: springer.com/series/12/
Control of polymeric structure is among the most important endeavours of modern macromolecular science. In particular, tailoring the positioning and strength of intermolecular forces within macromolecules by synthetic me- odsandthusgaining structuralcontrolover the?nalpolymeric materials has become feasible, resulting in the?eld of supramolecular polymer science. - sides other intermolecular forces, hydrogen bonds are unique intermolecular forces enabling the tuning of material properties via self-assembly processes -1 overawiderangeofinteractionstrengthrangingfromseveralkJmol tosev- -1 eraltensofkJmol . Centralfortheformationofthesestructuresareprecursor molecules of small molecular weight (usually lower than 10 000), which can assembleinsolidorsolutiontoaggregatesofde?nedgeometry. Intermolecular hydrogenbondsatde?nedpositionsofthesebuildingblocksaswellastheir- spectivestartinggeometryandtheinitialsizedeterminethemodeofassembly into supramolecular polymers forming network-, rodlike-,?brous-, disclike-, helical-, lamellar- and chainlike architectures. In all cases, weak to strong hydrogen-bondinginteractionscanactasthecentralstructure-directingforce fortheorganizationofpolymerchainsandthusthe?nalmaterials'properties. Theimportantcontributionofhydrogenbondstotheareaofsupramole- lar polymer chemistry is de?nitely outstanding, most of all since the potency of hydrogen-bonding systems has been found to be unique in relation to other supramolecular interactions. Thus the high level of structural diversity of many hydrogen-bonding systems as well as their high level of direction- ity and speci?city in recognition-phenomena is unbeaten in supramolecular chemistry. The realization, that their stability can be tuned over a wide range of binding strength is important for tuning the resulting material prop- ties, ranging from elastomeric to thermoplastic and even highly crosslinked duroplastic structures and networks. On the basis of the thermal reversib- ity, new materials with highly tunable properties can now be prepared, - ing able to change their mechanical and optoelectronic properties with very smallchangesofexternalstimuli. Thusthe?eldofhydrogen-bondedpolymers forms the basis for stimuli responsive and adaptable materials of the future.
Intrinsic Molecular Mobility and Toughness of Polymers I by Hans-Henning Kausch Pdf
Ce livre historique peut contenir de nombreuses coquilles et du texte manquant. Les acheteurs peuvent generalement telecharger une copie gratuite scannee du livre original (sans les coquilles) aupres de l'editeur. Non reference. Non illustre. 1838 edition. Extrait: ...a tetat naissant, et particularite relative a ce principe dans quelques legumineuses. Afin de rechercher si les memes proprietes existaient dans l'amidon, a l'etat naissant ou tres jeune, j'examinai cette secretion au moment ou elle se montre dans les cotyledons encore baignes par le liquide sucre de l'ovule du pisum sativum. Ses grains tres petits alors, offrent aussi les caracteres physiques et chimiques qui precedent, et ceux que nous exposerons plus loin; une particularite remarquable dans leurs formes a ete decrite et figuree pi. 4 fig-' ' ' Dans les cotyledons de la feve commune, on trouve des grains d'amidon plus sinueux encore. L'amidon extrait des haricots et des lentilles presente des grains qui se dessinent par des contours moins sinueux que les precedens. Enfin, l'amidon en tres petite quantite dans les-graines de Colutea arborescens (Baguenaudier), est en grains excessivement petits, qui sont arrondis quoique plus ou moins irreguliers. X. Botak.--Stptrmlre. i La configuration sinueuse, contournee ou vermiforme, observee dans plusieurs graines des legumineuses, ne se retrouve donc pas dans toutes au meme degre; elle offrfun exemple de plus des varietes de formes que peut affecter l'amidon dans les circonstances legerement variables, ou se produit cette secretion, sans que les caracteres physiques essentiels ni la composition chimique soient differentes.;; ..., r..', ', ., Amidon completement epure, ...
Neodymium Based Ziegler Catalysts - Fundamental Chemistry by Oskar Nuyken Pdf
In spite of the vast number of patents and publications mainly issued duringthelastdecade, acomprehensivereviewthatcoversthescienti?caswell as the patent literature has been missing until now. In this volume we try to review the available literature by two independent approaches to Nd and Ln-catalyzed diene polymerizations. In the?rst part of thevolume, whichisentitled"Neodymium-Based Ziegler/NattaCatalystsand their Application in Diene Polymerization", a polymer chemist's view is given with strong emphasis on Nd-based catalyst systems. Also technological and industrialaspectsofNd-catalyzeddienepolymerizationsareaddressed. Inthe secondpartofthevolume, whichisentitled"Rare-EarthMetalsandAluminum Getting Close in Ziegler-type Organometallics", a more organometallic p- spective isgivenandLn-based catalystsystems areaddressed
