Green Solvents In Organic Synthesis

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Green Solvents for Organic Synthesis

Author : V. K. Ahluwalia
Publisher : Alpha Science International, Limited
Page : 356 pages
File Size : 40,7 Mb
Release : 2009
Category : Nature
ISBN : UOM:39015084161812

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Green Solvents for Organic Synthesis by V. K. Ahluwalia Pdf

Solvents play an important role in organic synthesis. Most of the common organic solvents which have been used for organic synthesis include benzene, chloroform, toluene, carbon tetrachloride etc. Most of these are volatile (VOC) and have undesirable properties like toxicity or being harmful to the environment or may be obtained from non renewable petroleum sources. This book describes some of the most important green solvents, their merits and demerits. These green solvents include water, supercritical carbon dioxide, ionic liquids, polyethylene glycol and its solutions and the Florous Phase Technique. A large number of representative synthetic applications for each of the green solvents are described.

Green Solvents in Organic Synthesis

Author : Xiao-Feng Wu,Zhiping Yin,Liang-nian He,Feng Wang
Publisher : John Wiley & Sons
Page : 469 pages
File Size : 40,6 Mb
Release : 2024-03-11
Category : Science
ISBN : 9783527352005

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Green Solvents in Organic Synthesis by Xiao-Feng Wu,Zhiping Yin,Liang-nian He,Feng Wang Pdf

Green Solvents in Organic Synthesis Essential reference on replacing conventional solvents with greener alternatives in industrial chemicals synthesis and production A well-timed book promoting sustainability in synthesis and production of chemicals, Green Solvents in Organic Synthesis details various green solvents, solvent systems, and solubilization techniques, including their chemistry, physiochemical properties, performance, and distinct applications, presenting a greener approach to conventional solvents by replacing them with sustainable alternatives that have similarities in their reaction mechanisms. Edited by four highly qualified academics with significant research experience in the field, Green Solvents in Organic Synthesis includes information on: Water and liquid polymers (Polyethylene glycol PEG), Acetonitrile, DMSO, Dimethyl carbonate, Ionic liquids, and Supercritical fluids) Bio-based solvents (Cyrene, γ-Valerolactone (GVL), Lactic acid, 2-MeTHF) and deep eutectic solvents (DESs) Alcohols (MeOH, EtOH, i-PrOH, n-BuOH, t-BuOH, Ethylene glycol), ketones (Acetones, MEK, MIBK, Cyclohexanone), and esters (Methyl acetate, Ethyl acetate, i-PrOAc, n-BuOAc) Technical, economic, and environmental aspects of green solvents and how to maximize their reuse and recycling to alleviate pollution and reduce energy consumption For chemists in a variety of disciplines, Green Solvents in Organic Synthesis is an essential reference that provides foundational knowledge of green solvents, along with key features of each class of green solvent within the context of organic reactions for industrial and laboratory synthesis.

Industrial Applications of Green Solvents

Author : Inamuddin,Mohd Imran Ahamed,Abdullah M. Asiri
Publisher : Materials Research Forum LLC
Page : 534 pages
File Size : 46,6 Mb
Release : 2019-06-20
Category : Technology & Engineering
ISBN : 9781644900222

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Industrial Applications of Green Solvents by Inamuddin,Mohd Imran Ahamed,Abdullah M. Asiri Pdf

Green chemistry aims at reducing pollution and avoiding hazardous waste in the environment, as well as in a number of industrial applications, including chemical, pharmaceutical, paint and leather industries. The book focuses on new applications of green solvents (water, ionic liquids, supercritical carbon dioxide, terpenes) in such areas as chemical synthesis (including lipase-catalyzed reactions, organic synthesis, esterification reactions), gas separation membranes, environment-friendly products, low energy requirement processes and alternatives to hazardous substances.

Green Solvents II

Author : Ali Mohammad,Dr. Inamuddin
Publisher : Springer Science & Business Media
Page : 518 pages
File Size : 43,9 Mb
Release : 2012-03-19
Category : Science
ISBN : 9789400728905

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Green Solvents II by Ali Mohammad,Dr. Inamuddin Pdf

The conventional solvents used in chemical, pharmaceutical, biomedical and separation processes represent a great challenge to green chemistry because of their toxicity and flammability. Since the beginning of “the 12 Principles of Green Chemistry” in 1998, a general effort has been made to replace conventional solvents with environmentally benign substitutes. Water has been the most popular choice so far, followed by ionic liquids, surfactant, supercritical fluids, fluorous solvents, liquid polymers, bio-solvents and switchable solvent systems. Green Solvents Volume I and II provides a throughout overview of the different types of solvents and discusses their extensive applications in fields such as extraction, organic synthesis, biocatalytic processes, production of fine chemicals, removal of hydrogen sulphide, biochemical transformations, composite material, energy storage devices and polymers. These volumes are written by leading international experts and cover all possible aspects of green solvents’ properties and applications available in today’s literature. Green Solvents Volume I and II is an invaluable guide to scientists, R&D industrial specialists, researchers, upper-level undergraduates and graduate students, Ph.D. scholars, college and university professors working in the field of chemistry and biochemistry.

Green Techniques for Organic Synthesis and Medicinal Chemistry

Author : Wei Zhang,Berkeley W. Cue
Publisher : John Wiley & Sons
Page : 769 pages
File Size : 41,7 Mb
Release : 2012-05-10
Category : Science
ISBN : 9781118308653

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Green Techniques for Organic Synthesis and Medicinal Chemistry by Wei Zhang,Berkeley W. Cue Pdf

An updated overview of the rapidly developing field of green engineering techniques for organic synthesis and medicinal chemistry Green chemistry remains a high priority in modern organic synthesis and pharmaceutical R&D, with important environmental and economic implications. This book presents comprehensive coverage of green chemistry techniques for organic and medicinal chemistry applications, summarizing the available new technologies, analyzing each technique’s features and green chemistry characteristics, and providing examples to demonstrate applications for green organic synthesis and medicinal chemistry. The extensively revised edition of Green Techniques for Organic Synthesis and Medicinal Chemistry includes 7 entirely new chapters on topics including green chemistry and innovation, green chemistry metrics, green chemistry and biological drugs, and the business case for green chemistry in the generic pharmaceutical industry. It is divided into 4 parts. The first part introduces readers to the concepts of green chemistry and green engineering, global environmental regulations, green analytical chemistry, green solvents, and green chemistry metrics. The other three sections cover green catalysis, green synthetic techniques, and green techniques and strategies in the pharmaceutical industry. Includes more than 30% new and updated material—plus seven brand new chapters Edited by highly regarded experts in the field (Berkeley Cue is one of the fathers of Green Chemistry in Pharma) with backgrounds in academia and industry Brings together a team of international authors from academia, industry, government agencies, and consultancies (including John Warner, one of the founders of the field of Green Chemistry) Green Techniques for Organic Synthesis and Medicinal Chemistry, Second Edition is an essential resource on green chemistry technologies for academic researchers, R&D professionals, and students working in organic chemistry and medicinal chemistry.

Alternative Solvents for Green Chemistry

Author : Francesca Kerton,Ray Marriott
Publisher : Royal Society of Chemistry
Page : 350 pages
File Size : 51,6 Mb
Release : 2015-11-09
Category : Science
ISBN : 9781782626138

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Alternative Solvents for Green Chemistry by Francesca Kerton,Ray Marriott Pdf

Everyone is becoming more environmentally conscious and therefore, chemical processes are being developed with their environmental burden in mind. This also means that more traditional chemical methods are being replaced with new innovations and this includes new solvents. Solvents are everywhere, but how necessary are they? They are used in most areas including synthetic chemistry, analytical chemistry, pharmaceutical production and processing, the food and flavour industry and the materials and coatings sectors. However, the principles of green chemistry guide us to use less of them, or to use safer, more environmentally friendly solvents if they are essential. Therefore, we should always ask ourselves, do we really need a solvent? Green chemistry, as a relatively new sub-discipline, is a rapidly growing field of research. Alternative solvents - including supercritical fluids and room temperature ionic liquids - form a significant portion of research in green chemistry. This is in part due to the hazards of many conventional solvents (e.g. toxicity and flammability) and the significant contribution that solvents make to the waste generated in many chemical processes. Solvents are important in analytical chemistry, product purification, extraction and separation technologies, and also in the modification of materials. Therefore, in order to make chemistry more sustainable in these fields, a knowledge of alternative, greener solvents is important. This book, which is part of a green chemistry series, uses examples that tie in with the 12 principles of green chemistry e.g. atom efficient reactions in benign solvents and processing of renewable chemicals/materials in green solvents. Readers get an overview of the many different kinds of solvents, written in such a way to make the book appropriate to newcomers to the field and prepare them for the 'green choices' available. The book also removes some of the mystique associated with 'alternative solvent' choices and includes information on solvents in different fields of chemistry such as analytical and materials chemistry in addition to catalysis and synthesis. The latest research developments, not covered elsewhere, are included such as switchable solvents and biosolvents. Also, some important areas that are often overlooked are described such as naturally sourced solvents (including ethanol and ethyl lactate) and liquid polymers (including poly(ethyleneglycol) and poly(dimethylsiloxane)). As well as these additional alternative solvents being included, the book takes a more general approach to solvents, not just focusing on the use of solvents in synthetic chemistry. Applications of solvents in areas such as analysis are overviewed in addition to the more widely recognised uses of alternative solvents in organic synthesis. Unfortunately, as the book shows, there is no universal green solvent and readers must ascertain their best options based on prior chemistry, cost, environmental benefits and other factors. It is important to try and minimize the number of solvent changes in a chemical process and therefore, the importance of solvents in product purification, extraction and separation technologies are highlighted. The book is aimed at newcomers to the field whether research students beginning investigations towards their thesis or industrial researchers curious to find out if an alternative solvent would be suitable in their work.

Green Solvents I

Author : Ali Mohammad,Inamuddin Dr.
Publisher : Springer Science & Business Media
Page : 440 pages
File Size : 40,7 Mb
Release : 2012-03-16
Category : Science
ISBN : 9789400717114

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Green Solvents I by Ali Mohammad,Inamuddin Dr. Pdf

The conventional solvents used in chemical, pharmaceutical, biomedical and separation processes represent a great challenge to green chemistry because of their toxicity and flammability. Since the beginning of “the 12 Principles of Green Chemistry” in 1998, a general effort has been made to replace conventional solvents with environmentally benign substitutes. Water has been the most popular choice so far, followed by ionic liquids, surfactant, supercritical fluids, fluorous solvents, liquid polymers, bio-solvents and switchable solvent systems. Green Solvents Volume I and II provides a throughout overview of the different types of solvents and discusses their extensive applications in fields such as extraction, organic synthesis, biocatalytic processes, production of fine chemicals, removal of hydrogen sulphide, biochemical transformations, composite material, energy storage devices and polymers. These volumes are written by leading international experts and cover all possible aspects of green solvents’ properties and applications available in today’s literature. Green Solvents Volume I and II is an invaluable guide to scientists, R&D industrial specialists, researchers, upper-level undergraduates and graduate students, Ph.D. scholars, college and university professors working in the field of chemistry and biochemistry.

Industrial Applications of Green Solvents

Author : Inamuddin
Publisher : Materials Research Forum LLC
Page : 300 pages
File Size : 55,5 Mb
Release : 2019-08-20
Category : Technology & Engineering
ISBN : 9781644900307

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Industrial Applications of Green Solvents by Inamuddin Pdf

The book explores industrial applications of green solvents in industrially important areas such as oil extraction, sensors and biosensors, CO2 capture, lignocellulosic biomass utilization, bio-based chemicals and their application in catalysis, electrochemical devices, purification of pharmaceuticals, organic synthesis and transformations, bio-lubricant additives, aluminum and aluminum-alloy production. The solvents covered include water, ionic liquids, supercritical carbon dioxide and glycerol.

Green Organic Reactions

Author : Gopinathan Anilkumar,Salim Saranya
Publisher : Springer Nature
Page : 349 pages
File Size : 46,5 Mb
Release : 2021-03-27
Category : Technology & Engineering
ISBN : 9789813368972

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Green Organic Reactions by Gopinathan Anilkumar,Salim Saranya Pdf

This book presents important developments and applications of green chemistry, especially in the field of organic chemistry. The chapters give a brief account of green organic reactions in water, green organic reactions using microwave and in solvent-free conditions. In depth discussions on the green aspects of ionic liquids, flow reactions, and recoverable catalysts are provided in this book. An exclusive chapter devoted to green Lewis acid is also included. The potential of supercritical fluids as green solvents in various areas of organic reactions is explained as well. This book will be a valuable reference for beginners as well as advanced researchers interested in green organic chemistry.

Green Solvents

Author : Anonim
Publisher : John Wiley & Sons
Page : 436 pages
File Size : 51,5 Mb
Release : 2014-04-11
Category : Science
ISBN : 9783527688555

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Green Solvents by Anonim Pdf

The shift towards being as environmentally-friendly as possible has resulted in the need for this important volume on the topic of reactions in water. Edited by one of the leaders in the field, Professor C.-J. Li, this is an essential resource for anyone wishing to gain an understanding of the world of green chemistry, as well as for chemists, environmental agencies and chemical engineers.

Green Reaction Media in Organic Synthesis

Author : Koichi Mikami
Publisher : John Wiley & Sons
Page : 200 pages
File Size : 47,8 Mb
Release : 2008-04-15
Category : Science
ISBN : 9781405172455

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Green Reaction Media in Organic Synthesis by Koichi Mikami Pdf

Green, sustainable chemistry involves the designing of chemicalprocesses with a view to reducing or even eliminating the use andproduction of hazardous materials. Recent endeavors have focused onlimiting the use of organic solvents and replacing them with new,environmentally benign media. The chemical industry is interestedin these cost-effective, alternative solvents and processes. This book provides a broad overview of the three most commonly usedgreen reaction media. Directed at synthetic organic chemistsworking in academic and industrial laboratories, it will also serveas a textbook for graduate courses on green chemistry. Successfulgreen reactions are considered, and experimental sections at theends of the chapters provide important practical details, withillustrations of potential applications. Sufficient information isincluded to allow selection of the most appropriate medium.Extensively referenced, the volume offers a point of entry into thedetailed literature.

Green Sustainable Process for Chemical and Environmental Engineering and Science

Author : Inamuddin,Rajender Boddula,Abdullah M. Asiri
Publisher : Elsevier
Page : 242 pages
File Size : 40,6 Mb
Release : 2021-11-17
Category : Technology & Engineering
ISBN : 9780128198513

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Green Sustainable Process for Chemical and Environmental Engineering and Science by Inamuddin,Rajender Boddula,Abdullah M. Asiri Pdf

Green Sustainable Process for Chemical and Environmental Engineering and Science: Switchable Solvents explores the preparation, properties, chemical processes and applications of this class of green solvents. The book provides an in-depth overview on the area of switchable solvents in various industrial applications, focusing on the purification and extraction of chemical compounds utilizing green chemistry protocols that include liquid-liquid, solid-liquid, liquid-gas and lipids separation technologies. In addition, it includes recent advances in greener extraction and separation processes. This book will be an invaluable guide to students, professors, scientists and R&D industrial specialists working in the field of sustainable chemistry, organic, analytical, chemical engineering, environmental and pharmaceutical sciences. Provides a broad overview of switchable solvents in sustainable chemical processes Compares the use of switchable solvents as greener solvents over conventional solvents Outlines eco-friendly organic synthesis and chemical processes using switchable solvents Lists various industrial separations/extraction processes using switchable solvents

Green Solvents for Chemistry

Author : William M. Nelson
Publisher : Oxford University Press
Page : 400 pages
File Size : 49,7 Mb
Release : 2003-03-27
Category : Science
ISBN : 9780198035763

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Green Solvents for Chemistry by William M. Nelson Pdf

The aim of this book is to introduce the use of green solvents throughout chemistry and to provide a comprehensive reference for solvents currently applicable in green chemistry. The first section covers solvents in chemical perspective, and the second section is a guide to green solvents. Overall, this volume defines characteristics of green solvents and their current usage, and explores their importance ecologically and economically. It includes a full range of commercial, industrial, and academic green solvents, and discusses solvents in specific commercial and non-commercial practices. Green Solvents for Chemistry differs from other works on solvents in that only solvents for green chemistry are included along with their chemical properties and toxicological issues.

Solvent-free Organic Synthesis

Author : Koichi Tanaka
Publisher : John Wiley & Sons
Page : 442 pages
File Size : 49,7 Mb
Release : 2006-03-06
Category : Science
ISBN : 9783527605361

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Solvent-free Organic Synthesis by Koichi Tanaka Pdf

The demand for increasingly clean and efficient chemical syntheses is continuously becoming more urgent from both an economic and an environmental standpoint. So-called green technologies are looking for alternatives, yet they focus on large quantities of hazardous even toxic solvents. One could even say that the best solvent is no solvent. It is against this background that chemical synthesis without the use of solvents has increasingly developed into a powerful methodology. Once the chemical reactivity is increased, the amount of initial substances needed is reduced; in particular it removes the need for the complex recycling and disposal of solvents. In this book, the third in our open "Green Chemistry" series, Koichi Tanaka describes the latest developments in this exciting field. Packed with advice on applications, this will be equally useful to practitioners in research as well as process chemists in industry, such that it is sure to become an invaluable reference source.

Organic Synthesis, Natural Products Isolation, Drug Design, Industry and the Environment

Author : Chhanda Mukhopadhyay,Bubun Banerjee
Publisher : Walter de Gruyter GmbH & Co KG
Page : 358 pages
File Size : 44,7 Mb
Release : 2023-07-04
Category : Science
ISBN : 9783111244075

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Organic Synthesis, Natural Products Isolation, Drug Design, Industry and the Environment by Chhanda Mukhopadhyay,Bubun Banerjee Pdf

Over the years, applications of various non-conventional solvents diversified in various fields such as organic synthesis, natural products, drug design, pharmaceuticals, dyes and agrochemical industries. This book consists of nine chapters, which present recent advances and applications of various non-conventional solvents in organic transformations, drug design and bioremediation. Environmental impacts of non-conventional solvents and comparison between traditional solvents and non-conventional solvents are also discussed in this book.