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Cross-Linked Liquid Crystalline Systems by Dirk Broer,Gregory P Crawford,Slobodan Zumer Pdf
Liquid crystal displays were discovered in the 1960s, and today we continue to enjoy the benefits of that fundamental discovery and its translation into a wide variety of products. Like liquid crystals, polymers are unusual materials, and have similarly enjoyed a great deal of research attention because of their vast applications and uses and compl
Liquid Crystalline Polymer Systems by Avraam I. Isayev,American Chemical Society. Meeting Pdf
Provides a comprehensive report on the synthesis, structure, rheology, processing, performance, and applications of liquid-crystalline polymers (LCPs). Discusses self-reinforced composites prepared through the melt processing of thermoplastics and thermotropic LCPs. Addresses current research efforts in making polymer-dispersed liquid crystals. Reports recent studies on the structure and phase behavior of mesophases. Describes the synthesis and properties of new main-chain and side-chain liquid-crystalline block copolymers, mesogen-jacketed LCPs, and liquid-crystalline thermosets.
Recent Advances in Liquid Crystalline Polymers by L. L. Chapoy Pdf
This volume contains an eclectic collection of 22 papers on liquid crystalline polymers presented at the Sixth Polymer Workshop, in the series sponsored by the European Science Foundation, entitled: 'Liquid Crystal Polymer Systems', in Gentofte, Denmark, 12-14 September 1983. Since a contribution to this volume was strictly voluntary, and in some cases represents a considerably expanded version of that which was presented, it is strictly speaking not correct to term this a 'proceedings'. A description of the aims and purposes of the European Science Foundation with respect to the polymer area has been presented in: Shell Polymers, Vol. 5, No.2, pp. 34-35, 1981. The papers given here represent a cross-section of current research interests in liquid crystalline polymers in the areas of theory, synthesis, characterization, structure-property relationships and applications. At least some of the current interest is motivated by attempts to practically exploit the novel properties of these materials in the developing tech nologies of high strength fibres and advanced materials for constructional purposes, but also for functional materials in the areas of information retrieval, electronics and opto-electronics applications. The editor wishes to thank all those involved for their courtesy and co-operation.
Drawing a picture of the current situation of this new field, this volume both summarizes the past achievements and analyzes the present unsolved problems.
Liquid Crystal Polymer Nanocomposites by P. M. Visakh,Artem Semkin,Zeynep Guven Ozdemir Pdf
Liquid Crystal Polymer Nanocomposites summarizes, in a comprehensive manner, numerous modern technical research accomplishments on the development of nanocomposites from liquid crystalline polymers. It emphasizes various studies at the nano-scale, including discussions of liquid crystalline block copolymers, liquid crystalline epoxy nanocomposites, barrier property studies of liquid crystalline epoxy and their nanocomposites, liquid crystalline polymer-based microfibrillar and nanofibrillar composites, liquid crystalline polymer/nanoplatelet nanocomposites, liquid-crystalline elastomer/graphene oxide nanocomposites, and thermotropic liquid crystalline polymers. It provides detailed information on methods of preparation, the properties of these materials and a discussion on the structure-properties relationship. With an emphasis on data and experimental results, the book's authors illustrate how the liquid crystal structure can have an impact on the final properties of nanocomposite. Contains contributions from leading experts working in this specialized field of research Provides detailed information on the preparation, characterization and application of nanocomposites of liquid crystalline polymers Presents solutions to both fundamental and applied problems
Crystallization in Multiphase Polymer Systems by Sabu Thomas,Mohammed Arif P.,E. Bhoje Gowd,Nandakumar Kalarikkal Pdf
Crystallization in Multiphase Polymer Systems is the first book that explains in depth the crystallization behavior of multiphase polymer systems. Polymeric structures are more complex in nature than other material structures due to their significant structural disorder. Most of the polymers used today are semicrystalline, and the subject of crystallization is still one of the major issues relating to the performance of semicrystalline polymers in the modern polymer industry. The study of the crystallization processes, crystalline morphologies and other phase transitions is of great significance for the understanding the structure-property relationships of these systems. Crystallization in block copolymers, miscible blends, immiscible blends, and polymer composites and nanocomposites is thoroughly discussed and represents the core coverage of this book. The book critically analyzes the kinetics of nucleation and growth process of the crystalline phases in multi-component polymer systems in different length scales, from macro to nanoscale. Various experimental techniques used for the characterization of polymer crystallization process are discussed. Written by experts in the field of polymer crystallization, this book is a unique source and enables professionals and students to understand crystallization behavior in multiphase polymer systems such as block copolymers, polymer blends, composites and nanocomposites. Covers crystallization of multiphase polymer systems, including copolymers, blends and nanocomposites Features comprehensive, detailed information about the basic research, practical applications and new developments for these polymeric materials Analyzes the kinetics of nucleation and growth process of the crystalline phases in multi-component polymer systems in different length scales, from macro to nanoscale
Liquid Crystalline and Mesomorphic Polymers by Valery P. Shibaev,Lui Lam Pdf
Among the various new directions in modern polymer science, the design and investigation of liquid crystal (LC) polymers have been the ones growing most actively and fruitfully. In spite of that, the possible formation of an anisotropic LC phase was only demonstrated theoretically for the first time in the 1950s by Onsager [1] and Flory [2], and then experimentally verified in the studies with polypeptides solutions. In essence, the studies of these LC lyotropic systems did not deviate from the theme of purely academic interest. It was at the beginning of the 1970s that the experimental "explosion" occurred, when aromatic polyamides were synthesized and their ability to form LC solutions in certain very aggressive solvents was discovered. The search for practical applications of such LC systems was crowned with the successful creation of the new generation of ultrastrong high-modulus ther mostable fibers, such as the Kevlar, due to the high degree of order of the macromolecules in the anisotropic LC state. In fact, these investigations coincided with the swift emergence on the practical "scene" of thermotropic low-molar-mass liquid crystals, with the use of these materials in microelectronics and electro optics (figures and let ters indicators, displays in personal computers, and flat TV, etc.). Polymer scientists also began to develop methods of synthesizing thermotropic LC polymers by incorporating mesogenic fragments in the main (main-chain LC polymers) or side branchings of the macromolecules (side-chain or comb shaped polymers).
Liquid Crystalline Polymers by Xin-jiu Wang,Qi-feng Zhou Pdf
This textbook consists of six chapters. The first chapter highlights the concept of liquid crystals, including chemical structure, phase classification, defect and texture, and continuum theory. It has been carefully written to meet the needs of readers who do not specialize in liquid crystals. The second chapter is related to the theoretical description of liquid crystalline polymers, networks, and gels, which deals with subjects such as the formation of liquid crystallinity in the polymer system, the phase transition and phase diagram, the molecular weight effect, chain conformation, physics properties, etc. In Chapter 3, the molecular engineering of liquid crystalline polymers is introduced. The molecular composition and the molecular weight play essential roles in the molecular design, which are reviewed in detail. In addition, some unusual liquid crystalline polymers are discussed. Chapter 4 is devoted to the phase identification of liquid crystalline polymers. The techniques involved cover polarizing microscopy, thermal analysis, X-ray diffraction, and other areas. Chapters 5 and 6 summarize the properties and applications of liquid crystalline polymers: Chapter 5 deals mainly with mechanical performance in fiber and composites; Chapter 6 presents the elasticity, viscosity and rheology of liquid crystalline polymers, as well as other important properties.
Liquid Crystalline Order in Polymers by Alexandre Blumstein Pdf
Liquid Crystalline Order in Polymers examines the topic of liquid crystalline order in systems containing rigid synthetic macromolecular chains. Each chapter of the book provides a review of one important area of the field. Chapter 1 discusses scattering in polymer systems with liquid crystalline order. It also introduces the field of liquid crystals. Chapter 2 treats the origin of liquid crystalline order in macromolecules by describing the in-depth study of conformation of such macromolecules in their unassociated state. The chapters that follow describe successively the liquid crystalline order in polymers with mesogenic side groups and rigid backbones, in polypeptides, and in block copolymers. Chapter 7 discusses the rheology of such systems. The last two chapters examine liquid crystalline order in biological materials and mesomorphic order in the realm of polymers with inorganic backbones. This book is intended to provide the polymer scientist, the materials scientist, and the biologist with a valuable source of information.
Liquid Crystal Polymers: From Structures to Applications by A.A. Collyer Pdf
The subject of liquid crystals and their use in electronic displays and in non-linear optical systems has become of tremendous importance during the last decade; and the incorporation of liquid crystal units into polymeric materials has led to a group of new materials with diverse properties. Some of these properties have been utilized in new products and some have yet to be used. Much published work has appeared that deals with specific materials or particular applications, and it was felt that a book was needed to examine and explain the underlying principles governing the diverse properties of these liquid crystal polymers, LCPs. The current work describes the diverse nature of LCPs, their synthesis, characterization, properties and finally their applications. It describes the manner in which liquid crystallinity or mesomorphism occurs in small molecules, monomer liquid crystals and polymer liquid crystals. Chapter 1 gives a classification of the various ways in which the meso gens may be connected to the polymer chains. Currently, the bulk of LCP material is based on main chain or longitudinal LCPs for use in engineering applications. The side chain or comb polymers are intended for use in electronics and opto-electronic systems and as surfactants. Many other variants and possibilities exist but their properties have not yet been fully studied or used. In this respect it is hoped that the current work will indicate future possibilities as well as discussing current opinion. v Preface vi Chapters 2 and 3 describe methods of characterizing the mesophases.
Liquid Crystalline Polymers by Lei Zhu,Christopher Y. Li Pdf
This book provides a comprehensive overview of various self-assemblies in liquid crystalline polymers and their electrical, optical, mechanical, and flame retardant properties. Liquid crystalline polymers are unique self-assembled, functional soft materials with electrical, magnetic, and thermal responses which find potential applications in numerous areas. As well as providing an overview of their synthesis, self-assembly and dynamics the various applications are also discussed. Such applications as liquid crystalline elastomers, light responsive actuators, optical reflectors, gas barrier films, and even flame retardant polymers will be presented. The book is a useful resource for undergraduates, postgraduates and experienced researchers.
Liquid Crystalline Polymers by Vijay Kumar Thakur,Michael R. Kessler Pdf
This book introduces anisotropic innovations in liquid crystalline polymers as well as new nanocomposite materials and testing techniques. The authors detail the newest discoveries of material properties, material types and phases, and material characterization. This interdisciplinary work creates valuable links that strengthen the approach to the evolving field of liquid crystalline polymers/ materials.
Principles of Polymer Systems, Sixth Edition by Ferdinand Rodriguez,Claude Cohen,Christopher K. Ober,Lynden Archer Pdf
Maintaining a balance between depth and breadth, the Sixth Edition of Principles of Polymer Systems continues to present an integrated approach to polymer science and engineering. A classic text in the field, the new edition offers a comprehensive exploration of polymers at a level geared toward upper-level undergraduates and beginning graduate students. Revisions to the sixth edition include: A more detailed discussion of crystallization kinetics, strain-induced crystallization, block copolymers, liquid crystal polymers, and gels New, powerful radical polymerization methods Additional polymerization process flow sheets and discussion of the polymerization of polystyrene and poly(vinyl chloride) New discussions on the elongational viscosity of polymers and coarse-grained bead-spring molecular and tube models Updated information on models and experimental results of rubber elasticity Expanded sections on fracture of glassy and semicrystalline polymers New sections on fracture of elastomers, diffusion in polymers, and membrane formation New coverage of polymers from renewable resources New section on X-ray methods and dielectric relaxation All chapters have been updated and out-of-date material removed. The text contains more theoretical background for some of the fundamental concepts pertaining to polymer structure and behavior, while also providing an up-to-date discussion of the latest developments in polymerization systems. Example problems in the text help students through step-by-step solutions and nearly 300 end-of-chapter problems, many new to this edition, reinforce the concepts presented.
Multiphase Polymer Systems by Andreea Irina Barzic,Silvia Ioan Pdf
Phase morphology in multicomponent polymer-based systems represents the main physical characteristic that allows for control of the material design and implicitly the development of new plastics. Emphasizing properties of these promising new materials in both solution and solid phase, this book describes the preparation, processing, properties, and practical implications of advanced multiphase systems from macro to nanoscales. It covers a wide range of systems including copolymers, polymer blends, polymer composites, gels, interpenetrating polymers, and layered polymer/metal structures, describing aspects of polymer science, engineering, and technology. The book analyzes experimental and theoretical aspects regarding the thermal and electrical transport phenomena and magnetic properties of crucial importance in advanced technologies. It reviews the most recent advances concerning morphological, rheological, interfacial, physical, fire-resistant, thermophysical, and biomedical properties of multiphase polymer systems. Concomitantly the book deals with basic investigation techniques that are sensitive in elucidating the features of each phase. It also discusses the latest research trends that offer new solutions for advanced bio- and nanotechnologies. Introduces an overview of recent studies in the area of multiphase polymer systems, their micro- and nanostructural evolutions in advanced technologies, and provides future outlooks, new challenges and opportunities. Discusses multicomponent structures that offer enhanced physical, mechanical, thermal, electrical, magnetic, and optical properties adapted to current requirements of modern technologies. Covers a wide range of materials, such as composites, blends, alloys, gels and interpenetrating polymer networks. Presents new strategies for controlling the micro- and nanomorphology and the mechanical properties of multiphase polymeric materials. Describes different applications of multiphase polymeric materials in various fields, including automotive, aeronautics and space industry, displays, and medicine.
