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Author : Stephen Cradock,A. J. Hinchcliffe
Publisher : CUP Archive
Page : 160 pages
File Size : 47,8 Mb
Release : 1975-10-09
Category : Science
ISBN : 0521207592
This 1975 book shows how and why matrix isolation developed and describes the necessary apparatus.
Author : A. Barnes,W.J. Orville-Thomas,R. Gaufrès,Achim Müller
Publisher : Springer Science & Business Media
Page : 602 pages
File Size : 42,6 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789400985407
The matrix isolation (MI) method has now been used for nearly thirty years. During this period it has been actively developed and the range of problems tackled greatly extended. Originally it was used for studies of transient species involv ing vibrational, electronic and ESR spectroscopy. Nowadays the study of transient species forms a comparatively small part of HI work since it has been amply demonstrated that very fruitful information can be obtained of the structure and interactions of stable molecules and their aggregates. In addition to the s~ectroscopic methods mentioned above the MI technique is nowadays a standard method in research based on vibrational relaxation, luminescence, Mossbauer, magnetic circular dichroism, pulsed NMR and photoelectron spectroscopy. The matrix isolation technique affords considerable advantages over more conventional methods in most applications of spectroscopy. Areas where the technique has been widely applied, or shows great potential, include: metal atom chemistry, and its relation to surface chemistry, high temperature inorganic species, transition metal complexes, interstellar species, free radicals and unstable molecules, conformational studies, molecular com plexes, and intermolecular forces.
Author : Lester Andrews,Martin Moskovits
Publisher : Unknown
Page : 448 pages
File Size : 54,7 Mb
Release : 1989
Category : Science
ISBN : UOM:39015016086616
Matrix-isolation spectroscopy, as a technique for studying unstable species, has had tremendous lasting powers. Since 1954, matrix-isolation has been able to assimilate new technology rather than being replaced by it. The matrix-isolation technique for producing and trapping new chemical species has been applied to an ever increasing range of chemical and physical problems since its inception. The last 12 years have seen a substantial number of new developments and applications of the matrix technique. The chapters in this book describe many of the contributions of matrix-isolation spectroscopy to chemistry and physics in the last decade, and as such predict the continued evolution of this technique over the next decade. Experimental techniques are generally closely related to the development of new apparatus, and each chapter has a section describing innovations in instrumentation such as the closed-cycle cryogenic cooler that has revolutionized the technique. In addition, each chapter describes many of the specialized methods used to prepare, trap and study particular new subject species. The volume will be an indispensable reference source for graduate students and other scientists new to this field, as well as chemists and physicists already involved in applied spectroscopy.
Author : A. Barnes,W. J. Orville-Thomas,R. Gaufres
Publisher : Unknown
Page : 620 pages
File Size : 51,5 Mb
Release : 1981-09-30
Category : Electronic
ISBN : 940098541X
Author : Anonim
Publisher : Unknown
Page : 128 pages
File Size : 54,5 Mb
Release : 1981
Category : Electronic
ISBN : OCLC:251433174
Author : Ian R. Dunkin
Publisher : Unknown
Page : 0 pages
File Size : 54,8 Mb
Release : 1998
Category : Matrix isolation spectroscopy
ISBN : OCLC:1392387729
Author : Leonid Khriachtchev
Publisher : Pan Stanford Publishing
Page : 533 pages
File Size : 42,8 Mb
Release : 2011-06-22
Category : Medical
ISBN : 9789814267519
Covering the fundamental and practical aspects of the processes of thermodynamics as well as experimental and theoretical methods used in the field, this informed examination highlights how the development of thermodynamics has been essentially based on the potentials of cryogenic technology. Penned by leading scientists with strong experience in the field who predict that many useful and exciting phenomena remain to be discovered in the future, this well-researched educational resource contains both a history of and practical recommendations for the ongoing study of matter at low temperature.
Author : David Warren Ball
Publisher : Unknown
Page : 670 pages
File Size : 54,5 Mb
Release : 1988
Category : Science
ISBN : UOM:39015018128754
Author : Darryl W. Ochsner,David Warren Ball,Zakya H. Kafafi
Publisher : Unknown
Page : 223 pages
File Size : 54,6 Mb
Release : 1998
Category : Matrix isolation spectroscopy
ISBN : OCLC:42696913
Author : Jaan Laane
Publisher : Elsevier
Page : 788 pages
File Size : 46,7 Mb
Release : 2017-11-13
Category : Science
ISBN : 9780128112212
Frontiers and Advances in Molecular Spectroscopy once again brings together the most eminent scientists from around the world to describe their work at the cutting-edge of molecular spectroscopy. Much of what we know about atoms, molecules and the nature of matter has been obtained using spectroscopy over the last one hundred years or so. Going far beyond the topics discussed in Jaan Laane’s earlier book on the subject, these chapters describe new methodologies and applications, instrumental developments and theory, which are taking spectroscopy into still new frontiers. The robust range of topics once again demonstrates the wide utility of spectroscopic techniques. New topics include ultrafast spectroscopy of the transition state, SERS/far-uv spectroscopy, femtosecond coherent anti-Stokes Raman spectroscopy, high-resolution laser induced fluorescence spectroscopy, Raman spectroscopy and biosensors, vibrational optical activity, ultrafast two-dimensional spectroscopy, biology with x-ray lasers, isomerization dynamics and hydrogen bonding, single molecule imaging, spectra of intermediates, matrix isolation spectroscopy and more. Covers spectroscopic investigations on the cutting edge of science Written and edited by leading experts in their respective fields Allows researchers to access a broad range of essential modern spectroscopy content from a single source rather than wading through hundreds of scattered journal articles
Author : Eric Stephen Ball
Publisher : Unknown
Page : 182 pages
File Size : 45,8 Mb
Release : 2000
Category : Electronic
ISBN : WISC:89075849679
Author : Harry Evans Hallam
Publisher : Wiley-Interscience
Page : 464 pages
File Size : 40,5 Mb
Release : 1973
Category : Science
ISBN : UCAL:B5012493
Author : Steven Anderson Clarke
Publisher : Unknown
Page : 378 pages
File Size : 53,8 Mb
Release : 2000
Category : Electronic
ISBN : UOM:39015047536142
Author : Anonim
Publisher : Unknown
Page : 0 pages
File Size : 46,9 Mb
Release : 1975
Category : Electronic
ISBN : OCLC:1414747980
Author : Rui Fausto
Publisher : Springer Science & Business Media
Page : 622 pages
File Size : 52,5 Mb
Release : 2013-11-11
Category : Science
ISBN : 9789400902817
Molecular spectroscopy has achieved rapid and significant progress in recent years, the low temperature techniques in particular having proved very useful for the study of reactive species, phase transitions, molecular clusters and crystals, superconductors and semiconductors, biochemical systems, astrophysical problems, etc. The widening range of applications has been accompanied by significant improvements in experimental methods, and low temperature molecular spectroscopy has been revealed as the best technique, in many cases, to establish the connection between experiment and theoretical calculations. This, in turn, has led to a rapidly increasing ability to predict molecular spectroscopic properties. The combination of an advanced tutorial standpoint with an emphasis on recent advances and new perspectives in both experimental and theoretical molecular spectroscopy contained in this book offers the reader insight into a wide range of techniques, particular emphasis being given to supersonic jet and matrix isolation techniques, spectroscopy in cryogenic solutions (including liquid noble gases), and in both crystalline and amorphous states. Suitable quantum chemical methods are also considered, as are empirically based force field methods for calculating spectra of large molecular systems. The wide range of topics covered includes: molecular dynamics and reactivity, time-resolved and high-resolution spectroscopy, conformational analysis, hydrogen bonding and solvent effects, structure and dynamics of weakly bound complexes, transition metal and organic photochemistry, spectroscopy of excited states, ab initio prediction of molecular spectra, and biochemical and astrophysical applications.
