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Author : Ian R. Dunkin
Publisher : Unknown
Page : 0 pages
File Size : 41,6 Mb
Release : 1998
Category : Matrix isolation spectroscopy
ISBN : OCLC:1392387729
Author : Stephen Cradock,A. J. Hinchcliffe
Publisher : CUP Archive
Page : 160 pages
File Size : 53,6 Mb
Release : 1975-10-09
Category : Science
ISBN : 0521207592
This 1975 book shows how and why matrix isolation developed and describes the necessary apparatus.
Author : Lester Andrews,Martin Moskovits
Publisher : Unknown
Page : 448 pages
File Size : 47,5 Mb
Release : 1989
Category : Science
ISBN : UOM:39015016086616
Matrix-isolation spectroscopy, as a technique for studying unstable species, has had tremendous lasting powers. Since 1954, matrix-isolation has been able to assimilate new technology rather than being replaced by it. The matrix-isolation technique for producing and trapping new chemical species has been applied to an ever increasing range of chemical and physical problems since its inception. The last 12 years have seen a substantial number of new developments and applications of the matrix technique. The chapters in this book describe many of the contributions of matrix-isolation spectroscopy to chemistry and physics in the last decade, and as such predict the continued evolution of this technique over the next decade. Experimental techniques are generally closely related to the development of new apparatus, and each chapter has a section describing innovations in instrumentation such as the closed-cycle cryogenic cooler that has revolutionized the technique. In addition, each chapter describes many of the specialized methods used to prepare, trap and study particular new subject species. The volume will be an indispensable reference source for graduate students and other scientists new to this field, as well as chemists and physicists already involved in applied spectroscopy.
Author : John Dickson Baldeschwieler
Publisher : Unknown
Page : 472 pages
File Size : 49,7 Mb
Release : 1959
Category : Low temperature research
ISBN : UCAL:C2862556
Author : A. Barnes,W.J. Orville-Thomas,R. Gaufrès,Achim Müller
Publisher : Springer Science & Business Media
Page : 602 pages
File Size : 52,5 Mb
Release : 2012-12-06
Category : Science
ISBN : 9789400985407
The matrix isolation (MI) method has now been used for nearly thirty years. During this period it has been actively developed and the range of problems tackled greatly extended. Originally it was used for studies of transient species involv ing vibrational, electronic and ESR spectroscopy. Nowadays the study of transient species forms a comparatively small part of HI work since it has been amply demonstrated that very fruitful information can be obtained of the structure and interactions of stable molecules and their aggregates. In addition to the s~ectroscopic methods mentioned above the MI technique is nowadays a standard method in research based on vibrational relaxation, luminescence, Mossbauer, magnetic circular dichroism, pulsed NMR and photoelectron spectroscopy. The matrix isolation technique affords considerable advantages over more conventional methods in most applications of spectroscopy. Areas where the technique has been widely applied, or shows great potential, include: metal atom chemistry, and its relation to surface chemistry, high temperature inorganic species, transition metal complexes, interstellar species, free radicals and unstable molecules, conformational studies, molecular com plexes, and intermolecular forces.
Author : Ian R. Dunkin
Publisher : Oxford University Press on Demand
Page : 242 pages
File Size : 43,9 Mb
Release : 1998
Category : Language Arts & Disciplines
ISBN : 0198558635
Matrix isolation is a technique for trapping reactive species at very low temperatures and studying them spectroscopically. This book offers detailed practical advice on how to carry out matrix-isolation experiments, and is a unique introduction to the subject. Chapter 1 introduces a briefhistorical survey of the development of the technique that incorporates a discussion of its strength and limitations. Chapter 2 provides a thorough description of the building of a matrix-isolation laboratory from scratch. All the necessary equipment is described in full and there are diagrammaticexamples throughout. In later chapters, ancillary equipment for generating reactive species, and an informative description of the various methods for forming low-temperature matrices are dealt with. There then follows a chapter on the specialized technique of matrix photochemistry with polarizedlight. The final chapter comprises an extensive collection of classic matrix experiments which have been selected due to their ease of application and which will thus serve as useful exercises for testing new pieces of equipment. This accessible text offers thorough coverage of the topic and willbe invaluable to postgraduate and industrial chemists as an introduction to matrix isolation techniques. Researchers in chemistry and related fields who are considering whether matrix isolation can play a part in their own research will also find this book useful.
Author : Anonim
Publisher : Unknown
Page : 0 pages
File Size : 44,9 Mb
Release : 1975
Category : Electronic
ISBN : OCLC:1414747980
Author : Andrei A. Vigasin,Zden?k Slanina
Publisher : World Scientific
Page : 296 pages
File Size : 53,9 Mb
Release : 1998
Category : Science
ISBN : 981023211X
This book introduces systematically the concept of weakly-bound complexes into the broad field of atmospheric sciences. To fill up the gap between our rapidly expanding knowledge of the individual properties of Van der Waals and hydrogen-bonded molecules, and our understanding of their role in the atmospheric processes, an ensemble of related topics are covered by a team of expert co-authors. The general properties of the weakly bound molecular complexes (or ?clusters?) are discussed, as well as their distribution in the planetary atmospheres. Collision-induced and dimeric absorption and emission are considered in the context of atmospheric spectroscopy. The advanced experimental techniques which enable us to study the spectroscopic features of molecular complexes in the gas phase, or which are adsorbed, are reviewed. The role of molecular complexes in the cometary atmosphere, the Earth mesosphere, and the atmospheres of the giant planets and some of their satellites are also discussed in detail.
Author : John R. Ferraro,Louis J. Basile
Publisher : Elsevier
Page : 321 pages
File Size : 45,6 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323140171
Fourier Transform Infrared Spectroscopy: Applications to Chemical Systems presents the chemical applications of the Fourier transform interferometry (FT-IR). The book contains discussions on the applications of FT-IR in the fields of chromatography FT-IR, polymers and biological macromolecules, emission spectroscopy, matrix isolation, high-pressure interferometry, and far infrared interferometry. The final chapter is devoted to the presentation of the use of FT-IR in solving national technical problems such as air pollution, space exploration, and energy related subjects. Research and analytical chemists will find the book insightful.
Author : Rui Fausto
Publisher : Springer Science & Business Media
Page : 622 pages
File Size : 41,8 Mb
Release : 2013-11-11
Category : Science
ISBN : 9789400902817
Molecular spectroscopy has achieved rapid and significant progress in recent years, the low temperature techniques in particular having proved very useful for the study of reactive species, phase transitions, molecular clusters and crystals, superconductors and semiconductors, biochemical systems, astrophysical problems, etc. The widening range of applications has been accompanied by significant improvements in experimental methods, and low temperature molecular spectroscopy has been revealed as the best technique, in many cases, to establish the connection between experiment and theoretical calculations. This, in turn, has led to a rapidly increasing ability to predict molecular spectroscopic properties. The combination of an advanced tutorial standpoint with an emphasis on recent advances and new perspectives in both experimental and theoretical molecular spectroscopy contained in this book offers the reader insight into a wide range of techniques, particular emphasis being given to supersonic jet and matrix isolation techniques, spectroscopy in cryogenic solutions (including liquid noble gases), and in both crystalline and amorphous states. Suitable quantum chemical methods are also considered, as are empirically based force field methods for calculating spectra of large molecular systems. The wide range of topics covered includes: molecular dynamics and reactivity, time-resolved and high-resolution spectroscopy, conformational analysis, hydrogen bonding and solvent effects, structure and dynamics of weakly bound complexes, transition metal and organic photochemistry, spectroscopy of excited states, ab initio prediction of molecular spectra, and biochemical and astrophysical applications.
Author : M. W. Roberts
Publisher : Royal Society of Chemistry
Page : 194 pages
File Size : 53,9 Mb
Release : 1978
Category : Solid state chemistry
ISBN : 9780851863108
Author : Anonim
Publisher : Unknown
Page : 800 pages
File Size : 51,8 Mb
Release : 1968
Category : Weights and measures
ISBN : STANFORD:36105130367332
Author : United States. National Bureau of Standards
Publisher : Unknown
Page : 788 pages
File Size : 48,5 Mb
Release : 1978
Category : Electronic
ISBN : OSU:32435028396430
Author : Anonim
Publisher : Unknown
Page : 1264 pages
File Size : 42,5 Mb
Release : 1967
Category : Aeronautics
ISBN : OSU:32435062863618
Author : Matthew John Almond,Anthony John Downs
Publisher : Unknown
Page : 552 pages
File Size : 50,7 Mb
Release : 1989-08-15
Category : Science
ISBN : UCAL:B4456375
Intended as a standard reference in the subject of matrix isolation spectroscopy. Leads the reader logically through experimental techniques, physical processes in matrices, photochemistry in matrices, low energy species and interconversions, high-energy species, atoms and small clusters, astrochemistry and atmospheric processes. Also, a unique feature is a detailed compilation of the results of matrix-isolation experiments in the decade of 1977-1986.