Metal Ions In Solution

Author : John Burgess
Publisher : Unknown
Page : 492 pages
File Size : 48,6 Mb
Release : 1978
Category : Science
ISBN : UOM:39015016008909

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Metal Ions in Solution by John Burgess Pdf

Author : Arthur E. Martell,Robert D. Hancock
Publisher : Springer Science & Business Media
Page : 259 pages
File Size : 48,9 Mb
Release : 2013-06-29
Category : Science
ISBN : 9781489914866

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Metal Complexes in Aqueous Solutions by Arthur E. Martell,Robert D. Hancock Pdf

Stability constants are fundamental to understanding the behavior of metal ions in aqueous solution. Such understanding is important in a wide variety of areas, such as metal ions in biology, biomedical applications, metal ions in the environment, extraction metallurgy, food chemistry, and metal ions in many industrial processes. In spite of this importance, it appears that many inorganic chemists have lost an appreciation for the importance of stability constants, and the thermodynamic aspects of complex formation, with attention focused over the last thirty years on newer areas, such as organometallic chemistry. This book is an attempt to show the richness of chemistry that can be revealed by stability constants, when measured as part of an overall strategy aimed at understanding the complexing properties of a particular ligand or metal ion. Thus, for example, there are numerous crystal structures of the Li+ ion with crown ethers. What do these indicate to us about the chemistry of Li+ with crown ethers? In fact, most of these crystal structures are in a sense misleading, in that the Li+ ion forms no complexes, or at best very weak complexes, with familiar crown ethers such as l2-crown-4, in any known solvent. Thus, without the stability constants, our understanding of the chemistry of a metal ion with any particular ligand must be regarded as incomplete. In this book we attempt to show how stability constants can reveal factors in ligand design which could not readily be deduced from any other physical technique.

Author : Paul L. Brown,Christian Ekberg
Publisher : John Wiley & Sons
Page : 954 pages
File Size : 43,5 Mb
Release : 2016-05-31
Category : Science
ISBN : 9783527330102

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Hydrolysis of Metal Ions by Paul L. Brown,Christian Ekberg Pdf

Filling the need for a comprehensive treatment that covers the theory, methods and the different types of metal ion complexes with water (hydrolysis), this handbook and ready reference is authored by a nuclear chemist from academia and an industrial geochemist. The book includes both cation and anion complexes, and approaches the topic of metal ion hydrolysis by first covering the background, before proceeding with an overview of the dissociation of water and then all different metal-water hydrolysis complexes and compounds. A must-have for scientists in academia and industry working on this interdisciplinary topic.

Author : David Raymond Williams
Publisher : Unknown
Page : 186 pages
File Size : 43,8 Mb
Release : 1971
Category : Medical
ISBN : MINN:31951P00706609U

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The Metals of Life by David Raymond Williams Pdf

Author : John P. Hunt
Publisher : Unknown
Page : 144 pages
File Size : 55,5 Mb
Release : 1963
Category : Ions
ISBN : UCSD:31822013370358

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Metal Ions in Aqueous Solution by John P. Hunt Pdf

Author : Helmut Sigel
Publisher : CRC Press
Page : 432 pages
File Size : 48,9 Mb
Release : 1984-09-12
Category : Science
ISBN : 0824775511

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Metal Ions in Biological Systems by Helmut Sigel Pdf

Author : Welby G. Courtney,Frederick R. Duke
Publisher : Unknown
Page : 54 pages
File Size : 50,8 Mb
Release : 1951
Category : Metal ions
ISBN : UOM:39015086503235

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Thermodynamic and Kinetic Properties of Metal Ions in Aqueous Solution by Welby G. Courtney,Frederick R. Duke Pdf

Author : Astrid Sigel,Helmut Sigel,Roland K. O. Sigel
Publisher : Springer
Page : 628 pages
File Size : 44,6 Mb
Release : 2016-02-09
Category : Science
ISBN : 9783319217567

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The Alkali Metal Ions: Their Role for Life by Astrid Sigel,Helmut Sigel,Roland K. O. Sigel Pdf

MILS-16 provides an up-to-date review of the impact of alkali metal ions on life. Their bioinorganic chemistry and analytical determination, the solid state structures of bio-ligand complexes and the properties of alkali metal ions in solution in the context of all kinds of biologically relevant ligands are covered, this includes proteins (enzymes) and nucleic acids (G-quadruplexes). Minerals containing sodium (Na+) and potassium (K+) are abundant in the Earth's crust, making Na+ and K+ easily available. In contrast, the alkali elements lithium (Li+), rubidium, and cesium are rare and the radioactive francium occurs only in traces. Since the intra- and extracellular, as well as the compartmental concentrations of Na+ and K+ differ significantly, homeostasis and active transport of these ions are important; this involves transporters/carriers and pore-forming ion channel proteins. Systems like Na+/K+-ATPases, H+/K+-ATPases or Na+/H+ antiporters are thoroughly discussed. The role of K+ in photosynthesis and the role of Na+ in charging the "battery of life" are pointed out. Also, the relationships between alkali metal ions and diseases (e.g., Parkinson or traumatic brain injury) are covered and the relevance of Li+ salts in medicine (pharmacology and mechanism) is reviewed. This and more is treated in an authoritative and timely manner in the 16 stimulating chapters of Volume 16, The Alkali Metal Ions: Their Role for Life, which are written by 44 internationally recognized experts from 12 nations. The impact of this vibrant research area is manifested in nearly 3000 references, over 30 tables and more than 150 illustrations (two thirds in color). MILS-16 also provides excellent information for teaching. Astrid Sigel, Helmut Sigel, and Roland K. O. Sigel have long-standing interests in Biological Inorganic Chemistry. Their research focuses on metal ion interactions with nucleotides and nucleic acids and on related topics. They edited previously 44 volumes in the series Metal Ions in Biological Systems.

Author : Astrid Sigel,Helmut Sigel
Publisher : CRC Press
Page : 860 pages
File Size : 47,9 Mb
Release : 1996-02-05
Category : Science
ISBN : 0824795490

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Metal Ions in Biological Systems by Astrid Sigel,Helmut Sigel Pdf

Volume 32 covers metal ion bonding to phosphate, sugar and nucleobase residues; the ambidentate as well as the stacking properties of nucleotides; kinetic aspects as well as properties of nucleobase and nucleotide analogs; and the oligonucleotides and nucleic acids. It examines electron transfer reactions over a large number of base repairs in DNA, the role of metal ions in ribozymes, ternary metal-nucleic acid base-protein complexes, metal responsive gene regulation, and the structure-activity relationships of anticancer drugs and their action on DNA, including cisplatin and the role of proteins.

Author : Sotira Yiacoumi,Chi Tien
Publisher : Springer Science & Business Media
Page : 239 pages
File Size : 45,5 Mb
Release : 2013-11-27
Category : Science
ISBN : 9781461523192

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Kinetics of Metal Ion Adsorption from Aqueous Solutions by Sotira Yiacoumi,Chi Tien Pdf

This monograph is intended to provide a systematic presentation of theories concerning the adsorption of metal ions from aqueous solutions onto surfaces of natural and synthetic substances and to outline methods and procedures to estimate the extent and progress ofadsorption. As heavy metals and the problems associated with their transport and distribution are of serious concern to human health and the environment, the materials presented in this volume have both theoretical and practical significance. In writing this monograph, one ofour goals was to prepare a book useful to environmental workers and practicing engineers. For this reason, our presentation relies heavily on concepts commonly used in the environmental engineering literature. In fact, the volume was prepared for readers with a basic understanding of environmental engineering principles and some knowledge of adsorption processes. No prior familiarity with the ionic solute adsorption at solid-solution interfaces is assumed. Instead, introduction of the necessary background information was included. Generally speaking, metal ion adsorption may be studied in terms of three distinct but interrelated phenomena: surface ionization, complex formation, and the formation and presence of an electrostatic double layer adjacent to adsorbent surfaces. Analyses of these phenomena with various degrees of sophistication are xviii ADSORPTION OF METAL IONS FROM AQUEOUS SOLUTIONS presented, and their various combinations yield different models that describe metal ion adsorption.

Author : Helmut Sigel
Publisher : CRC Press
Page : 416 pages
File Size : 55,5 Mb
Release : 1986-02-21
Category : Science
ISBN : 0824775406

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Metal Ions in Biological Systems by Helmut Sigel Pdf

Metal Ions in Biological Systems is devoted to increasing our understanding of the relationship between the chemistry of metals and life processes. The volumes reflect the interdisciplinary nature of bioinorganic chemistry and coordinate the efforts of researchers in the fields of biochemistry, inorganic chemistry, coordination chemistry, environmental chemistry, biophysics, pharmacy, and medicine. Volumes deal with such topics as the formation, stability, structure, and reactivity of biological compounds of low and high molecular weight containing metal ions; the metabolism and transport of metal ions and their complexes; and new models of complicated natural structures and processes. Volume 21 describes the underlying theories of nuclear magnetic resonance (NMR), promoting a wider use of NMR in studies of paramagnetic species. In six concise chapters by leading international authorities, Applications of Nuclear Magnetic Resonance to Paramagnetic Species outlines the most recent developments regarding the use of nuclear relaxation as a source for structural information ... examines studies of magnetically coupled metalloproteins and metal-porphyrin induced dipolar shifts for conformational analysis ... and evaluates the potential of paramagnetic ions as agents for enhancing NMR image contrast. With over 500 references that facilitate further research, Applications of Nuclear Magnetic Resonance to Paramagnetic Species is an essential resource for scientists and students in such disciplines as biophysics; bioinorganic, inorganic, and coordination chemistry; biochemistry; molecular biology; and enzymology. Book jacket.

Author : Astrid Sigel
Publisher : Routledge
Page : 848 pages
File Size : 51,5 Mb
Release : 2018-05-04
Category : Science
ISBN : 9781351432146

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Metal Ions in Biological Systems by Astrid Sigel Pdf

Continues the tradition of excellence established in previous volumes in this acclaimed series. Volume 36 focuses on the vibrant research area concerning the interrelation between free radicals and metal ions and their resulting effects on life processes; it offers an authoritative and timely account of this fascinating area of research in 21 chapters.

Author : Bruce Averill,Patricia Eldredge
Publisher : Unknown
Page : 1233 pages
File Size : 44,5 Mb
Release : 2007
Category : Chemistry
ISBN : 0321413709

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Chemistry by Bruce Averill,Patricia Eldredge Pdf

Emphasises on contemporary applications and an intuitive problem-solving approach that helps students discover the exciting potential of chemical science. This book incorporates fresh applications from the three major areas of modern research: materials, environmental chemistry, and biological science.

Author : Astrid Sigel,Helmut Sigel
Publisher : CRC Press
Page : 736 pages
File Size : 46,6 Mb
Release : 1996-02-29
Category : Science
ISBN : 0824796888

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Metal Ions in Biological Systems by Astrid Sigel,Helmut Sigel Pdf

"Volume 33 focuses on the vibrant research area of probing nucleic acids--the carriers of the genetic code--by metal ion complexes of small molecules providing an authoritative, timely account of this fascinating topic by over 50 distinguished experts."

Author : J Burgess
Publisher : Elsevier
Page : 232 pages
File Size : 45,8 Mb
Release : 1999-10-01
Category : Science
ISBN : 9781782420569

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Ions in Solution by J Burgess Pdf

This outline of the principles and chemical interactions in inorganic solution chemistry delivers a course module in an area of considerable complexity. Problems with solutions and tutorial hints to test comprehension have been added as a feature to check readers' understanding and assist self-study. Exercises and projects are also provided to help readers deepen and extend their knowledge and understanding. Inorganic solution chemistry is treated thoroughly Emphasis is placed upon NMR, UV-VIS, IR Raman spectroscopy, X-ray diffraction, and such topics as acid-base behaviour, stability constants and kinetics