Modern Supramolecular Gold Chemistry

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Modern Supramolecular Gold Chemistry

Author : Antonio Laguna
Publisher : John Wiley & Sons
Page : 525 pages
File Size : 47,9 Mb
Release : 2008-09-26
Category : Science
ISBN : 9783527623761

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Modern Supramolecular Gold Chemistry by Antonio Laguna Pdf

Filling a gap in our systematic knowledge of gold, this monograph covers the fundamental aspects, while also considering new applications of gold compounds in catalysis, as nanoparticles, and their potential application as luminescent compounds. Written by an eminent team of authors from academia, the book analyzes the current status of gold chemistry, its special characteristics, oxidation states and main type of complexes, before going on to look at the synthesis of supramolecular aggregates due to the formation of gold-gold, gold-metal interactions or other secondary bonds. Final sections deal with LEDs, solvoluminescent and electroluminescent materials, liquid crystals and catalysis. While of interest to advanced chemistry students, this book is also useful for researchers interested in the chemistry of gold and its applications, as well as those involved in metal-metal interactions, heteronuclear chemistry or in the optical properties of coordination compounds.

The Chemistry of Organogold Compounds, 2 Volume Set

Author : Zvi Rappoport,Ilan Marek,Joel F. Liebman
Publisher : John Wiley & Sons
Page : 1158 pages
File Size : 52,6 Mb
Release : 2015-04-20
Category : Science
ISBN : 9781118438732

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The Chemistry of Organogold Compounds, 2 Volume Set by Zvi Rappoport,Ilan Marek,Joel F. Liebman Pdf

The first book in the PATAI Series was published in 1964 and the Series will celebrate its 50th Anniversary in 2014. This "Golden Jubilee" is accompanied by the publication of the first volume on the chemistry of organogold. In the history of the PATAI Series there was, so far, no volume dedicated to gold alone. In 1999 we published a volume on The Chemistry of Gold and Silver Compounds. Since then a lot of new chemistry using gold has been developed and it is timely to focus a volume on methods and applications of organogold compounds in organic synthesis, reflecting the enormous progress which has been made in the use of gold compounds as reagents and catalysts. A second area of great importance covered in the book is the use of gold surfaces in the synthesis of peptides, proteins and other natural products. A whole range of applications in the area of biochemistry has resulted from these developments. A third area of interest is the synthesis and engineering of nanostructures, where organogold chemistry has opened the door for a wide range of methods and applications in the field of nanoscience and materials science. As with all new volumes, the chapters are first published online in Patai's Chemistry of Functional Groups. Once a volume is completed online, it is then published in print format. The printed book offers the traditional quality of the Patai Book Series, complete with an extensive index.

Gold Chemistry

Author : Mohr
Publisher : John Wiley & Sons
Page : 424 pages
File Size : 41,7 Mb
Release : 2009-03-12
Category : Science
ISBN : 9783527626731

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Gold Chemistry by Mohr Pdf

Written by world-class authors, this most recent major book on the topic highlights new and current trends as well as future directions. It is comprehensive in its scope, covering all aspects of gold chemistry -- from homogeneous to heterogeneous catalysis, from supramolecular assemblies to sensors and medicinal applications. The result is an invaluable work for both organic and inorganic chemists working in universities and industry, as well as material scientists.

Supramolecular Catalysis

Author : Piet W. N. M. van Leeuwen
Publisher : John Wiley & Sons
Page : 318 pages
File Size : 42,6 Mb
Release : 2008-06-25
Category : Science
ISBN : 9783527621798

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Supramolecular Catalysis by Piet W. N. M. van Leeuwen Pdf

In the past few years, supramolecular chemistry has led to new approaches in homogeneous catalysis. While host-guest chemistry had already found applications in catalysis as a result of the pioneering work carried out by Professor Ronald Breslow and Nobel prizewinner Professor Jean-Marie Lehn that began some 40 years ago, the construction of catalysts by supramolecular forces has only recently become a powerful tool. This development paves the way for large numbers of new potential catalysts that can be varied in an expedient way by changing the constituting building blocks. Written by some of the leading contributors in the field, this book is intended for both industrial and academic chemists with an interest in this area of catalysis. With its discussion of topics from ligand libraries to chirality-directed self-assembly, this is a must-have for chemists with organic, catalytic and polymer backgrounds, as well as those employing such compounds in industrial processes.

Modern Gold Catalyzed Synthesis

Author : A. Stephen K. Hashmi,F. Dean Toste
Publisher : John Wiley & Sons
Page : 419 pages
File Size : 40,8 Mb
Release : 2012-04-06
Category : Science
ISBN : 9783527646883

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Modern Gold Catalyzed Synthesis by A. Stephen K. Hashmi,F. Dean Toste Pdf

With its impressive features, gold has led to completely new reaction types in recent years, which in turn have strongly influenced both organic catalysis and material science. Other fields where a significant amount of new results has been obtained include nanotechnology, self assembly/supramolecular systems and biochemical/medicinal chemistry. As a result, gold is one of the hottest topics in catalysis at the moment, with an increasing amount of research being carried out in this field. While focusing on homogeneous catalysis, this monograph also covers the main applications in heterogeneous catalysis. Following a look at the gold-catalyzed addition of heteroatom nucleophiles to alkynes, it goes on to discuss gold-catalyzed additions to allenes and alkenes, gold-catalyzed benzannulations, cycloisomerization and rearrangement reactions, as well as oxidation and reduction reactions. The whole is finished off with a section on gold-catalyzed aldol and related reactions and the application of gold-catalyzed reactions to natural product synthesis. Of interest to synthetic chemists and inorganic chemists, as well as organic chemists working in homogeneous catalysis, physical and technical chemists.

Gold Chemistry

Author : Fabian Mohr
Publisher : John Wiley & Sons
Page : 425 pages
File Size : 52,5 Mb
Release : 2009-04-20
Category : Science
ISBN : 9783527320868

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Gold Chemistry by Fabian Mohr Pdf

Written by world-class authors, this most recent major book on the topic highlights new and current trends as well as future directions. It is comprehensive in its scope, covering all aspects of gold chemistry -- from homogeneous to heterogeneous catalysis, from supramolecular assemblies to sensors and medicinal applications. The result is an invaluable work for both organic and inorganic chemists working in universities and industry, as well as material scientists.

Modern Gold Catalyzed Synthesis

Author : A. Stephen K. Hashmi,F. Dean Toste
Publisher : John Wiley & Sons
Page : 419 pages
File Size : 41,5 Mb
Release : 2012-05-21
Category : Science
ISBN : 9783527319527

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Modern Gold Catalyzed Synthesis by A. Stephen K. Hashmi,F. Dean Toste Pdf

With its impressive features, gold has led to completely new reaction types in recent years, which in turn have strongly influenced both organic catalysis and material science. Other fields where a significant amount of new results has been obtained include nanotechnology, self assembly/supramolecular systems and biochemical/medicinal chemistry. As a result, gold is one of the hottest topics in catalysis at the moment, with an increasing amount of research being carried out in this field. While focusing on homogeneous catalysis, this monograph also covers the main applications in heterogeneous catalysis. Following a look at the gold-catalyzed addition of heteroatom nucleophiles to alkynes, it goes on to discuss gold-catalyzed additions to allenes and alkenes, gold-catalyzed benzannulations, cycloisomerization and rearrangement reactions, as well as oxidation and reduction reactions. The whole is finished off with a section on gold-catalyzed aldol and related reactions and the application of gold-catalyzed reactions to natural product synthesis. Of interest to synthetic chemists and inorganic chemists, as well as organic chemists working in homogeneous catalysis, physical and technical chemists.

Gold and its Complexes in Anticancer Chemotherapy

Author : Mohmmad Younus Wani,Manzoor Ahmad Malik
Publisher : Springer Nature
Page : 173 pages
File Size : 42,9 Mb
Release : 2021-02-11
Category : Medical
ISBN : 9789813363144

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Gold and its Complexes in Anticancer Chemotherapy by Mohmmad Younus Wani,Manzoor Ahmad Malik Pdf

This book presents an overview of cancer and the genesis, and development of different treatment strategies and modalities against cancer. The emergence of gold and its complexes as promising anticancer chemotherapeutic agents have the potential to substitute or replace the platinum based chemotherapeutic agents. Gold complexes have demonstrated considerable anti-proliferative properties, chiefly attributed to their anti-mitochondrial effects, they make gold complexes excellent candidates as anti-cancer agents compared to their platinum-based counterparts. This book provides a critical review of recent advances made in the development of gold complexes as anti-cancer agents. In this context, it examines a number of different ligand architectures, provides comprehensive information on gold complexes’ mechanism of action and toxicity issues and, in closing, outlines future research directions.

Terpyridine-based Materials

Author : Ulrich S. Schubert,Andreas Winter,George R. Newkome
Publisher : John Wiley & Sons
Page : 562 pages
File Size : 54,5 Mb
Release : 2012-09-25
Category : Technology & Engineering
ISBN : 9783527639632

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Terpyridine-based Materials by Ulrich S. Schubert,Andreas Winter,George R. Newkome Pdf

In recent years, the utilization of terpyridines both in macromolecular structure assembly and device chemistry has exploded, enabling, for example, supramolecular polymer architectures with switchable chemical and physical properties as well as novel functional materials for optoelectronic applications such as light-emitting diodes and solar cells. Further applications include the usage of terpyridines and their metal complexes as catalysts for asymmetric organic reactions and, in a biological context, as anti-tumor agents or biolabels. This book covers terpyridine-based materials topics ranging from syntheses, chemistry, and multinuclear metal complexes, right up to functionalized polymers, 3D-architectures, and surfaces. Aimed at materials scientists, (in)organic chemists, polymer chemists, complex chemists, physical chemists, biochemists, and libraries.

Homogeneous Gold Catalysis

Author : LeGrande M. Slaughter
Publisher : Springer
Page : 288 pages
File Size : 40,6 Mb
Release : 2015-03-30
Category : Science
ISBN : 9783319137223

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Homogeneous Gold Catalysis by LeGrande M. Slaughter Pdf

The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students.

Novel Luminescent Crystalline Materials of Gold(I) Complexes with Stimuli-Responsive Properties

Author : Mingoo Jin
Publisher : Springer Nature
Page : 200 pages
File Size : 47,5 Mb
Release : 2020-04-18
Category : Science
ISBN : 9789811540639

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Novel Luminescent Crystalline Materials of Gold(I) Complexes with Stimuli-Responsive Properties by Mingoo Jin Pdf

This book highlights and investigates novel solid-state luminescent properties of crystals with stimuli-responsive behavior. Several novel molecular designs for controlling crystal structures with photo-physical properties are described, with a special focus on external stimuli-responsive properties. The major goal of the material design concept was to capitalize on the chirality of crystals with stimuli-responsive properties. To allow crystals’ chirality to be controlled and modified by means of external stimulation, the axial chirality of biaryl moiety was employed and, interestingly, produced several novel mechano- and vapo-responsive luminescent properties based on crystal-to-crystal or single-crystal-to-single-crystal phase transitions. In addition, the book details how the molecular rotation of luminophores in the solid phase can be used to achieve corresponding thermal-responsive phosphorescence. The reports presented here illustrate how the author has succeeded in controlling structural factors in a bulk environment by using molecular design with linking to photo-physical properties. The content will be of great interest to researchers in the field, and to members of chemical and material science societies.

Molecular Metal-Metal Bonds

Author : Stephen T. Liddle
Publisher : John Wiley & Sons
Page : 592 pages
File Size : 53,8 Mb
Release : 2016-03-16
Category : Science
ISBN : 9783527673384

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Molecular Metal-Metal Bonds by Stephen T. Liddle Pdf

Systematically covering all the latest developments in the field, this is a comprehensive and handy introduction to metal-metal bonding. The chapters follow a uniform, coherent structure for a clear overview, allowing readers easy access to the information. The text covers such topics as synthesis, properties, structures, notable features, reactivity and examples of applications of the most important compounds in each group with metal-metal bonding throughout the periodic table. With its general remarks at the beginning of each chapter, this is a must-have reference for all molecular inorganic chemists, including PhD students and postdocs, as well as more experienced researchers.

Encyclopedia of Supramolecular Chemistry

Author : J. L. Atwood,Jonathan W. Steed
Publisher : CRC Press
Page : 1022 pages
File Size : 48,6 Mb
Release : 2004
Category : Science
ISBN : 0824747232

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Encyclopedia of Supramolecular Chemistry by J. L. Atwood,Jonathan W. Steed Pdf

Crystallizing a rapidly expanding interdisciplinary field and one of the most popular and newsworthy areas in contemporary chemistry, this two-volume encyclopaedia offers authoritative information with user-friendly and high-quality articles.

Smart Multifunctional Nano-inks

Author : Ram K. Gupta,Tuan Anh Nguyen
Publisher : Elsevier
Page : 728 pages
File Size : 55,6 Mb
Release : 2022-10-26
Category : Technology & Engineering
ISBN : 9780323984959

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Smart Multifunctional Nano-inks by Ram K. Gupta,Tuan Anh Nguyen Pdf

Smart Multifunctional Nano-inks: Fundamentals and Emerging Applications covers nano-inks and how they can be used in inkjet printers for printing complex circuitry on flexible substrates or as a paste for 3D printers. Microstructures can be 3D-printed using nano-inks in a combination of high-resolution plasma printing and subsequent rotogravure printing. In addition, smart multifunctional nano-inks are not only required for the electronic, but also in other applications, such as for secure inks, for currency, and in immigration documents. This book focuses on fundamental design concepts, promising applications, and future challenges of nano-inks in various areas, such as optoelectronics, energy, security and biomedical fields. The current challenge for the successful industrial application of nano-inks is in the preparation of a stable dispersion of advanced materials for nano-inks. The functionalization, synthesizing, and theoretical modeling provide the solution for most of the current issues, but there are still remaining challenges which are covered in this comprehensive resource. Outlines the major nanomaterials used in the manufacture of smart nano-inks Provides information on the major industrial applications of nano-inks Assesses the major challenges of using nano-inks in a cost-effective way, and on an industrial scale

Anti-Cancer N-Heterocyclic Carbene Complexes of Gold(III), Gold(I) and Platinum(II)

Author : Taotao Zou
Publisher : Springer
Page : 164 pages
File Size : 48,8 Mb
Release : 2016-02-19
Category : Science
ISBN : 9789811006579

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Anti-Cancer N-Heterocyclic Carbene Complexes of Gold(III), Gold(I) and Platinum(II) by Taotao Zou Pdf

This thesis focuses on the development of gold- and non-classical platinum-based anti-cancer agents that display distinctively different anti-cancer mechanisms compared to the commonly used cisplatin. These metal complexes contain N-heterocyclic carbene (NHC) ligands which are able to form strong M-C(NHC) bonds, conferring high stability and favorable lipophilicity, reactivity and binding specificity of metal complexes on biomolecules. The author demonstrates significant advances made in anti-cancer gold(III), gold(I) and platinum(II) complexes. Detailed chemical synthesis, in vitro and/or in vivo anti-cancer activities are clearly presented including: (i) a class of Au(III) complexes containing a highly fluorescent N^N^N ligand and NHC ligand that simultaneously act as fluorescent thiol “switch-on” probes and anti-cancer agents; (ii) a dinuclear gold(I) complex with a mixed diphosphine and bis(NHC) ligand displaying favorable stability and showing significant inhibition of tumor growth in two independent mice models with no observable side effects; and (iii) a panel of stable luminescent cyclometalated platinum(II) complexes exhibiting high specificity to localize to the endoplasmic reticulum (ER) domain, inducing ER stress and cell apoptosis. These works highlight the clinical potential that gold and platinum complexes offer for cancer treatment.