Molecular Magnets Recent Highlights

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Molecular Magnets Recent Highlights

Author : Wolfgang Linert,Michel Verdaguer
Publisher : Springer Science & Business Media
Page : 222 pages
File Size : 46,7 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783709160183

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Molecular Magnets Recent Highlights by Wolfgang Linert,Michel Verdaguer Pdf

The book deals with recent scientific highlights on molecular magnetism in Europe. Molecular magnetism is a new interdisciplinary discipline gathering together chemists and physicists, theoreticians and experimentalists. The book intends to provide the reader with documented answers to many current questions: How can chemists use soft conditions to transform molecules in light and transparent magnets. How does a molecular system can behave as a single molecule magnet. How to combine several functions in the same molecular system. How light can be used to switch molecular magnetic properties. How can molecules be used for ultimate high density information storage or in quantum computing. What kind of methods do physicists develop and use to explore these new properties of matter. What kind of concepts and calculations can be provided for theoreticians to design new objects and to better understand the field and to enlarge its exciting developments.

Comprehensive Inorganic Chemistry II

Author : Anonim
Publisher : Newnes
Page : 7694 pages
File Size : 46,7 Mb
Release : 2013-07-23
Category : Science
ISBN : 9780080965291

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Comprehensive Inorganic Chemistry II by Anonim Pdf

Comprehensive Inorganic Chemistry II, Nine Volume Set reviews and examines topics of relevance to today’s inorganic chemists. Covering more interdisciplinary and high impact areas, Comprehensive Inorganic Chemistry II includes biological inorganic chemistry, solid state chemistry, materials chemistry, and nanoscience. The work is designed to follow on, with a different viewpoint and format, from our 1973 work, Comprehensive Inorganic Chemistry, edited by Bailar, Emeléus, Nyholm, and Trotman-Dickenson, which has received over 2,000 citations. The new work will also complement other recent Elsevier works in this area, Comprehensive Coordination Chemistry and Comprehensive Organometallic Chemistry, to form a trio of works covering the whole of modern inorganic chemistry. Chapters are designed to provide a valuable, long-standing scientific resource for both advanced students new to an area and researchers who need further background or answers to a particular problem on the elements, their compounds, or applications. Chapters are written by teams of leading experts, under the guidance of the Volume Editors and the Editors-in-Chief. The articles are written at a level that allows undergraduate students to understand the material, while providing active researchers with a ready reference resource for information in the field. The chapters will not provide basic data on the elements, which is available from many sources (and the original work), but instead concentrate on applications of the elements and their compounds. Provides a comprehensive review which serves to put many advances in perspective and allows the reader to make connections to related fields, such as: biological inorganic chemistry, materials chemistry, solid state chemistry and nanoscience Inorganic chemistry is rapidly developing, which brings about the need for a reference resource such as this that summarise recent developments and simultaneously provide background information Forms the new definitive source for researchers interested in elements and their applications; completely replacing the highly cited first edition, which published in 1973

World Scientific Reference On Spin In Organics (In 4 Volumes)

Author : Vardeny Zeev Valy,Wohlgenannt Markus
Publisher : World Scientific
Page : 1368 pages
File Size : 55,8 Mb
Release : 2012-08-23
Category : Technology & Engineering
ISBN : 9789813230163

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World Scientific Reference On Spin In Organics (In 4 Volumes) by Vardeny Zeev Valy,Wohlgenannt Markus Pdf

"This series summarizes the field of Organic Spintronics up to 2017. It contains four volumes dedicated to spin injection, spin transport, spin pumping, organic magnetic field effect, and molecular spintronics. The field of Organic Spintronics has accelerated and matured in the last dozen years with the realization of an organic spin-valve (in 2004) and magneto-resistance and magneto-electroluminescence in organic optoelectronic devices (2006). The book series is comprehensive in that it summarizes all aspects of Organic Spintronics to date. The first two volumes deal with spin injection, spin transport, spin manipulation and spin pumping into organic semiconductors. The main device that is thoroughly discussed here is the organic spin-valve, where spinterface states at the interface between the organic semiconductor and the ferromagnetic (FM) electrode has been the focus of many chapters. An interesting emerging subject is the role of chirality in the organic layer of the device. A relatively new method of achieving spin aligned carriers in organic semiconductors is spin pumping, where magnons in the FM substrate generate spin aligned carriers in the organic layer at the FM/organic interface. The third volume deals mainly with magnetic field effect in organic devices. Several spin-mixture processes that lead to magnetic field effect in devices and films are thoroughly discussed, such as hyperfine interaction, direct spin-orbit coupling, indirect spin-orbit coupling via [delta]g, triplet-triplet annihilation, and thermal spin alignment. The similarity between the magnetic field effect obtained in optoelectronic devices based on organic semiconductors and the novel hybrid organic-inorganic semiconductors is also a subject of intense interest. The fourth volume deals with spin in molecular films and devices. It includes thorough discussion of spin exchange interaction that leads to organic ferromagnets, as well as manifestation of various spin interactions in thin molecular films and devices."--

Organometallic Magnets

Author : Vadapalli Chandrasekhar,Fabrice Pointillart
Publisher : Springer Nature
Page : 422 pages
File Size : 44,5 Mb
Release : 2019-11-22
Category : Science
ISBN : 9783030260095

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Organometallic Magnets by Vadapalli Chandrasekhar,Fabrice Pointillart Pdf

This volume highlights the recent advances and state of art in the experimental and theoretical studies of organometallic magnets. A plethora of organic ligands such as Mannich-base derivatives, redox-active chromophores, cyanides, Schiff base among others are used to coordinate to 3d transition metals, 4f lanthanides and 5f actinides to design the molecular magnets. Deep analysis of the coordination sphere symmetry, electronic distribution, luminescence are investigated to perform magneto-structural correlation leading to a better understanding of the magnetic properties. Furthermore, the rationalization of the magnetic behavior can be reached using ab initio calculations. The multiple applications that these molecular magnets offer could revolutionize the high-density data storage, spintronics and quantum computing technologies. This volume provides a discussion of these topics from leading international experts and will be a useful reference for researchers working in this field.

Molecular Magnets

Author : Maria Bałanda,Magdalena Fitta
Publisher : MDPI
Page : 166 pages
File Size : 43,8 Mb
Release : 2019-03-19
Category : Science
ISBN : 9783038977100

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Molecular Magnets by Maria Bałanda,Magdalena Fitta Pdf

Molecular magnets show many properties not met in conventional metallic magnetic materials, i.e. low density, transparency to electromagnetic radiation, sensitivity to external stimuli such as light, pressure, temperature, chemical modification or magnetic/electric fields, and others. They can serve as “functional” materials in sensors of different types or be applied in high-density magnetic storage or nanoscale devices. Research into molecule-based materials became more intense at the end of the 20th century and is now an important branch of modern science. The articles in this Special Issue, written by physicists and chemists, reflect the current work on molecular magnets being carried out in several research centers. Theoretical papers in the issue concern the influence of spin anisotropy in the low dimensional lattice of the resulting type of magnet, as well as thermodynamics and magnetic excitations in spin trimers. The impact of external pressure on structural and magnetic properties and its underlying mechanisms is described using the example of Prussian blue analogue data. The other functionality discussed is the magnetocaloric effect, investigated in coordination polymers and high spin clusters. In this issue, new molecular magnets are presented: (i) ferromagnetic high-spin [Mn6] single-molecule magnets, (ii) solvatomagnetic compounds changing their structure and magnetism dependent on water content, and (iii) a family of purely organic magnetic materials. Finally, an advanced calorimetric study of anisotropy in magnetic molecular superconductors is reviewed.

Magnetism

Author : Joel S. Miller,Marc Drillon
Publisher : John Wiley & Sons
Page : 395 pages
File Size : 51,6 Mb
Release : 2006-03-06
Category : Science
ISBN : 9783527604500

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Magnetism by Joel S. Miller,Marc Drillon Pdf

Combining the contemporary knowledge from widely scattered sources, this is a much-needed and comprehensive overview of the field. In maintaining a balance between theory and experiment, the book guides both advanced students and specialists to this research area. Topical reviews written by the foremost scientists explain recent trends and advances, focusing on the correlations between electronic structure and magnetic properties. The book spans recent trends in magnetism for molecules -- as well as inorganic-based materials, with an emphasis on new phenomena being explored from both experimental and theoretical viewpoints with the aim of understanding magnetism on the atomic scale. The volume helps readers evaluate their own experimental observations and serves as a basis for the design of new magnetic materials. Topics covered include: * Metallocenium Salts of Radical Anion Bis-(dichalcogenate) metalates * Chiral Molecule-Based Magnets * Cooperative Magnetic Behavior in Metal-Dicyanamide Complexes * Lanthanide Ions in Molecular Exchange Coupled Systems * Monte Carlo Simulation * Metallocene-Based Magnets * Magnetic Nanoporous Molecular Materials A unique reference work, indispensable for everyone concerned with the phenomena of magnetism.

Functional Materials

Author : S. Banerjee,A.K. Tyagi
Publisher : Elsevier
Page : 732 pages
File Size : 45,6 Mb
Release : 2011-12-12
Category : Science
ISBN : 9780123851420

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Functional Materials by S. Banerjee,A.K. Tyagi Pdf

Functional materials have assumed a very prominent position in several high-tech areas. Such materials are not being classified on the basis of their origin, nature of bonding or processing techniques but are classified on the basis of the functions they can perform. This is a significant departure from the earlier schemes in which materials were described as metals, alloys, ceramics, polymers, glass materials etc. Several new processing techniques have also evolved in the recent past. Because of the diversity of materials and their functions it has become extremely difficult to obtain information from single source. Functional Materials: Preparation, Processing and Applications provides a comprehensive review of the latest developments. Serves as a ready reference for Chemistry, Physics and Materials Science researchers by covering a wide range of functional materials in one book Aids in the design of new materials by emphasizing structure or microstructure - property correlation Covers the processing of functional materials in detail, which helps in conceptualizing the applications of them

Fragments of Fullerenes and Carbon Nanotubes

Author : Marina A. Petrukhina,Lawrence T. Scott
Publisher : John Wiley & Sons
Page : 432 pages
File Size : 50,7 Mb
Release : 2011-11-01
Category : Science
ISBN : 1118011252

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Fragments of Fullerenes and Carbon Nanotubes by Marina A. Petrukhina,Lawrence T. Scott Pdf

This book is the first of its kind to reflect upon the intense and rapidly growing interest in open geodesic polyaromatic molecules, specifically focusing on their synthesis and reactivity in metal binding reactions. The book broadly covers all aspects related to the fullerene fragment chemistry: current synthetic techniques, description of the available members of this new family (which has grown to more than two dozens members, with none being available commercially), molecular geometry and trends in the solid state packing, as well as extensions into physical properties and new buckybowl-based molecules and materials. It covers fundamental research related to a new class of hydrocarbons, namely open geodesic polyarenes that map onto the surfaces of fullerenes (and referred to as fullerene fragments or buckybowls.

Stable Radicals

Author : Robin Hicks
Publisher : John Wiley & Sons
Page : 628 pages
File Size : 43,9 Mb
Release : 2011-08-02
Category : Science
ISBN : 9781119956969

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Stable Radicals by Robin Hicks Pdf

Stable radicals - molecules with odd electrons which are sufficiently long lived to be studied or isolated using conventional techniques - have enjoyed a long history and are of current interest for a broad array of fundamental and applied reasons, for example to study and drive novel chemical reactions, in the development of rechargeable batteries or the study of free radical reactions in the body. In Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds a team of international experts provide a broad-based overview of stable radicals, from the fundamental aspects of specific classes of stable neutral radicals to their wide range of applications including synthesis, materials science and chemical biology. Topics covered include: triphenylmethyl and related radicals polychlorinated triphenylmethyl radicals: towards multifunctional molecular materials phenalenyls, cyclopentadienyls, and other carbon-centered radicals the nitrogen oxides: persistent radicals and van der Waals complex dimers nitroxide radicals: properties, synthesis and applications the only stable organic sigma radicals: di-tert-alkyliminoxyls. delocalized radicals containing the hydrazyl [R2N-NR] unit metal-coordinated phenoxyl radicals stable radicals containing the thiazyl unit: synthesis, chemical, and materials properties stable radicals of the heavy p-block elements application of stable radicals as mediators in living-radical polymerization nitroxide-catalyzed alcohol oxidations in organic synthesis metal-nitroxide complexes: synthesis and magneto-structural correlations rechargeable batteries using robust but redox-active organic radicals spin labeling: a modern perspective functional in vivo EPR spectroscopy and imaging using nitroxides and trityl radicals biologically relevant chemistry of nitroxides Stable Free Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds is an essential guide to this fascinating area of chemistry for researchers and students working in organic and physical chemistry and materials science.

A Themed Issue of Functional Molecule-based Magnets

Author : Keiichi Katoh
Publisher : MDPI
Page : 134 pages
File Size : 40,6 Mb
Release : 2020-05-29
Category : Science
ISBN : 9783039289011

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A Themed Issue of Functional Molecule-based Magnets by Keiichi Katoh Pdf

Research on molecule-based magnetic materials was systematized in the 1980s and expanded rapidly. A Special Issue focusing on molecule-based magnetic substances was published in Magnetochemistry. However, the functionalities of the substances increase daily; therefore, the researchers’ quest is not yet in decline. Research on molecule-based magnetism developed across many fields, including chemistry, physics, material chemistry, and applied physics, and the use of the various functionalities of these molecule-based magnetic substances has greatly influenced research on spin-based devices. In honor of Professor Masahiro Yamashita, who contributed greatly to this field, I have put together a Special Issue that highlights ten groundbreaking articles. The issue is entitled, “A Themed Issue of Functional Molecule-Based Magnets: Dedicated to Professor Masahiro Yamashita on the Occasion of his 65th Birthday”. I wish to thank the authors for their dedicated work, and the referees and editorial staff for the time they invested commenting on the articles.

Handbook of Magnetic Materials

Author : Ekkes Brück
Publisher : Elsevier
Page : 528 pages
File Size : 43,6 Mb
Release : 2017-11-13
Category : Science
ISBN : 9780444639288

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Handbook of Magnetic Materials by Ekkes Brück Pdf

Handbook of Magnetic Materials, Volume 26, covers the expansion of magnetism over the last few decades and its applications in research, notably the magnetism of several classes of novel materials that share the presence of magnetic moments with truly ferromagnetic materials. The book is an ideal reference for scientists active in magnetism research, providing readers with novel trends and achievements in magnetism. Each article contains an extensive description given in graphical, as well as, tabular form, with much emphasis placed on the discussion of the experimental material within the framework of physics, chemistry and material science. Comprises topical review articles written by leading authorities Includes a variety of self-contained introductions to a given area in the field of magnetism without requiring recourse to the published literature Introduces given topics in the field of magnetism Describes novel trends and achievements in magnetism

Current Developments in Solid State NMR Spectroscopy

Author : Norbert Müller,Perunthiruthy K. Madhu
Publisher : Springer Science & Business Media
Page : 143 pages
File Size : 45,7 Mb
Release : 2013-04-17
Category : Science
ISBN : 9783709137154

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Current Developments in Solid State NMR Spectroscopy by Norbert Müller,Perunthiruthy K. Madhu Pdf

Why to apply solid-state NMR? - By now, we should have learned that NMR is mainly used for the study of molecules in solution, while x-ray diffraction is the method of choice for solids. Based on this fact, the two recent 'NMR-Nobelprizes' went indeed into the liquid phase: my own one eleven years ago, and particularly the most recent one to Kurt Wuthrich. His prize is beyond any doubts very well justified. His contribution towards the study of biomolecules in solution, in their native (or almost native) environment is truly monumental. We all will profit from it indirectly when one of our future diseases will be cured with better drugs, based on the insightful knowledge gained through liquid-state NMR. Two fields of NMR are still left out of the Nobel Prize game: magnetic reso nance imaging (MRI) and solid-state NMR. The disrespect for MRI in Stockholm is particularly difficult to understand; but this is not a subject to be discussed at the present place. Solid-state NMR is the third of the three great fields of NMR, powerful already today and very promising for the near future.

Macromolecules Containing Metal and Metal-Like Elements, Volume 9

Author : Alaa S. Abd-El-Aziz,Charles E. Carraher, Jr.,Charles U. Pittman, Jr.,Martel Zeldin
Publisher : John Wiley & Sons
Page : 565 pages
File Size : 50,9 Mb
Release : 2009-11-02
Category : Technology & Engineering
ISBN : 9780470251447

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Macromolecules Containing Metal and Metal-Like Elements, Volume 9 by Alaa S. Abd-El-Aziz,Charles E. Carraher, Jr.,Charles U. Pittman, Jr.,Martel Zeldin Pdf

Volume 9 in a scientific research series, covering macromolecules This book, Macromolecules Containing Metal and Metal-like Elements, presents research developments in the study of: supramolecular chemistry, supramolecular architecture and supramolecular self-assemblies. The topics addressed involve materials containing metals and metal-like elements as well as the possible applications of hybrid materials. The volume offers a broad series of coverage with conclusions and perspectives for the various areas covered.

Synthesis and Applications of New Spin Crossover Compounds

Author : Takafumi Kitazawa
Publisher : MDPI
Page : 254 pages
File Size : 51,9 Mb
Release : 2019-10-11
Category : Science
ISBN : 9783039213610

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Synthesis and Applications of New Spin Crossover Compounds by Takafumi Kitazawa Pdf

The crystal chemistry of spin crossover (SCO) behavior in coordination compounds can potentially be in association with smart materials—promising materials for applications as components of memory devices, displays, sensors and mechanical devices and, especially, actuators, such as artificial muscles. This Special Issue is devoted to various aspects of SCO and related research, comprising 18 interesting original papers on valuable and important SCO topics. Significant and fundamental scientific attention has been focused on the SCO phenomena in a wide research range of fields of fundamental chemical and physical and related sciences, containing the interdisciplinary regions of chemical and physical sciences related to the SCO phenomena. Coordination materials with bistable systems between the LS and the HS states are usually triggered by external stimuli, such as temperature, light, pressure, guest molecule inclusion, soft X-ray, and nuclear decay. Since the first Hofmann-like spin crossover (SCO) behavior in {Fe(py)2[Ni(CN)4]}n (py = pyridine) was demonstrated, this crystal chemistry motif has been frequently used to design Fe(II) SCO materials to enable determination of the correlations between structural features and magnetic properties.

Molecular Cluster Magnets

Author : Richard Winpenny
Publisher : World Scientific
Page : 312 pages
File Size : 49,8 Mb
Release : 2012
Category : Science
ISBN : 9789814322942

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Molecular Cluster Magnets by Richard Winpenny Pdf

This work covers new developments in the field of molecular nanomagnetism, complementing previous books in this area (for example the volume by Gatteschi, Sessoli and Villain on Single Molecule Magnets). The book is written by experts in the field and is intended as a compilation of critical reviews of new areas rather than a comprehensive text.