Non Equilibrium Phenomena Near Vapor Liquid Interfaces

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Non-Equilibrium Phenomena near Vapor-Liquid Interfaces

Author : Alexei Kryukov,Vladimir Levashov,Puzina Yulia
Publisher : Springer
Page : 54 pages
File Size : 48,7 Mb
Release : 2013-05-04
Category : Science
ISBN : 3319000845

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Non-Equilibrium Phenomena near Vapor-Liquid Interfaces by Alexei Kryukov,Vladimir Levashov,Puzina Yulia Pdf

This book presents information on the development of a non-equilibrium approach to the study of heat and mass transfer problems using vapor-liquid interfaces, and demonstrates its application to a broad range of problems. In the process, the following peculiarities become apparent: 1. At vapor condensation on the interface from gas-vapor mixture, non-condensable components can lock up the interface surface and condensation stops completely. 2. At the evolution of vapor film on the heater in superfluid helium (He-II), the boiling mass flux density from the vapor-liquid interface is effectively zero at the macroscopic scale. 3. In problems concerning the motion of He-II bridges inside capillaries filled by vapor, in the presence of axial heat flux the He-II bridge cannot move from the heater as would a traditional liquid, but in the opposite direction instead. Thus the heater attracts the superfluid helium bridge. 4. The shape of liquid-vapor interface at film boiling on the axis-symmetric heaters immersed in liquid greatly depends on heat flux in the interface. Thus a new type of hydrostatic problems appears when in contrast to traditional statements the shape of the liquid-vapor interface has a complex profile with a point of inflection and a smooth exit on a free liquid surface.

Non-Equilibrium Phenomena near Vapor-Liquid Interfaces

Author : Alexei Kryukov,Vladimir Levashov,Puzina Yulia
Publisher : Springer Science & Business Media
Page : 54 pages
File Size : 53,9 Mb
Release : 2013-03-28
Category : Science
ISBN : 9783319000831

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Non-Equilibrium Phenomena near Vapor-Liquid Interfaces by Alexei Kryukov,Vladimir Levashov,Puzina Yulia Pdf

This book presents information on the development of a non-equilibrium approach to the study of heat and mass transfer problems using vapor-liquid interfaces, and demonstrates its application to a broad range of problems. In the process, the following peculiarities become apparent: 1. At vapor condensation on the interface from gas-vapor mixture, non-condensable components can lock up the interface surface and condensation stops completely. 2. At the evolution of vapor film on the heater in superfluid helium (He-II), the boiling mass flux density from the vapor-liquid interface is effectively zero at the macroscopic scale. 3. In problems concerning the motion of He-II bridges inside capillaries filled by vapor, in the presence of axial heat flux the He-II bridge cannot move from the heater as would a traditional liquid, but in the opposite direction instead. Thus the heater attracts the superfluid helium bridge. 4. The shape of liquid-vapor interface at film boiling on the axis-symmetric heaters immersed in liquid greatly depends on heat flux in the interface. Thus a new type of hydrostatic problems appears when in contrast to traditional statements the shape of the liquid-vapor interface has a complex profile with a point of inflection and a smooth exit on a free liquid surface.

Kinetics of Evaporation

Author : Denis N. Gerasimov,Eugeny I. Yurin
Publisher : Springer
Page : 321 pages
File Size : 43,5 Mb
Release : 2018-09-03
Category : Science
ISBN : 9783319963044

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Kinetics of Evaporation by Denis N. Gerasimov,Eugeny I. Yurin Pdf

This monograph discusses the essential principles of the evaporationprocess by looking at it at the molecular and atomic level. In the first part methods of statistical physics, physical kinetics andnumerical modeling are outlined including the Maxwell’s distributionfunction, the Boltzmann kinetic equation, the Vlasov approach, and theCUDA technique. The distribution functions of evaporating particles are then defined.Experimental results on the evaporation coefficient and the temperaturejump on the evaporation surface are critically reviewed and compared tothe theory and numerical results presented in previous chapters. The book ends with a chapter devoted to evaporation in differentprocesses, such as boiling and cavitation.This monograph addressesgraduate students and researchers working on phase transitions andrelated fields.

Dynamic Surface Phenomena

Author : Paul Joos
Publisher : Unknown
Page : 0 pages
File Size : 53,9 Mb
Release : 2023
Category : SCIENCE
ISBN : 0429070926

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Dynamic Surface Phenomena by Paul Joos Pdf

This monograph provides a comprehensive introduction into the fast developing research field of dynamic processes at liquid/gas and liquid/liquid interfaces to postgraduate students, scientists and engineers interested in the fundamentals of non-equilibrium interfacial properties. It also addresses to some extent application fields, such as foams and emulsions. Theory and experiments on dynamic adsorption layers are considered systematically and discussed with respect to processes at interfaces.It is both an introduction for beginners in the present field as well as a systematic preparation of a vast range of the current scientific investigations generalised, together with accumulated knowledge for those already being an insider. It is the first extensive review available on the subject of dynamics of adsorption and gives a general summary of the current state of adsorption kinetics theory and experiments. The book also reviews recent progress in new-designed set-ups and improved and generalised known methods for studying interfacial relaxations.

Interfacial Phenomena

Author : J.T. Davies
Publisher : Academic Press
Page : 488 pages
File Size : 46,9 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323148344

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Interfacial Phenomena by J.T. Davies Pdf

Interfacial Phenomena examines the fundamental properties of various liquid interfaces. This book discusses the physics of surfaces; electrostatic and electrokinetic phenomena; and adsorption at liquid interfaces. The properties of monolayers; reactions at liquid surfaces; diffusion through interfaces; and disperse systems and adhesion are also deliberated. Other topics include the vapor pressures over curved surfaces; electrical capacity of the double layer; applications of electrophoresis; and thermodynamics of adsorption and desorption. The experimental methods of spreading films at the oil-water interface; penetration into monolayers; experiments on dynamic systems; and spontaneous emulsification are likewise covered in this text. This book is beneficial to chemical engineers and students concerned with interfacial phenomena.

Liquid-Vapor Phase-Change Phenomena

Author : Van P. Carey
Publisher : CRC Press
Page : 592 pages
File Size : 54,6 Mb
Release : 2018-08-15
Category : Technology & Engineering
ISBN : 9781498716673

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Liquid-Vapor Phase-Change Phenomena by Van P. Carey Pdf

Since the second edition of Liquid Vapor Phase Change Phenomena was written, research has substantially enhanced the understanding of the effects of nanostructured surfaces, effects of microchannel and nanonchannel geometries and the effects of extreme wetting on liquid-vapor phase change processes. This edition includes significant new coverage of microchannels and nanostructures along with many other updates. More worked examples and numerous new problems have been added along with a complete solutions manual and electronic figures for classroom projection.

Interfacial Phenomena

Author : Clarence A. Miller,P. Neogi
Publisher : CRC Press
Page : 520 pages
File Size : 43,8 Mb
Release : 2007-10-08
Category : Science
ISBN : 1420044435

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Interfacial Phenomena by Clarence A. Miller,P. Neogi Pdf

Since the publication of the first edition of Interfacial Phenomena, the interest in interfaces and surfactants has multiplied, along with their applications. Experimental and theoretical advances have provided scientists with greater insight into the structure, properties, and behavior of surfactant and colloid systems. Emphasizing equilibrium phenomena, flow, transport, and stability, Interfacial Phenomena: Equilibrium and Dynamic Effects, Second Edition presents a concise and current summary of the fundamental principles governing interfacial interactions. This new edition features updated and expanded topics in every chapter. It highlights key experimental techniques that have expanded the scope of our understanding, such as in mass transfer, microstructure determination in colloidal dispersions, and surfactant–polymer interactions. Interfacial Phenomena, Second Edition reflects the progress scientists have made in understanding the surface chemistry and interfacial dynamics of colloid and surfactant systems. The book also illustrates the growing applicability of these systems in a variety of fields including pharmaceuticals, cosmetics, detergents, paints, agricultural chemicals, and foods.

Vapor-Liquid Interfaces, Bubbles and Droplets

Author : Shigeo Fujikawa,Takeru Yano,Masao Watanabe
Publisher : Springer Science & Business Media
Page : 230 pages
File Size : 45,8 Mb
Release : 2011-04-18
Category : Technology & Engineering
ISBN : 9783642180385

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Vapor-Liquid Interfaces, Bubbles and Droplets by Shigeo Fujikawa,Takeru Yano,Masao Watanabe Pdf

Physically correct boundary conditions on vapor-liquid interfaces are essential in order to make an analysis of flows of a liquid including bubbles or of a gas including droplets. Suitable boundary conditions do not exist at the present time. This book is concerned with the kinetic boundary condition for both the plane and curved vapor-liquid interfaces, and the fluid dynamics boundary condition for Navier-Stokes(fluid dynamics) equations. The kinetic boundary condition is formulated on the basis of molecular dynamics simulations and the fluid dynamics boundary condition is derived by a perturbation analysis of Gaussian-BGK Boltzmann equation applicable to polyatomic gases. The fluid dynamics boundary condition is applied to actual flow problems of bubbles in a liquid and droplets in a gas.

Advanced Transport Phenomena

Author : P. A. Ramachandran
Publisher : Cambridge University Press
Page : 805 pages
File Size : 54,8 Mb
Release : 2014-09-25
Category : Science
ISBN : 9780521762618

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Advanced Transport Phenomena by P. A. Ramachandran Pdf

Integrated, modern approach to transport phenomena for graduate students, featuring examples and computational solutions to develop practical problem-solving skills.

Competence in High Performance Computing 2010

Author : Christian Bischof,Heinz-Gerd Hegering,Wolfgang E. Nagel,Gabriel Wittum
Publisher : Springer Science & Business Media
Page : 234 pages
File Size : 51,6 Mb
Release : 2012-02-13
Category : Computers
ISBN : 9783642240256

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Competence in High Performance Computing 2010 by Christian Bischof,Heinz-Gerd Hegering,Wolfgang E. Nagel,Gabriel Wittum Pdf

This book presents the state-of-the-art in simulation on supercomputers. Leading researchers present results achieved on systems of the Gauss-Allianz, the association of High-Performance Computing centers in Germany. The reports cover all fields of computational science and engineering, ranging from CFD to Computational Physics and Biology to Computer Science, with a special emphasis on industrially relevant applications. Presenting results for large-scale parallel microprocessor-based systems and GPU and FPGA-supported systems, the book makes it possible to compare the performance levels and usability of various architectures. Its outstanding results in achieving the highest performance for production codes are of particular interest for both scientists and engineers. The book includes a wealth of color illustrations and tables.

Dynamics of Adsorption at Liquid Interfaces

Author : S.S. Dukhin,G. Kretzschmar,R. Miller
Publisher : Elsevier
Page : 600 pages
File Size : 46,8 Mb
Release : 1995-04-11
Category : Technology & Engineering
ISBN : 0080530613

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Dynamics of Adsorption at Liquid Interfaces by S.S. Dukhin,G. Kretzschmar,R. Miller Pdf

As the first of its kind, this book provides a valuable introduction for scientists and engineers interested in liquid/fluid interfaces and disperse systems to the rapidly developing area of adsorption dynamics. It is the first extensive review available on the subject of dynamics of adsorption and gives a general summary of the current state of adsorption kinetics theory and experiments. Current progress in recently designed set-ups and improved and generalised known methods for studying interfacial relaxations is reviewed. In addition, the role of the electric charge of surfactants in the adsorption process is discussed in terms of a non-equilibrium distribution of adsorbing ions in the diffuse layer. Present theories of the effect of dynamic adsorption layers on mobile surfaces, such as moving drops and bubbles, based on both diffusion and kinetic controlled adsorption models are described and efficient approximate analytical methods to solve the mathematical problem of coupling surfactant transport and hydrodynamics are introduced. The role of a dynamic adsorption layer in bubble rising, film drainage and film stabilisation and in complex processes such as flotation and microflotation is discussed. Containing more than 1100 references, the book is essential reading for industrial scientists and graduate and post-graduate students in physical, surface and colloid chemistry, physico-chemical hydrodynamics, water purification and mineral processing.

Multicomponent Interfacial Transport

Author : Kirill Glavatskiy
Publisher : Springer Science & Business Media
Page : 174 pages
File Size : 50,8 Mb
Release : 2011-01-18
Category : Science
ISBN : 9783642152665

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Multicomponent Interfacial Transport by Kirill Glavatskiy Pdf

A thermodynamically consistent description of the transport across interfaces in mixtures has for a long time been an open issue. This research clarifies that the interface between a liquid and a vapor in a mixture is in local equilibrium during evaporation and condensation. It implies that the thermodynamics developed for interfaces by Gibbs can be applied also away from equilibrium, which is typically the case in reality. A description of phase transitions is of great importance for the understanding of both natural and industrial processes. For example, it is relevant for the understanding of the increase of CO2 concentration in the atmosphere, or improvements of efficiency in distillation columns. This excellent work of luminescent scientific novelty has brought this area a significant step forward. The systematic documentation of the approach will facilitate further applications of the theoretical framework to important problems.

Liquid Interfacial Systems

Author : Rudolph V. Birikh,Vladimir A. Briskman,Manuel G. Velarde,Jean-Claude Legros
Publisher : CRC Press
Page : 389 pages
File Size : 49,7 Mb
Release : 2003-06-17
Category : Science
ISBN : 9780824755843

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Liquid Interfacial Systems by Rudolph V. Birikh,Vladimir A. Briskman,Manuel G. Velarde,Jean-Claude Legros Pdf

Despite factoring in countless natural, biological, and industrial processes, fixed attention on the singular attributes and behavior of fluids near or at interfaces has not received enough attention in the surface science literature. Liquid Interfacial Systems assembles and analyzes concepts and findings as an inclusive summation of fluid-fluid interfacial phenomena. This book covers excitation, stabilization, and suppression of instability at liquid interfaces. From the influential original research and scholarship of leaders in the discipline comes a volume to impart and explain definitions, scales, governing equations, and boundary conditions used in liquid interfacial system research.

Non-equilibrium Phenomena in Confined Soft Matter

Author : Simone Napolitano
Publisher : Springer
Page : 300 pages
File Size : 54,6 Mb
Release : 2015-08-28
Category : Science
ISBN : 9783319219486

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Non-equilibrium Phenomena in Confined Soft Matter by Simone Napolitano Pdf

This book deals with those properties of non-equilibrium soft matter that deviate greatly from the bulk properties as a result of nanoscale confinement.The ultimate physical origin of these confinement effects is not yet fully understood. At the state of the art, the discussion on confinement effects focuses on equilibrium properties, finite size effects and interfacial interactions. However this is a limited vision which does not fully capture the peculiar behaviour of soft matter under confinement and some exotic phenomena that are displayed. This volume will be organized in the following three main themes. Equilibration and physical aging: treating non-equilibrium via the formal methodology of statistical physics in bulk, we analyse physical origin of the non-equilibrium character of thin polymer. We then focus on the impact of nanoconfinement on the equilibration of glasses of soft matter (a process of tremendous technological interest, commonly known as physical aging), comparing the latest trends of polymers in experiments, simulations with those of low-molecular weight glass formers. Irreversible adsorption: the formation of stable adsorbed layers occurs at timescales much larger than the time necessary to equilibrate soft matter in bulk. Recent experimental evidence show a strong correlation between the behaviour of polymers under confinement and the presence of a layer irreversibly adsorbed onto the substrate. This correlation hints at the possibility to tailor the properties of ultrathin films by controlling the adsorption kinetics. The book reports physical aspects of irreversible chain adsorption, such as the dynamics, structure, morphology, and crystallization of adsorbed layers. Glass transition and material properties: this section of the book focuses on the spread of absolute values in materials properties of confined systems, when measured by different experimental and computation techniques and a new method to quantify the effects of confinement in thin films and nanocomposites independently on the investigation procedure will be presented.

Introduction to Non-equilibrium Physical Chemistry

Author : R. P. Rastogi
Publisher : Elsevier
Page : 356 pages
File Size : 46,5 Mb
Release : 2007-10-16
Category : Science
ISBN : 0080551807

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Introduction to Non-equilibrium Physical Chemistry by R. P. Rastogi Pdf

Introduction to Non-equilibrium Physical Chemistry presents a critical and comprehensive account of Non-equilibrium Physical Chemistry from theoretical and experimental angle. It covers a wide spectrum of non-equilibrium phenomena from steady state close to equilibrium to non-linear region involving transition to bistability, temporal oscillations, spatio-temporal oscillations and finally to far from equilibrium phenomena such as complex pattern formation, dynamic instability at interfaces, Chaos and complex growth phenomena (fractals) in Physico-chemical systems. Part I of the book deals with theory and experimental studies concerning transport phenomena in membranes (Thermo-osmosis,Electroosmotic ) and in continuous systems (Thermal diffusion,Soret effect) close to equilibrium Experimental tests provide insight into the domain of validity of Non-equilibrium Thermodynamics ,which is the major theoretical tool for this region. Later developments in Extended Irreversible Thermodynamics and Non-equilibrium Molecular dynamics have been discussed in the Appendix. Part II deals with non-linear steady states and bifurcation to multistability, temporal and spatio- temporal oscillations (Chemical waves). Similarly Part II deals with more complex phenomena such as Chaos and fractal growth occurring in very far from equilibrium region. Newer mathematical techniques for investigating such phenomena along with available experimental studies. Part IV deals with analogous non-equilibrium phenomena occurring in the real systems (Socio-political, Finance and Living systems etc.) for which physico-chemical systems discussed in earlier chapters provide a useful model for development of theories based on non-linear science and science of complexity. The book provides a critical account of theoretical studies on non-equilibrium phenomenon from region close to equilibrium to far equilibrium Experimental studies have been reported which provide test of the theories and their limitations Impacts of the concepts developed in non-equilibrium Physical Chemistry in sociology, economics and other social science and living systems has been discussed