Organoborane Chemistry

Author : Thomas Onak
Publisher : Elsevier
Page : 373 pages
File Size : 43,8 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323153614

Get Book

Organoborane Chemistry by Thomas Onak Pdf

Organoborane Chemistry deals with the chemistry of organoboranes, with emphasis on compounds containing a carbon-boron bond. The structure and physical properties of organoboranes are discussed, along with the reactions of three-coordinate and four-coordinate organoboranes, organodiboranes, and other organopolyboranes such as organotetraboranes and organopentaborane compounds. Comprised of seven chapters, this book begins with an overview of multistep synthetic or degradative reactions involving organoboron compounds, along with the nomenclature for such compounds. The next chapter examines the structure and physical properties of organoboranes, with emphasis on boron-carbon bond lengths, electronic transitions, and molecular orbital calculations. Subsequent chapters focus on three-coordinate and four-coordinate organoboranes, together with their synthesis, reactions, and properties; hydroboration and dehydroboration of organodiboranes; and the synthesis, reactions, and physical properties of other organopolyboranes such as organotetraboranes, organopentaborane compounds, and organodecaborane compounds. The final chapter is devoted to cyclic boron-carbon systems and the applications of organoboron compounds. This monograph should be of interest to organic chemists.

Author : Herbert C. Brown
Publisher : Cornell University Press
Page : 488 pages
File Size : 54,6 Mb
Release : 2019-06-30
Category : Science
ISBN : 9781501741432

Get Book

Boranes in Organic Chemistry by Herbert C. Brown Pdf

The leading researcher in the uses of boranes in organic synthesis here reviews his work over the past thirty-five years, covering such areas as steric strains, the nonclassical ion problem, selective reductions, hydroboration, and the organoboranes as synthetic intermediates. But more than an exposition of enormous accomplishment, the book is a scientific autobiography that will provide chemists with historical perspective on their profession. The author's detailed narrative of his own research experiences not only adds to the understanding of the present state of the study of boranes, but will serve as a stimulus to imaginative research in the future.

Author : Gordon M. L. Cragg
Publisher : Unknown
Page : 448 pages
File Size : 52,7 Mb
Release : 1973
Category : Science
ISBN : UOM:39015016063615

Get Book

Organoboranes in Organic Synthesis by Gordon M. L. Cragg Pdf

Author : Anonim
Publisher : John Wiley & Sons
Page : 4 pages
File Size : 48,9 Mb
Release : 2021-10-25
Category : Science
ISBN : 9781119518044

Get Book

The Chemistry of Organoboron Compounds, 2 Volume Set by Anonim Pdf

The ultimate resource in organoboron chemistry Professor Mark Gandelman and his colleagues delve deeply into the theory, structure, analysis, synthesis, and reactions of organoboron chemistry in The Chemistry of Organoboron Compounds. Organoborons are used heavily as highly efficient reagents in many reactions, including cross-coupling and radical reactions. The highly regarded authors have tied together organic-chemical and physico-chemical knowledge usually unavailable from a single source. The book focuses on the use of completely biodegradable "green" reagents, as opposed to environmentally hazardous heavy metal catalysts. The Chemistry of Organoboron Compounds delivers comprehensive and complete information on: The behavior of organoboron compounds The use of organoboron compounds in organic synthesis The commercial applications of organoboron compounds As a volume in the celebrated Patai book series, The Chemistry of Organoboron Compounds includes all the features that readers of that series are used to enjoying, including a comprehensive index at the back of the book.

Author : Elena Fernández,Andrew Whiting
Publisher : Springer
Page : 331 pages
File Size : 46,9 Mb
Release : 2015-03-04
Category : Science
ISBN : 9783319130545

Get Book

Synthesis and Application of Organoboron Compounds by Elena Fernández,Andrew Whiting Pdf

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Author : E. Fernández
Publisher : Thieme
Page : 582 pages
File Size : 43,9 Mb
Release : 2020-05-22
Category : Science
ISBN : 9783132429734

Get Book

Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis by E. Fernández Pdf

The widespread use of organoboron compounds justifies the efforts devoted to their synthesis, as well as toward developing an understanding of their reactivity. The nature of the mono- or diboron species is of paramount importance in determining the reversible covalent binding properties of the boron atom with both nucleophiles and electrophiles. By wedding the rich chemical potential of organoboron compounds to the ubiquity of organic scaffolds, advanced borylation reactions have the potential to open unprecedented synthetic alternatives, and new knowledge in the field should encourage chemists to use organoboron compounds. In this volume, the main objective is to provide a collection of the most useful, practical, and reliable methods, reported mainly within the last decade, for boron activation and boron reactivity. The volume covers the main concepts of organoboron compounds and includes experimental procedures, enabling newcomers to the field the instant and reliable application of the new tools in synthesis. Rather than aiming for a comprehensive coverage, the most advanced solutions for challenging transformations are introduced. To this end, a team of pioneers and leaders in the field have been assembled who discuss both the practical and conceptual aspects of this rapidly growing field.

Author : Donald S. Matteson
Publisher : Springer Science & Business Media
Page : 417 pages
File Size : 52,5 Mb
Release : 2012-12-06
Category : Science
ISBN : 9783642797095

Get Book

Stereodirected Synthesis with Organoboranes by Donald S. Matteson Pdf

This monograph has been written to demonstrate to organic chemists and graduate students the strategies for controlling stereochemistry in carbon-carbon bond formations with borane intermediates. The boranes were initially found to be useful reagents by Nobel Laureate H.C. Brown. Their precursors are commercially available and derivatization is fast, clean and simple.

Author : E W Abel,F G A Stone
Publisher : Royal Society of Chemistry
Page : 510 pages
File Size : 43,5 Mb
Release : 2007-10-31
Category : Science
ISBN : 9781847554024

Get Book

Organometallic Chemistry by E W Abel,F G A Stone Pdf

Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Author : Anonim
Publisher : Georg Thieme Verlag
Page : 971 pages
File Size : 55,5 Mb
Release : 2014-05-14
Category : Science
ISBN : 9783131806741

Get Book

Houben-Weyl Methods of Organic Chemistry Vol. XIII/3a, 4th Edition by Anonim Pdf

Houben-Weyl is the acclaimed reference series for preparative methods in organic chemistry, in which all methods are organized accor ding to the class of compound or functional group to be synthesized. The Houben-Weyl volumes contain 146 000 product-specific experi mental procedures, 580 000 structures, and 700 000 references. The preparative significance of the methods for all classes of compou nds is critically evaluated. The series includes data from as far back as the early 1800s to 2003. // The content of this e-book was originally published in 1982.

Author : Matthew G Davidson,Ken Wade,T B Marder,Andrew K Hughes
Publisher : Royal Society of Chemistry
Page : 555 pages
File Size : 44,6 Mb
Release : 2007-10-31
Category : Science
ISBN : 9781847550644

Get Book

Contemporary Boron Chemistry by Matthew G Davidson,Ken Wade,T B Marder,Andrew K Hughes Pdf

The continued and evolving significance of boron chemistry to the wider chemical community is demonstrated by the international and interdisciplinary nature of the research reported in this book. Contemporary Boron Chemistry encompasses inorganic and organic compounds as well as polymers, solid-state materials, medicinal aspects and theoretical studies. Covering many areas of chemistry with boron at its centre, topics include applications to polyolefin catalysis, medicine, materials and polymers; boron cluster chemistry, including carboranes and metal-containing clusters; organic and inorganic chemistry of species containing only 1 or 2 boron atoms; and theoretical studies of boron-containing compounds. New materials with novel optical and electronic properties are also discussed. Comprehensive and up to date, graduates and researchers in a wide range of fields, particularly those in organometallic and organic chemistry and materials science, will welcome this book.

Author : Dennis G. Hall,Hugo Lachance
Publisher : John Wiley & Sons
Page : 6 pages
File Size : 54,6 Mb
Release : 2012-05-29
Category : Science
ISBN : 9781118344453

Get Book

Organic Reactions, Volume 73 by Dennis G. Hall,Hugo Lachance Pdf

Allylic boron compounds have gained a prominent position as a truly practical class of synthetic reagents in the past twenty-five years. Their main application as a method for the stereoselective synthesis of homoallylic alcohols by allyl-transfer to carbonyl compounds is essentially unmatched. In this process, a new carbon-carbon bond is formed, and up to two new stereogenic centers are created in a predictably controlled manner. Highly effective and general enantioselective variants are available, with countless applications in the total syntheses of polyacetate and polypropionate natural products. Furthermore, the residual allylic unit can be manipulated through a number of different transformations such as oxidative cleavage, olefin metathesis, hydrometalations, and many others. The discovery of Lewis and Brønsted acid catalyzed manifolds recently, has opened new doors for further development of this important reaction. This book provides an up-to-date, comprehensive survey of the literature of this rich chemistry as it pertains to organic synthesis. Consistent with the goal of Organic Reactions, the content and presentation emphasize the preparative aspects of the reactions, giving considerable attention to the scope and limitations of the individual transformations along with detailed experimental procedures. A tabular survey of all examples of carbonyl allylboration used in organic synthesis is presented in nine tables organized by type of allylic boron reagent with listings within each table according to increasing carbon number of the carbonyl substrates. The literature is covered through December 2010, including a new listing of nearly 200 literature citations that supplement the original coverage of 834 references used in the earlier hard cover version of the chapter. Allylboration of Carbonyl Compounds is intended to be a useful, easily read reference book for all practitioners of synthetic organic chemistry working in academic and industrial laboratories.

Author : Atta-ur-Rahman
Publisher : Elsevier
Page : 1022 pages
File Size : 51,8 Mb
Release : 2008-06-23
Category : Science
ISBN : 0080569838

Get Book

Studies in Natural Products Chemistry by Atta-ur-Rahman Pdf

This volume presents frontier reviews on recent developments on bioactive natural products in cutting-edge areas by eminent experts in their respective fields. Fourteen reviews treat diverse and different topics in natural products chemistry - basic ones, medicinally oriented ones, agro-oriented ones and ecologically oriented ones. It is an important addition to this important series on Natural Products Chemistry, generally acknowledged to be the leading series on this topic.

Author : Anonim
Publisher : Georg Thieme Verlag
Page : 952 pages
File Size : 46,8 Mb
Release : 2014-05-14
Category : Science
ISBN : 9783131806840

Get Book

Houben-Weyl Methods of Organic Chemistry Vol. XIII/3b, 4th Edition by Anonim Pdf

Houben-Weyl is the acclaimed reference series for preparative methods in organic chemistry, in which all methods are organized accor ding to the class of compound or functional group to be synthesized. The Houben-Weyl volumes contain 146 000 product-specific experi mental procedures, 580 000 structures, and 700 000 references. The preparative significance of the methods for all classes of compou nds is critically evaluated. The series includes data from as far back as the early 1800s to 2003. // The content of this e-book was originally published in 1983.

Author : Todd B. Marder,Zhenyang Lin
Publisher : Springer Science & Business Media
Page : 227 pages
File Size : 53,6 Mb
Release : 2008-07-11
Category : Science
ISBN : 9783540786337

Get Book

Contemporary Metal Boron Chemistry I by Todd B. Marder,Zhenyang Lin Pdf

With information that will remain valid for years, this series presents critical reviews of the present position and future trends in modern research into chemical structure and bonding. It features concise reports, each written by world-renowned experts.

Author : Howard Steinberg,Robert J.. Brotherton
Publisher : Unknown
Page : 568 pages
File Size : 55,9 Mb
Release : 1964
Category : Chemistry, Organic
ISBN : OCLC:86742166

Get Book

Organoboron Chemistry by Howard Steinberg,Robert J.. Brotherton Pdf