Physical Chemistry Of Organic Solvent Systems

Author : A. Covington
Publisher : Springer Science & Business Media
Page : 821 pages
File Size : 46,9 Mb
Release : 2012-12-06
Category : Science
ISBN : 9781468419597

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Physical Chemistry of Organic Solvent Systems by A. Covington Pdf

We believe this to be the first monograph devoted to the physicochemical properties of solutions in organic solvent systems. Although there have 1 been a number of books on the subject of non-aqueous solvents - 4, they have been devoted, almost entirely, to inorganic solvents such as liquid ammonia, liquid sulphur dioxide, etc. A variety of new solvents such as dimethylformamide, dimethylsulphoxide and propylene carbonate have become commercially available over the last twenty years. Solutions in these solvents are of technological interest in connection with novel battery systems and chemical synthesis, while studies of ion solvation and transport properties have fostered academic interest. This monograph is primarily concerned with electrolytic solutions although discussion of non-electrolyte solutions has not been excluded. We have deliberately omitted consideration of the important area of solvent extraction, since this has been adequately covered elsewhere. Our contributors were asked to review and discuss their respective areas with particular reference to differences in technique necessitated by use of non-aqueous solvents while not reiterating facts well-known from experience with aqueous solutions. We have striven to build their contributions into a coherent and consistent whole. We thank our con tributors for following our suggestions so ably and for their forebearance in the face of our editorial impositions.

Author : Xiao-Feng Wu,Zhiping Yin,Liang-nian He,Feng Wang
Publisher : John Wiley & Sons
Page : 469 pages
File Size : 48,7 Mb
Release : 2024-03-07
Category : Science
ISBN : 9783527841936

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Green Solvents in Organic Synthesis by Xiao-Feng Wu,Zhiping Yin,Liang-nian He,Feng Wang Pdf

Green Solvents in Organic Synthesis Essential reference on replacing conventional solvents with greener alternatives in industrial chemicals synthesis and production A well-timed book promoting sustainability in synthesis and production of chemicals, Green Solvents in Organic Synthesis details various green solvents, solvent systems, and solubilization techniques, including their chemistry, physiochemical properties, performance, and distinct applications, presenting a greener approach to conventional solvents by replacing them with sustainable alternatives that have similarities in their reaction mechanisms. Edited by four highly qualified academics with significant research experience in the field, Green Solvents in Organic Synthesis includes information on: Water and liquid polymers (Polyethylene glycol PEG), Acetonitrile, DMSO, Dimethyl carbonate, Ionic liquids, and Supercritical fluids) Bio-based solvents (Cyrene, γ-Valerolactone (GVL), Lactic acid, 2-MeTHF) and deep eutectic solvents (DESs) Alcohols (MeOH, EtOH, i-PrOH, n-BuOH, t-BuOH, Ethylene glycol), ketones (Acetones, MEK, MIBK, Cyclohexanone), and esters (Methyl acetate, Ethyl acetate, i-PrOAc, n-BuOAc) Technical, economic, and environmental aspects of green solvents and how to maximize their reuse and recycling to alleviate pollution and reduce energy consumption For chemists in a variety of disciplines, Green Solvents in Organic Synthesis is an essential reference that provides foundational knowledge of green solvents, along with key features of each class of green solvent within the context of organic reactions for industrial and laboratory synthesis.

Author : Christian Reichardt,Thomas Welton
Publisher : John Wiley & Sons
Page : 722 pages
File Size : 49,5 Mb
Release : 2011-08-04
Category : Science
ISBN : 9783527642137

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Solvents and Solvent Effects in Organic Chemistry by Christian Reichardt,Thomas Welton Pdf

Now in its 4th edition, this book remains the ultimate reference for all questions regarding solvents and solvent effects in organic chemistry. Retaining its proven concept, there is no other book which covers the subject in so much depth, the handbook is completely updated and contains 15% more content, including new chapters on "Solvents and Green chemistry", "Classification of Solvents by their Environmental Impact", and "Ionic Liquids". An essential part of every organic chemist's library.

Author : Anonim
Publisher : Academic Press
Page : 322 pages
File Size : 50,8 Mb
Release : 1991-11-22
Category : Science
ISBN : 9780080581668

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Advances in Physical Organic Chemistry by Anonim Pdf

This series, established by Victor Gold in 1963, presents substantial and authoritative reviews of areas of chemistry in which quantitative methods are used in the study of the structures of organic compounds and their relation to physical and chemical properties. Organometallic compounds are included, and relevant aspects of physical, theoretical, inorganic, and biological chemistry are incorporated in reviews where appropriate.

Author : Ali Mohammad,Inamuddin Dr.
Publisher : Springer Science & Business Media
Page : 440 pages
File Size : 50,5 Mb
Release : 2012-03-16
Category : Science
ISBN : 9789400717114

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Green Solvents I by Ali Mohammad,Inamuddin Dr. Pdf

The conventional solvents used in chemical, pharmaceutical, biomedical and separation processes represent a great challenge to green chemistry because of their toxicity and flammability. Since the beginning of “the 12 Principles of Green Chemistry” in 1998, a general effort has been made to replace conventional solvents with environmentally benign substitutes. Water has been the most popular choice so far, followed by ionic liquids, surfactant, supercritical fluids, fluorous solvents, liquid polymers, bio-solvents and switchable solvent systems. Green Solvents Volume I and II provides a throughout overview of the different types of solvents and discusses their extensive applications in fields such as extraction, organic synthesis, biocatalytic processes, production of fine chemicals, removal of hydrogen sulphide, biochemical transformations, composite material, energy storage devices and polymers. These volumes are written by leading international experts and cover all possible aspects of green solvents’ properties and applications available in today’s literature. Green Solvents Volume I and II is an invaluable guide to scientists, R&D industrial specialists, researchers, upper-level undergraduates and graduate students, Ph.D. scholars, college and university professors working in the field of chemistry and biochemistry.

Author : United States. Environmental Protection Agency. Library Systems Branch
Publisher : Unknown
Page : 490 pages
File Size : 52,8 Mb
Release : 1975
Category : Environmental protection
ISBN : MINN:30000010543365

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U.S. Environmental Protection Agency Library System Book Catalog by United States. Environmental Protection Agency. Library Systems Branch Pdf

Author : Paul Knochel
Publisher : Springer
Page : 210 pages
File Size : 44,5 Mb
Release : 2003-07-01
Category : Science
ISBN : 9783540486640

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Modern Solvents in Organic Synthesis by Paul Knochel Pdf

In recent years the choice of a given solvent for performing a reaction has become increasingly important. More and more, selective reagents are used for chemical transformations and the choice of the solvent may be determining for reaching high reaction rates and high selectivities. The toxicity and recycling considerations have also greatly influenced the nature of the solvents used for industrial reactions. Thus, the development of reactions in water is not only important on the laboratory scale but also for industrial applications. The p- formance of metal-catalyzed reactions in water for example has led to several new hydrogenation or hydroformylation procedures with important industrial applications. The various aspects of organic chemistry in water will be prese- ed in this book. Recently, novel reaction media such as perfluorinated solvents or supercritical carbon dioxide has proven to have unique advantages leading to more practical and more efficient reactions. Especially with perfluorinated solvents, new biphasic catalyses and novel approaches to perform organic reactions have been developed. These aspects will be examined in detail in this volume. Finally, the performance of reactions in the absence of solvents will show practical alternatives for many reactions. More than ever before, the choice of the solvent or the solvent system is ess- tial for realizing many chemical transformations with the highest efficiency. This book tries to cover the more recent and important new solvents or solvent systems for both academic and industrial applications.

Author : J.J. Lagowski
Publisher : Elsevier
Page : 316 pages
File Size : 44,5 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323156318

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The Chemistry of Nonaqueous Solvents VA by J.J. Lagowski Pdf

The Chemistry of Nonaqueous Solvents, Volume V-A: Principles and Basic Solvents provides the theoretical aspects of nonaqueous solution chemistry independent of solvent and information on individual solvent systems. This volume contains chapters on solvation and complex formation in protic and aprotic solvents; solvent basicity; ion-selective electrodes in nonaqueous solvents; nonaqueous solvents in organic electroanalytical chemistry; and anhydrous hydrazine and water-hydrazine mixtures. Chemists, researchers, and students of chemistry and chemical engineering will find the book a good reference material.

Author : J.J. Lagowski
Publisher : Elsevier
Page : 422 pages
File Size : 43,9 Mb
Release : 2012-12-02
Category : Science
ISBN : 9780323151030

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The Chemistry of Nonaqueous Solvents III by J.J. Lagowski Pdf

The Chemistry of Nonaqueous Solvents, Volume III: Inert, Aprotic, and Acidic Solvents is a compilation of critical surveys of specific solvent systems. The compendium contains discussions on the solution chemistry of sulfur dioxide and acyl halides; the solvent properties of hydrogen sulfide and carboxylic acids; and the Bronsted acid-base behavior in inert organic solvents. Chemists, researchers, and students of chemistry and chemical engineering will find the book a good reference material.

Author : Kosuke Izutsu
Publisher : John Wiley & Sons
Page : 432 pages
File Size : 41,7 Mb
Release : 2009-09-22
Category : Science
ISBN : 3527629165

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Electrochemistry in Nonaqueous Solutions by Kosuke Izutsu Pdf

An excellent resource for all graduate students and researchers using electrochemical techniques. After introducing the reader to the fundamentals, the book focuses on the latest developments in the techniques and applications in this field. This second edition contains new material on environmentally-friendly solvents, such as room-temperature ionic liquids.

Author : Darian V. Bostrelli
Publisher : Nova Publishers
Page : 200 pages
File Size : 46,7 Mb
Release : 2008
Category : Science
ISBN : 1600219934

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Solution Chemistry Research Progress by Darian V. Bostrelli Pdf

Solution chemistry deals with liquid solutions in such fields as physical chemistry, chemical physics, molecular biology, statistical mechanics, biochemistry, and biophysics. This book includes experimental investigations of the dielectric, spectroscopic, thermodynamic, transport, or relaxation properties of both electrolytes and non-electrolytes in liquid solutions. The latest research in the world has been selected, gathered and presented here.

Author : Dave J. Adams,Paul J. Dyson,Stewart J. Tavener
Publisher : John Wiley & Sons
Page : 268 pages
File Size : 51,8 Mb
Release : 2005-09-01
Category : Science
ISBN : 9780470869659

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Chemistry In Alternative Reaction Media by Dave J. Adams,Paul J. Dyson,Stewart J. Tavener Pdf

At a time when environmental concerns are increasing, it's important that chemical processes are as environmentally friendly as possible. This book outlines various methods for producing inorganic and organic solvents without the use of traditional solvents that can have detrimental effects on the environment. This is the first book to give extensive and exclusive coverage to the topic Includes important environmental issues This book will appeal to anyone with an interest in organic synthesis; reaction chemistry; catalysis; and process development, and to undergraduate and graduate students of organic chemistry; catalysis; green chemistry; clean technology and environmental chemistry courses.

Author : Andrew J Hunt,Thomas M Attard
Publisher : Royal Society of Chemistry
Page : 678 pages
File Size : 43,7 Mb
Release : 2018-08-27
Category : Technology & Engineering
ISBN : 9781782628804

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Supercritical and Other High-pressure Solvent Systems by Andrew J Hunt,Thomas M Attard Pdf

Exploring the range and utility of high-pressure solvent systems across a variety of different chemical applications, this book brings together recent advances in supercritical technology and other pressurised-solvent systems. It provides an in-depth overview of the latest advances and developments and discusses the limitations and drawbacks that need to be addressed. Wherever possible, the greenness and economic viability of the different solvent systems is highlighted. This book is ideal for researchers and industrialists working in environmental science, green chemistry and biorefineries.

Author : Jack Cazes
Publisher : CRC Press
Page : 986 pages
File Size : 53,5 Mb
Release : 2005
Category : Science
ISBN : 0824727878

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Encyclopedia of Chromatography by Jack Cazes Pdf

A convenient source of information for workers in analytical chemistry, experimental biology, physics, and engineering, the Encyclopedia of Chromatography, Second Edition stands as a quick reference source and clear guide to specific chromatographic techniques and principles. The book offers a basic introduction to the science and technology of the method, as well as additional references on the theory and methodology for analysis of specific chemicals and applications in a range of industries. It contains over 400 cross-referenced articles with more than 80 entirely new articles, including many new discussions on emerging technologies, instrumentation, and applications in chromatography.

Author : George Wypych
Publisher : Elsevier
Page : 997 pages
File Size : 41,8 Mb
Release : 2024-02-07
Category : Technology & Engineering
ISBN : 9781774670415

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Handbook of Solvents, Volume 1 by George Wypych Pdf

This 4th edition of Handbook of Solvents, Volume 1, contains the most recent findings and trends in solvent applications. It is a comprehensive survey of the science of solvents and their properties, covering all aspects of solvent behavior that are relevant to their use in chemical and related industries including agricultural and technical processes, inorganic synthesis and materials chemistry, and more. Divided into two volumes, this first volume covers high-level information on the physical chemical properties of the most relevant solvent systems. Each chapter is focused on a specific aspect of solvent properties that determine its selection, such as the effect on properties of solutes and solutions, properties of different groups of solvents, and the summary of their applications’ effect on health and the environment (given in tabulated form). Also covered is swelling of solids in solvents, solvent diffusion and drying processes, nature of the interaction of solvent and solute in solutions, acid-base interactions, the effect of solvents on spectral and other electronic properties of solutions, the effect of solvents on the rheology of the solution, aggregation of solutes, permeability, molecular structure, crystallinity, configuration, conformation of dissolved high molecular weight compounds, and the effect of solvents on chemical reactions and reactivity of dissolved substances. With insight from specialists in a broad array of different areas and written with an interdisciplinary audience in mind, this thoroughly revised 4th edition provides readers with a complete overview of all the organic solvents available for industrial applications today. The book contains numerous references to key sources of more detailed information, and together with Handbook of Solvents Volume 2: Use, Health, and Environment; Databook of Green Solvents; and Databook of Solvents, represents the most comprehensive and up-to-date information ever published on solvents. Provides key insights that will help engineers and scientists select the best solvent for the job Includes practical information and ideas on how to improve existing processes involving solvents Presents the latest advances in solvent technology and their applications